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At least 559 records · Page 31

Alternative, Less Water-Intensive, Fracturing Fluids for Enhanced Geothermal Systems

Four fracturing fluids; water, CO2, CO2 with water, and CO2 with an aqueous solution of a CO2-reactive polymer, poly(allylamine) (PAA, 1wt%) were evaluated using a high-temperature true-triaxial fracturing apparatus and ½ foot side granite cubic samples. All three CO2-based fracturing fluids, CO2, CO2 with water, and CO2 with aqueous PAA fractured granite at higher breakdown pressures, high transient flow rates, and produce higher-conductivity fractures as compared to water. Additionally, faster pressurization rates with CO2-based fracturing fluids (obtained when fracturing at constant flow rate mode) are found to be associated with higher fracture conductivities. When partially saturating the rock sample with PAA solution followed by fracturing with CO2, the volume expansion caused by CO2-induced cross-linking of PAA leads to a faster pressure increase due to the associated stress generated and increase in viscosity. It was also found that CO2 as a fracturing fluid injected in hot dry rock (HDR) attain the highest fracture conductivity only when injected at very high flow rates, followed very closely by the CO2/PAA fracturing fluid system that generates fractures with, on average, similarly high conductivity values though independently of injection flow rate and using 1/6 of the mass of CO2 as compared to CO2 in HDR. Breakdown pressures were also similar for CO2 stimulation in HDR and CO2/PAA fluid system under identical injection flow rates. It is concluded that CO2 (when injected in HDR) and CO2/PAA are the fluids of choice for stimulation of granitic rock samples under the studied geothermal P/T conditions. CO2/PAA, however, offer the following three additional advantages; 1) it requires significantly lower volumes of CO2, 2) fracture permeability is independent of injection flow rate, and 3) the reversible (previously reported) viscosity increase is beneficial to transport proppants if they are ever developed enhanced geothermal systems.

Jian, Guoqing↗

Open aperture flow cells for on-line optical analysis of process fluids

A flow cell system includes a vessel and a fluid located in the vessel. A fluid surface of the fluid can be vented to a first gas pressure. The fluid surface can have a first cross-sectional area. The flow cell system includes a conduit in fluid communication with the vessel and positioned downstream of the vessel. The conduit can have a region that includes one or more orifices and has a second cross-sectional area. The second cross-sectional area can be less than the first cross-sectional area. The one or more orifices can be vented to a second gas pressure. The second gas pressure can be equal to or greater than the first gas pressure. Methods for analyzing a process fluid can include characterizing the fluid in the conduit.

Launiere, Cari A.↗

Toward better hydraulic fracturing fluids and their application in energy production: A review of sustainable technologies and reduction of potential environmental impacts

Recent advances in hydraulic fracturing, in conjunction with horizontal drilling, have enabled large-scale extraction of natural gas and oil from shale formations. Despite its advances and enormous economic benefits, opportunities remain to increase hydraulic fracturing efficiency and minimize potential environmental impacts. This review specifically examines three key themes associated with development and utilization of hydraulic fracturing fluids: 1) characteristics and behavior of fracturing fluids, 2) understanding and predicting migration and fate of fracturing fluids, 3) technologies to reduce environmental impact of fracturing fluids. Furthermore, the paper discusses key and new techniques and findings on rheology of hydrogel-based fluids, high fidelity simulation of propagation transport, potential environmental impacts, geosynthetics in mitigating contamination, and greener fracturing fluids. It is indicated that future development relies on advances in understanding of physical processes, modeling capabilities, and monitoring techniques.

02 PETROLEUM↗

Hydrodynamic interactions of two nearly touching Brownian spheres in a stiff potential: Effect of fluid inertia

The hydrodynamic interaction of two closely spaced micron-scale spheres undergoing Brownian motion was measured as a function of their separation. Each sphere was attached to the distal end of a different atomic force microscopy cantilever, placing each sphere in a stiff one-dimensional potential (0.08 Nm{sup −1}) with a high frequency of thermal oscillations (resonance at 4 kHz). As a result, the sphere’s inertial and restoring forces were significant when compared to the force due to viscous drag. We explored interparticle gap regions where there was overlap between the two Stokes layers surrounding each sphere. Our experimental measurements are the first of their kind in this parameter regime. The high frequency of oscillation of the spheres means that an analysis of the fluid dynamics would include the effects of fluid inertia, as described by the unsteady Stokes equation. However, we find that, for interparticle separations less than twice the thickness of the wake of the unsteady viscous boundary layer (the Stokes layer), the hydrodynamic interaction between the Brownian particles is well-approximated by analytical expressions that neglect the inertia of the fluid. This is because elevated frictional forces at narrow gaps dominate fluid inertial effects. The significance is that interparticle collisions and concentrated suspensions at this condition can be modeled without the need to incorporate fluid inertia. We suggest a way to predict when fluid inertial effects can be ignored by including the gap-width dependence into the frequency number. We also show that low frequency number analysis can be used to determine the microrheology of mixtures at interfaces.

