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Exploiting the Temperature/Concentration Dependence of Magnetic Susceptibility to Control Convection in Fundamental Studies of Solidification Phenomena

The objective of this new research project is to demonstrate by experiment, supplemented by mathematical modeling and physical property measurement, that the effects of buoyancy driven convection can be largely eliminated in ground-based experiments, and further reduced in flight, by applying a new technique. That technique exploits the dependence of magnetic susceptibility on composition or temperature. It is emphasized at the outset that the phenomenon to be exploited is fundamentally and practically different from the magnetic damping of convection in conducting liquids that has been the subject of much prior research. The concept suggesting this research is that all materials, even non-conductors, when placed in a magnetic field gradient, experience a force. Of particular interest here are paramagnetic and diamagnetic materials, classes which embrace the "model alloys", such as succinonitrile-acetone, that have been used by others investigating the fundamentals of solidification. Such alloys will exhibit a dependence of susceptibility on composition. The consequence is that, with a properly oriented field (gradient) a force will arise that can be made to be equal to, but opposite, the buoyancy force arising from concentration (or temperature) gradients. In this way convection can be stilled. The role of convection in determining the microstructure, and thereby properties, of materials is well known. Elimination of that convection has both scientific and technological consequences. Our knowledge of diffusive phenomena in solidification, phenomena normally hidden by the dominance of convection, is enhanced if we can study solidification of quiescent liquids. Furthermore, the microstructure, microchemistry and properties of materials (thereby practical value) are affected by the convection occurring during their solidification. Hitherto the method of choice for elimination of convection has been experimentation in microgravity. However, even in low Earth orbit, residual convection has effects. That residual convection arises from acceleration (drag on the spacecraft), displacement from the center of mass or transients in the gravitational field (g-jitter). There is therefore a need for both further reducing buoyancy driven flow in flight and allowing the simulation of microgravity during ground based experiments. Previous investigations, the research project description, theory behind the study and experimental methods as well as plots of magnetic fields and forces are presented.

Evans, J. W.↗

Comparison Between Navier-Stokes and Thin-Layer Computations for Separated Supersonic Flow

In the numerical simulation of high Reynolds-number flow, one can frequently supply only enough grid points to resolve the viscous terms in a thin layer. As a consequence, a body-or stream-aligned coordinate system is frequently used and viscous terms in this direction are discarded. It is argued that these terms cannot be resolved and computational efficiency is gained by their neglect. Dropping the streamwise viscous terms in this manner has been termed the thin-layer approximation. The thin-layer concept is an old one, and similar viscous terms are dropped, for example, in parabolized Navier-Stokes schemes. However, such schemes also make additional assumptions so that the equations can be marched in space, and such a restriction is not usually imposed on a thin-layer model. The thin-layer approximation can be justified in much the same way as the boundary-layer approximation; it requires, therefore, a body-or stream-aligned coordinate and a high Reynolds number. Unlike the boundary-layer approximation, the same equations are used throughout, so there is no matching problem. Furthermore, the normal momentum equation is not simplified and the convection terms are not one-sided differenced for marching. Consequently, the thin-layer equations are numerically well behaved at separation and require no special treatment there. Nevertheless, the thin-layer approximation receives criticism. It has been suggested that the approximation is invalid at separation and, more recently, that it is inadequate for unsteady transonic flow. Although previous comparisons between the thin-layer and Navier-Stokes equations have been made, these comparisons have not been adequately documented.

Degani, David↗

Low-Temperature Friction-Stir Welding of 2024 Aluminum

Solid state friction-stir welding (FSW) has been demonstrated to involve dynamic recrystallization producing ultra-fine, equiaxed grain structures to facilitate superplastic deformation as the welding or joining mechanism. However, the average residual, equiaxed, grain size in the weld zone has ranged from roughly 0.5 micron to slightly more than 10 micron, and the larger weld zone grain sizes have been characterized as residual or static grain growth as a consequence of the temperatures in the weld zone (where center-line temperatures in the FSW of 6061 Al have been shown to be as high as 480C or -0.8 T(sub M) where T(sub M) is the absolute melting temperature)). In addition, the average residual weld zone grain size has been observed to increase near the top of the weld, and to decrease with distance on either side of the weld-zone centerline, an d this corresponds roughly to temperature variations within the weld zone. The residual grain size also generally decreases with decreasing FSW tool rotation speed. These observations are consistent with the general rules for recrystallization where the recrystallized grain size decreases with increasing strain (or deformation) at constant strain rate, or with increasing strain-rate, or with increasing strain rate at constant strain; especially at lower ambient temperatures, (or annealing temperatures). Since the recrystallization temperature also decreases with increasing strain rate, the FSW process is somewhat complicated because the ambient temperature, the frictional heating fraction, and the adiabatic heating fraction )proportional to the product of strain and strain-rate) will all influence both the recrystallization and growth within the FSW zone. Significantly reducing the ambient temperature of the base metal or work pieces to be welded would be expected to reduce the residual weld-zone grain size. The practical consequences of this temperature reduction would be the achievement of low temperature welding. This study compares the residual grain sizes and microstructures in 2024 Al friction-stir welded at room temperature (about 30C and low temperature (-30C).

