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At least 559 records · Page 31

Design, scaling and cost evaluations of circulating fluidized-bed systems for biomass pyrolysis

To generate updated and transparent capital cost estimates for biomass fast pyrolysis equipment, refinery fluidized catalytic cracking design and sizing principles are examined and extended to pyrolysis of woody biomass. Capital costs for the sized equipment are estimated with process-industry software. A one-dimensional flow simulation with pyrolysis kinetics is leveraged to validate the fluidization conditions and thermal energy balance. After successful sizing and a system cost estimate of $\$$2.8 M (in 2016 US$\$$) at the biorefinery scale of 1000 metric tons per day (MTD), these methods were exercised for even smaller equipment at the distributed pyrolysis scale with modifications to the process design constraints, and not directly comparable with the 1000 MTD case, arriving at capital cost estimates of $\$$1.2 M for a 500 ton/day system and $\$$0.9 M for a 200 ton/day system. Here in this work, It is noted that this work only estimates purchased equipment costs at the ±50% accuracy level; there are significant other custom factors applicable to each installation based on location, maturity, scale, complexities during installation, engineering and licensing costs, etc. that need to be added on to these estimates to derive investment costs.

09 BIOMASS FUELS↗

Chemo-Enzymatic Synthesis of Long-Chain Oligosaccharides for Studying Xylan-Modifying Enzymes

Plant research is hampered in several aspects by a lack of pure oligosaccharide samples that closely represent structural features of cell wall glycans. An alternative to purely chemical synthesis to access these oligosaccharides is chemo-enzymatic synthesis using glycosynthases. These enzymes enable the ligation of oligosaccharide donors, when activated for example as α-glycosyl fluorides, with suitable acceptor oligosaccharides. Herein, the synthesis of xylan oligosaccharides up to dodecasaccharides is reported, with glycosynthase-mediated coupling reactions as key steps. The xylo-oligosaccharide donors were protected at the non-reducing end with a 4-O-tetrahydropyranyl (THP) group to prevent polymerization. Installation of an unnatural 3-O-methylether substituent at the reducing end xylose of the oligosaccharides ensured good water solubility. Biochemical assays demonstrated enzymatic activity for the xylan acetyltransferase XOAT1 from Arabidopsis thaliana, xylan arabinofuranosyl-transferase XAT3 enzymes from rice and switchgrass, and the xylan glucuronosyltransferase GUX3 from Arabidopsis thaliana. In case of the glucuronosyltransferase GUX3, MALDI-MS/MS analysis of the reaction product suggested that a single glucuronosyl substituent was installed primarily at the central xylose residues of the dodecasaccharide acceptor, demonstrating the value of long-chain acceptors for assaying biosynthetic glycosyltransferases.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Artificial ground reflector size and position effects on energy yield and economics of single‐axis‐tracked bifacial photovoltaics

Abstract Artificial ground reflectors improve bifacial energy yield by increasing both front and rear‐incident irradiance. Studies have demonstrated an increase in energy yield due to the addition of artificial reflectors; however, they have not addressed the effect of varying reflector dimensions and placement on system performance and the impact of these parameters on the reflectors' financial viability. We studied the effect of high albedo (70% reflective) artificial reflectors on single‐axis‐tracked bifacial photovoltaic systems through ray‐trace modeling and field measurements. In the field, we tested a range of reflector configurations by varying reflector size and placement and demonstrated that reflectors increased daily energy yield up to 6.2% relative to natural albedo for PERC modules. To confirm the accuracy of our model, we compared modeled and measured power and found a root mean square error (RMSE) of 5.4% on an hourly basis. We modeled a typical meteorological year in Golden, Colorado, to demonstrate the effects of artificial reflectors under a wide range of operating conditions. Seventy percent reflective material can increase total incident irradiance by 1.9%–8.6% and total energy yield by 0.9%–4.5% annually after clipping is considered with a DC–AC ratio of 1.2. Clipping has a significant effect on reflector impact and must be included when assessing reflector viability because it reduces reflector energy gain. We calculated a maximum viable cost for these improvements of up to $2.50–4.60/m 2 , including both material and installation, in Golden. We expanded our analysis to cover a latitude range of 32–48°N and demonstrated that higher‐latitude installations with lower energy yield and higher diffuse irradiance content can support higher reflector costs. In both modeling and field tests, and for all locations, the ideal placement of the reflectors was found to be directly underneath the module due to the optimized rear irradiance increase.