42 ENGINEERING↗

Vibration energy harvesting in a small channel fluid flow using piezoelectric transducer

This work is aimed at developing a way to harvest energy from a fluid stream with the application of piezoelectric transducers in a small channel. In this COMSOL Multiphysics based simulation study, it is attempted to harvest energy from the abundant renewable source of energy available in the form of kinetic energy of naturally occurring flow of fluids. The strategy involves harnessing energy from a fluid-actuator through generation of couples, eddies and vortices, resulting from the stagnation and separation of flow around a semi-circular bluff-body attached to a cantilever beam containing a piezoceramic layer. Fluctuation of fluidic pressure impulse on the beam due to vortex shedding and varying lift forces causes the flexible cantilever beam to oscillate in the direction normal to the fluid flow in a periodic manner. The periodic application and release of a mechanical strain upon the beam effected a generation of electric potential within the piezoelectric layer, thus enabling extraction of electrical energy from the kinetic energy of the fluid. The piezoelectric material properties and transducer design are kept unchanged throughout the study, whereas the configuration is tested with different fluids and varying flow characteristics. The size and geometry of the obstructing entity are systematically varied to closely inspect the output from different iterations and for finding the optimum design parameters. The intermittent changes in the generated forces and subsequent variation in the strain on the beam are also monitored to find definitive relationship with the electrical energy output.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Fluid System Stability Analysis Techniques

Fluid systems, or networks, consist of multiple components that work together to achieve some desired thermofluid state. For any generic application, this fluid state can be a combination of the fluid pressure, flow rate, enthalpy, or species concentration. Fluid system components, such as pumps and valves, are often governed by nonlinear differential equations, resulting in complex component-to-component interactions. System-level fluid network stability occurs when the flow through the system can maintain a steady-state solution in the presence of small perturbations, which depends on these component interactions. System instability, however, can go undetected until issues arise during integrated system testing. This presentation explores a method for system designers to think of the fluid network as an assembly of components, each with their own thermofluid surfaces of partial stability, called nullclines. The intersections of all nullclines yields system-level solutions, called equilibrium points. When designers define operating points, they are tuning system parameters so that these equilibrium points move to the desired location in the thermofluid state plane. However, linearization theory shows us that the dynamic behavior around these points can be unstable. The local stability of these equilibrium points can be assessed analytically with eigen-analysis, or numerically by propagating state-plane samples to construct a phase portrait. Investigating a phase portrait can help designers gain a qualitative understanding of a system’s dynamic performance. This understanding can then help inform requirement definitions, component selection, and operational procedures. This presentation includes an example of the phase portrait technique on a system featuring a centrifugal pump and a back-pressure regulator (BPR). Numerical modeling of this system suggests that equilibrium points on the left-hand side of the pump curve are dynamically unstable.

Fluid System↗

Seismic velocity changes associated with aseismic deformations of a fault stimulated by fluid injection

Fluid pressure plays an important role in the stability of tectonic faults. However, the in situ mechanical response of faults to fluid pressure variations is still poorly known. To address this question, we performed here a fluid injection experiment in a fault zone in shales while monitoring fault movements at the injection source and seismic velocity variations from a near-distance (<10 m) monitoring network. We measured and located the P and S wave velocity perturbations in and around the fault using repetitive active sources. We observed that seismic velocity perturbations dramatically increase above 1.5 MPa of injection pressure. This is consistent with an increase of fluid flow associated with an aseismic dilatant shearing of the fault as shown by numerical modeling. We find that seismic velocity changes are sensitive to both fault opening by fluid invasion and effective stress variations and can be an efficient measurement for monitoring fluid-driven aseismic deformations of faults.