Benavides, S.↗

Lean Premixed Combustion Stabilized by Low Swirl a Promising Concept for Practical Applications

Since its inception, the low-swirl burner (LSB) has shown to be a useful laboratory apparatus for fundamental studies of premixed turbulent flames. The LSB operates under wide ranges of equivalence ratios, flow rates, and turbulence intensities. Its flame is lifted and detached from the burner and allows easy access for laser diagnostics. The flame brush is axisymmetric and propagates normal to the incident reactants. Therefore, the LSB is well suited for investigating detailed flame structures and empirical coefficients such as flame speed, turbulence transport, and flame generated turbulence. Due to its capability to stabilize ultra-lean premixed turbulent flames (phi approx. = 0.55), the LSB has generated interest from the gas appliance industry for use as an economical low-NO(x) burner. Lean premixed combustion emits low levels of NO(x), due primarily to the low flame temperature. Therefore, it is a very effective NO(x) prevention method without involving selective catalytic reduction (SCR), fuel-air staging, or flue gas recirculation (FGR). En the gas turbine industry, substantial research efforts have already been undertaken and engines with lean premixed combustors are already in use. For commercial and residential applications, premixed pulsed combustors and premixed ceramic matrix burners are commercially available. These lean premixed combustion technologies, however, tend to be elaborate but have relatively limited operational flexibility, and higher capital, operating and maintenance costs. Consequently, these industries are continuing the development of lean premixed combustion technologies as well as exploring new concepts. This paper summarizes the research effects we have undertaken in the past few years to demonstrate the feasibility of applying the low-swirl flame stabilization method for a wide range of heating and power generation systems. The principle of flame stabilization by low-swirl is counter to the conventional high-swirl methods that rely on a recirculation zone to anchor the flame. In LSBS, flow recirculation is not promoted to allow the premixed turbulent flames to propagate freely. A LSB with an air-jet swirler is essentially an open tube with the swirler at its mid section. The small air-jets generate swirling motion only in the annular region and leaving the central core of the flow undisturbed, When this flow exits the burner tube, the angular momentum generates radial mean pressure gradient to diverge the non-swirling reactants stream. Consequently, the mean flow velocity decreases linearly. Propagating against this decelerating flow, the flame self-sustains at the position where the local flow velocity equals the flame speed, S(sub f). The LSB operates with a swirl number, S, between 0.02 to 0.1. This is much lower than the minimum S of 0.6 required for the high-swirl burners. We found that the swirl number needed for flame stabilization varies only slightly with fuel type, flow velocity, turbulent conditions and burner dimensions (i.e. throat diameter and swirl injection angle).

Cheng, R. K.↗

The Role of Self-Organized Criticality in the Substorm Phenomenon and its Relation to Localized Reconnection in the Magnetospheric Plasma Sheet

Evidence is presented that suggests there is a significant self-organized criticality (SOC) component in the dynamics of substorms in the magnetosphere. Observations of BBFs, fast flows, localized dipolarizations, plasma turbulence, etc. are taken to show that multiple localized reconnection sites provide the basic avalanche phenomenon in the establishment of SOC in the plasma sheet. First results are presented from a continuing plasma physical study of this avalanche process. A one-dimensional resistive MHD model of a magnetic field reversal is discussed. Resistivity, in this model, is self-consistently generated in response to the excitation of an idealized current-driven instability. When forced by convection of magnetic flux into the field reversal region, the model yields rapid magnetic field annihilation through a dynamic behavior that is shown to exhibit many of the characteristics of SOC. Over a large range of forcing strengths, the annihilation rate is shown to self-adjust to balance the rate at which flux is convected into the reversal region. Several analogies to magnetotail dynamics are discussed: (1) It is shown that the presence of a localized criticality in the model produces a remarkable stability in the global configuration of the field reversal while simultaneously exciting extraordinarily dynamic internal evolution. (2) Under steady forcing, it is shown that a loading-unloading cycle may arise that, as a consequence of the global stability, is quasi-periodic and, therefore, predictable despite the presence of internal turbulence in the field distribution. Indeed, it is shown that the global loading-unloading cycle is a consequence of the internal turbulence. (3) It is shown that, under steady, strong forcing the loading-unloading cycle vanishes. Instead, a recovery from a single unloading persists indefinitely. The field reversal is globally very steady while internally it is very dynamic as field annihilation goes on at the rate necessary to match the strong forcing. From this result we speculate that steady magnetospheric convection events result when the plasma sheet has been driven close to criticality over an extended spatial domain. During these events, we would expect to find localized reconnection sites distributed over the spatial domain of near criticality and we would expect to find plasma sheet transport in that domain to be closely related to that of BBF and fast flow events.

