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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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DOE OSTI2020

Development of Tools Training and Outreach to Address Solar Glare and Flux-Related Avian Impacts

Millions of dollars and significant resources are being spent by developers of utility-scale solar photovoltaic (PV) and concentrating solar power (CSP) plants to address federal and local requirements regarding glare and avian hazards. Solar glare can occur from the glass surfaces of PV modules and from mirrors in CSP systems, which can produce safety and health risks for pilots, motorists, and residents located near these systems. In addition, concentrated solar flux at CSP plants has the potential to singe birds as they fly through regions of high solar flux. This work will develop tools to characterize and mitigate these potential hazards, which will address regulatory policies and reduce costs and efforts associated with the proposed deployment of gigawatts of solar energy systems throughout the nation. The development of standardized and publicly available tools to address these regulatory policies and ensure public and environmental safety is an appropriate role for the government.

14 SOLAR ENERGY↗
DOE OSTI2024

Lessons Learned from Three Agrivoltaic Installations in New Jersey

Agrivoltaics is a new technology that has the potential to positively impact commercial farming by combining agricultural practices with the generation of solar energy. While some yield reduction is to be expected, resulting from less sunlight reaching the plant canopy and ground occupied by support structures, the generated electricity provides a low-risk supplemental income to farmers. In order to combine farming with electricity generation, agrivoltaic systems use a lower ground coverage ratio compared to normal solar farms and the PV panels are often mounted higher above the ground in order to facilitate the movement of agricultural equipment and to reduce the contrast between shaded and non-shaded areas. With funding provided from the state of New Jersey and the New Jersey Agricultural Experiment Station (NJAES), we designed and installed three unique agrivoltaic research systems at Rutgers/NJAES farms. These projects were recently completed and are generating electricity that is exported to the grid. This paper discusses the lessons we have learned along the way, including all the steps necessary to see an agrivoltaic project through to completion.

14 SOLAR ENERGY↗
DOE OSTI2024

Lessons Learned from Three Agrivoltaic Installations in New Jersey

Agrivoltaics is a new technology that has the potential to positively impact commercial farming by combining agricultural practices with the generation of solar energy. While some yield reduction is to be expected, resulting from less sunlight reaching the plant canopy and ground occupied by support structures, the generated electricity provides a low-risk supplemental income to farmers. In order to combine farming with electricity generation, agrivoltaic systems use a lower ground coverage ratio compared to normal solar farms and the PV panels are often mounted higher above the ground in order to facilitate the movement of agricultural equipment and to reduce the contrast between shaded and non-shaded areas. With funding provided from the state of New Jersey and the New Jersey Agricultural Experiment Station (NJAES), we designed and installed three unique agrivoltaic research systems at Rutgers/NJAES farms. These projects were recently completed and are generating electricity that is exported to the grid. This paper discusses the lessons we have learned along the way, including all the steps necessary to see an agrivoltaic project through to completion.

14 SOLAR ENERGY↗
DOE OSTI2022

Gen3 Gas Phase System Development and Demonstration (Final Technical Report)

Work undertaken in this project seeks to transform the current baseline technology – which is a collection of related but separately developed components and concepts – into a unified and operating test facility and an accompanying preliminary commercial design. This project is motivated by the primary goal of developing a system to absorb concentrated solar energy and deliver it into thermal energy storage at temperatures above 700°C, thereby enabling integration with a high-efficiency supercritical carbon dioxide (sCO 2 ) power cycle to achieve or exceed a levelized cost of electricity (LCOE) target of 6 ¢ per kilowatt-hour electric (kW e -hr). The proposed baseline solution utilizes a high-temperature gas phase (GP) system interfacing with a two-tank particle thermal energy storage (TES) and intermediate heat exchangers to supply sCO 2 at 20-25 megapascals (MPa) and 700°C at the turbine inlet.