58 GEOSCIENCES↗

Potential landscape and flux field theory for turbulence and nonequilibrium fluid systems

Highlights: •The notion of nonequilibrium trinity based on detailed balance breaking is proposed. •Nonequilibrium trinity captures the nonequilibrium irreversible nature of turbulence. •Nonequilibrium trinity leads to the potential-flux form of stochastic fluid dynamics. •Energy flux in turbulence energy cascade is connected to nonequilibrium trinity. •The four-fifths law of turbulence is a manifestation of nonequilibrium trinity. -- Abstract: Turbulence is a paradigm for far-from-equilibrium systems without time reversal symmetry. To capture the nonequilibrium irreversible nature of turbulence and investigate its implications, we develop a potential landscape and flux field theory for turbulent flow and more general nonequilibrium fluid systems governed by stochastic Navier–Stokes equations. We find that equilibrium fluid systems with time reversibility are characterized by a detailed balance constraint that quantifies the detailed balance condition. In nonequilibrium fluid systems with nonequilibrium steady states, detailed balance breaking leads directly to a pair of interconnected consequences, namely, the non-Gaussian potential landscape and the irreversible probability flux, forming a ‘nonequilibrium trinity’. The nonequilibrium trinity characterizes the nonequilibrium irreversible essence of fluid systems with intrinsic time irreversibility and is manifested in various aspects of these systems. The nonequilibrium stochastic dynamics of fluid systems including turbulence with detailed balance breaking is shown to be driven by both the non-Gaussian potential landscape gradient and the irreversible probability flux, together with the reversible convective force and the stochastic stirring force. We reveal an underlying connection of the energy flux essential for turbulence energy cascade to the irreversible probability flux and the non-Gaussian potential landscape generated by detailed balance breaking. Using the energy flux as a center of connection, we demonstrate that the four-fifths law in fully developed turbulence is a consequence and reflection of the nonequilibrium trinity. We also show how the nonequilibrium trinity can affect the scaling laws in turbulence.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Data-driven, multi-moment fluid modeling of Landau damping

Deriving governing equations of complex physical systems based on first principles can be quite challenging when there are certain unknown terms and hidden physical mechanisms in the systems. In this work, we apply a deep learning architecture to learn fluid partial differential equations (PDEs) of a plasma system based on the data acquired from a fully kinetic model. Here, the learned multi-moment fluid PDEs are demonstrated to incorporate kinetic effect such as Landau damping. Based on the learned fluid closure, the data-driven, multi-moment fluid modeling can well reproduce all the physical quantities derived from the fully kinetic model. The calculated damping rate of Landau damping is consistent with both the fully kinetic simulation and the linear theory. The data-driven fluid modeling of PDEs for complex physical systems may be applied to improve the fluid closure and reduce the computational cost of multi-scale modeling of global systems.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Seismicity and fault aseismic deformation caused by fluid injection in decametric in-situ experiments

Seismicity induced by fluid perturbations became an important societal concern since felt earthquakes ( M w up to 6) occurred after anthropogenic activities. In order to mitigate the risks associated with undesired seismicity, as well as to be able to use the micro-seismicity as a probe for in-depth investigation of fluid-driven processes, it is of crucial importance to understand the links between seismicity, fluid pressure and flow. We have developed a series of in-situ, decameter-scale experiments of fault zone reactivation by controlled fluid injection, in order to improve the near-source geophysical and hydromechanical observations. The deployed geophysical monitoring close to the injection allows one to cover the full frequency range of the fault responses from the static deformation to the very high-frequency seismic emissions (up to 4 kHz). Here, we focus on the microseismicity ( M w ~ –4 to –3) recorded during two fluid injection experiments in low-permeable shale and highly-fractured limestone formations. In both experiments, the spatio-temporal distribution of the seismic events, the energy balance, and the seismic velocity changes of the fractured medium show that most of the deformation does not actually emit seismic signals. The induced deformation is mainly aseismic. Based on these high-resolution multiparametric observations in the near-field, we therefore proposed a new model for injection-induced seismicity: the seismicity is not directly induced by the increasing fluid pressure, but it is rather triggered by the stress perturbations transferred from the aseismic motion caused by the injection.

58 GEOSCIENCES↗

A level set approach for the computational study of a yield stress fluid filling a thin mold

Many important engineering and scientific applications such as cement slurries, foams, crude oil, and granular avalanches involve the concept of yield stress. Therefore, modeling yield stress fluids in different flow configurations, including the accurate prediction of the yield surface, is important. In this paper, we present a computational model based on the finite element method to study the flow of yield stress fluids in a thin mold and compare the results with data from flow visualization experiments. Here, we use the level set method to describe the interface between the filling fluid and air. We use polypropylene glycol as a model Newtonian fluid and Carbopol for the model yield stress fluid, as the Carbopol solution demonstrates yielding without thixotropy. To describe the yielding and shear-thinning behavior, we use a generalized Newtonian constitutive equation with a Bingham–Carreau–Yasuda form. We compare the results obtained from the mold filling experiments with the results from the three-dimensional (3D) model and from a reduced-order Hele-Shaw (HS) model that is two-dimensional, including the effect of shear-thinning along the thin direction only approximately. We show that both the 3D and the HS model can capture the experimental meniscus shape reasonably well for all the fluids considered at three different flow rates. This indicates that the shape evolution is insensitive to the dimensionality of the model. However, the viscosity and yield surfaces predicted by the 3D and HS models are different. The HS model underestimates the high viscosity and unyielded regions compared to the estimation by the 3D model.

