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At least 559 records · Page 31

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NASA NTRS1976

Investigation of structure-property relationships in systematic series of novel polymers

Solid state transitions in polymeric materials was associated with the onset of sub-molecular motions of the polymer chains. Although these were considered to be intramolecular in general, the local environment of the polymer molecule exerts a strong influence through, for example, the effects of crystallinity, polarity and diluents. The manner of specimen preparation and previous history also affect transitions. The transitions are considered to arise when sufficient free volume is available to permit the occurrence of these side chain and backbone reorientations. The glass transition is the principal transition of amorphous polymeric materials and is associated with the onset of long range segmental motion of the polymer backbone. The various types of shorter range motion occurring below the glass transition have been catalogued.

Gillham, J. K.↗

NASA NTRS1975

Molecular correlations with fracture in fibers and granular-filled composites

Results are presented for an experimental electron spin resonance study of chain-scission kinetics in oriented nylon fibers and in granular-filled elastomer composites. A reaction-rate molecular model is proposed as a tool to predict failure under various loadings. The model assumes a statistical distribution in stress on the polymeric chain structure. Interfacial failure in the filled composites is examined. Failure at the interface between the filler and the matrix may be largely adhesive or cohesive, depending on the magnitude of the interactive forces. It appears that the mechanical behavior of both single-component and filled composites depends on the composite nature of the structure. The electron spin resonance technique is shown to be suitable for experimental observation of phenomena directly related to atomic occurrences.

Devries, K. L.↗

NASA NTRS1976

Radical formation, chemical processing, and explosion of interstellar grains

The ultraviolet radiation in interstellar space is shown to create a sufficient steady-state density of free radicals in the grain mantle material consisting of oxygen, carbon, nitrogen, and hydrogen to satisfy the critical condition for initiation of chain reactions. The criterion for minimum critical particle size for maintaining the chain reaction is of the order of the larger grain sizes in a distribution satisfying the average extinction and polarization measures. The triggering of the explosion of interstellar grains leading to the ejection of complex interstellar molecules is shown to be most probable where the grains are largest and where radiation is suddenly introduced; i.e., in regions of new star formation. Similar conditions prevail at the boundaries between very dark clouds and H II regions. When the energy released by the chemical activity of the free radicals is inadequate to explode the grain, the resulting mantle material must consist of extremely large organic molecules which are much more resistant to the hostile environment of H II regions than the classical dirty-ice mantles made up of water, methane, and ammonia.

Greenberg, J. M.↗

NASA NTRS1975

Markov information sources

A regular Markov source is defined as the output of a deterministic, but noisy, channel driven by the state sequence of a regular finite-state Markov chain. The rate of such a source is the per letter uncertainty of its digits. The well-known result that the rate of a unifilar regular Markov source is easily calculable is demonstrated, where unifilarity means that the present state of the Markov chain and the next output of the deterministic channel uniquely determine the next state. At present, there is no known method to calculate the rate of a nonunifilar source. Two tentative approaches to this unsolved problem are given, namely source identical twins and the master-slave source, which appear to shed some light on the question of rate calculation for a nonunifilar source.

Massey, J. L.↗

NASA NTRS1977

A closed life-support system for space colonies

In 1975, a system design study was performed to examine a completely self-contained system for a permanent colony of 10,000 inhabitants in space. Fundamental to this design was the life support system. Since resupply from earth is prohibitive in transportation costs, it was decided to use a closed system with the initial supply of oxygen coming from processing of lunar ores, and the supply of carbon, nitrogen and hydrogen from earth. The problem of life support was treated starting with the nutritional and metabolic requirements for the human population, creating a food and water chain sufficient to supply these demands, adding the additional requirements for the animal and plant sources in the food chain, feeding back useful waste products, supplying water as required from different sources, and closing the loop by processing organic wastes into CO2. This concept places the burden of the system upon plants for O2 generation and waste processing the CO2 generation.

Johnson, R. D.↗

NASA NTRS1977

Topographic analysis of lunar secondary craters of Copernicus and implications

An analysis is conducted of the topography of lunar secondary craters and the associated herringbone pattern observed on lunar topophotomaps. The topography and the patterns are compared with those of crater pairs produced in the laboratory. The results are used to identify secondaries on the lunar uplands. The chain of craters that was selected for mapping and which is described is known to be a secondary impact crater chain produced by material ejected from Copernicus Crater because it lies on a well-developed ray system of Copernicus. Oberbeck et al. (1977) had hypothesized that most lunar areas exhibit more craters smaller than 50 km than are observed on Mars and Mercury because lower lunar gravity permitted more widespread distribution of secondaries for the moon. After removal of basin secondaries it is found that the surfaces of the lunar uplands are only sparsely populated by craters between 5 and 50 km. The lunar uplands appear then similar to the Mercurian terrain.