14 SOLAR ENERGY↗

Photovoltaic Deployment Scenarios toward Global Decarbonization: Role of Disruptive Technologies

To totally decarbonize global electrical systems using photovoltaics (PVs) in the 2050–2060 decade, the world would need to install 63.4 TW of PV. This article models and explores how a PV manufacturing ramp‐up trajectory toward this goal can be achieved while assuming that investors continue to make financially rational decisions avoiding stranded production assets and therefore protecting their return on investment. The model effectively exploits experience curve benefits in both the scaling of the manufacturing process and continued progress in product design technologies. The scale‐up challenge is amplified because trajectories that achieve this goal require an unprecedented ramp‐up of production capacity over just two decades, followed by relatively modest demand to maintain the installed base and support continued population growth. It is demonstrated that sustainable ramp‐up of manufacturing is indeed possible and shown that the deployment of the requisite manufacturing capacity can be accelerated and accomplished at lower total capital cost by the introduction of disruptive technologies that have lower capital intensity, embedded energy, or higher efficiency.

14 SOLAR ENERGY↗

Weather radar in Nepal: opportunities and challenges in a mountainous region

Extreme rainfall is one of the major causes of natural hazards in the central Himalayan region, including Nepal. The performance of strategies to manage hazards and related risks relies on the accuracy of quantitative hydrometeorological prediction. Rain gauges have traditionally been used to measure the rainfall amount. However, point measurements with limited gauge coverage cannot accurately represent spatial precipitation variability in complex topography. Weather radar have shown potential for useful information on accurate areal rainfall estimates. The Department of Hydrology and Meteorology (DHM) in Nepal installed their first weather radar in 2019 in the western region of the country. Two more radars will be added to the planned radar network in the near future, in the country's central and eastern regions, respectively. We highlight both the opportunities and challenges with radar installation and observation in the mountainous regions. Radar-rainfall estimates across the Himalayas can be useful to inform decision-making in a broad range of infrastructure sectors, including water, energy, construction, transportation, and agriculture.

54 ENVIRONMENTAL SCIENCES↗

Pincers with diverse donors and their interconversion: application to Ni(II)

Abstract A pincer ligand composed of a pyridine with ortho positions substituted by a bulky phosphine arm and a pyrazole arm (PNNH) is installed on nickel(II) to yield the diamagnetic planar complex [(PNNH)NiCl]Cl. The chloride anion can be replaced by BPh 4 − by a metathesis. The acidic pyrazole proton can be removed with LiN(SiMe 3 ) 2 to yield the square planar neutral molecule (PNN − )NiCl. The coordinated chloride can be metathetically replaced by azide to yield diamagnetic (PNN − )Ni(N 3 ). To evaluate changing the phosphine donor for a phosphine sulfide, the corresponding pincer ligand SPNNH was synthesized and installed on NiBr 2 . The reduced steric bulk from the more distant phosphorous keeps both halides coordinated in the paramagnetic molecular species (SPNNH)NiBr 2 . Several attempts to dehydrobrominate this species result in synthesis and characterization of two unexpected products. One effort revealed that the electrophilic character of P(V) leaves the phosphorus atom in (SPNNH)NiBr 2 vulnerable to nucleophilic attack, resulting in a P/C cleavage product which was characterized.