14 SOLAR ENERGY↗
DOE OSTI2024

Effect of Iron Contamination and Polysilicon Gettering on the Performance of Polysilicon‐Based Passivating Contact Solar Cells

Over the past decade, silicon solar cells with carrier-selective passivating contacts based on polysilicon capping an ultra-thin silicon oxide (commonly known as TOPCon or POLO) have demonstrated promising efficiency potentials and are regarded as an evolutionary upgrade to the PERC (passivated emitter and rear contact) cells in manufacturing. The polysilicon-based passivating contacts also exhibit excellent gettering effects that relax the wafer and cleanroom requirements to some extent. Here, in this work, we experimentally explore the impact of bulk iron contamination and polysilicon gettering on the passivation quality of the polysilicon/oxide structure and the resulting solar cells performance. Results show that both n- and p-type polysilicon/oxide passivating contacts are not affected by iron gettering, demonstrating robust and stable passivation quality. However, for a very high bulk iron contamination (1 × 10 13 cm −3 ), the accumulated iron in the p-type lightly boron-doped emitter in crystalline silicon would degrade the emitter saturation current density. This can cause a reduction in both open-circuit voltage and short-circuit current. Meanwhile, this very high iron content (1 × 10 13 cm −3 ) can further degrade the fill factor and temperature coefficient of the cells. On the other hand, for an initial iron content of 2 × 10 12 cm −3 , which should be well above the iron level in the current industrial Czochralski silicon wafers, the resulting cells demonstrate similar performance as the control group with no intentional iron contamination. This work brings attention to both the benefits of polysilicon gettering effects as well as the potential degradation due to the accumulation of metal impurities in the p-type emitter region.

14 SOLAR ENERGY↗
DOE OSTI2023

Conference Support, 32nd Western Photosynthesis Conference 2023

This DOE-BES award provided conference support for the 32nd Western Photosynthesis Conference (WPC2023), held January 5–8, 2023 at the Bodega Bay Marine Laboratory in Bodega Bay, California. The Western Photosynthesis Conference is one of three regional photosynthesis meetings held annually in the United States and serves as a primary venue for early-career scientists—graduate students, postdoctoral researchers, and undergraduates—to present research and build professional networks alongside established investigators in the field. Photosynthesis research is central to the DOE Office of Science's Basic Energy Sciences mission, underpinning fundamental understanding of solar energy conversion, biofuels, and the biological transformation of light into chemical energy. DOE-BES funds were used, as proposed, to support registration and housing costs for 20 early-career participants (9 postdoctoral researchers, 9 graduate students, and 2 undergraduates) and to help defray travel costs for two junior invited speakers based outside California, for a total DOE-BES expenditure of $10,060. The meeting was executed as planned, with no significant deviations from the approved program, budget, or schedule. WPC2023 drew 76 registrants across six scientific topic areas, featured 8 of 9 invited/keynote speakers, and provided extensive opportunities for early-career scientists to present talks and posters, compete for recognition awards, and network with senior researchers in the field.

conference↗
DOE OSTI2023

NREL Pyrheliometer Comparisons: September 23 - September 28, 2023 (NPC-2023)

Accurate measurements of direct normal (beam) solar irradiance from pyrheliometers are important for developing and deploying solar energy conversion systems, for improving our understanding of Earth's energy budget for climate change studies, and for other science and technology applications involving solar flux. Providing these measurements places many demands on the quality system used by the operator of commercially available radiometers. Maintaining accurate radiometer calibrations that are traceable to an international standard is the first step in producing research-quality solar irradiance measurements. In 1977, the World Meteorological Organization (WMO) established the World Radiometric Reference (WRR) as the international standard for the measurement of direct normal solar irradiance (Frohlich 1991). The WRR is an internationally recognized, detector-based measurement standard determined by the collective performance of six electrically self-calibrated absolute cavity radiometers comprising the World Standard Group (WSG). Various countries, including the United States, have contributed these specialized radiometers to the Physikalisch-Meteorologisches Observatorium Davos - World Radiation Center (PMOD/WRC) to establish the WSG. As with all measurement systems, Absolute Cavity Radiometers (ACR) are subject to performance changes over time. Therefore, PMOD/WRC in Davos, Switzerland, hosts an quinquennial International Pyrheliometer Comparison (IPC) event for transferring the WRR to participating radiometers by invitation. The National Renewable Energy Laboratory (NREL) has represented the U.S. Department of Energy (DOE) in each IPC since 1980. And NREL has developed and maintained a select group of absolute cavity radiometers with direct calibration traceability to the WRR, and it uses these reference instruments to calibrate pyrheliometers and pyranometers using the International Organization for Standardization (ISO) 17025-accredited Broadband Outdoor Radiometer Calibration (BORCAL) process (Reda et al. 2008). To fill the gap between each IPC, NREL pyrheliometer comparisons (NPCs) are held annually at the Solar Radiation Research Laboratory (SRRL) in Golden, Colorado. Open to all ACR owners and operators, each NPC provides an opportunity to determine the unique WRR transfer factor (WRR-TF) for each participating pyrheliometer. By adjusting all subsequent pyrheliometer measurements by the appropriate WRR-TF, the solar irradiance data are traceable to the WRR.

