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At least 559 records · Page 31

Impact of Humidity and Temperature on the Stability of the Optical Properties and Structure of MAPbI3, MA0.7FA0.3PbI3 and (FAPbI3)0.95(MAPbBr3)0.05 Perovskite Thin Films

In situ real-time spectroscopic ellipsometry (RTSE) measurements have been conducted on MAPbI3, MA0.7FA0.3PbI3, and (FAPbI3)0.95(MAPbBr3)0.05 perovskite thin films when exposed to different levels of relative humidity at given temperatures over time. Analysis of RTSE measurements track changes in the complex dielectric function spectra and structure, which indicate variations in stability influenced by the underlying material, preparation method, and perovskite composition. MAPbI3 and MA0.7FA0.3PbI3 films deposited on commercial fluorine-doped tin oxide coated glass are more stable than corresponding films deposited on soda lime glass directly. (FAPbI3)0.95(MAPbBr3)0.05 films on soda lime glass showed improved stability over the other compositions regardless of the substrate, and this is attributed to the preparation method as well as the final composition.

36 MATERIALS SCIENCE↗

Equation of State and Progenitor Dependence of Stellar-mass Black Hole Formation

The core collapse of a massive star results in the formation of a proto-neutron star (PNS). If enough material is accreted onto a PNS, it will become gravitationally unstable and further collapse into a black hole (BH). We perform a systematic study of failing core-collapse supernovae in spherical symmetry for a wide range of pre-supernova progenitor stars and equations of state (EOSs) of nuclear matter. We analyze how variations in progenitor structure and the EOS of dense matter above nuclear saturation density affect the PNS evolution and subsequent BH formation. Comparisons of core collapse for a given progenitor star and different EOSs show that the path traced by the PNS in mass-specific entropy phase space ${M}_{\mathrm{grav}}^{\mathrm{PNS}}-\tilde{s}$ is well correlated with the progenitor compactness and is almost EOS independent, apart from the final end point. Furthermore, BH formation occurs, to a very good approximation, soon after the PNS overcomes the maximum gravitational mass supported by a hot NS with constant specific entropy equal to $\tilde{s}$. These results show a path to constraining the temperature dependence of the EOS through the detection of neutrinos from a failed galactic supernova.

79 ASTRONOMY AND ASTROPHYSICS↗

Climate model projections from the Scenario Model Intercomparison Project (ScenarioMIP) of CMIP6

Abstract. The Scenario Model Intercomparison Project (ScenarioMIP) defines and coordinates the main set of future climate projections, based on concentration-driven simulations, within the Coupled Model Intercomparison Project phase 6 (CMIP6). This paper presents a range of its outcomes by synthesizing results from the participating global coupled Earth system models. We limit our scope to the analysis of strictly geophysical outcomes: mainly global averages and spatial patterns of change for surface air temperature and precipitation. We also compare CMIP6 projections to CMIP5 results, especially for those scenarios that were designed to provide continuity across the CMIP phases, at the same time highlighting important differences in forcing composition, as well as in results. The range of future temperature and precipitation changes by the end of the century (2081–2100) encompassing the Tier 1 experiments based on the Shared Socioeconomic Pathway (SSP) scenarios (SSP1-2.6, SSP2-4.5, SSP3-7.0 and SSP5-8.5) and SSP1-1.9 spans a larger range of outcomes compared to CMIP5, due to higher warming (by close to 1.5 ∘C) reached at the upper end of the 5 %–95 % envelope of the highest scenario (SSP5-8.5). This is due to both the wider range of radiative forcing that the new scenarios cover and the higher climate sensitivities in some of the new models compared to their CMIP5 predecessors. Spatial patterns of change for temperature and precipitation averaged over models and scenarios have familiar features, and an analysis of their variations confirms model structural differences to be the dominant source of uncertainty. Models also differ with respect to the size and evolution of internal variability as measured by individual models' initial condition ensemble spreads, according to a set of initial condition ensemble simulations available under SSP3-7.0. These experiments suggest a tendency for internal variability to decrease along the course of the century in this scenario, a result that will benefit from further analysis over a larger set of models. Benefits of mitigation, all else being equal in terms of societal drivers, appear clearly when comparing scenarios developed under the same SSP but to which different degrees of mitigation have been applied. It is also found that a mild overshoot in temperature of a few decades around mid-century, as represented in SSP5-3.4OS, does not affect the end outcome of temperature and precipitation changes by 2100, which return to the same levels as those reached by the gradually increasing SSP4-3.4 (not erasing the possibility, however, that other aspects of the system may not be as easily reversible). Central estimates of the time at which the ensemble means of the different scenarios reach a given warming level might be biased by the inclusion of models that have shown faster warming in the historical period than the observed. Those estimates show all scenarios reaching 1.5 ∘C of warming compared to the 1850–1900 baseline in the second half of the current decade, with the time span between slow and fast warming covering between 20 and 27 years from present. The warming level of 2 ∘C of warming is reached as early as 2039 by the ensemble mean under SSP5-8.5 but as late as the mid-2060s under SSP1-2.6. The highest warming level considered (5 ∘C) is reached by the ensemble mean only under SSP5-8.5 and not until the mid-2090s.