42 ENGINEERING↗

Experimental procedures to mitigate electron beam induced artifacts during in situ fluid imaging of nanomaterials

Currently there are few standardized experimental practices in the field of fluid stage transmission electron microscopy. To obtain consistency in this emerging field, a crucial step is to establish the common artifacts and electron beam-sample interactions that can occur. Recently many unintended phenomena have been observed during in situ fluid stage scanning transmission electron microscopy (STEM) experiments, including growth of crystals on the fluid stage windows, repulsion of particles from the irradiated area, bubble formation, and the loss of atomic information during prolonged imaging of individual nanoparticles. Here we provide a comprehensive review of these fluid stage artifacts, and we present new experimental evidence that sheds light on their origins in terms of experimental apparatus issues and indirect electron beam sample interactions with the fluid layer. The results here will provide a methodology for minimizing fluid stage imaging artifacts and acquiring quantitative in situ observations of nanomaterial behavior in a liquid environment.

in situ fluid↗

The Effects of Earthquakes and Fluids on the Metamorphism of the Lower Continental Crust

Rock rheology and density have first-order effects on the lithosphere's response to plate tectonic forces at plate boundaries. Changes in these rock properties are controlled by metamorphic transformation processes that are critically dependent on the presence of fluids. At the onset of a continental collision, the lower crust is in most cases dry and strong. However, if exposed to internally produced or externally supplied fluids, the thickened crust will react and be converted into a mechanically weaker lithology by fluid-driven metamorphic reactions. Fluid introduction is often associated with deep crustal earthquakes. Microstructural evidence, suggest that in strong highly stressed rocks, seismic slip may be initiated by brittle deformation and that wall-rock damage caused by dynamic ruptures plays a very important role in allowing fluids to enter into contact with dry and highly reactive lower crustal rocks. The resulting metamorphism produces weaker rocks which subsequently deform by viscous creep. Volumes of weak rocks contained in a highly stressed environment of strong rocks may experience significant excursions toward higher pressure without any associated burial. Slow and highly localized creep processes in a velocity strengthening regime may produce mylonitic shear zones along faults initially characterized by earthquake-generated frictional melting and wall rock damage. However, stress pulses from earthquakes in the shallower brittle regime may kick start new episodes of seismic slip at velocity weakening conditions. These processes indicate that the evolution of the lower crust during continental collisions is controlled by the transient interplay between brittle deformation, fluid-rock interactions, and creep flow.

58 GEOSCIENCES↗

Determination of the thermodynamic correction factor of fluids confined in nano-metric slit pores from molecular simulation

The multi-component diffusive mass transport is generally quantified by means of the Maxwell-Stefan diffusion coefficients when using molecular simulations. These coefficients can be related to the Fick diffusion coefficients using the thermodynamic correction factor matrix, which requires to run several simulations to estimate all the elements of the matrix. In a recent work, Schnell et al. [“Thermodynamics of small systems embedded in a reservoir: A detailed analysis of finite size effects,” Mol. Phys. 110, 1069–1079 (2012)] developed an approach to determine the full matrix of thermodynamic factors from a single simulation in bulk. This approach relies on finite size effects of small systems on the density fluctuations. We present here an extension of their work for inhomogeneous Lennard Jones fluids confined in slit pores. We first verified this extension by cross validating the results obtained from this approach with the results obtained from the simulated adsorption isotherms, which allows to determine the thermodynamic factor in porous medium. We then studied the effects of the pore width (from 1 to 15 molecular sizes), of the solid-fluid interaction potential (Lennard Jones 9-3, hard wall potential) and of the reduced fluid density (from 0.1 to 0.7 at a reduced temperature T* = 2) on the thermodynamic factor. The deviation of the thermodynamic factor compared to its equivalent bulk value decreases when increasing the pore width and becomes insignificant for reduced pore width above 15. We also found that the thermodynamic factor is sensitive to the magnitude of the fluid-fluid and solid-fluid interactions, which softens or exacerbates the density fluctuations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Cosmology with moving bimetric fluids

We study cosmological implications of bigravity and massive gravity solutions with non-simultaneously diagonal metrics by considering the generalized Gordon and Kerr-Schild ansatzes. The scenario that we obtain is equivalent to that of General Relativity with additional non-comoving perfect fluids. We show that the most general ghost-free bimetric theory generates three kinds of effective fluids whose equations of state are fixed by a function of the ansatz. Different choices of such function allow to reproduce the behaviour of different dark fluids. In particular, the Gordon ansatz is suitable for the description of various kinds of slowly-moving fluids, whereas the Kerr-Schild one is shown to describe a null dark energy component. The motion of those dark fluids with respect to the CMB is shown to generate, in turn, a relative motion of baryonic matter with respect to radition which contributes to the CMB anisotropies. CMB dipole observations are able to set stringent limits on the dark sector described by the effective bimetric fluid.