Cabelof, Alyssa C.↗

The Simons Observatory: Magnetic Shielding Measurements for the Universal Multiplexing Module

The Simons Observatory (SO) includes four telescopes that will measure the temperature and polarization of the cosmic microwave background using over 60,000 highly sensitive transition-edge bolometers (TES). These multichroic TES bolometers are read out by a microwave RF SQUID multiplexing system with a multiplexing factor of 910. Given that both TESes and SQUIDs are susceptible to magnetic field pickup and that it is hard to predict how they will respond to such fields, it is important to characterize the magnetic response of these systems empirically. This information can then be used to limit spurious signals by informing magnetic shielding designs for the detectors and readout. This paper focuses on measurements of magnetic pickup with different magnetic shielding configurations for the SO universal multiplexing module (UMM), which contains the SQUIDs, associated resonators, and TES bias circuit. The magnetic pickup of a prototype UMM was tested under three shielding configurations: no shielding (copper packaging), aluminum packaging for the UMM, and a tin/lead-plated shield surrounding the entire dilution refrigerator 100 mK cold stage. We also present measurements of the pickup in the UMM when aluminum feedhorns are installed. The measurements show that the aluminum packaging outperforms the copper packaging by a shielding factor of 8-10, and adding the tin/lead-plated 1K shield further increases the relative shielding factor in the aluminum configuration by 1-2 orders of magnitude. Furthermore, the addition of feedhorns provides a factor of 30 improvement when the tin/lead shield is not installed and a factor of 5 improvement when it is.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

An agent-based approach to study the diffusion rate and the effect of policies on joint placement of photovoltaic panels and green roof under climate change uncertainty

As two of the highest trending green technologies, photovoltaic panels and green roofs are proven to be effective practices for energy generation and energy saving. The achievable impact from the widespread installation of such technologies is, however, not clearly established. This is mainly because the degree of this impact highly depends on the inherently uncertain environmental and climate factors, as well as the unknown adoption rates of these technologies, which in turn depend on different characteristics of decision makers and interactions among them. To that end, this study aims to investigate the diffusion rate of these green technologies under uncertainties caused by climate change, characteristics of adopters, and their interactions. An integrated framework is developed to capture the interplay between financial and attitudinal aspects, as well as the uncertainties due to both the stochastic nature of system parameters and the interactions among agents involving human beings. Specifically, this framework consists of a integer programming model to optimize the green roof and/or photovoltaic panel installation settings for a given building under climate change uncertainty, and an agent-based model to factor in the role of human behavior and interactions. A case study for the city of Knoxville, TN, is presented to evaluate the effects of different policies on the diffusion rate of the green technologies of interest. The results show that the affordability of green technologies and public awareness are the key drivers of the adoption of these technologies, which highlight the important role of the decision makers in impacting the diffusion rate.

14 SOLAR ENERGY↗

Evaluation of smart charging for electric vehicle-to-building integration: A case study

Higher electric vehicle (EV) adoption will stress the importance of demand flexibility to achieve more economic, efficient, and reliable grid operation. Charging technologies will be paramount in shifting temporally to better fit the variable generation of wind and solar. As such, analysis is warranted on the benefits of EV charge scheduling with respect to installation cost, operation cost, difficulty of implementation, and grid flexibility. We tackle this by analyzing the cost savings of implementing an EV charge scheduling infrastructure to reduce demand charges and installation costs. In this paper, we analyze a case study for operation of 16 level 2 chargers and 1 fast charger for two different building types. We then evaluate various test phases for controlling building and charging loads using an adaptive charging network (ACN) algorithm to characterize the ACN’s potential to reduce overall project cost.

30 DIRECT ENERGY CONVERSION↗

Unsupervised Azimuth Estimation of Solar Arrays in Low-Resolution Satellite Imagery through Semantic Segmentation and Hough Transform

This paper explains the use of a convolutional neural network (CNN) to segment solar panels in a satellite image containing solar arrays, and extract associated metadata from the arrays. A novel unsupervised technique is introduced to estimate the azimuth of each individual solar panel from the predicted mask of the convolutional neural network. This pipeline was developed with the aim of extracting necessary metadata for a solar installation, using only a set of latitude–longitude coordinates. Azimuth prediction results for 669 individual solar installations associated with 387 sites located across the United States are provided. A mean average error and median average error of 21.65 degrees and 1.0 degrees were obtained, respectively, when predicting the azimuth of the solar fleet data set, with about 80% of the results within an error of zero degrees of the ground truth azimuth value and about 85% within an error of 25 degrees. The predicted azimuth was then used to estimate the energy conversion of the solar arrays. Results show a 90.9 and 90.6 R-squared value for estimating alternating current (AC) and direct current (DC) energy, respectively, and a mean absolute percentage error (MAPE) of 1.70% in estimating the alternating current (AC) energy using the fully automated algorithm.