Klimas, Alex J.↗

Role of Inflammatory Reponse in Experimental Decompression Sickness

Decompression to altitude can result in gas bubble formation both in tissues and in the systemic veins. The venous gas emboli (VGE) are often monitored during decompression exposures to assess risk for decompression sickness (DCS). Astronauts are at risk for DCS during extravehicular activities (EVA), where decompression occurs from the Space Shuttle or Space Station atmospheric pressure of 14.7 pounds per square inch (PSI) to that of the space suit pressure of 4.3 PSI. DCS symptoms include diffuse pain, especially around joints, inflammation and edema. Pathophysiological effects include interstitial inflammatory responses and recurring injury to the vascular endothelium. Such responses can result in vasoconstriction and associated hemodynamic changes.The granulocyte cell activation and chemotaxin release results in the formation of vasoactive and microvascular permeability altering mediators, especially from the lungs which are the principal target organ for the venous bubbles, and from activated cells (neutrophils, platelets, macrophages). Such mediators include free arachidonic acid and the byproducts of its metabolism via the cyclooxygenase and lipoxygenase pathways (see figure). The cyclooxygenase pathway results in formation of prostacyclin and other prostaglandins and thromboxanes that cause vasoconstriction, bronchoconstriction and platelet aggregation. Leukotrienes produced by the alternate pathway cause pulmonary and bronchial smooth muscle contraction and edema. Substances directly affecting vascular tone such as nitric oxide may also play a role in the respose to DCS. We are studying the role and consequent effects of the release inflammatory bioactive mediators as a result of DCS and VGE. More recent efforts are focused on identifying the effects of the body's circadian rhythm on these physiological consequences to decompression stress. al

Butler, B. D.↗

A Methodology for Investigating Adaptive Postural Control

Our research on postural control and human-environment interactions provides an appropriate scientific foundation for understanding the skill of mass handling by astronauts in weightless conditions (e.g., extravehicular activity or EVA). We conducted an investigation of such skills in NASA's principal mass-handling simulator, the Precision Air-Bearing Floor, at the Johnson Space Center. We have studied skilled movement-body within a multidisciplinary context that draws on concepts and methods from biological and behavioral sciences (e.g., psychology, kinesiology and neurophysiology) as well as bioengineering. Our multidisciplinary research has led to the development of measures, for manual interactions between individuals and the substantial environment, that plausibly are observable by human sensory systems. We consider these methods to be the most important general contribution of our EVA investigation. We describe our perspective as control theoretic because it draws more on fundamental concepts about control systems in engineering than it does on working constructs from the subdisciplines of biomechanics and motor control in the bio-behavioral sciences. At the same time, we have attempted to identify the theoretical underpinnings of control-systems engineering that are most relevant to control by human beings. We believe that these underpinnings are implicit in the assumptions that cut across diverse methods in control-systems engineering, especially the various methods associated with "nonlinear control", "fuzzy control," and "adaptive control" in engineering. Our methods are based on these theoretical foundations rather than on the mathematical formalisms that are associated with particular methods in control-systems engineering. The most important aspects of the human-environment interaction in our investigation of mass handling are the functional consequences that body configuration and stability have for the pick up of information or the achievement of overt goals. It follows that an essential characteristic of postural behavior is the effective maintenance of the orientation and stability of the sensory and motor "platforms" (e.g., head or shoulders) over variations in the human, the environment and the task. This general skill suggests that individuals should be sensitive to the functional consequences of body configuration and stability. In other words, individuals should perceive the relation between configuration, stability, and performance so that they can adaptively control their interaction with the surroundings. Human-environment interactions constitute robust systems in that individuals can maintain the stability of such interactions over uncertainty about and variations in the dynamics of the interaction. Robust interactions allow individuals to adopt orientations and configurations that are not optimal with respect to purely energetic criteria. Individuals can tolerate variation in postural states, and such variation can serve an important function in adaptive systems. Postural variability generates stimulation which is "textured" by the dynamics of the human-environment system. The texture or structure in stimulation provides information about variation in dynamics, and such information can be sufficient to guide adaption in control strategies. Our method were designed to measure informative patterns of movement variability.

McDonald, P. V.↗

Some Behavioral Effects of Exposure to Low Doses of Fe-56 Particles

Future missions in space (such as a mission to Mars) will involve long-term travel beyond the magnetic field of the Earth. As a result, astronauts will be exposed to radiation qualities and doses that differ from those experienced in low earth orbit, including exposure to heavy particles, such as Fe-56, which are a component of cosmic rays. Although the hazards of exposure to heavy particles are often minimized, they can affect neural functioning, and as a consequence, behavior. Unless the effects of exposure to cosmic rays can somehow be reduced, their effects on the brain throughout long duration flights could be disastrous. In the extreme case, it is possible that the effects of cosmic rays on space travelers could result in symptomatology resembling that of Alzheimer's or Parkinson's diseases or of advancing age, including significant cognitive and/or motor impairments. Because successful operations in space depend in part on the performance capabilities of astronauts, such impairments could jeopardize their ability to satisfy mission requirements, as well as have long-term consequences on the health of astronauts. As such, understanding the nature and extent of this risk may be vital to the effective performance and possibly the survival of astronauts during future missions in space.

