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All sourcesNASA NTRSDOE OSTI
NASA NTRS2005

Aerosol properties computed from aircraft-based observations during the ACE- Asia campaign: A case study of lidar ratio closure and aerosol radiative effects - 2

For a vertical profile with three distinct layers (marine boundary, pollution and dust), observed during the ACE-Asia campaign, we carried out a comparison between the modeled lidar ratio vertical profile and that obtained from collocated airborne NASA AATS-14 sunphotometer and shipborne Micro-Pulse Lidar (MPL) measurements. Vertically resolved lidar ratio was calculated from two size distribution vertical profiles - one obtained by inversion of sunphotometer-derived extinction spectra, and one measured in-situ - combined with the same refractive index model based on aerosol chemical composition. The aerosol model implies single scattering albedos of 0.78 - 0.81 and 0.93 - 0.96 at 0.523 microns (the wavelength of the lidar measurements), in the pollution and dust layers, respectively. The lidar ratios calculated from the two size distribution profiles have close values in the dust layer; they are however, significantly lower than the lidar ratios derived from combined lidar and sunphotometer measurements, most probably due to the use of a simple nonspherical model with a single particle shape in our calculations. In the pollution layer, the two size distribution profiles yield generally different lidar ratios. The retrieved size distributions yield a lidar ratio which is in better agreement with that derived from lidar/sunphotometer measurements in this layer, with still large differences at certain altitudes (the largest relative difference was 46%). We explain these differences by non-uniqueness of the result of the size distribution retrieval and lack of information on vertical variability of particle refractive index. Radiative transfer calculations for this profile showed significant atmospheric radiative forcing, which occurred mainly in the pollution layer. We demonstrate that if the extinction profile is known then information on the vertical structure of absorption and asymmetry parameter is not significant for estimating forcing at TOA and the surface, while it is of importance for estimating vertical profiles of radiative forcing and heating rates.

Kuzmanoski, Maja↗
NASA NTRS2011

Pulsed Lidar for Measurement of C02 Concentrations for the ASCENDS Mission - Update

We have been developing a laser-based sounding technique for the remote measurement of the tropospheric CO2 concentrations from orbit for NASA is ASCENDS mission. The mission's goals are to provide measurements of tropospheric CO2 abundance with global-coverage, a few hundred km spatial and monthly temporal resolution. These are needed to better understand CO2 fluxes and the processes that regulate CO2 storage by the land and oceans. For the lIP, we are developing and demonstrating the lidar techniques and key lidar technology that will permit measurements of the CO2 column abundance in the lower troposphere from aircraft. Our final goal is to demonstrate the key capabilities needed for a space lidar and mission approach for the ASCENDS mission. We use a pulsed lidar technique, which is much less sensitive to errors from cloud and atmospheric scattering and to noise from solar background. It allows continuous measurements of CO2 mixing ratio in the lower troposphere during day and night. Our approach uses the 1570nm CO2 band and a two-wavelength laser absorption spectrometer, which continuously measures at nadir from a circular polar orbit. It directs the narrow co-aligned laser beams from the instrument's lasers toward nadir, and measures the energy of the laser echoes reflected from land and water surfaces. It uses a pair of tunable laser transmitters, which allowing measurement of the extinction from a single selected CO2 absorption line in the 1570 nm band and from a line pair in the Oxygen A-band near 765 nm. These regions have temperature insensitive absorption lines are free from interference from other gases. The lasers pulse at 10KHz, use tunable diode seed lasers followed by laser amplifiers, and have MHz spectral widths. During the measurement the lasers are stepped across the selected lines at a kHz rate. The receiver uses a 1-m class telescope and photon sensitive detectors and measures the background light and energies of the laser echoes from the surface. The extinction and column densities for the CO2 and O2 gases are estimated from the ratio of the on and off line echo pulse energies via the integrated path differential absorption (IPDA) technique. Our technique exploits the atmospheric pressure broadening of the lines to weight the measurement sensitivity to the atmospheric column below 5 km. Pulsed laser signals, time gated receiver are used to isolate the surface laser echo signals and to exclude photons scattered from clouds and aerosols. We have successfully demonstrated many key aspects of the approach and lidar technology in the laboratory. We have demonstrated CO2 column measurements in airborne flights during the summers of 2009 and 2010. These included measurements from 3-l3 km altitudes made over a variety of surfaces and through thin and broken clouds. We demonstrated initial airborne measurements of O2 column density to 10 km altitudes during the summer 2010 flights. More details approach, key technologies, and demonstration measurements will be given in the presentation.