14 SOLAR ENERGY↗
DOE OSTI2025

Single Component Dye-Sensitized Solar Cells Enabled by Copper Chemistry: Introduction of the Retro Cell

The possibility of utilizing a single molecule to act as both a chromophore and a redox shuttle in a new configuration of a dye-sensitized solar cell (DSSC) is investigated. This design, termed a retro cell, exploits the copper chromophore, [Cu(dsbtmp) 2 ] + (dsbtmp = bis(2,9-di(sec-butyl)-3,4,7,8- tetramethyl-1,10-phenanthroline), which has been shown to have excited state lifetimes in excess of a microsecond, enabling sensitization of TiO 2 while dissolved in solution. The oxidized chromophore can then diffuse to the counter electrode to be regenerated. This concept simplifies the device components and fabrication and eliminates a charge transfer step compared to that of traditional DSSCs. Initial investigations show the concept is viable; however, the performance is suboptimal. We have found the addition of 4-tertbutylpyridine (TBP) to the electrolyte plays a crucial role in enabling solar energy conversion. Evidence of TBP displacing one of the dsbtmp ligands in the oxidized [Cu(dsbtmp) 2 ] 2+ complex has been presented, which likely plays an important role in reducing recombination and enabling charge collection. The performance-limiting steps and routes to improved performance and viability of a retro cell are further discussed.

14 SOLAR ENERGY↗
DOE OSTI2022

2020 Solar Decathlon Education Partner: Cooperative Research and Development (Final Report, CRADA Number CRD-19-00802)

The U.S. Department of Energy Solar Decathlon (DOE/SD) is a collegiate competition, comprising 10 contests, that challenges student teams to design and build highly efficient and innovative buildings powered by renewable energy. The winners will be those teams that best blend architectural and engineering excellence with innovation, market potential, building efficiency, and smart energy production. The DOE/SD is comprised of two Challenges--Design Challenge (annual, in April of each year at NREL in Golden, Colo.) and Build Challenge (biennial, held next in June/July 2020 in Washington D.C.). NREL provides competition management for DOE/SD. For over 35 years, EEBA has provided the most trusted resources for building science information and education in the construction industry. EEBA delivers turn-key educational resources and events designed to transform residential construction practices through high performance design, marketing, materials, and technologies. NREL and EEBA establish this CRADA to enable the success of the DOE/SD program in managing sponsorship funds and creating a professional education program. EEBA acted as an Education Partner to DOE/SD, which included: 1) accepting and dispersing sponsorship funds for DOE/SD; and 2) providing professional development content.

14 SOLAR ENERGY↗
DOE OSTI2020

Surface photovoltage spectroscopy observes junctions and carrier separation in gallium nitride nanowire arrays for overall water-splitting

Gallium nitride (GaN) nanowire arrays on silicon are able to drive the overall water-splitting reaction with up to 3.3% solar-to-hydrogen efficiency. Photochemical charge separation is key to the operation of these devices, but details are difficult to observe experimentally because of the number of components and interfaces. Here, we use surface photovoltage spectroscopy to study charge transfer in i-, n-, and p-GaN nanowire arrays on n+ -Si wafers in the presence and absence of Rh/Cr 2 O 3 co-catalysts. The effect of the space charge layer and sub-bandgap defects on majority and minority carrier transport can be clearly observed, and estimates of the built-in potential of the junctions can be made. Transient illumination of the p-GaN/n + -Si junction generates up to -1.4 V surface photovoltage by carrier separation along the GaN nanowire axis. This process is central to the overall water-splitting function of the n + -Si/p-GaN/Rh/Cr 2 O 3 nanowire array. Overall, these results improve our understanding of photochemical charge transfer and separation in group III–V semiconductor nanostructures for the conversion of solar energy into fuels.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Sustainability pathways for perovskite photovoltaics