Rabin, Bernard M.↗

Mission Study and Optics Development Support for Constellation X

This document is the Final Report for NASA Cooperative Agreement NCC5-268 between NASA Goddard Space Flight Center (GSFC) and the Smithsonian Astrophysical Observatory (SAO). The Agreement is entitled "Constellation X-ray Mission Study and Optics Development." The report is required by the terms of the Agreement. There were four modifications to the Agreement. The period of performance was from February 1, 1998 through March 31, 1999. The report summarizes the main areas of SAO activity. Other than the design and analysis related to the SXT Mirror (see Section 4.0), most of the work was carried out jointly with personnel from GSFC and Marshall Space Flight Center (MSFC). Consequently, we do not mean to imply that such activities were carried out exclusively by SAO. Rather, we have tried to describe the SAO participation in these efforts.The report summarizes the main areas of SAO activity. Other than the design and analysis related to the SXT Mirror (see Section 4.0), most of the work was carried out jointly with personnel from GSFC and Marshall Space Flight Center (MSFC). Consequently, we do not mean to imply that such activities were carried out exclusively by SAO. Rather, we have tried to describe the SAO participation in these efforts. As is appropriate to a Cooperative Agreement, SAO worked with GSFC in an integrated team mode. SAO was involved in the mission management, technology development, and mission definition. The organization is shown in Figure 1. While overall management responsibility resided with GSFC, scientific lead and subordinate responsibilities were shared between GSFC and SAO.

Tananbaum, H.↗

Aeolian Sand Transport in the Planetary Context: Respective Roles of Aerodynamic and Bed-Dilatancy Thresholds

The traditional view of aeolian sand transport generally estimates flux from the perspective of aerodynamic forces creating the airborne grain population, although it has been recognized that "reptation" causes a significant part of the total airborne flux; reptation involves both ballistic injection of grains into the air stream by the impact of saltating grains as well as the "nudging" of surface grains into a creeping motion. Whilst aerodynamic forces may initiate sand motion, it is proposed here that within a fully-matured grain cloud, flux is actually governed by two thresholds: an aerodynamic threshold, and a bed-dilatancy threshold. It is the latter which controls the reptation population, and its significance increases proportionally with transport energy. Because we only have experience with terrestrial sand transport, extrapolations of aeolian theory to Mars and Venus have adjusted only the aerodynamic factor, taking gravitational forces and atmospheric density as the prime variables in the aerodynamic equations, but neglecting reptation. The basis for our perspective on the importance of reptation and bed dilatancy is a set of experiments that were designed to simulate sand transport across the surface of a martian dune. Using a modified sporting crossbow in which a sand-impelling sabot replaced the bolt-firing mechanism, individual grains of sand were fired at loose sand targets with glancing angles typical of saltation impact; grains were projected at about 80 m/s to simulate velocities commensurate with those predicted for extreme martian aeolian conditions. The sabot impelling method permitted study of individual impacts without the masking effect of bed mobilization encountered in wind-tunnel studies. At these martian impact velocities, grains produced small craters formed by the ejection of several hundred grains from the bed. Unexpectedly, the craters were not elongated, despite glancing impact; the craters were very close to circular in planform. High-speed photography showed them to grow in both diameter and depth after the impactor had ricochetted from the crater site. The delayed response of the bed was "explosive" in nature, and created a miniature ejecta curtain spreading upward and outward for many centimeters for impact of 100-300 micron-diameter grains into similar material. Elastic energy deposited in the bed by the impacting grain creates a subsurface stress regime or "quasi-Boussinesq" compression field. Elastic recovery of the bed occurs by dilatancy; shear stresses suddenly convert the grains from closed to open packing, and grains are consequently able to eject themselves forcefully from the impact site. Random jostling of the grains causes radial homogenization of stress vectors and a resulting circular crater. There is a great temptation to draw parallels with cratering produced by meteorite impacts, but a rigorous search for common modelling ground between the two phenomena has not been conducted at this time. For every impact of an aerodynamically energized grain, there are several hundred grains ejected into the wind for the high-energy transport that might occur on Mars. Many of these grains will themselves become subject to the boundary layer's aerodynamic lift forces (their motion will not immediately die and add to the creep population), and these grains will become indistinguishable from those lifted entirely by aerodynamic forces. As each grain impacts the bed, it will eject even more grains into the flow. A cascading effect will take place, but because it must be finite in its growth, damping will occur as the number of grains set in motion causes mid-air collisions that prevent much of the impact energy from reaching the surface of the bed -thus creating a dynamic equilibrium in a high-density saltation cloud. It is apparent that for a given impact energy, the stress field permits a smaller volume of grains to convert to open packing as the size of the bed grains increases, or as the energy of the "percussive" grain decreases (by decrease in velocity or mass). Thus, the mass of the "repercussive" grain population that is ejected from the impact site becomes a function of the scale of the stress field in relation to the scale of the bed material (self-similarity being applicable if both bed size and energy are simultaneously adjusted). In other words, in a very high energy aeolian system where an aerodynamically raised grain can ballistically raise many more grains, the amount of material lifted into the wind becomes largely a function of a dilatancy threshold. If this threshold is exceeded, grains are repercussively injected into the saltation cloud. The "dilatancy threshold" may be defined in terms of the saltation percussive force required to convert the bed, through elastic response, from a closed to an open packing system. If open packing cannot be created, the grains cannot escape from the impact site, even though the elastic deformation and percussive force may be able to reorganize the grains with respect to one another. As the crossbow experiments showed, for an ever-increasing bed grain size, a point is reached when no material can be moved because the energy of the percussive grain is insufficient to dilate the relatively coarse bed. Although this seems to be stating the obvious -- that too little energy will not cause the bed to splash -- the consequences of exceeding the "splash threshold" by dilatancy are not so obvious for high-energy aeolian transport. It is noted that the force required to elastically dilate the bed has to overcome Coulombic grain attractions such as dipole-dipole coupling, dielectric, monopole, contact-induced dipole attractions, van der Waals forces, molecular monolayer capillary forces, as well as the mechanical interlocking frictional resistance of the grains. On Mars, it is predicted that the dilatancy threshold may be the prime control of grain flux. Additional information is contained in the original.