Oberbeck, V. R.↗

NASA NTRS1979

Low-level processing for real-time image analysis

A system that detects object outlines in television images in real time is described. A high-speed pipeline processor transforms the raw image into an edge map and a microprocessor, which is integrated into the system, clusters the edges, and represents them as chain codes. Image statistics, useful for higher level tasks such as pattern recognition, are computed by the microprocessor. Peak intensity and peak gradient values are extracted within a programmable window and are used for iris and focus control. The algorithms implemented in hardware and the pipeline processor architecture are described. The strategy for partitioning functions in the pipeline was chosen to make the implementation modular. The microprocessor interface allows flexible and adaptive control of the feature extraction process. The software algorithms for clustering edge segments, creating chain codes, and computing image statistics are also discussed. A strategy for real time image analysis that uses this system is given.

Eskenazi, R.↗

NASA NTRS1979

Computing region moments from boundary representations

The class of all possible formulas for computing arbitrary moments of a region from the region's boundary is derived. The selection of a particular formula depends on the choice of an independent parameter. Several choices of this parameter are explored for region boundaries approximated by polygons. The parameter choice that minimizes computation time for boundaries represented by chain code is derived. Algorithms are presented for computing arbitrary moments for a region from a polygonal approximation of its boundary and for computing low order moments from chain encoded boundaries.

Wilf, J. M.↗

NASA NTRS1979

Synthesis of perfluoroalkylether oxadiazole elastomers

A method for the simultaneous chain extension and crosslinking of perfluoroalkylethers which yields a thermally stable perfluoroalkylether oxadiazole elastomer crosslinked by trifunctional perfluoroalkylether-1,3,5-triazine is reported. In the preparation, hydroxylamine crystals prepared from hydroxylamine hydrochloride to which sodium butoxide had been added is mixed with perfluoroalkylether dinitrile to obtain the monomer, as the nitrile is converted to amidoxime. Monomers are heated at 140 to 200 C to form poly(perfluoroalkylether oxadiazole) with a 1,2,4-oxadiazole structure by a step-growth polymerization reaction. Simultaneous chain extension and crosslinking are observed to occur when the purified monomer is heated directly and when the remaining nitrile in the monomer is allowed to react with excess ammonia to form the corresponding amidine, which is then heated. Weight loss studies show the thermal stability of the perfluoroalkylether elastomer to be generally better than fluorosilicone or polyester elastomers, especially in air, indicating its potential usefulness for high-performance elastomeric applications.

Rosser, R. W.↗

NASA NTRS1982

Small Fixture Strains Composites for Environmental Tests

Fixture for long-term strain tests of composites is based on inexpensive tool for repairing motorcycle chains. (In normal use tool forces rivet out of chain element.) As modified for composite testing, tool has precision screw and shim. Qualification tests for graphite/epoxy composites are made less expensive by simple test fixture. Used in quantity, fixtures apply precisely similar loads to many samples.

Tervet, F. W.↗

NASA NTRS1981

Studies conducted as a search for physical mechanisms relating solar variability and the troposphere

Chains of causative mechanisms that are hypothesized to relate solar variability to the behavior of the Earth's lower atmosphere were assessed. Solar variations believed most likely to constitute the forcing functions in hypothesized solar terrestrial atmosphere chain, changes in the Earth's atmospheric electrical characteristics due to solar variability, and the observed variations in atmospheric behavior that are influenced by solar variability were also examined.

Wu, S. T.↗

NASA NTRS1981

Effects of lateral resolution on the identification of volcanotectonic provinces on earth and Venus

In an attempt to learn what volcanotectonic features can still be discerned in continental and oceanic areas of the earth when topographic data are degraded to simulate the data sampled by the Pioneer-Venus altimeter, two digital topographic data sets (the 30-second continental U.S. altitude data and the 30 x 30 nautical mile bathymetry data for the North Pacific) were degraded and displayed in the same way as the altimeter data from Venus. The Appalachians were reduced to a gentle swell, with a wavelength of 300 km, and a height of 500 m. The Cordillera was seen as a broad swell, 2500 km wide, and about 2 km high. The east Pacific rise, east Pacific fractures, seamount chains, the Hawaiian swell, and most trenches were discernible in the degraded Pacific data; whereas rises, transforms, seamount chains, and trenches were not seen in the Venus data, even after corrections were made for the higher surface temperature and the absence of oceans on Venus. It was concluded that a plate tectonic regime, similar to earth's does not currently appear to exist on Venus. As shown by the Cordillera data, the Pioneer-Venus information is not of sufficiently high quality to discern whether the highlands of Venus preserve evidence for orogenic events related to plate tectonics.

