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At least 559 records · Page 31

Phyllosilicate Decomposition on Bennu Due to Prolonged Surface Exposure

The Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) mission to carbonaceous asteroid (101955) Bennu performed detailed mapping with a suite of instruments to characterize the composition and geology of its surface. Here we use data from the OSIRIS-REx Thermal Emission Spectrometer (OTES) instrument to investigate the relationship of OTES-derived spectral indices to other derived data products from OTES, the OSIRIS-REx Camera Suite (OCAMS), and the OSIRIS-REx Visible and InfraRed Spectrometer (OVIRS) at global and local scales. We quantitatively confirm that high values of the OTES silicate stretching slope (from ∼10 to ∼12 μm) in midday spectra that are indicative of thin and/or patchy dust cover are strongly associated with low thermal inertia (high porosity), low albedo boulders on Bennu. These high porosity boulders have brecciated textures with embedded clasts that likely originated on Bennu's parent body or during its disruption. The high porosity of these boulders is a key factor in the local production of the dust or its entrapment, as some large, brecciated boulders with a lower porosity have little evidence of dust. A second OTES spectral parameter, the silicate bending band depth near 22.7 μm applied to early evening spectra, is not correlated to thermal inertia, but is weakly to strongly correlated to albedo, OVIRS-derived 1.05 μm and 2.74 μm band depths, OVIRS-derived hydrogen abundance, and modeled nanophase troilite abundance. In several regions on Bennu there is a strong spatial relationship between these parameters, whereby areas with shallower silicate bending bands also have shallower 1.05 μm and 2.74 μm bands and lower albedo with higher nanophase troilite abundances. These correlations, combined with analysis of the silicate bending band in laboratory experiments of space weathered and mildly heated carbonaceous chondrites, suggests that decreased silicate bending band depths signify decomposition of phyllosilicates, likely Fe-bearing, due to space weathering or mild heating (<600 °C) via solar radiation during Bennu's time in near-Earth space. There is a strong association of larger silicate bending band depths in areas dominated by small rocks and unresolved material and in areas with small (≤ 25 m) craters identified as the spectrally reddest on Bennu, suggesting that this material has been more recently exposed due to impact and/or mass wasting processes. The shallowest silicate bending depths are associated with larger rocks and boulders that appear to have the longest surface exposure history, although there is band depth variation among them suggesting either initial composition variation that resulted in different responses to space weathering or heating, or varied exposure history of individual boulders themselves. We predict that any grains returned from Bennu with a significant surface exposure history will be characterized by shallower 22.7 μm, 1.05 μm and 2.7 μm band depths and increased sulfide (troilite) abundance, as well as textural and chemical evidence for phyllosilicate dehydration.

Asteroids, surfaces↗

Cape Hatteras Ecological Conservation: Delineating Shoreline and Mapping Change Along the Cape Hatteras National Seashore for Coastline Management and Transportation Corridor Adaptation Strategies

The National Park Service at Cape Hatteras National Seashore works to protect North Carolina’s Outer Banks where frequent storms bring heavy winds and flooding, leading to overwash events on the main highway, North Carolina Highway 12. Shorelines are susceptible to erosion directly affecting transportation and housing infrastructures. Storm events can disrupt transportation on NC-12 and ferry service from Ocracoke Island to Hatteras Island, leaving inhabitants stranded on Ocracoke Island for indefinite amounts of time. The National Park Service’s current decision-making practices involve mitigating infrastructure damage by enlisting the help of North Carolina’s Department of Transportation and finding ways to relocate this infrastructure, as well as dredging and sediment placement that support beach nourishment efforts. Our NASA DEVELOP team partnered with the National Park Service to explore the use of optical data to delineate shoreline and map coastline change from 2014 to 2024. We used Earth observations collected by Landsat 8 Operational Land Imager, Landsat 9 Operational Land Imager-2, and Sentinel-2 MultiSpectral instrument to support decision-making related to prioritizing strategic planning for transportation corridor adaptations including potential relocation of infrastructure, and beach nourishment efforts. We derived coastline maps by consolidating images from each year to create composite images for winter and summer coastline seasonal oscillation patterns. The results highlight shoreline loss over the ~10-year study period, and the difference in shoreline inundation in the winter and summer seasons. These observations create a better understanding of successful mitigation efforts and allow the National Park Service to continue to focus on plans for infrastructure updates.

