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At least 559 records · Page 31

A review on snake robot testbeds in granular and restricted maneuverability spaces

Here this article reviews the state of the art in evaluating snake robots for small spaces such as a collapsed building where the snake is either locomoting in restricted maneuverability spaces, such as narrow pipes or tunnels, or pushing through granular regions, such as dirt and rubble. It makes recommendations on designing a testbed that can enable a comprehensive evaluation of a snake robot’s overall capability and an objective comparison of different snakes. A survey of 31 papers reveals that 20 testbeds were used to test snake robots in restricted maneuverability environments. All of those were built specifically to test a particular snake robot rather than for comparison with other snake robots, but each offers insights into designing comprehensive, comparative testbeds. The article analyzed these 20 testbeds in terms of how well they addressed the previously established disaster robotics metrics of scale (a dimensionless number) and four traversability elements, i.e. verticality, tortuosity, accessibility elements, and surface properties. This review suggests that two kinds of general testbeds are in need for the snake robot community: (1) a testbed with high physical fidelity for measuring suitability for a target application, and (2) a testbed which provides a dimensionless comparison of different snake robots. The review is expected to benefit the community in several ways. It can help form a consensus on a suite of metrics and test methods to incorporate into a testbed for evaluating and comparing different types of snake robots and capturing the performance of snake robots in more realistic work envelopes. The metrics and test methods can also pro-actively inform snake robot design as they offer more formally quantified work envelopes, thus accelerating technology transfer. The use of scale and traversability is expected to be applicable to robots in general.

42 ENGINEERING↗

Advancing hydrogen production: A comprehensive review of wastewater reforming techniques, feedstocks, and opportunities

Wastewater is produced across nearly all human activities and requires treatment to safeguard human health and the natural environment. Treatment of wastewater often requires a large amount of thermal energy, resulting in wasted heat after the treatment process. Because hydrocarbon reforming needs both water and heat, the integration of wastewater treatment with hydrocarbon reforming, a process that produces synthesis gas rich in hydrogen, offers an excellent opportunity to utilize this waste heat and the impurities in wastewater to produce valuable hydrogen gas, to minimize waste from industrial processes, and to integrate water treatment with the hydrogen economy. Yet, no comprehensive literature review has been conducted to examine the integration of reforming and wastewater. To address this lack, we summarize the variety of catalytic reforming techniques available in the open literature and review the current literature on wastewater reforming with these techniques. Subsequently, we conduct a review of common types of wastewater contaminants and their possible effects on reforming catalyst performance and life. Lastly, three underexamined wastewater sources are identified, namely, oilfield wastewater, geothermal water, and mining and mineral processing wastewater, and their potential for future study as a reforming feedstock is examined.

08 HYDROGEN↗

Photon management in silicon photovoltaic cells: A critical review

With the practical efficiency of the silicon photovoltaic (PV) cell approaching its theoretical limit, pushing conversion efficiencies even higher now relies on reducing every type of power loss that can occur within the device. Limiting optical losses is therefore critical and requires effective management of incident photons in terms of how they interact with the device. Ultimately, photon management within a PV cell means engineering the device and constituent materials to maximize photon absorption within the active semiconductor and therefore reduce the number of photons lost through other means, most notably reflection and parasitic absorption. There have been great advancements in the front and the rear side photon management techniques in recent years. This review aims to discuss these advancements and compare the various approaches, not only in terms of increases in photogenerated current, but also their compatibility with different PV cell architectures and potential trade-offs, like increased surface recombination or scalability for high-volume manufacturing. In this review, a comprehensive discussion of a wide variety of the front and the rear side photon management structures are presented with suggestions to improve the already achieved performance further. Here, this review is unique because it not only presents the recent development in photon management techniques, but also offers through analysis of these techniques and pathways to improve further.

14 SOLAR ENERGY↗

A review of dark fermentative hydrogen production from biodegradable municipal waste fractions

Highlights: ► A large number of factors affect fermentative hydrogen production. ► Harmonization and systematic comparison of results from different literature sources are needed. ► More than 80 publications on H{sub 2} production from food waste and OFMSW have been examined. ► Experimental data from the reviewed literature were analyzed using statistical tools. ► For a reliable assessment of the process performance, the use of multiple parameters appears to be recommended. - Abstract: Hydrogen is believed to play a potentially key role in the implementation of sustainable energy production, particularly when it is produced from renewable sources and low energy-demanding processes. In the present paper an attempt was made at critically reviewing more than 80 recent publications, in order to harmonize and compare the available results from different studies on hydrogen production from FW and OFMSW through dark fermentation, and derive reliable information about process yield and stability in view of building related predictive models. The review was focused on the effect of factors, recognized as potentially affecting process evolution (including type of substrate and co-substrate and relative ratio, type of inoculum, food/microorganisms [F/M] ratio, applied pre-treatment, reactor configuration, temperature and pH), on the fermentation yield and kinetics. Statistical analysis of literature data from batch experiments was also conducted, showing that the variables affecting the H{sub 2} production yield were ranked in the order: type of co-substrate, type of pre-treatment, operating pH, control of initial pH and fermentation temperature. However, due to the dispersion of data observed in some instances, the ambiguity about the presence of additional hidden variables cannot be resolved. The results from the analysis thus suggest that, for reliable predictive models of fermentative hydrogen production to be derived, a high level of consistency between data is strictly required, claiming for more systematic and comprehensive studies on the subject.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A review of technologies and performances of thermal treatment systems for energy recovery from waste

