Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Sn”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 559 records · Page 31

Long wavelength PbSnTe lasers with CW operation above 77 K

Lead tin telluride diode lasers with emission wavelengths of 6 to 9 micrometers easily operate continuously at temperatures above 77K. These lasers have the Pb(1-y) Sn(y) TE/Pb(1-y) Te/Pb(1-y) Sn(y) Te/PbTe (substrate), (x y) double heterostructure. To prepare this structure by LPE, the growth temperature must be below 600 C to suppress diffusion of the tin during the epitaxial growth. When the heterojunctions are formed by the usual LPE method, the junction boundaries become irregular in the case for the lasers with wavelengths of over 10 micrometers at 77K. The mechanism by which the heterojunction boundaries become irregular is cleared and a new LPE method which prevents the irregularity is explained. The lasers prepared from the wafers grown by the new method have demonstrated CW operation at wavelengths longer than 10 micrometers above liquid nitrogen temperature.

Shinohara, K.↗

Elemental abundances in a Type I supernova remnant

The solid-state spectrometer (SSS) on the HEAO 2 (Einstein) X-ray observatory observed the X-ray spectrum of Tycho's SNR. The observations show a relative excess of line emission from Si, S, and Ar by not less than 6 compared to that expected from a plasma of solar composition in collisional equilibrium and by a factor of not less than 3 compared to Cas A. Similar excesses are not found for line emission from Mg and Fe. The data suggest that the SN observed by Tycho in 1572 produced significant amounts of Si group elements but did not eject large amounts of Fe as predicted by some models of Type I SN events.

Becker, R. H.↗

Liquid-phase electroepitaxy - Dopant segregation

A theoretical model is presented which accounts for the dopant segregation in liquid-phase electroepitaxy in terms of dopant transport in the liquid phase (by electromigration and diffusion), the growth velocity, and the Peltier effect at the substrate-solution interface. The contribution of dopant electromigration to the magnitude of the effective segregation coefficient is dominant in the absence of convection; the contribution of the Peltier effect becomes significant only in the presence of pronounced convection. Quantitative expressions which relate the segregation coefficient to the growth parameters also permit the determination of the diffusion constant and electromigration mobility of the dopant in the liquid phase. The model was found to be in good agreement with the measured segregation characteristics of Sn in the electroepitaxial growth of GaAs from Ga-As solutions. For Sn in Ga-As solution at 900 C the diffusion constant was found to be 4 x 10 to the -5 sq cm/s and the electromigration velocity (toward the substrate with a positive polarity 2 x 10 to the -5 cm/s current density of 10 A/sq cm.

Lagowski, J.↗

Cyanamide mediated synthesis under plausible primitive earth conditions. VI - The synthesis of glycerol and glycerophosphates

The formation of glycerol occurs when a solution of DL-glyceraldehyde is heated in the presence of hydrogen sulfide at room temperature. DL-glyceraldehyde and dihydroxyacetone treated with hydrazine, as well as DL-glyceraldehyde incubated with formaldehyde are also partially converted to glycerol. The yields of the above reactions are from approximately 1% to about 3%. The formation of glycerophosphates occurs when glycerol is heated with ammonium dihydrogen phosphate and either urea or cyanamide. The yield of glycerophosphates is about 30%, most of which is sn-glycero-1(3)-phosphate. These findings indicate that glycerol and sn-glycero-3-phosphate, which are moieties of glycerolipids, could have been formed under conditions which may have prevailed on the primitive earth.

Epps, D. E.↗

Solidification mechanism of highly undercooled metal alloys

Experiments were conducted on metal droplet undercooling, using Sn-25wt%Pb and Ni-34wt%Sn alloys. To achieve the high degree of undercooling, emulsification treatments were employed. Results show the fraction of supersaturated primary phase is a function of the amount of undercooling, as is the fineness of the structures. The solidification behavior of the tin-lead droplets during recalescence was analyzed using three different hypotheses; (1) solid forming throughout recalescence is of the maximum thermodynamically stable composition; (2) partitionless solidification below the T sub o temperature, and solid forming thereafter is of the maximum thermodynamically stable composition; and (3) partitionless solidification below the T sub o temperature with solid forming thereafter that is of the maximum thermodynamically metastable composition that is possible. The T sub o temperature is calculated from the equal molar free energies of the liquid solid using the regular solution approximation.

Shiohara, Y.↗

Hydrogen two photon emission in the UV spectrum of type 2 supernovae

The continuum emission of Type 2 supernovae demonstrates an ultraviolet (UV) excess when fit by black body emission is attempted. The H two photon emission is advanced as an explanation of the UV excess. A function by which the UV spectra of two Type 2 supernovae (SN 1979c in NGC 4321 and SN 1980k in NGC 6946) are fitted with U,B,V photometric data is presented. The angular velocity of expansion of the supernovae envelope is derived. From this, the linear velocity of expansion and the distances of the parent galaxies are derived. A distance of 17.3 Mpc is obtained for NGC 4321, and a distance of 7.1 Mpc for NGC 6946.