54 ENVIRONMENTAL SCIENCES↗

A sinusoidal-vibration analysis program for experimental data

A program is described for obtaining resonant frequencies, modal amplitudes, and damping of a structure from a sinusoidal force-controlled vibration test. Presented are the theoretical basis for the analysis (the Kennedy-Pancu method), recommendations for a test procedure based on experience with several earlier test programs, and an outline of the data analysis technique. Although the program was developed for structural vibration problems, variations for processing any sinusoidal data are available.

Schoenster, J. A.↗

Aeroelastic-stability characteristics of a V/STOL tilt-rotor aircraft with hingeless blades - Correlation of analysis and test

The potential aeroelastic problems of a tilt rotor aircraft are described. The type of mathematical model required to predict such behavior is discussed and results of a design study on a specific configuration are presented. The sensitivity of the results to variation of the structural parameters is evaluated. The methodology used for analytical studies is shown to predict accurately the behavior of a full-scale rotor-pylon-wing system tested in the NASA-Ames 40- by 80-foot wind tunnel. It is concluded that there is no impediment from an aeroelastic viewpoint in designing and flying a tilt-rotor aircraft using a soft-in-plane hingeless rotor.

Alexander, H. R.↗

Lunakhod-2: Preliminary research results

Results from the Lunakhod 2 experiment on the surface property variations and relief structure of lunar craters are presented. Tectonic fractures, iron composition of lunar rocks, magnetic measurements, lunar sky brightness, and corpuscular radiation of the lunar body were studied.

Vinogradov, A. P.↗

Neutral point detection by satellites

The concept of a neutral point depends on the physical phenomena described. The regions with B less than about 1 gamma detected by Schindler and Ness may be interpreted as neutral regions for the ion-tearing process. The assumption of the presence of a multiple neutral point structure (with temporal variations) is still the most promising interpretation of the Explorer 34 data. Alternatives suggested by Russell lead to difficulties. Nevertheless, the final answer can come only from multiple satellite systems. A 1-day displacement of the day count in the data discussed by Schindler and Ness is corrected.

Schindler, K.↗

A grid of model atmospheres for metal-deficient giant stars. I

A grid of flux-constant model atmospheres for stars with effective temperatures between 3750 and 6000 K, log g between 0.75 and 3.0, and (A/H) between -3.0 and 0.0 has been constructed. The line absorption is approximated by opacity distribution functions. Metal lines and molecular lines, including those from the infrared bands of CO and CN, are taken into account. The variation of the structure of the models with metal abundance and microturbulence parameter is found to be quite regular and not very drastic. The surface cooling produced by CO is important for all the models with a maximum temperature of 5000 K, while CN mainly causes a backwarming effect but is not very important for solar CNO abundances. The effects of convection, estimated by using the mixing-length approximation, are important only for the coldest models. The models compare very well with models from overlapping regions of other grids. A solar model consistent with the grid models is found to agree satisfactorily with empirical solar model atmospheres. The careful use of scaled solar models for stars with (A/H) approximately equal to zero is justified.