14 SOLAR ENERGY↗

A comparison of building system parameters between affordable and market-rate housing in New York City

Low-income households in the United States experience higher than average energy burdens (defined as the proportion of household income spent on energy utilities), and many of these households struggle to simultaneously pay for rent, energy, and basic household necessities. The analysis presented here in this study examines whether the underlying characteristics of buildings and their energy systems could contribute to this disparity for affordable housing residents in New York City. It combines an energy audit dataset of 7,328 multifamily buildings with a database of properties receiving local, state, or federal housing subsidies. The results of this analysis indicate that the building-level installed equipment in large (greater than 50,000 square feet) affordable housing buildings in New York City is more efficient than that in market-rate buildings, but this trend largely disappears when considering overall building characteristics, such as location, size, or age. Significant differences in the types of systems installed in affordable and market-rate housing are also observed, as well as the types of energy efficiency recommendations made by energy auditors. However, these latter data were not normalized by building system characteristics, as that analysis is much more difficult to interpret for categorical data such as heating system type. These findings indicate that retrofit policies and building performance standards focused on affordable housing will likely need to account for underlying differences in building characteristics between affordable and market-rate housing to achieve intended impacts.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Effects of land-based wind turbine upsizing on community sound levels and power and energy density

Multiple technological, social, and market factors of wind power are evolving rapidly. Most notably, significant wind turbine scaling is occurring and is forecasted to continue. While the larger turbines expected to be deployed in the future are more powerful and efficient, they are also expected to operate at higher sound levels and require larger setbacks than those installed in the last decade. These sometimes-competing deployment trends and impacts cannot be understood via simple extrapolations of past trends. This study analyzes the effect of these future larger turbines on wind turbine micro-siting, project-level power and energy density, and community noise impacts. Due to their taller heights, larger rotors, and higher sound power levels, future wind turbines will require larger setbacks from homes and greater inter-turbine spacing, resulting in fewer turbines deployed for a given land area. This research finds these changes more than offset the effect of the higher turbine sound emissions, significantly decreasing the average sound levels that wind plant hosting communities experience. Yet, simultaneously, plant layouts using future turbine designs also result in projects with higher installed capacities and annual energy output for a given land area. These increases will likely lead to increased tax benefits and local income in the community. The deployment of fewer turbines on a smaller number of parcels could have implications on siting flexibility and landowner payments.

17 WIND ENERGY↗

Cost analysis of distributed storage in AC and DC microgrids

Building and microgrid designs with highly-distributed electrical storage have potential advantages over today's conventional topologies with centralized storage. Herein this paper studies the capital cost benefits of several residential behind-the-meter distributed-storage topologies, including AC and DC versions of systems with load-packaged batteries and resilient sub-networks. The study begins by defining the block configuration of each topology. This work then develops a model for the cost of the power electronics necessary to interface with the storage elements. Finally, the analysis develops a model for the total cost of each storage topology, incorporating the installation and soft costs. The results suggest that while the cost of power electronics is lower in centralized topologies, the total cost is lower for distributed storage due to the avoided costs of installation and permitting. This paper also explores the benefits of load-packaged batteries for savings in electrical infrastructure.

25 ENERGY STORAGE↗

Investigation of a high-temperature combination heat pump for lower-cost electrification in multifamily buildings

The development of space and water heating combination heat pumps capable of generating water temperatures high enough for convective heat emitters will enable more cost-effective and equitable decarbonization solutions for electrifying multifamily buildings. Here, in this paper, multifamily building models and a charge-sensitive mechanistic cycle model of a combination heat pump are developed, and the system performance is predicted based on the models. Unlike other state-of-the-art residential heat pumping equipment, the modeled combination heat pump using an economized, fluid-injected variable-speed compressor can achieve higher temperature lifts of 40° - 85°C, with lower installation costs and complexity. The model predicted heating coefficient of performance (COP h ) is 2.1 at an ambient temperature of -15°C with a high-temperature lift of nearly 85°C, and a seasonal coefficient of performance in heating mode (SCOP h ) ranges from 2 - 4 for different locations. The system shows 30% - 90% lower CO 2 eq emissions over a condensing gas boiler and 9% - 13% lower projected installation costs than two separate space and water heat pumping appliances.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Soft costs and EVSE – Knowledge gaps as a barrier to successful projects