Marshall, J. R.↗

Radiation Effects: Core Project

The risks to personnel in space from the naturally occurring radiations are generally considered to be one of the most serious limitations to human space missions, as noted in two recent reports of the National Research Council/National Academy of Sciences. The Core Project of the Radiation Effects Team for the National Space Biomedical Research Institute is the consequences of radiations in space in order to develop countermeasure, both physical and pharmaceutical, to reduce the risks of cancer and other diseases associated with such exposures. During interplanetary missions, personnel in space will be exposed to galactic cosmic rays, including high-energy protons and energetic ions with atomic masses of iron or higher. In addition, solar events will produce radiation fields of high intensity for short but irregular durations. The level of intensity of these radiations is considerably higher than that on Earth's surface, and the biological risks to astronauts is consequently increased, including increased risks of carcinogenesis and other diseases. This group is examining the risk of cancers resulting from low-dose, low-dose rate exposures of model systems to photons, protons, and iron by using ground-based accelerators which are capable of producing beams of protons, iron, and other heavy ions at energies comparable to those encountered in space. They have begun the first series of experiments using a 1-GeV iron beam at the Brookhaven National Laboratory and 250-MeV protons at Loma Linda University Medical Center's proton synchrotron facility. As part of these studies, this group will be investigating the potential for the pharmaceutical, Tamoxifen, to reduce the risk of breast cancer in astronauts exposed to the level of doses and particle types expected in space. Theoretical studies are being carried out in a collaboration between scientists at NASA's Johnson Space Center and Johns Hopkins University in parallel with the experimental program have provided methods and predictions which are being used to assess the levels of risks to be encountered and to evaluate appropriate strategies for countermeasures. Although the work in this project is primarily directed toward problems associated with space travel, the problem of protracted exposures to low-levels of radiation is one of national interest in our energy and defense programs, and the results may suggest new paradigms for addressing such risks.

Dicello, John F.↗

Lunar Meteorites and Implications for Compositional Remote Sensing of the Lunar Surface