Abshire, James↗
NASA NTRS2006

Fiber-Optic Gratings for Lidar Measurements of Water Vapor

Narrow-band filters in the form of phase-shifted Fabry-Perot Bragg gratings incorporated into optical fibers are being developed for differential-absorption lidar (DIAL) instruments used to measure concentrations of atmospheric water vapor. The basic idea is to measure the relative amounts of pulsed laser light scattered from the atmosphere at two nearly equal wavelengths, one of which coincides with an absorption spectral peak of water molecules and the other corresponding to no water vapor absorption. As part of the DIAL measurement process, the scattered light is made to pass through a filter on the way to a photodetector. Omitting other details of DIAL for the sake of brevity, what is required of the filter is to provide a stop band that: Surrounds the water-vapor spectral absorption peaks at a wavelength of 946 nm, Has a spectral width of at least a couple of nanometers, Contains a pass band preferably no wider than necessary to accommodate the 946.0003-nm-wavelength water vapor absorption peak [which has 8.47 pm full width at half maximum (FWHM)], and Contains another pass band at the slightly shorter wavelength of 945.9 nm, where there is scattering of light from aerosol particles but no absorption by water molecules. Whereas filters used heretofore in DIAL have had bandwidths of =300 pm, recent progress in the art of fiber-optic Bragg-grating filters has made it feasible to reduce bandwidths to less than or equal to 20 pm and thereby to reduce background noise. Another benefit of substituting fiber-optic Bragg-grating filters for those now in use would be significant reductions in the weights of DIAL instruments. Yet another advantage of fiber-optic Bragg-grating filters is that their transmission spectra can be shifted to longer wavelengths by heating or stretching: hence, it is envisioned that future DIAL instruments would contain devices for fine adjustment of transmission wavelengths through stretching or heating of fiber-optic Bragg-grating filters nominally designed and fabricated to have transmission wavelengths that, in the absence of stretching, would be slightly too short.

Vann, Leila B.↗
NASA NTRS2015

Optical Parametric Technology for Methane Measurements

Atmospheric methane (CH4) is the second most important anthropogenic greenhouse gas, with approximately 25 times the radiative forcing of carbon dioxide (CO2) per molecule. Yet, lack of understanding of the processes that control CH4 sources and sinks and its potential release from stored carbon reservoirs contributes significant uncertainty to our knowledge of the interaction between carbon cycle and climate change. At Goddard Space Flight Center (GSFC) we have been developing the technology needed to remotely measure CH4 from orbit. Our concept for a CH4 lidar is a nadir viewing instrument that uses the strong laser echoes from the Earth's surface to measure CH4. The instrument uses a tunable, narrow-frequency light source and photon-sensitive detector to make continuous measurements from orbit, in sunlight and darkness, at all latitudes and can be relatively immune to errors introduced by scattering from clouds and aerosols. Our measurement technique uses Integrated Path Differential Absorption (IPDA), which measures the absorption of laser pulses by a trace gas when tuned to a wavelength coincident with an absorption line. We have already demonstrated ground-based and airborne CH4 detection using Optical Parametric Amplifiers (OPA) at 1651 nm using a laser with approximately 10 microJ/pulse at 5kHz with a narrow linewidth. Next, we will upgrade our OPO system to add several more wavelengths in preparation for our September 2015 airborne campaign, and expect that these upgrades will enable CH4 measurements with 1% precision (10-20 ppb).

oscillator↗
NASA NTRS2005

GOES Satellite Data Validation Via Hand-held 4 LED Sun Photometer at Norfolk State University

Sun photometry is a passive means of measuring a quantity of light radiation. The GIFTS- IOMI/GLOBE Water Vapor/Haze Sun photometer contains four light emitting diodes (LEDs), which are used to convert photocurrent to voltage. The intensity of the incoming and outgoing radiation as detected on the Earth s surface can be affected by aerosols and gases in the atmosphere. The focus of this research is primarily on aerosol and water vapor particles that absorb and reemit energy. Two LEDs in the photometer correspond to light scattered at 530 nm (green spectrum) and 620 nm (red spectrum). They collect data pertaining to aerosols that scatter light. The other two LEDs detect the light scattered by water vapor at wavelengths of 820 nm and 920 nm. The water vapor measurements will be compared to data collected by the Geostationary Observation Environmental Satellite (GOES). Before a comparison can be made, the extraterrestrial constant (ET), which is intrinsic to each sun photometer, must be measured. This paper will present determination of the ET constant, from which the aerosol optical thickness (AOT) can be computed for comparison to the GOES satellite to ascertain the reliability of the sun photometer.