Gustafsson, B.↗

Observation of radioactive background in the OSO-7 gamma ray monitor

The counting rate as measured by the gamma ray monitor on the OSO-7 satellite, covering the energy range 0.3-10 MeV, during a sixteen month period (October 1971-December 1972) was considerably higher than expected from balloon data previously reported. Dyer et al. (1971) have shown the importance of activation in satellites for diffuse gamma flux measurements. The OSO-7 spectra exhibit strong, complex line structure, especially between 400 keV and 900 keV, and several identifications can be made consistent with the model of Dyer et al. The spectral structure and time variations are presented which must be explained by any activation model.

Dunphy, P. P.↗

Lidar observations of the stratospheric aerosol - California, October 1972 to March 1974

The paper describes the results of a series of 30 observations of stratospheric aerosol made with a ground-based lidar on the North Pacific Coast during a period relatively uninfluenced by major volcanic penetrations and displaying a relative temporal minimum in particulate content. The objectives were to provide a record of aerosol behavior during this intervolcanic period, to compare this behavior with that revealed by previous studies using a variety of techniques, and to provide comparative data on the stratospheric aerosol by conducting joint lidar and aircraft observations. Determination of scattering profile ratios from lidar signal profiles and analysis of experimental errors are described. Analysis of the data shows that significant temporal variability of the aerosol was observed, probably of nonvolcanic origin. Much of the variability was confined to the 23-30 km height region, above the major peak in scattering ratio. The evidence is that this is not due to influxes of extraterrestrial material. Vertical motions of the centroid of the scattering ratio peak were recorded during the 1973 stratospheric warming, and illustrate the value of lidar's ability to monitor temporal variations of vertical structure.

Russell, P. B.↗

Engineering analysis division internal note. OFT-1 margin assessment

The results are documented of an analysis conducted to determine space shuttle vehicle (SSV) subsystem margins for the reference flight profile for the first orbital flight test (OFT-1). In general, the results show increased margins for the OFT-1 indicators when compared to Mission 3A resutls. The inclusion of element and wing aerodynamic variations on OFT-1, in combination with winds and systems dispersions, resulted in the forward Z (FTO1) attach load indicator exceeding specified limits. The inboard and outboard elevon hinge moment margins (9 percent and 3 percent, respectively) on OFT-1 reflect values consistent with the load relief requirements dictated by elevon hinge moment variations. All other structural load indicators for OFT-1 had margins in excess of 10 percent. The SSV first stage stagnation heating indicators for OFT-1 were about 45 percent less than for Mission 3A. The hydraulic systems demands for both missions were essentially the same. The results also show OFT-1 performance requirements from the consideration of winds and dispersions to be approximately 3,300 lbs greater than Mission 3A.

Austin, L. D., Jr.↗

Application of LANDSAT data to delimitation of avalanche hazards in Montane Colorado

The author has identified the following significant results. Many avalanche hazard zones can be identified on LANDSAT imagery, but not consistently over a large region. Therefore, regional avalanche hazard mapping, using LANDSAT imagery, must draw on additional sources of information. A method was devised that depicts three levels of avalanche hazards according to three corresponding levels of certainty that active avalanches occur. The lowest level, potential avalanche hazards, was defined by delineating slopes steep enough to support avalanches at elevations where snowfall was likely to be sufficient to produce a thick snowpack. The intermediate level of avalanche hazard was interpreted as avalanche hazard zones. These zones have direct and indirect indicators of active avalanche activity and were interpreted from LANDSAT imagery. The highest level of known or active avalanche hazards was compiled from existing maps. Some landslides in Colorado were identified and, to a degree, delimited on LANDSAT imagery, but the conditions of their identification were highly variable. Because of local topographic, geologic, structural, and vegetational variations, there was no unique landslide spectral appearance.