Lunar meteorites (LMs) are rocks found on Earth that were ejected from the Moon by impact of an asteroidal meteoroid. Three factors make the LMs important to remote-sensing studies: (1) Most are breccias composed of regolith or fragmental material; (2) all are rocks that resided (or breccias composed of material that resided) in the upper few meters of the Moon prior to launch and (3) most apparently come from areas distant from the Apollo sites. How Many Lunar Locations? At this writing (June 1999), there are 18 known lunar meteorite specimens. When unambiguous cases of terrestrial pairing are considered, the number of actual LMs reduces to 13. (Terrestrial pairing is when a single piece of lunar rock entered Earth's atmosphere, but multiple fragments were produced because the meteoroid broke apart on entry, upon hitting the ground or ice, or while being transported through the ice.) We have no reason to believe that LMs preferentially derive from any specific region(s) of the Moon; i.e., we believe that they are samples from random locations. However, we do not know how many different locations are represented by the LMs; mathematically, it could be as few as 1 or as many as 13. The actual maximum is < 13 because in some cases a single impact appears to have yielded more than one LM. Yamato 793169 and Asuka 881757 are considered "source-crater paired" or "launch paired" because they are compositionally and petrographically similar to each other and distinct from the others, and both have similar cosmic-ray exposure (CRE) histories. The same can be said of QUE 94281 and Y 793274. Thus the 13 meteorites probably represent a maximum of 11 locations on the Moon. The minimum number of likely source craters is debated and in flux as new data for different isotopic systems are obtained. Conservatively, considering CRE data only, a minimum of about 5 impacts is required. Compositional and petrographic data offer only probabilistic constraints. An extreme, but not unreasonable viewpoint, is that such data offer no constraint. For example, if one were to cut up the Apollo 17 landing site (which was selected for its diversity) into softball-sized pieces, some of those pieces (e.g., sample 70135) would be crystalline mare basalts like Y 793169 whereas others (e.g., sample 73131 would be feldspathic regolith breccias like MAC 88104/ 88105. However, nature is not so devious. Warren argues that LMs come from craters of only a few kilometers in diameter. If so, even though CRE data allow, for example, that ALHA 81005 and Y 791197) were launched simultaneously from the same crater, the probability is nevertheless low because the two meteorites are compositionally and mineralogically distinct. Thus, within the allowed range (5-11) for the number of locations represented by the LMs, values at the high end of the range are probably more likely. Mare Meteorites: Three LMs consist almost entirely of mare basalt. Two, Y 793169 and Asuka 881757, are unbrecciated, low-Ti, crystalline rocks that are compositionally and mineralogically similar (but not identical) to each other; they probably derive from a single lunar-mare location. The third, EET 87521/96008, is a fragmental breccia consisting predominantly of VLT mare basalt. Thus, these LMs probably represent only two lunar mare locations. The basaltic LMs have mineral and bulk compositions distinct from Apollo mare basalts. The petrography of Calcalong Creek has not been described in detail, but compositionally it is unique in that it corresponds to a mixture (breccia) of about one-half feldspathic material (i.e., the mean composition of the feldspathic lunar meteorites, below), one-fourth KREEP norite, one-fourth VLT mare basalt (like EET 87521), and 1% CI chondrite. With 4 micro g/g Th and correspondingly high concentrations of other incompatible elements, it is the only lunar meteorite that is likely to have come from within the Procellarum KREEP Terrane (PKT). Yamato 793274 and QUE 94281 are together distinct in being fragmental breccias containing subequal parts of feldspathic highland material and VLT mare basalt. Jolliff et al. estimate a mare to highland ratio of 54:46 for QUE 94281 and 62:38 for Y 793274; this difference is well within the range observed for soils collected only centimeters apart (in cores) at interface site like Apollo 15 and 17 [11]. Although the two meteorites were found on opposite sides of Antarctica, they are probably launch-paired. The strongest evidence is that the pyroclastic glass spherules that occur in both are of two compositional groups and the two groups are essentially the same in both meteorites. Yamato 791197 is nominally a feldspathic lunar meteorite (below), but among FLMs, it probably contains the highest abundance of clasts and glasses of mare derivation. As a consequence, its composition is at the high-Fe, low-Mg end of the range for FLMs and is not included in the FLM average of Table 1. Its composition is consistent with about 10% mare-derived material. Similarly, the two small (Y 82) pieces of Y 82192/82193186032 are more mafic than the large (Y 86) piece, probably as a result of about 7% mare-derived material. All Apollo missions went to areas in or near the PKT, and, consequently, all Apollo regolith samples are contaminated with Th-rich material from the PKT. At the nominally "typical" highland site, Apollo 16, about 30% of the regolith (<1-mm fines) is Th-rich ejecta from the Imbrium impact and about 6% is mare material probably derived from mare basins. Thus Apollo 16 regolith is not typical of the highlands. Among Apollo rocks, the compositions of the FLMs correspond most closely to the feldspathic granulitic breccias of Apollo 16 and 17. (Additional information is contained in original)

Korotev, R. L.↗

Atmospheric Effects of Biomass Burning

Biomass fires are both natural and anthropogenic in origin. The natural trigger is lightning, which leads to mid- and high-latitude fires and episodes of smoke and pollution associated with them. Lightning is also prominent in tropical regions when the dry season gives way to the wet season and lightning in convective systems ignites dry vegetation. Atmospheric consequences of biomass fires are complex. When considering the impacts of fires for a given ecosystem, inputs of fires must be compared to other process that emit trace gases and particles into the atmosphere. Other processes include industrial activity, fires for household purposes and biogenic sources which may themselves interact with fires. That is, fires may promote or restrict biogenic processes. Several books have presented various aspects of fire interactions with atmospheric chemistry and a cross-disciplinary review of a 1992 fire-oriented experiment appears in SAFARI: The Role of southern African Fires in Atmospheric and Ecological Environments. The IGAC/BIBEX core activity (see acronyms at end of Chapter) has sponsored field campaigns that integrate multiple aspects of fires ground-based measurements with an ecological perspective, atmospheric measurements with chemical and meteorological components, and remote sensing. This Chapter presents two aspects of biomass fires and the environment. Namely, the relationship between biomass burning and ozone is described, starting with a brief description of the chemical reactions involved and illustrative measurements and interpretation. Second, because of the need to observe biomass burning and its consequences globally, a summary of remote sensing approaches to the study of fires and trace gases is given. Examples in this Chapter are restricted to tropical burning for matters of brevity and because most burning activity globally is within this zone.

Thompson, Anne M.↗

A Comprehensive Reliability Methodology for Assessing Risk of Reusing Failed Hardware Without Corrective Actions with and Without Redundancy