Ella Haugen↗

Geologic exploration: The contribution of LANDSAT-4 thematic mapper data

The major advantages of the TM data over that of MSS systems are increased spatial resolution and a greater number of narrow, strategically placed spectral bands. The 30 meter pixel size permits finer definition of ground features and improves reliability of the photointerpretation of geologic structure. The value of the spatial data increases relative to the value of the spectral data as soil and vegetation cover increase. In arid areas with good exposure, it is possible with careful digital processing and some inventive color compositing to produce enough spectral differentiation of rock types and thereby produce facsimiles of standard geologic maps with a minimum of field work or reference to existing maps. Hue-saturation value images are compared with geological maps of Death Valley, California, the Big Horn/Wind River Basin of Wyoming, the area around Cement, Oklahoma, and Detroit. False color composites of the Ontario region are also examined.

Everett, J. R.↗

Distribution of materials excavated by the lunar crater Bullialdus and implications for the geologic history of the Nubium region

Previous spectroscopic studies of the lunar crater Bullialdus, located in the Nubium Basin, indicated an unusual stratigraphy of two gabbroic layers overlying a noritic unit. The possible existence of a layered mafic pluton at Bullialdus was suggested. To investigate the geologic context with more detailed spatial information, charge-coupled device (CCD) images of Bullialdus were obtained using eight filters. A linear mixing model was used to investigate the fractional abundances of spectral end-members chosen from within the multispectral image. Since the reflectance properties of lunar materials over this wavelength range are sensitive to variations in composition and soil maturity, fractional abundance images were used to create a new geologic map of the crater. The spatial relationships of the surface materials confirm the previously inferred stratigraphy, and further reveal the central peaks to exhibit two distinct compositional units: noritic anorthosite and anorthositic norite. Three models for the origin of the observed stratigraphy are considered: Bullialdus has excavated stratigraphic units containing (1) early mare basalt overlying anorthositic-noritic crustal material, (2) part of a layered mafic pluton, and/or (3) part of an impact melt sheet formed by the Nubium Basin impact event.

Tompkins, Stefanie↗

Detection and mapping of mineralized areas in the Cortez-Uinta Belt, Utah-Nevada using computer-enhanced ERTS imagery

The author has identified the following significant results. The reflectance spectra of most hydrothermally altered rocks were characterized by broad ferric iron absorption bands short of 1.1 microns and a sharper hydroxyl band near 2.2 microns; maximum reflectance occurred near 1.6 microns. Their features became more prominent as albedo increased. The MSS color ratio composite images were the most effective and practical means for detecting and mapping limonitic rocks in areas having less than about 50 percent desert brush cover and less than 25-35 percent coniferous tree cover. Limonitic altered and unaltered rocks could not be distinguished in MSS color ratio composite images.

Rowan, L. C.↗

Mass spectral molecular mapping shows benefits of thermal evaporation in prelithiated silicon-based electrodes