There has been a recent push to increase access to electric vehicle (EV) charging infrastructure. The National Electric Vehicle Infrastructure (NEVI) program, part of the Bipartisan Infrastructure Law (BIL) has made significant funding available for major charging infrastructure projects along state thruways, and many state and local incentives exist for EV owners to install chargers in their homes. However, deployment of these chargers has not kept up with demand, primarily due to issues in project planning, permitting processes, and unforeseen delays. This paper serves as a review of the current understanding of these and other non-hardware costs in EV charging infrastructure projects (collectively known as “soft costs”). We found that soft costs in EV charging infrastructure projects are not well understood. Specifically, there is little agreement on how soft costs should be categorized and tracked, and less agreement still on best practices for controlling these costs and lowering barriers to infrastructure deployment. A broader review of EV charging infrastructure cost analyses shows that these costs can have significant impacts on project outcomes. EV charging infrastructure projects may be able to examine the success of the solar industry in lowering soft costs, and a similar effort may lower project costs significantly. Further work on standardizing and collecting data on EV charging infrastructure costs is required to begin addressing and controlling these costs.

32 - ENERGY CONSERVATION, CONSUMPTION, AND UTILIZA↗

Benchmarking thermal energy storage cost for industrial process heat

Process heat accounts for roughly half of industrial energy demand, and currently 95% of process heat is derived from the combustion of natural gas, oil, and coal. Electrification of industrial heating could be an alternative, potentially expanding locations suitable for manufacturing; however, industrial facility owners may desire energy storage to stabilize energy costs. In this work, the economic benefits of pairing thermal storage with electrified process heat to reduce the average price paid for energy are analyzed. Cost savings focus on energy arbitrage, or leveraging flexible energy pricing schemes, alone. The cost of natural gas combustion across decades (2019-2060) is compared to the costs of electricity and thermal energy storage in four United States Independent System Operator (ISO) regions. Systems installed today may not yield positive net present value (NPV) compared to the use of natural gas. However, using estimated electricity prices, systems installed in 2030 using arbitrage alone could be profitable when compared to natural gas in some regions of the U.S. Furthermore, if capital expenditures could be reduced by 50% for sensible thermal storage systems by 2030, profitable systems are found across all regions. This implies that electrification of industrial process heat, when paired with inexpensive thermal energy storage systems, could be less expensive than brownfield natural gas systems, using arbitrage as the only source of revenue and without a dependency on any future policy drivers such as pricing externalities that could further incentivize the electrification of industrial process heat.

24 POWER TRANSMISSION AND DISTRIBUTION↗

A novel shallow bore ground heat exchanger for ground source heat pump applications—Model development and validation

A novel ground heat exchanger design, the Underground Thermal Battery (UTB), was proposed as a low-cost alternative to the conventional vertical bore ground heat exchanger (VBGHE) for the application of ground source heat pumps (GSHPs). The UTB is designed to be installed in a shallow borehole (less than 6 m deep) and thus could cost much less than the conventional VBGHE, which usually is installed in vertical bores 60 m deep. By utilizing natural convection of water and phase change materials, the UTB tempers its temperature change in response to thermal loads, which helps improve the efficiency of GSHPs. A one-dimensional (1D) model of the UTB has been developed and validated with the measured performance data of a small-scale UTB, as well as the simulation results of a more detailed three dimensional (3D) numerical model, which accounts for both heat transfer and fluid dynamics in the UTB. Further, this 1D model is computationally much more efficient than the 3D model and thus can simulate the annual performance of the UTB with acceptable computation time. The 1D model has been used to evaluate the performance of the UTB so that it can be compared with the conventional VBGHE.

42 ENGINEERING↗