This paper deals with the development of a reliability methodology to assess the consequences of using hardware, without failure analysis or corrective action, that has previously demonstrated that it did not perform per specification. The subject of this paper arose from the need to provide a detailed probabilistic analysis to calculate the change in probability of failures with respect to the base or non-failed hardware. The methodology used for the analysis is primarily based on principles of Monte Carlo simulation. The random variables in the analysis are: Maximum Time of Operation (MTO) and operation Time of each Unit (OTU) The failure of a unit is considered to happen if (OTU) is less than MTO for the Normal Operational Period (NOP) in which this unit is used. NOP as a whole uses a total of 4 units. Two cases are considered. in the first specialized scenario, the failure of any operation or system failure is considered to happen if any of the units used during the NOP fail. in the second specialized scenario, the failure of any operation or system failure is considered to happen only if any two of the units used during the MOP fail together. The probability of failure of the units and the system as a whole is determined for 3 kinds of systems - Perfect System, Imperfect System 1 and Imperfect System 2. in a Perfect System, the operation time of the failed unit is the same as that of the MTO. In an Imperfect System 1, the operation time of the failed unit is assumed as 1 percent of the MTO. In an Imperfect System 2, the operation time of the failed unit is assumed as zero. in addition, simulated operation time of failed units is assumed as 10 percent of the corresponding units before zero value. Monte Carlo simulation analysis is used for this study. Necessary software has been developed as part of this study to perform the reliability calculations. The results of the analysis showed that the predicted change in failure probability (P(sub F)) for the previously failed units is as high as 49 percent above the baseline (perfect system) for the worst case. The predicted change in system P(sub F) for the previously failed units is as high as 36% for single unit failure without any redundancy. For redundant systems, with dual unit failure, the predicted change in P(sub F) for the previously failed units is as high as 16%. These results will help management to make decisions regarding the consequences of using previously failed units without adequate failure analysis or corrective action.

Putcha, Chandra S.↗

The Earth Science Vision

NASA's Earth Science Enterprise's long range vision is to enable the development of a national proactive environmental predictive capability through targeted scientific research and technological innovation. Proactive environmental prediction means the prediction of environmental events and their secondary consequences. These consequences range from disasters and disease outbreak to improved food production and reduced transportation, energy and insurance costs. The economic advantage of this predictive capability will greatly outweigh the cost of development. Developing this predictive capability requires a greatly improved understanding of the earth system and the interaction of the various components of that system. It also requires a change in our approach to gathering data about the earth and a change in our current methodology in processing that data including its delivery to the customers. And, most importantly, it requires a renewed partnership between NASA and its sister agencies. We identify six application themes that summarize the potential of proactive environmental prediction. We also identify four technology themes that articulate our approach to implementing proactive environmental prediction.

Schoeberl, Mark↗

Solar Spicules: A Review of Recent Models and Targets for Future Observations

Since their discovery over 100 years ago, there have been many suggestions for the origin and development of solar spicules. Because the velocities of spicules are comparable to the sound and Alfven speeds of the low chromosphere, linear theory cannot fully describe them. Consequently, detailed tests of theoretical ideas had to await the development of computing power that only became available during the 1970s. This work reviews theories for spicules and spicule-like features over approximately the past 25 years, with an emphasis on the models based on nonlinear numerical simulations. These models have given us physical insight into wave propagation in the solar atmosphere, and have helped elucidate how such waves, and associated shock waves, may be capable of creating motions and structures on magnetic flux tubes in the lower solar atmosphere. So far, however, it has been difficult to reproduce the most- commonly -quoted parameters for spicules with these models, using what appears to be the most suitable input parameters. A key impediment to developing satisfactory models has been the lack of reliable observational information, which is a consequence of the small angular size and transient lifetime of spicules. I close with a list of key observational questions to be addressed with space-based satellites, such as the currently operating TRACE satellite, and especially the upcoming Solar-B mission. Answers to these questions will help determine which, if any, of the current models correctly explains spicules.