Silicon based composites have become increasingly popular as potential anodes for lithium-ion batteries due to their large storage capacity and potential ability to generate batteries with energy densities greater than 350 Wh kg −1 . These anodes often see reduced initial columbic efficiency (ICE) due to disruptive volume expansionup to 300% and continuous solid electrolyte interphase (SEI) layer formation. Prelithiation, where an excess reservoir of Li is added to the electrode to compensate for irreversible SEI formation losses during their sample preparation, has proven to solve the issue of immediate capacity loss. Thermal evaporation is a prelithiation technique with limited studies on its effectiveness. In this study, time-of-flight secondary ion mass spectrometry (ToF-SIMS) is used to highlight the benefits of prelithiation via thermal evaporation. ToF-SIMS provides chemical mapping and spatial information in 2D and 3D visualizing the deposition of lithium, identifying Li x Si y alloy and Li x Si y O z silicate formation, and the distribution of lithium passivation into the electrodes. Passivation under different atmospheric conditions, such as inert Argon (Ar) and Ar/ carbon dioxide (CO 2 ), highlights the impact of the environment on the passivation effectiveness and formation of Li x Si y alloy and Li x Si y O z silicate. The ToF-SIMS molecular imaging and depth profiling results indicate that prelithiation via thermal evaporation effectively distributes lithium throughout the depth profile thickness of several hundred nanometers. It induces a greater degree of Li x Si y O z silicate formation over Li x Si y alloy. Our ToF-SIMS characterization results show the effectiveness of thermal evaporation in producing a more stable electrode and an electrode with an effective lithium reserve that can preserve its capacity.

Parker, Gabriel D. [Oak Ridge National Laboratory ↗

Identification, definition and mapping of terrestrial ecosystems in interior Alaska

The author has identified the following significant results. A reconstituted color infrared image covering the western Seward Peninsula was used for identifying vegetation types by simple visual examination. The image was taken by ERTS-1 approximately 1120 hours on August 1, 1972. Seven major colors were identified. Four of these were matched with four units on existing vegetation maps: bright red - shrub thicket; light gray-red - upland tundra; medium gray-red - coastal wet tundra; gray - alpine barrens. In the bright red color, two phases, violet and orange, were recognized and tentatively ascribed to differences in species composition in the shrub thicket type. The three colors which had no map unit equivalents were interpreted as follows: pink - grassland tundra; dark gray-red - burn scars; light orange-red - senescent vegetation. It was concluded that the image provides a considerable amount of information regarding the distribution of vegetation types, even at so simple a leval of analysis. It was also concluded that sequential imagery of this type could provide useful information on vegetation fires and phenologic events.

Anderson, J. H.↗

4 Vesta in Color: High Resolution Mapping from Dawn Framing Camera Images

Rotational surface variations on asteroid 4 Vesta have been known from ground-based and HST observations, and they have been interpreted as evidence of compositional diversity. NASA s Dawn mission entered orbit around Vesta on July 16, 2011 for a year-long global characterization. The framing cameras (FC) onboard the Dawn spacecraft will image the asteroid in one clear (broad) and seven narrow band filters covering the wavelength range between 0.4-1.0 microns. We present color mapping results from the Dawn FC observations of Vesta obtained during Survey orbit (approx.3000 km) and High-Altitude Mapping Orbit (HAMO) (approx.950 km). Our aim is to create global color maps of Vesta using multi spectral FC images to identify the spatial extent of compositional units and link them with other available data sets to extract the basic mineralogy. While the VIR spectrometer onboard Dawn has higher spectral resolution (864 channels) allowing precise mineralogical assessment of Vesta s surface, the FC has three times higher spatial resolution in any given orbital phase. In an effort to extract maximum information from FC data we have developed algorithms using laboratory spectra of pyroxenes and HED meteorites to derive parameters associated with the 1-micron absorption band wing. These parameters will help map the global distribution of compositionally related units on Vesta s surface. Interpretation of these units will involve the integration of FC and VIR data.

Reddy, V.↗

Remote sensing of evaporite mineral zonation in salt flats (salars)

Compositional zoning within Salar de Atacama and Salar de Llulliallaco has been mapped from Landsat Thematic Mapper (TM) data. The data were enhanced using decorrelation stretching of TM bands 7, 5, and 4, which were considered to possess the majority of the mineralogical information. The resulting 7, 5, 4 (red, green, blue) color composites provide excellent discrimination of evaporite mineral zones within the salar. The interpretation is supported by fieldwork at the Salar de Atacama and spectral considerations. A strong relationship between the mineralogy of a unit and surface roughness was observed in the field, hence there is potential for imaging radar to provide complementary zonal data.