Reynolds, Arthur, Jr.↗
NASA NTRS2005

Improvement of Raman lidar algorithm for quantifying aerosol extinction

Aerosols are particles of different composition and origin and influence the formation of clouds which are important in atmospheric radiative balance. At the present there is high uncertainty on the effect of aerosols on climate and this is mainly due to the fact that aerosol presence in the atmosphere can be highly variable in space and time. Monitoring of the aerosols in the atmosphere is necessary to better understanding many of these uncertainties. A lidar (an instrument that uses light to detect the extent of atmospheric aerosol loading) can be particularly useful to monitor aerosols in the atmosphere since it is capable to record the scattered intensity as a function of altitude from molecules and aerosols. One lidar method (the Raman lidar) makes use of the different wavelength changes that occur when light interacts with the varying chemistry and structure of atmospheric aerosols. One quantity that is indicative of aerosol presence is the aerosol extinction which quantifies the amount of attenuation (removal of photons), due to scattering, that light undergoes when propagating in the atmosphere. It can be directly measured with a Raman lidar using the wavelength dependence of the received signal. In order to calculate aerosol extinction from Raman scattering data it is necessary to evaluate the rate of change (derivative) of a Raman signal with respect to altitude. Since derivatives are defined for continuous functions, they cannot be performed directly on the experimental data which are not continuous. The most popular technique to find the functional behavior of experimental data is the least-square fit. This procedure allows finding a polynomial function which better approximate the experimental data. The typical approach in the lidar community is to make an a priori assumption about the functional behavior of the data in order to calculate the derivative. It has been shown in previous work that the use of the chi-square technique to determine the most likely functional behavior of the data prior to actually calculating the derivative eliminates the need for making a priori assumptions. We note that the a priori choice of a model itself can lead to larger uncertainties as compared to the method that is validated here. In this manuscript, the chi-square technique that determines the most likely functional behavior is validated through numerical simulation and by application to a large body of Raman lidar measurements. In general, we show that the chi-square approach to evaluate aerosol extinction yields lower extinction uncertainty than the traditional technique. We also use the technique to study the feasibility of developing a general characterization of the extinction uncertainty that could permit the uncertainty in Raman lidar aerosol extinction measurements to be estimated accurately without the use of the chi-square technique.

Russo, Felicita↗
NASA NTRS2001

Aerosol Measurements by the Globally Distributed Micro Pulse Lidar Network

Full time measurements of the vertical distribution of aerosol are now being acquired at a number of globally distributed MP (micro pulse) lidar sites. The MP lidar systems provide full time profiling of all significant cloud and aerosol to the limit of signal attenuation from compact, eye safe instruments. There are currently eight sites in operation and over a dozen planned. At all sited there are also passive aerosol and radiation measurements supporting the lidar data. Four of the installations are at Atmospheric Radiation Measurement program sites. The network operation includes instrument operation and calibration and the processing of aerosol measurements with standard retrievals and data products from the network sites. Data products include optical thickness and extinction cross section profiles. Application of data is to supplement satellite aerosol measurements and to provide a climatology of the height distribution of aerosol. The height distribution of aerosol is important for aerosol transport and the direct scattering and absorption of shortwave radiation in the atmosphere. Current satellite and other data already provide a great amount of information on aerosol distribution, but no passive technique can adequately resolve the height profile of aerosol. The Geoscience Laser Altimeter System (GLAS) is an orbital lidar to be launched in early 2002. GLAS will provide global measurements of the height distribution of aerosol. The MP lidar network will provide ground truth and analysis support for GLAS and other NASA Earth Observing System data. The instruments, sites, calibration procedures and standard data product algorithms for the MPL network will be described.