Benvenuti, P.↗

Detection of X-rays during the outburst of supernova 1980k

X-ray emission from SN 1980k in NGC 6946 was detected about 35 days after maximum light using the imaging proportional counter on the Einstein Observatory. The absorption corrected X-ray flux of SN 1980k was about 0.03 micro-Jy at 0.24 x 10 to the 18th Hz (1 keV), which corresponds to a luminosity of about 2 x 10 to the 39th ergs/s (0.2-4 keV) at 10 Mpc. This detection of radio emission suggests the presence of relativistic electrons and a magnetic field strength of not greater than about 1 gauss. Inverse Compton scattering of the optical photons on the electrons can explain the X-ray emission without additional ad hoc assumptions, although other emission mechanisms are possible.

Canizares, C. R.↗

Gamma ray lines from buried supernovae

An investigation is conducted concerning the possibility that supernovae (SN), located in dense interstellar clouds, might become the sources of gamma ray lines. The SN progenitor, in such a case, has to be an O or B star so that its evolutionary lifetime is short, and an explosion inside the cloud is still possible. It is shown that, in principle, a measurement of the abundances in the ejecta is possible. Attention is given to the characteristics of a model, the expected luminosity of gamma-ray lines, and the study of specific numerical examples for testing the feasibility of the considered mechanism. On the basis of the obtained results, it is concluded that gamma-ray line production by collisional excitation in confined supernovae remnants may be quite important.

Morfill, G. E.↗

Cavitation Erosion of Copper, Brass, Aluminum and Titanium Alloys in Mineral Oil

The variations of the mean depth of penetration, the mean depth rate of penetration, MDRP, the pit diameter 2a and depth h due to cavitation attack on Al 6061-T6, Cu, brass of composition Cu-35Zn-3Pb and Ti-5A1-2.5Sn are presented. The experiments are conducted in a mineral oil of viscosity 110 CS using a magnetostrictive oscillator of 20 kHz frequency. Based on MDRP on the materials, it is found that Ti-5Al-2.5Sn exhibits cavitation erosion resistance which is two orders of magnitude higher than the other three materials. The values of h/a are the largest for copper and decreased with brass, titanium, and aluminum. Scanning electron microscope studies show that extensive slip and cross slip occurred on the surface prior to pitting and erosion. Twinning is also observed on copper and brass.

Rao, B. C. S.↗

Einstein observations of supernova remnants

Recent observations of SNRs have produced X-ray images with resolution comparable to that routinely achieved at optical wavelengths. There has also been a great improvement in the quality of X-ray spectra. Since most of the energy radiated by SNRs appears as X-rays, these new data are crucial to studies of SNRs, the interaction of SNRs with the interstellar medium, and the SN explosion itself. Images show a variety of shapes ranging from shell-like remnants to those dominated by the influence of central objects which appear both as point sources and as centers of diffuse activity. Once the temperature and spatial distribution of X-ray emitting material is known, the mass of ejected material and the energy release of the SN explosion can sometimes be calculated. X-ray images and spectra of several remnants are shown, and some quantitative results are given.

Seward, F. D.↗

The young sun and the atmosphere and photochemistry of the early earth

The origin and evolution of the earth's early atmosphere depend crucially on the dissipation time of the primitive solar nebula (SN). Using different theories of turbulence, the dissipation time of an SN of 0.1 solar mass is estimated as 2.5-8.3 Myr. Because accretion times are usually much longer, it is concluded that most planetary accretion must have occurred in a gas-free environment. Using new IUE data, a wavelength-dependent UV flux is constructed for the young sun which is then used to study the photochemistry and concentrations of O, O2, O3, OH, H, HCO and formaldehyde H2CO in the earth's early prebiological atmosphere.

Canuto, V. M.↗

X-ray synchrotron nebulae and the origin of neutron stars

Einstein Observatory (EO) X ray data on supernova remnants (SNR) and radio pulsars are examined for evidence supporting the concept that neutron stars arise after supernova (SN) events. Recent data reviews have revealed that only 13 of the 140 known galactic SNR exhibit characteristics, e.g., radio pulsars, X ray binaries or synchrotron nebulae, that link neutron stars with SNR. An EO survey of radio pulsars 1 kyr-1 Myr old found eight objects, all embedded in X ray emitting nebulae. The data indicated that all the SNR and pulsar objects had about 1 percent of their spin down energy converted into synchrotron X rays. The majority of SNRs did not have X ray emitting nebulae. It is therefore concluded that only some SN events result in a neutron star, while the event may leave no remnant at all.