Chapman, J. E.↗

Land use mapping and modelling for the Phoenix Quadrangle

The author has identified the following significant results. The mapping of generalized land use (level 1) from ERTS 1 images was shown to be feasible with better than 95% accuracy in the Phoenix quadrangle. The accuracy of level 2 mapping in urban areas is still a problem. Updating existing maps also proved to be feasible, especially in water categories and agricultural uses; however, expanding urban growth has presented with accuracy. ERTS 1 film images indicated where areas of change were occurring, thus aiding focusing-in for more detailed investigation. ERTS color composite transparencies provided a cost effective source of information for land use mapping of very large regions at small map scales.

Place, J. L.↗

Development of Multi-Sensor Global Cloud and Radiance Composites for Earth Radiation Budget Monitoring from DSCOVR

The Deep Space Climate Observatory (DSCOVR) enables analysis of the daytime Earth radiation budget via the onboard Earth Polychromatic Imaging Camera (EPIC) and National Institute of Standards and Technology Advanced Radiometer (NISTAR). Radiance observations and cloud property retrievals from low earth orbit and geostationary satellite imagers have to be co-located with EPIC pixels to provide scene identification in order to select anisotropic directional models needed to calculate shortwave and longwave fluxes. A new algorithm is proposed for optimal merging of selected radiances and cloud properties derived from multiple satellite imagers to obtain seamless global hourly composites at 5-kilometer resolution. An aggregated rating is employed to incorporate several factors and to select the best observation at the time nearest to the EPIC measurement. Spatial accuracy is improved using inverse mapping with gradient search during reprojection and bicubic interpolation for pixel resampling. The composite data are subsequently remapped into EPIC-view domain by convolving composite pixels with the EPIC point spread function (PSF) defined with a half-pixel accuracy. PSF-weighted average radiances and cloud properties are computed separately for each cloud phase. The algorithm has demonstrated contiguous global coverage for any requested time of day with a temporal lag of under 2 hours in over 95 percent of the globe.

Khlopenkov, Konstantin↗

Geochemical Mapping of 4 Vesta Begins

By December, the NASA Dawn spacecraft will have descended to a low altitude mapping orbit (LAMO), where the Gamma Ray and Neutron Detector (GRaND) will acquire global mapping data for up to four months. Measurements by GRaND will help answer elusive questions about how Vesta differentiated and the nature of processes that shaped Vesta s surface. The data will be analyzed to determine the abundances of Mg, Si, Fe, K, Th, and H at a spatial resolution of roughly 300 km full-width-at-half-maximum from a 465 km radius orbit. Thermal and fast neutron counting data will be analyzed to determine the neutron macroscopic absorption cross section and average atomic mass, providing constraints on additional elements, such as Ca and Al. GRaND will quantify the elemental composition of coarse spatial units identified by Dawn s Framing Camera (FC) and the Visible & Infrared Spectrometer (VIR). In addition, GRaND will map the mixing ratio of compositional end members selected from the howardite, eucrite and diogenite (HED) meteorites, determine the relative proportions of plagioclase and mafic minerals, and search for compositions that are absent or under-represented in the meteorite collection. While it is generally thought that Vesta s crust on a regional scale should be well-represented by linear mixing of HED whole-rock compositions, there are hints that Vesta may be more diverse than implied by this model. For example, the discovery of K-rich impact glasses in howardites suggests that K-rich rocks may be present on a portion of Vesta s surface, and the analysis of diogenites indicates considerable variability in the magmatic processes that formed them. The chemical composition of materials within Vesta s south polar structure may provide further clues to how it formed. An impact might have exposed mantle and lower crustal materials, which should have a distinctive compositional signature. We present the analysis of data acquired by GRaND from cruise through the descent to LAMO, including GRaND s sensitivity to different elements and geochemical processes.