79 ASTRONOMY AND ASTROPHYSICS↗

Deep Eutectic Salt Formulations Suitable as Advanced Heat Transfer Fluids

Concentrating solar power (CSP) facilities are comprised of many miles of fluid-filled pipes arranged in large grids with reflective mirrors used to capture radiation from the sun. Solar radiation heats the fluid which is used to produce steam necessary to power large electricity generation turbines. Currently, organic, oil-based fluid in the pipes has a maximum temperature threshold of 400 °C, allowing for the production of electricity at approximately 15 cents per kilowatt hour. The DOE hopes to foster the development of an advanced heat transfer fluid that can operate within higher temperature ranges. The new heat transfer fluid, when used with other advanced technologies, could significantly decrease solar electricity cost. Lower costs would make solar thermal electricity competitive with gas and coal and would offer a clean, renewable source of energy. Molten salts exhibit many desirable heat transfer qualities within the range of the project objectives. Halotechnics developed advanced heat transfer fluids (HTFs) for application in solar thermal power generation. This project focused on complex mixtures of inorganic salts that exhibited a high thermal stability, a low melting point, and other favorable characteristics. A high-throughput combinatorial research and development program was conducted in order to achieve the project objective. Over 19,000 candidate formulations were screened. The workflow developed to screen various chemical systems to discover salt formulations led to mixtures suitable for use as HTFs in both parabolic trough and heliostat CSP plants. Furthermore, salt mixtures which will not interfere with fertilizer based nitrates were discovered. In addition for use in CSP, the discovered salt mixtures can be applied to electricity storage, heat treatment of alloys and other industrial processes.

25 ENERGY STORAGE↗

Development of an Environmentally Acceptable Hydraulic Fluid

Hydroelectric plants operators like the United States Army Corps of Engineers seek their traditional petroleum-based fluids with environmentally acceptable hydraulic fluids (EAHF) to reduce their impact and liability related to spills and leakages to the water and environment. Artesion, Inc. and its sub-contractor Washington State University (WSU) sought to optimize WSU’s existing EAHF blend into an improved product that would demonstrate long-term stability while meeting the EAHF requirements of the EPA’s Vessel General Permit (VGP). Multiple rounds of Design of Experiments testing were performed from WSU’s base formulation, modifying mixing ratios to generate multiple test fluids. These fluids were then tested for hydraulic fluid properties. It was found that there was a significant tradeoff between oxidative stability and biodegradability; highly stable materials were not sufficiently biodegradable, while the highly biodegradable materials quickly failed in stability tests. After four rounds of Design of Experiments, AI and WSU had found a base fluid which met the VGP, but only had a Rotating Pressure Vessel Oxidative Test (RPVOT) of 284-minute RPVOT stability, far short of the 500-minute target that would be needed for hydroelectric plants. It was determined that WSU’s route had shown initial promise but needed more refinement to be able to produce an acceptable EAHF.

36 MATERIALS SCIENCE↗

Systematic study on the phase transition of confined fluid mixture up to the critical region

Systematic experimental study on the phase transition of confined fluids up to the critical region has been performed, in which many new insights have been obtained. For confined pure fluids, compared to the bulk phase, the critical point shifts to lower pressure and temperature, but the relative shift of critical pressure is much larger than that of critical temperature. The behavior of the shift, i.e., the shift as a function of pore size, is dependent on the pore type. For confined fluid mixtures, compared to the bulk phase, the critical point also shifts to lower pressure and temperature, and the relative shift of critical pressure is also much larger than that of critical temperature. Confined fluid mixture behaves similarly to confined pure fluid, i.e., it exhibits hysteresis at lower temperature range and does not exhibit phase coexistence or phase envelope. An equation of state for confined pure fluids, based on the Generalized van der Waals partition function, has also been developed and demonstrated to accurately predict the capillary condensation of simple molecules in MCM-41. The parameters of the equation of state are derived from experimental critical point.

77 NANOSCIENCE AND NANOTECHNOLOGY↗