Knepper, D. H., Jr.↗

Apollo 14 revisited, or breccias aren't so bad after all

A study of large Apollo 14 samples suggests that they were formed by the same processes which formed the impactites found at Apollo 16 and 17 and in terrestrial craters, especially those in crystalline targets. The abundant crystalline matrix breccias of the Apollo 14 samples generally show higher clast contents and less refractory clast populations than the clast-laden impact melts abundant at the other Apollo nonmare landing sites. The Apollo 14 characteristics are attributed to the mixing of a greater amount of cold clastic debris into the superheated melt formed during impacts. The other major lithology at Apollo 14, the vitric matrix breccias, are made in part from agglutinate-bearing soil and cannot be the protolith of crystalline matrix breccias, because of differences in structure and composition. Variations among the breccias indicate the occurrence of several impact events.

Simonds, C. H.↗

Secondary mirror subassembly in the 2.4 m NASA optical telescope

The secondary mirror is a circular disc provided with a shoulder. Three clamps located 120 deg apart support the mirror shoulder. On one side of the mirror shoulder, a coated graphite-epoxy ring connects the three clamps. Three axial flexures with a low radial compliance extend out from a support platform constructed of coated graphite-epoxy box structs and invar corners, and provide a nominal in-plane zero coefficient of thermal expansion. In each invar corner piece, a ball joint provides a connection to a expansion. In each invar corner piece, a ball joint provides a connection to a six-degree-of-freedom adjustment system that can move the secondary mirror with a high degree of precision in defocus, decenter, and tilt. Thermal controls that maintain structural-element temperature variations within specified limits insure that the assembly exceeds stability and figure control requirements on the secondary mirror.

Ahmed, N.↗

An Instrument Employing a Coronal Discharge for the Determination of Droplet-Size Distribution in Clouds

A flight instrument that uses electric means for measuring the droplet-size distribution in above-freezing clouds has been devised and given preliminary evaluation in flight. An electric charge is placed on the droplets and they are separated aerodynamically according to their mass. Because the charge placed on the droplets is a. function of the droplet size, the size spectrum can 'be determined by measurement of the charge deposited on cylinders of several different sizes placed to intercept the charged droplets. An expression for the rate of charge acquisition by a water droplet in a field of coronal discharge is derived. The results obtained in flight with an instrument based on the method described indicate that continuous records of droplet-size spectrum variations in clouds can be obtained. The experimental instrument was used to evaluate the method and was not refined to the extent necessary for obtaining conclusive meteorological data. The desirable features of an instrument based on the method described are (i) The instrument can be used in clouds with temperatures above freezing; (2) the size and the shape of the cylinders do not change during the exposure time; (3) the readings are instantaneous and continuous; (4) the available sensitivity permits the study of variations in cloud structures of less than 200 feet in extent.

Brun, Rinaldo J.↗

Numerical simulation of a compressible homogeneous, turbulent shear flow

A direct, low Reynolds number, numerical simulation was performed on a homogeneous turbulent shear flow. The full compressible Navier-Stokes equations were used in a simulation on the ILLIAC IV computer with a 64,000 mesh. The flow fields generated by the code are used as an experimental data base, to examine the behavior of the Reynols stresses in this simple, compressible flow. The variation of the structure of the stresses and their dynamic equations as the character of the flow changed is emphasized. The structure of the tress tensor is more heavily dependent on the shear number and less on the fluctuating Mach number. The pressure-strain correlation tensor in the dynamic uations is directly calculated in this simulation. These correlations are decomposed into several parts, as contrasted with the traditional incompressible decomposition into two parts. The performance of existing models for the conventional terms is examined, and a model is proposed for the 'mean fluctuating' part.

Feiereisen, W. J.↗

Planetary-scale characteristics of the atmospheric circulation during January and February 1979

The global scale mass and wind fields observed during FGGE special observing period (SOP) are studied, with attention given to the time variation and vertical structure of the ultralong waves. A spherical harmonic representation is developed for the global fields. The tropical circulation is found to imprint more amplitude on the lower-order components than the midlatitude circulation does. High amplitude oscillations are determined to be present in the divergent fields on all time scales, i.e., diurnal to monthly. The global scale wind was found to change on scales approaching a week. Good agreement with teleconnection predictions was demonstrated for the cross-equatorial divergent and zonal rotational flow changes. The global scale was concluded to resemble force modes of linear tidal theory, with important contributions from longitudinal heating gradients.

Paegle, J.↗