Spinhirne, James↗
NASA NTRS2020

Radiative Heating Rate Profiles over the Southeast Atlantic Ocean during the 2016 and 2017 Biomass Burning Seasons

Marine boundary layer clouds, including the transition from stratocumulus to cumulus, are poorly represented in numerical weather prediction and general circulation models. Further uncertainties in the cloud structure arise in the presence of biomass burning carbonaceous aerosol, as is the case over the southeast Atlantic Ocean where biomass burning aerosol is transported from the African continent. As the aerosol plume progresses across the southeast Atlantic Ocean, radiative heating within the aerosol layer has the potential to alter the thermodynamic environment and therefore the cloud structure; however, limited work has been done to quantify this along the trajectory of the aerosol plume in the region. The deployment of the First Atmospheric Radiation Measurement Mobile Facility in support of the Layered Atlantic Smoke Interactions with Clouds field campaign provided a unique opportunity to collect observations of cloud and aerosol properties during two consecutive biomass burning seasons during July through October of 2016 and 2017 over Ascension Island (7.96 °S, 14.35 °W). Using observed profiles of temperature, humidity, and clouds from the field campaign, alongside aerosol optical properties from MERRA-2 as input for the Rapid Radiation Transfer Model, profiles of the radiative heating rate due to aerosols and clouds were computed. Radiative heating is also assessed across the southeast Atlantic Ocean using an ensemble of back trajectories from the Hybrid Single Particle Lagrangian Integrated Trajectory Model. Idealized experiments using the Rapid Radiation Transfer Model with and without aerosols and a range of values for the single scattering albedo demonstrate that shortwave heating within the aerosol layer above Ascension Island can locally range between 2 and 8 K per day depending on the aerosol optical properties, though impacts of the aerosol can be felt elsewhere in the atmospheric column. When considered under clear conditions, the aerosol has a cooling effect at the TOA and based on the observed cloud properties at Ascension Island, the cloud albedo is not large enough to overcome this. Shortwave radiative heating due to biomass burning aerosol is not balanced by additional longwave cooling, and the net radiative impact results in a stabilization of the lower troposphere. However, these results are extremely sensitive to the single scattering albedo assumptions in models.

Allison B. Marquardt Collow↗
NASA NTRS2003

Remote Sensing of Aerosol Optical and Microphysical Properties using Polarization and Lidar Techniques

Tropospheric aerosols cause a substantial forcing of the terrestrial climate, but the magnitude of this forcing remains largely unknown. This explains the significant interest of the climate community to the prospect of measuring key aerosol properties from space using advanced remote sensing techniques. It has been known for a long time that polarization of the scattered light is much more sensitive to the aerosol microphysics than the scattered intensity. It is, therefore, not surprising that the most recent addition to the New Polar Orbiting Operational Environmental Satellite System (NPOESS) payload is the so-called Aerosol Polarimetry Sensor (APS). The main objective of this instrument is to measure the aerosol and cloud properties with accuracy and coverage sufficient for a reliable estimate of the direct and indirect aerosol forcings of climate. Accordingly, the first part of this lecture course will focus on describing the basic concept of the APS, the physical principles of polarization data analyses, and the results already obtained with an aircraft version of the APS. Polar stratospheric clouds (PSCs) represent another poorly understood aerosol component of the terrestrial atmosphere which affects the climate by supporting chemical reactions destroying the ozone layer. The high altitude of the PSCs and their predominant occurrence in high latitude and polar regions make it very difficult to study PSCs using conventional in situ techniques. Most of the information that we have about this type of clouds has been gathered using ground-based polarization lidars. The second part of the course will focus on explaining the physical principles of the polarization lidar technique and describing retrievals of PSC particle microphysical characteristics by converting I multispectral lidar measurements of the backscattered intensity and depolarization.

Mishchenko, Michael↗
NASA NTRS1998

LASE measurements of aerosols and water vapor during TARFOX

The TARFOX (Tropospheric Aerosol Radiative Forcing Observational Experiment) intensive field campaign was designed to reduce uncertainties in estimates of the effects of anthropogenic aerosols on climate by measuring direct radiative effects and the optical, physical, and chemical properties of aerosols [1]. TARFOX was conducted off the East Coast of the United States between July 10-31, 1996. Ground, aircraft, and satellite-based sensors measured the sensitivity of radiative fields at various atmospheric levels to aerosol optical properties (i.e., optical thickness, phase function, single-scattering albedo) and to the vertical profile of aerosols. The LASE (Lidar Atmospheric Sensing Experiment) instrument, which was flown on the NASA ER-2 aircraft, measured vertical profiles of total scattering ratio and water vapor during a series of 9 flights. These profiles were used in real-time to help direct the other aircraft to the appropriate altitudes for intensive sampling of aerosol layers. We have subsequently used the LASE aerosol data to derive aerosol backscattering and extinction profiles. Using these aerosol extinction profiles, we derived estimates of aerosol optical thickness (AOT) and compared these with measurements of AOT from both ground and airborne sun photometers and derived from the ATSR-2 (Along Track and Scanning Radiometer 2) sensor on ERS-2 (European Remote Sensing Satellite-2). We also used the water vapor mixing ratio profiles measured simultaneously by LASE to derive precipitable water vapor and compare these to ground based measurements.