Prettyman, Thomas H.↗

3D printed water-stable Cd-doped Cs 4 MnBi 2 Cl 12 /polylactic acid perovskite/polymer composites for high-flux X-ray scintillation

Stable and efficient X-ray scintillators are crucial for medical diagnostics, industrial, and defense applications. However, conventional scintillator technologies face a trade-off between stability, optimal performance, and sustainability. Herein, we introduce 3D-printed Cs 4 MnBi 2 Cl 12 (Pero1) and Cs 4 Cd 0.68 Mn 0.32 Bi 2 Cl 12 (Pero2) perovskite microcrystals embedded within a polylactic acid (PLA) polymer composite as X-ray scintillators, combining efficiency, stability, and sustainability. The orange luminescent perovskite powder phosphors exhibited poor water stability, which was successfully addressed through incorporation into PLA via filament extrusion and fused deposition modeling (FDM) 3D printing. The resulting composite films demonstrated remarkable water stability while maintaining uniform orange emission throughout the polymer matrix, as confirmed by 3D topography scanning and X-ray fluorescence mapping. Structural characterization revealed minimal chemical interaction between the perovskite and PLA matrix, with the composites retaining their crystalline properties. The PLA-Pero2 composite exhibited superior optical properties, with a photoluminescence quantum yield of 47%, nearly 17 times higher than that of PLA-Pero1 (2.8%), attributed to the effective suppression of non-radiative decay pathways through Cd 2+ doping. Under hard X-ray irradiation at synchrotron beamlines, both composites exhibited excellent radioluminescence, with emission peaks at 605 nm, a linear response across a wide X-ray flux range, and remarkable radiation stability, showing less than 3% intensity degradation after 600 seconds of continuous high-dose exposure. The PLA-Pero2 composite achieved a spatial resolution of 5 line pairs per millimeter and a contrast ratio of 0.255. These performance metrics, combined with the polymer's biodegradability and scalability through additive manufacturing, position PLA-based composites as a more sustainable alternative to conventional petroleum-based polymer scintillators for next-generation medical imaging, radiation monitoring, and industrial radiography applications.

3D Printing↗

Use of remote sensing technology for inventorying and planning utilization of land resources in South Dakota

A comprehensive land use planning process model is being developed in Meade County, South Dakota, using remote sensing technology. The proper role of remote sensing in the land use planning process is being determined by interaction of remote sensing specialists with local land use planners. The data that were collected by remote sensing techniques are as follows: (1) level I land use data interpreted at a scale of 1:250,000 from false color enlargement prints of ERTS-1 color composite transparencies; (2) detailed land use data interpreted at a scale of 1:24,000 from enlargement color prints of high altitude RB-57 photography; and (3) general soils map interpreted at a scale of 1:250,000 from false color enlargement prints of ERTS-1 color composite transparencies. In addition to use of imagery as an interpretation aid, the utility of using photographs as base maps was demonstrated.

Source record↗

Geologic Mapping along the Arabia Terra Dichotomy Boundary: Mawrth Vallis and Nili Fossae, Mars: Introductory Report

Geologic mapping studies at the 1:1M-scale will be used to characterize geologic processes that have shaped the highlands along the Arabia Terra dichotomy boundary. In particular, this mapping will evaluate the distribution, stratigraphic position, and lateral continuity of compositionally distinct outcrops in Mawrth Vallis and Nili Fossae as identified by spectral instruments currently in orbit. Placing these landscapes, their material units, structural features, and unique compositional outcrops into spatial and temporal context with the remainder of the Arabia Terra dichotomy boundary will provide the ability to: 1) further test original dichotomy formation hypotheses, 2) constrain ancient paleoenvironments and climate conditions, and 3) evaluate various fluvial-nival modification processes related to past and present volatile distribution and their putative reservoirs (aquifers, lakes and oceans, surface and ground ice) and the influences of nearby volcanic and tectonic features on hydrologic processes in these regions. The result will be two 1:1M scale geologic maps of twelve MTM quadrangles (Mawrth Vallis - 20022, 20017, 20012, 25022, 25017, and 25012; and Nili Fossae - 20287, 20282, 25287, 25282, 30287, 30282).