Solar energy is the fastest-growing source of electricity generation globally. As deployment increases, photovoltaic (PV) panels need to be produced sustainably. Therefore, the resource utilization rate and the rate at which those resources become available in the environment must be in equilibrium while maintaining the well-being of people and nature. Metal halide perovskite (MHP) semiconductors could revolutionize PV technology due to high efficiency, readily available/accessible materials and low-cost production. Here we outline how MHP-PV panels could scale a sustainable supply chain while appreciably contributing to a global renewable energy transition. Further, we evaluate the critical material concerns, embodied energy, carbon impacts and circular supply chain processes of MHP-PVs. The research community is in an influential position to prioritize research efforts in reliability, recycling and remanufacturing to make MHP-PVs one of the most sustainable energy sources on the market.

14 SOLAR ENERGY↗
DOE OSTI2026

Connecting agriculture and renewable energy: insights into microclimatic changes, physiological, biochemical, and yield responses under agrivoltaics: a review

Agrivoltaics, the synergistic integration of agriculture and solar energy production on the same piece of land, has emerged as a compelling dual-use solution that maximizes land productivity while simultaneously addressing the need for sustainable agricultural practices and renewable energy generation. Despite the growing global interest in this dual-use system, the microclimatic shifts created beneath solar panels and their consequences for crop performance remain insufficiently synthesized. This review highlights the intricate interactions between agrivoltaics systems and plant microclimates, discussing their impacts on various physiological processes, metabolic pathways, and overall yield responses in different crop species. Evidence indicates that moderated light intensity and altered microclimates can enhance water-use efficiency, stabilize photosynthetic function, and trigger beneficial metabolic adjustments; however, responses remain highly species-specific and strongly dependent on regional climate conditions and panel configuration. Yield outcomes vary widely among vegetables, cereals, pulses, and fruit crops, highlighting the necessity for tailored agronomic strategies and crop selection within agrivoltaic designs. A critical knowledge gap identified in this review concerns the limited understanding of molecular and omics-level responses underlying plant adaptation to agrivoltaic environments. We further provide a detailed and interdisciplinary overview of adaptive agronomic strategies, and optimal crop selection, tailored to agrivoltaic systems. Despite the benefits of land use efficiency and simultaneous food and energy production, challenges remain concerning initial investment, technological adaptation, social and legal barriers, and shade-induced yield penalties. Further research in this area will be critical to enhancing the agricultural, environmental, and economic sustainability of agrivoltaics while simultaneously augmenting their practical utility and appeal to farmers in the future.

14 SOLAR ENERGY↗
DOE OSTI2023

Scenario Discovery Analysis of Drivers of Solar and Wind Energy Transitions Through 2050

Deep human-Earth system uncertainties and strong multi-sector dynamics make it difficult to anticipate which conditions are most likely to lead to higher or lower adoption of renewable energy, and models project a broad range of future solar and wind energy shares across future scenarios. To elucidate these dynamics, we explore a large data set of scenarios simulated from the Global Change Analysis Model (GCAM) and use scenario discovery to identify the most significant factors affecting solar and wind adoption by mid-century. We generated a data set of over 4,000 scenarios from GCAM by varying 12 different socioeconomic factors at high and low levels, including assumptions about future energy demand, resource costs, and fossil fuel emissions paths, as well as specific technology assumptions including wind and solar backup requirements and storage costs. Using scenario discovery, we assess the most important factors globally and regionally in creating high fractions of solar and wind energy and explore interconnected effects on other systems including water and non-CO 2 emissions. Globally and regionally, we found that solar and wind-related technology costs were the primary drivers of high wind and solar energy adoption, though a few regions depend heavily on other parameters like carbon capture and storage costs, population and gross domestic product trajectories, and fossil fuel costs. We also identify four key paths to high solar and wind energy by mid-century and discuss their tradeoffs in terms of other outcomes.