Ferrare, Richard A.↗
NASA NTRS2016

In-Situ and Remotely-Sensed Observations of Biomass Burning Aerosols at Doi Ang Khang, Thailand During 7-SEAS BASELInE 2015

The spring 2015 deployment of a suite of instrumentation at Doi Ang Khang (DAK) in northwestern Thailand enabled the characterization of air masses containing smoke aerosols from burning predominantly in Myanmar. Aerosol Robotic Network (AERONET) Sun photometer data were used to validate Moderate Resolution Imaging Spectroradiometer (MODIS) Collection 6 "Deep Blue" aerosol optical depth (AOD) retrievals; MODIS Terra and Aqua provided results of similar quality, with correlation coefficients of 0.93-0.94 and similar agreement within expected uncertainties to global-average performance. Scattering and absorption measurements were used to compare surface and total column aerosol single scatter albedo (SSA); while the two were well-correlated, and showed consistent positive relationships with moisture (increasing SSA through the season as surface relative humidity and total columnar water vapor increased), in situ surface-level SSA was nevertheless significantly lower by 0.12-0.17. This could be related to vertical heterogeneity and/or instrumental issues. DAK is at approximately 1,500 meters above sea level in heterogeneous terrain, and the resulting strong diurnal variability in planetary boundary layer depth above the site leads to high temporal variability in both surface and column measurements, and acts as a controlling factor to the ratio between surface particulate matter (PM) levels and column AOD. In contrast, while some hygroscopic effects were observed relating to aerosol particle size and Angstrom exponent, relative humidity variations appear to be less important for this ratio here. As part of the Seven South-East Asian Studies (7-SEAS) project, the Biomass-burning Aerosols & Stratocumulus Environment: Lifecycles and Interactions Experiment (BASELInE) was intended to probe physicochemical processes, interactions, and feedbacks related to biomass burning aerosols and clouds during the spring burning season (February-April) in southeast Asia (SEA).

biomass burning↗
NASA NTRS2001

A Thermal Infrared Radiation Parameterization for Atmospheric Studies

This technical memorandum documents the longwave radiation parameterization developed at the Climate and Radiation Branch, NASA Goddard Space Flight Center, for a wide variety of weather and climate applications. Based on the 1996-version of the Air Force Geophysical Laboratory HITRAN data, the parameterization includes the absorption due to major gaseous absorption (water vapor, CO2, O3) and most of the minor trace gases (N2O, CH4, CFCs), as well as clouds and aerosols. The thermal infrared spectrum is divided into nine bands. To achieve a high degree of accuracy and speed, various approaches of computing the transmission function are applied to different spectral bands and gases. The gaseous transmission function is computed either using the k-distribution method or the table look-up method. To include the effect of scattering due to clouds and aerosols, the optical thickness is scaled by the single-scattering albedo and asymmetry factor. The parameterization can accurately compute fluxes to within 1% of the high spectral-resolution line-by-line calculations. The cooling rate can be accurately computed in the region extending from the surface to the 0.01-hPa level.

Chou, Ming-Dah↗
NASA NTRS2003

New Examination of the Raman Lidar Technique for Water Vapor and Aerosols: Evaluating the Temperature Dependent Lidar Equations - Paper 1

The intent of this paper and its companion is to compile together the essential information required for the analysis of Raman lidar water vapor and aerosol data acquired using a single laser wavelength. In this first paper several details concerning the evaluation of the lidar equation when measuring Raman scattering are considered. These details include the influence of the temperature dependence of both pure rotational and vibrational-rotational Raman scattering on the lidar profile. These are evaluated for the first time using a new form of the lidar equation. The results indicate that, for the range of temperatures encountered in the troposphere, the magnitude of the temperature dependent effect can reach 10% or more for narrowband Raman water vapor measurements. Also the calculation of atmospheric transmission is examined carefully including the effects of depolarization. Different formulations of Rayleigh cross section determination commonly used in the lidar field are compared revealing differences up to 5% among the formulations. The influence of multiple scattering on the measurement of aerosol extinction using the Raman lidar technique is considered as are several photon pulse-pileup correction techniques.