Bleamaster, Leslie F., III↗

Geologic Mapping along the Arabia Terra Dichotomy Boundary: Mawrth Vallis and Nili Fossae, Mars

Geologic mapping studies at the 1:1M-scale are being used to assess geologic materials and processes that shape the highlands along the Arabia Terra dichotomy boundary. In particular, this mapping will evaluate the distribution, stratigraphic position, and lateral continuity of compositionally distinct outcrops in Mawrth Vallis and Nili Fossae as identified by spectral instruments currently in orbit. Placing these landscapes, their material units, structural features, and unique compositional outcrops into spatial and temporal context with the remainder of the Arabia Terra dichotomy boundary may provide constraints on: 1) origin of the dichotomy boundary, 2) paleo-environments and climate conditions, and 3) various fluvial-nival modification processes related to past and present volatile distribution and their putative reservoirs (aquifers, lakes and oceans, surface and ground ice) and the influences of nearby volcanic and tectonic features on hydrologic processes in these regions. The results of this work will include two 1:1M scale geologic maps of twelve MTM quadrangles (Mawrth Vallis - 20022, 20017, 20012, 25022, 25017, and 25012; and Nili Fossae - 20287, 20282, 25287, 25282, 30287, 30282).

Bleamaster, Leslie F., III↗

Chemical Design of Pb-Free Relaxors for Giant Capacitive Energy Storage

Dielectric capacitors have captured substantial attention for advanced electrical and electronic systems. Developing dielectrics with high energy density and high storage efficiency is challenging owing to the high compositional diversity and the lack of general guidelines. Herein, we propose a map that captures the structural distortion ($\delta$) and tolerance factor (t) of perovskites to design Pb-free relaxors with extremely high capacitive energy storage. Our map shows how to select ferroelectric with large $\delta$ and paraelectric components to form relaxors with a t value close to 1 and thus obtaining eliminated hysteresis and large polarization under a high electric breakdown. Taking the Bi 0.5 Na 0.5 TiO 3 -based solid solution as an example, we demonstrate that composition-driven predominant order-disorder characteristic of local atomic polar displacements endows the relaxor with a slushlike structure and strong local polar fluctuations at several nanoscale. This leads to a giant recoverable energy density of 13.6 J cm -3 , along with an ultrahigh efficiency of 94%, which is far beyond the current performance boundary reported in Pb-free bulk ceramics. In conclusion, our work provides a solution through rational chemical design for obtaining Pb-free relaxors with outstanding energy-storage properties.

25 ENERGY STORAGE↗

Spectrophotometric studies of the photometric function, composition, and distribution of the surface materials of Mars.

Results of a program of mapping the surface of Mars carried out at a spatial resolution of 300 to 500 km during the 1969 opposition at IR (0.60 to 2.27 microns). Spectral albedo curves were obtained for 150 mare and desert areas. These curves fall into two well-defined and fairly uniform color-albedo groups corresponding to mare and desert units. The lack of areas with color and albedo that are distinctively different from those of these groups is interpreted as an indication that the surface of Mars consists of basically only two types of materials. Laboratory comparison data support a model of the Martian regolith that suggests that the general color of these surface units is due to a limonite stain coating the particles of lithic soils. Features in the spectral albedo curves at 1.6 and 2.1 microns are interpreted as being due to the H2O ice on the surface or in the Martian atmosphere.

Binder, A. B.↗