Sterling, Alphonse C.↗

Comparative Magma Oceanography

The question of whether the Earth ever passed through a magma ocean stage is of considerable interest. Geochemical evidence strongly suggests that the Moon had a magma ocean and the evidence is mounting that the same was true for Mars. Analyses of martian (SNC) meteorites have yielded insights into the differentiation history of Mars, and consequently, it is interesting to compare that planet to the Earth. Three primary features of Mars contrast strongly to those of the Earth: (i) the extremely ancient ages of the martian core, mantle, and crust (about 4.55 b.y.); (ii) the highly depleted nature of the martian mantle; and (iii) the extreme ranges of Nd isotopic compositions that arise within the crust and depleted mantle. The easiest way to explain the ages and diverse isotopic compositions of martian basalts is to postulate that Mars had an early magma ocean. Cumulates of this magma ocean were later remelted to form the SNC meteorite suite and some of these melts assimilated crustal materials enriched in incompatible elements. The REE pattern of the crust assimilated by these SNC magmas was LREE enriched. If this pattern is typical of the crust as a whole, the martian crust is probably similar in composition to melts generated by small degrees of partial melting (about 5%) of a primitive source. Higher degrees of partial melting would cause the crustal LREE pattern to be essentially flat. In the context of a magma ocean model, where large degrees of partial melting presumably prevailed, the crust would have to be dominated by late-stage, LREE-enriched residual liquids. Regardless of the exact physical setting, Nd and W isotopic evidence indicates that martian geochemical reservoirs must have formed early and that they have not been efficiently remixed since. The important point is that in both the Moon and Mars we see evidence of a magma ocean phase and that we recognize it as such. Several lines of theoretical inference point to an early Earth that was also hot and, perhaps, mostly molten. The Giant Impact hypothesis for the origin of the Moon offers a tremendous input of thermal energy and the same could be true for core formation. And current solar system models favor the formation of a limited number of large (about 1000 km) planetesimals that, upon accreting to Earth, would cause great heating, being lesser versions of the Giant Impact. Several lines of geochemical evidence do not favor this hot early Earth scenario. (i) Terrestrial man-tle xenoliths are sometimes nearly chondritic in their major element compositions, suggesting that these rocks have never been much molten. Large degrees of partial melting probably promote differentiation rather than homogenization. (ii) Unlike the case of Mars, the continental crust probably did not form as a highly fractionated residual liquid from a magma ocean (about 99% crystallization), but, rather, formed in multiple steps. [The simplest model for the formation of continental crust is complicated: (a) about 10% melting of a primitive mantle, making basalt; (b) hydrothermal alteration of that basalt, converting it to greenstone; and (c) 10% partial melting of that greenstone, producing tonalite.] This model is reinforced by the recent observation from old (about 4.1 b.y.) zircons that the early crust formed from an undepleted mantle having a chondritic Lu/Hf ratio. (iii) If the mantle were once differentiated by a magma ocean, the mantle xenolith suite requires that it subsequently be homogenized. The Os isotopic compositions of fertile spinel lherzolites place constraints on the timing of that homogenization. The Os isotopic composition of spinel lherzolites approaches that of chondrites and correlates with elements such as Lu and Al. As Lu and Al concentrations approach those of the primitive mantle, Os isotopic compositions approach chondritic. The Re and Os in these xenoliths were probably added as a late veneer. Thus, the mantle that received the late veneer must have been nearly chondritic in terms of its major elements (excluding Fe). If the mantle that the veneer was mixed into was not al-ready homogenized, then Os isotopes should not correlate with incompatible elements such as Al. Consequently, either early differentiation of the mantle did not occur or the homogenization of this differentiation must have occurred before the late veneer was added. The timing of the late veneer is itself uncertain but presumably postdated core formation at about 4.45 b.y. and did not postdate the 3.8-3.9 b.y. late bombardment of the Moon. This timing based on siderophile elements is consistent with the Hf isotopic evidence cited above. If the Earth, Moon and Mars had magma oceans, the Earth subsequently rehomogenized whereas the Moon and Mars did not. The simplest solution to this observation is that homogenization of igneous differentiates was never necessary on Earth, either because the hypothetical magma ocean never occurred or because this event did not produce mantle differentiation.

Jones, J. H.↗

Interpreting Assemblages with Titanite (Sphene): It Does not have to be Greek to You.

Assemblages with titanite, pyroxene(s), olivine, ilmenite, magnetite, and quartz can be used to constrain the intensive and compositional variables that operate during crystallization. Such assemblages are relatively rare in metamorphic rocks, but they are more common in igneous rocks and more frequently reported in plutonic than volcanic rocks. We used the program QUILF, enhanced with thermodynamic data for titanite, to compute stable reactions among titanite (CaTiOSiO4), Fe-Mg-Ti ilmenite and magnetite (hereafter ilmenite and magnetite), Ca-Mg-Fe pyroxenes and olivine, and quartz, and to evaluate some of the factors that control titanite stability. Calculations at 1, 3, and 6 Kbar and 650, 850, 1100 0 C, in the system CaO - MgO - FeO Fe2O3 - TiO2 - SiO2, suggest that the reactions: Augitc + Ilmenite = Titanite + Magnetite + Quartz and Augite + Ilmenite + Quartz = Titanite + Orthopyroxene, impose well defined fugacity of O2, alpha(sub SiO2), , and compositional restrictions to the assemblages: (1) Titanite + Magnetite + Quartz, (2) Titanite + Orthopyroxene, (3) Augite + Ilmenite, and consequently titanite stability. From our calculations in this system we can draw the following general conclusions: (1) The assemblage Titanite + Magnetite + Quartz is always a good indicator of relatively high fugacity of O2, and it is likely more common in relatively iron-rich bulk compositions and for decreasing temperature and pressure conditions. (2) At high temperatures (>= 650 C) titanite is not stable in quartz-saturated rocks that contain the assemblage Orthopyroxene + Augite + Ilmenite + Magnetite. (3) In quartz-saturated rocks the coexistence of titanite and magnetite with either orthopyroxene or olivine requires a confluence of conditions relating bulk composition, fugacity of O2, and slow cooling. Thus, such assemblages must be rare. (4) Regardless of T and fugacity of O2 conditions, and bulk-composition, titanite is not stable in quartz-absent rocks that contain Olivine + Orthopyroxene + Augite + Ilmenite + Magnetite. Decreasing temperature and pressure conditions appear to favor titanite crystallization, thus, it is not unsurprising that titanite is frequently observed in slowly cooled rocks, albeit, in association with amphibole. We argue that the titanite + amphibole association is likely favored by high water activity, regardless of oxygen fugacity. Because water activity increases during crystallization of a pluton, the association titanite + amphibole, and consequently titanite, is likely to be more common in plutonic rocks than in volcanic rocks.

Xirouchakis, Dimitrios M.↗