Whiteman, David N.↗
NASA NTRS1980

Lidar determination of the composition of atmosphere aerosols

Theoretical and experimental studies of the feasibility of using DIfferential SCatter (DISC) lidar to measure the composition of atmospheric aerosols are described. This technique involves multiwavelength measurements of the backscatter cross section of aerosols in the middle infrared, where a number of materials display strong restrahlen features that significantly modulate the backscatter spectrum. The theoretical work indicates that a number of materials of interest, including sulfuric acid, ammonium sulfate, and silicates, can be discriminated among with a CO2 lidar. An initial evaluation of this procedure was performed in which cirrus clouds and lower altitude tropospheric aerosols were developed. The observed ratio spectrum of the two types of aerosol displays structure that is in crude accord with theoretical expectations.

Wright, M. L.↗
NASA NTRS1980

Atmospheric aerosols and climate

The impact of terrestrial aerosols on the earth's climate and solar and infrared radiation budget are considered. Attention is given to the optical properties of aerosols, that is, optical depth, the single scattering albedo, and the asymmetry parameter, and to the relation between the optical depth and surface temperature for tropospheric and stratospheric aerosols. Also considered are experimental projects to determine the single scattering albedo, as well as the optical properties of natural aerosols such as sea salt, soil, and sulfates, and their variability. In addition, the impact of volcanic activity and the question of whether aerosols cause climatic warming or cooling are discussed, and the available observational evidence linking aerosols and climate is reviewed.

Toon, O. B.↗
DOE OSTI2025

Development and validation of a humidified CAPS-PMSSA with an improved methodology to calculate the truncation correction factor

Absorbing aerosols play an important role in the Earth’s radiation budget, and current uncertainties associated with their radiative impacts remain substantial. An element of this uncertainty derives from insufficient understanding of the extent to which water, as a coating on absorbing particles, enhances the absorption. Here, we describe and characterize the performance of a cavity-attenuated phase shift single scatter albedo spectrometer (CAPS-PMSSA) system that has been modified to enable concurrent aerosol extinction and scattering measurements, from which aerosol absorption is derived, at relative humidities up to ~90%. The modified instrument is referred to as the humidified CAPS (HCAPS). Additionally, we develop and validate an update to a method to calculate the truncation correction factor, used to correct the scattering measurements, that can account for the effects of particle growth and compositional changes resulting from water uptake. The method can be applied to experiments that use either size-selected or polydisperse aerosol samples of either known or unknown composition. Overall, we show that measurements made with the HCAPS, when processed using the updated truncation correction method, enable accurate measurement of the influence of water uptake on light absorption.

Dal Porto, Rachael [University of California, Davi↗
NASA NTRS1997

Soot Aerosol from Aircraft: Is there Enough to Cause Middle-Latitude Lower Stratospheric Ozone

Soot aerosol from aircraft has been implicated to cause long-term ozone depletion at mid-latitudes in the lower stratosphere at a rate of approx. equals 5%,per decade. During the 1996 SUCCESS field campaign, we sampling aerosols in the exhaust wake of a Boeing 757 aircraft and determined emission indices for sulfuric acid (EIH2SO4=4.8E-2 and 5.7E- 1. g/kgFUEL for 75 and 675 ppm fuel-sulfur, respectively) and soot (EIsoot=7.5E-4 g/kgFUEL). The corresponding fuel-sulfur to H2SO4 conversion efficiency was 25 % and 30%,respctively. Applying the H2SO4 emission index to the 1990 fuel by the world's commercial fleets of 1.3E11 kg, a conversion efficiency of 30% would have led to an annual contribution to the atmospheric sulfur budget by aircraft of 2.E7 kg H2SO4, if the fuels averaged 500 ppmm.The soot emission index given above yielded a 1990 injection of soot aerosol by aircraft of 1.E5 kg. Thus, soot amounts to only one half of one percent of the aerosol generated by aircraft. The fractal nature of soot may increase its actual surface area by about a factor of 10. The findings, however, of (1) stratospheric soot loadings commensurate with aircraft fuel consumption, based on the emission index given above and the assumption of stratospheric residence times of the order of one year; and (2) a trend in stratospheric soot loading of approx.6% per year since 1981, similar to the annual increase of aircraft operations since that time, implicate aircraft as stratospheric polluters. A trend similar to soot of H2SO4 aerosol loading could not be deciphered, neither from in situ measurements nor SAGE II extinction, against the "noise" due to volcanic eruptions, The current single scatter albedo of the stratospheric aerosol is omega = 0.993+/-0.004.

Pueschel, R. F.↗