Arvidson, R. E.↗

NASA NTRS1981

Amino acids of the Murchison meteorite. I - Six carbon acyclic primary alpha-amino alkanoic acids

Six of the seven chain isomers of six-carbon acyclic primary alpha-amino alkanoic acids (leucine isomers) have been either identified or confirmed in hot-water extracts of the Murchison meteorite using combined gas chromatography-mass spectrometry (GC-MS) and ion exchange chromatography. 2-Amino-2-ethylbutyric acid, 2-amino-2,3-dimethylbutyric acid, pseudoleucine, and 2-methylnorvaline were positively identified by GC-MS. These amino acids have not been previously reported to occur in natural materials and may be uniquely meteoritic in origin. The presence of leucine and isoleucine (including the diastereoisomer, alloisoleucine) was confirmed. Peaks corresponding to norleucine were seen by ion-exchange and gas chromatography but characteristic mass spectra were not obtained. The alpha-branched chain isomers in this series are quantitatively the most significant. These results are compared with literature data on amino acid synthesis by electrical discharge and Fischer-Tropsch-type catalysis. Neither model system produces an amino acid suite that is completely comparable to that found in the Murchison meteorite.

Cronin, J. R.↗

NASA NTRS1982

Lock for Gantry Trolley

Single operator on ground controls trolley-locking mechanism on portable gantry. Mechanism prevents trolley and load from moving along track when gantry is wheeled from one location to another. A downward pull on chain withdraws brakeshoes from trolley wheels. When operator releases chain, brakeshoes reengage to wheels.

Newberg, H. F.↗

NASA NTRS1982

LORAN-C, an overview

LORAN-C a highly accurate radio navigation positioning system which operates at an assigned frequency of 10 kHz, and provides phase-coded pulses to develop hyperbolic time-difference lines-of-position (LOP's) was evaluated. LORAN-C provides precise time and time interval to within plus or minus 5 microseconds of UTC. The steps taken to plan, install, operate, and maintain the LORAN-C system up to the year 2000 are discussed. Topics included in the discussion were: theory of operation, timing, chain lanning, group repetition interval, coding delay versus emission delay, chain calibration, chart verification, system accuracy, signal reliability, and future developments.

Thrall, W. J.↗

NASA NTRS1981

Radiation effects on four polysulfone films

The response of polysulfones to proton and electron radiation is evaluated by assessing the radiation durability of four selected sulfones, establishing radiation interaction mechanisms with the polymer chain, and determining the dependence of radiation durability on chemical structure. Chain scission appears to predominate at lower doses up to about 10 to the 9th rad, and past this threshold the second mechanism, crosslinking, seems to predominate. This is evidenced by the increase in modulus, glass transition temperature, and increased quantity of thermally stable residue at high temperatures. The variations of chemical structure of the polysulfones appear to have little effect on the response to radiation.

Santos, B.↗

NASA NTRS1982

Literature review of organic matter transport from marshes

A conceptual model for estimating a transport coefficient for the movement of nonliving organic matter from wetlands to the adjacent embayments was developed in a manner that makes it compatible with the Earth Resources Laboratory's Productive Capacity Model. The model, which envisages detritus movement from wetland pixels to the nearest land-water boundary followed by movement within the water column from tidal creeks to the adjacent embayment, can be transposed to deal with only the interaction between tidal water and the marsh or to estimate the transport from embayments to the adjacent coastal waters. The outwelling hypothesis postulated wetlands as supporting coastal fisheries either by exporting nutrients, such as inorganic nitrogen, which stimulated the plankton-based grazing food chain in the water column, or through the export of dissolved and particulate organic carbon which provided a benthic, detritus-based food web which provides the food source for the grazing food chain in a more indirect fashion.

Dow, D. D.↗

NASA NTRS1984

Augmenting computer networks

Three methods of augmenting computer networks by adding at most one link per processor are discussed: (1) A tree of N nodes may be augmented such that the resulting graph has diameter no greater than 4log sub 2((N+2)/3)-2. Thi O(N(3)) algorithm can be applied to any spanning tree of a connected graph to reduce the diameter of that graph to O(log N); (2) Given a binary tree T and a chain C of N nodes each, C may be augmented to produce C so that T is a subgraph of C. This algorithm is O(N) and may be used to produce augmented chains or rings that have diameter no greater than 2log sub 2((N+2)/3) and are planar; (3) Any rectangular two-dimensional 4 (8) nearest neighbor array of size N = 2(k) may be augmented so that it can emulate a single step shuffle-exchange network of size N/2 in 3(t) time steps.

Bokhari, S. H.↗