Helfand, D. J.↗

Heating of the interstellar medium by supernova remnants

Models for the mechanisms active during supernova (SN) heating of surrounding regions are examined. SNs heat both the matrix material and material in the nearby interstellar medium, and also accelerate cosmic rays with shock waves. Fountain and wind models vary according to the SN power and mass acquisition rate. Additionally, a warm intercloud medium may be fed by returning fountain material and stellar mass loss. The thermal wind temperature varies with the number of solar massess heated, although remnants have been observed to vanish in the LMC when more than 100 solar masses were heated. The possibility that the solar system is inside a remnant that produces the observed soft X-ray background is considered.

Cox, D. P.↗

Solar neutrino: Flux, cosmic rays and the 11 year solar cycle

It is shown that the results of maximum likelihood treatment of Monte Carlo simulation with constant production rate of 7.6 SNU and 1.Epsilon SNU are consistent with the constant production rate when the tests of hypotheses (e.g., t-test, sigma squared-test, Wilcoxon-Mann-Whitney test, run test, etc.) are applied to the two groups of data formed from sunspot minimum range and sunspot maximum range, whereas the real data pulsates with the solar activity cycle. It is shown that SN flux-change is in opposition phase to the solar activity cycle and lags behind the latter by about one year. A correlation between SN flux and the cosmic rays is suggested.

Raychaudhuri, P.↗

The destruction of dust grains in collisions of a supernova with a circumstellar medium

Dust grains exist, if not abundantly, in systems composed of a Type II supernova and a circumstellar medium (CSM). The grains, however, may subsequently suffer intense sputtering by X-ray emitting plasmas during the collision of the supernova ejecta with the CSM. An approximate expression is obtained for the amount of grain erosion in both the blast-shocked CSM and the reverse-shocked ejecta, assuming their self-similar interaction. The distortion of the grain size distribution is also calculated. In the remnant of SN 1979c, the population of the grains of radius 0.1 micron, for example, will be diminished substantially in both the ejecta and the CSM, while in the remnant of SN 1980k, it will be affected considerably only in the ejecta. The infrared fluxes expected from the blast-shocked CSM are roughly estimated. The present destruction mechanism may be responsible for the severe under-abundance of dust in the Cassiopeia A supernova remnant.

Itoh, H.↗

Containerless Studies of Nucleation and Undercooling

The long term research goals are to perform experiments to determine the achievable limits of undercooling, the characteristics of heterogeneous nucleation, and the physical properties of significantly undercooled melts. The techniques used are based on the newly developed containerless manipulation methods afforded by acoustic levitation. Ground based investigations involved 0.1 to 2 mm specimens of pure metals and alloys (In, Ga, Sn, Ga-In, ...) as well as glass-forming organic compounds (O-Terphenyl). A currently operating ultrasonic high temperature apparatus has allowed the ground-based levitation of 1 to 2 mm samples of solid aluminum at 550 deg C in an argon atmosphere. Present work is concentrating on the undercooling of pure metal samples (In, Sn), and on the measurements of surface tension and viscosity of the undercooled melts via shape oscillation techniques monitored through optical detection methods. The sound velocity of undercooled O-Terphenyl is being measured in an immiscible liquid levitation cells.

Trinh, E. H.↗

Effects of supercooling in the initial solidification of PbTe-SnTe solid solutions

Deviations from compositions anticipated by the thermal equilibrium phase diagram have been observed in Bridgman-grown crystals of Pb(1-x)Sn(x)Te, in the first to freeze region of the boule. A set of experiments were conducted to determine the extent of thermal supercooling of Pb(1-x)Sn(x)Te in a Bridgman-like configuration. The results of the compositional profiles and the supercooling measurements are consistent with a diffusionless transformation occurring at the onset of solidification, and the length of uncontrolled growth is inversely related to the temperature gradient of the furnace.

Fripp, A. L.↗

IUE observations of magnetically controlled stellar winds in the helium peculiar stars

Dramatic periodic variations in the C IV resonance lines of magnetic helium-weak sn stars HD 5737 = alpha Scl, HD 21699 = HR 1063, and HD 79158 = 36 Lyn are discussed. In all three cases, the 1548,50 doublet is the only non-negligibly variable UV spectral feature. The line profiles are consistent with outflow in a jet-like structure. In HD 21699 this outflow arises from one of the magnetic polar regions. Observations of two additional He-wk sn stars do not reveal strong C IV absorption, implying that the UV characteristics of these stars are less uniform than the optical phenomenology.

Shore, Steven N.↗