14 SOLAR ENERGY↗
DOE OSTI2020

Effects of post-deposition CdCl 2 annealing on electronic properties of CdTe solar cells

The effects of post-deposition CdCl 2 annealing temperature on the electronic properties of CdTe solar cells were investigated. CdTe devices incorporate Mg doped ZnO as a buffer layer and selenization using a CdSe interlayer for reducing the buffer/absorber interface recombination and increasing solar energy absorption respectively. The post-deposition CdCl 2 annealing treatments were done under separate, inert atmospheres of nitrogen and helium across the temperature range 380 to 430 °C. Electrical characterization of devices is carried out including temperature dependent current-voltage characteristics, admittance spectroscopy, and Shockley-Read-Hall recombination analysis. Here, the best improvements in device efficiency are obtained upon annealing at temperature 410 °C. This anneal correlated with reduced back contact barrier in CdTe and reduced grain-boundary barrier height which is beneficial for enhanced charge transport.

14 SOLAR ENERGY↗
DOE OSTI2020

Model of Operation-and-Maintenance Costs for Photovoltaic Systems

This article presents a method for calculating costs associated with operation and maintenance (O&M) of photovoltaic (PV) systems. It compiles details regarding the cost and frequency of multiple O&M services to estimate annual O&M costs ($\$$/year) for each year of an analysis period, the net present value ($\$$) of life cycle costs accumulated over the analysis period, and the reserve account amount ($\$$). Here we show that this method is an improvement over the previous averaged or levelized per-unit ($\$$/kW/year) valuations for estimating PV O&M costs, because it allows a detailed selection of services to perform based on system size, market served (e.g., residential, commercial, or utility), type and configuration of system components (e.g., micro-, string or central inverter) and site and environmental conditions (e.g., snow, pollen, bird populations). This model also distinguishes costs that vary from year to year and increase at different rates over time because of heuristic failure distributions (e.g. Weibull or Lognormal distribution) based on actuarial data for many of the services. This cost model was created by the PV O&M Working Group of researchers and industry, sponsored by DOE Solar Energy Technologies Office, and has been published in an on-line version hosted by SunSpec Alliance at apsuite.sunspec.org. A spreadsheet version is included with this paper as supplementary material.

14 SOLAR ENERGY↗
DOE OSTI2025

SNL NSTTF Heliostat Refurbishment Project Final Report

This document provides an overview of re-start efforts at Sandia National Laboratories (SNL), National Solar Thermal Test Facility (NSTTF), for the DOE SETO SNL Heliostat Refurbishment project. Sandia continues to pursue innovative concentrating solar power (CSP) and thermal (CST) research in order to enhance commercial performance and reduce LCOE and LCOH of concentrating solar energy.

14 SOLAR ENERGY↗
DOE OSTI2020

Photophysical Properties and Electronic Structure of Zinc(II) Porphyrins Bearing 0–4 meso -Phenyl Substituents: Zinc Porphine to Zinc Tetraphenylporphyrin (ZnTPP)

Six zinc(II) porphyrins bearing 0–4 meso-phenyl substituents have been examined spectroscopically and theoretically. Comparisons with previously examined free base analogues afford a deep understanding of the electronic and photophysical effects of systematic addition of phenyl groups in porphyrins containing a central zinc(II) ion versus two hydrogen atoms. Trends in the wavelengths and relative intensities of the absorption bands are generally consistent with predictions from time-dependent density functional theory calculations and simulations from Gouterman’s four-orbital model. These trends derive from a preferential effect of the meso-phenyl groups to raise the energy of the highest occupied molecular orbital. The calculations reveal additional insights, such as a progressive increase in oscillator strength in the violet-red (B-Q) absorption manifold with increasing number of phenyls. Progressive addition of 0–4 phenyl substituents to the zinc porphyrins in O 2 -free toluene engenders a reduction in the measured lifetime of the lowest singlet excited state (2.5–2.1 ns), an increase in the S 1 → S o fluorescence yield (0.022–0.030), a decrease in the yield of S 1 → T 1 intersystem crossing (0.93–0.88), and an increase in the yield of S 1 → S o internal conversion (0.048–0.090). The derived rate constants for S 1 decay reveal significant differences in the photophysical properties of the zinc chelates versus free base forms. Here, the unexpected finding of a larger rate constant for internal conversion for zinc chelates versus free bases is particularly exemplary. Collectively, the findings afford fundamental insights into the photophysical properties and electronic structure of meso-phenylporphyrins, which are widely used as benchmarks for tetrapyrrole-based architectures in solar energy and life sciences research.

14 SOLAR ENERGY↗