Highlights: • The topic of energy recovery from waste by thermal treatment is reviewed. • Combustion, gasification and pyrolysis were considered. • Data about energy recovery performances were collected and compared. • Main limitations to high values of energy performances were illustrated. • Diffusion of energy recovery from waste in EU, USA and other countries was discussed. - Abstract: The aim of this work is to identify the current level of energy recovery through waste thermal treatment. The state of the art in energy recovery from waste was investigated, highlighting the differences for different types of thermal treatment, considering combustion/incineration, gasification and pyrolysis. Also different types of wastes – Municipal Solid Waste (MSW), Refuse Derived Fuel (RDF) or Solid Refuse Fuels (SRF) and some typologies of Industrial Waste (IW) (sludge, plastic scraps, etc.) – were included in the analysis. The investigation was carried out mainly reviewing papers, published in scientific journals and conferences, but also considering technical reports, to gather more information. In particular the goal of this review work was to synthesize studies in order to compare the values of energy conversion efficiencies measured or calculated for different types of thermal processes and different types of waste. It emerged that the dominant type of thermal treatment is incineration associated to energy recovery in a steam cycle. When waste gasification is applied, the produced syngas is generally combusted in a boiler to generate steam for energy recovery in a steam cycle. For both the possibilities – incineration or gasification – cogeneration is the mean to improve energy recovery, especially for small scale plants. In the case of only electricity production, the achievable values are strongly dependent on the plant size: for large plant size, where advanced technical solutions can be applied and sustained from an economic point of view, net electric efficiency may reach values up to 30–31%. In small-medium plants, net electric efficiency is constrained by scale effect and remains at values around 20–24%. Other types of technical solutions – gasification with syngas use in internally fired devices, pyrolysis and plasma gasification – are less common or studied at pilot or demonstrative scale and, in any case, offer at present similar or lower levels of energy efficiency.

09 BIOMASS FUELS↗

Review on landfill leachate treatment by electrochemical oxidation: Drawbacks, challenges and future scope

Highlights: • Comparison is made between conventional and bioreactor landfill leachate. • Organics and ammonium nitrogen removal mechanism have been described. • Various influencing factors of EO process have been discussed. • Application of EO combined with biological/physicochemical process is reviewed. • Incorporation of LCA in LL treatment technology selection is proposed. - Abstract: Various studies on landfill leachate treatment by electrochemical oxidation have indicated that this process can effectively reduce two major pollutants present in landfill leachate; organic matter and ammonium nitrogen. In addition, the process is able to enhance the biodegradability index (BOD/COD) of landfill leachate, which make mature or stabilized landfill leachate suitable for biological treatment. The elevated concentration of ammonium nitrogen especially observed in bioreactor landfill leachate can also be reduced by electrochemical oxidation. The pollutant removal efficiency of the system depends upon the mechanism of oxidation (direct or indirect oxidation) which depends upon the property of anode material. Applied current density, pH, type and concentration of electrolyte, inter-electrode gap, mass transfer mode, total anode area to volume of effluent to be treated ratio, temperature, flow rate or flow velocity, reactor geometry, cathode material and lamp power during photoelectrochemical oxidation may also influence the system performance. In this review paper, past and present scenarios of landfill leachate treatment efficiencies and costs of various lab scale, pilot scale electrochemical oxidation studies as a standalone system or integrated with biological and physicochemical processes have been reviewed with the conclusion that electrochemical oxidation can be employed as a complementary treatment system with biological process for conventional landfill leachate treatment as well as a standalone system for ammonium nitrogen removal from bioreactor landfill leachate. Furthermore, present drawbacks of electrochemical oxidation process as a landfill leachate treatment system and relevance of incorporating life cycle assessment into the decision-making process besides process efficiency and cost, have been discussed.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Global status of recycling waste solar panels: A review

Highlights: • Solar panel recycling minimizes waste of environmental and economic resources. • Several processing methods from the literature are evaluated. • The status of the management for waste solar panels are systemically reviewed and discussed. • Policy should be formulated to encourage recycling of waste solar panels. • Manufacturers should take greater responsibility for recycling. - Abstract: With the enormous growth in the development and utilization of solar-energy resources, the proliferation of waste solar panels has become problematic. While current research into solar panels has focused on how to improve the efficiency of the production capacity, the dismantling and recycling of end-of-life (EOL) panels are seldom considered, as can be seen, for instance, in the lack of dedicated solar-panel recycling plants. EOL solar-panel recycling can effectively save natural resources and reduce the cost of production. To address the environmental conservation and resource recycling issues posed by the huge amount of waste solar panels regarding environmental conservation and resource recycling, the status of the management and recycling technologies for waste solar panels are systemically reviewed and discussed in this article. This review can provide a quantitative basis to support the recycling of PV panels, and suggests future directions for public policy makers. At present, from the technical aspect, the research on solar panel recovery is facing many problems, and we need to further develop an economically feasible and non-toxic technology. The research on solar photovoltaic panels’ management at the end of life is just beginning in many countries, and there is a need for further improvement and expansion of producer responsibility.

14 SOLAR ENERGY↗

Designing clay-polymer nanocomposite sorbents for water treatment: A review and meta-analysis of the past decade

Clay-polymer nanocomposites (CPNs) have been studied for two decades as sorbents for water pollutants, but their applicability remains limited. Our aim in this review is to present the latest progress in CPN research using a meta-analysis approach and identify key steps necessary to bridge the gap between basic research and CPN application. Based on results extracted from 99 research articles on CPNs and 8 review articles on other widely studies sorbents, CPNs had higher adsorption capacities for several inorganic and organic pollutant classes (including heavy metals, oxyanions, and dyes, n = 308 observations). We applied principal component analysis, analysis of variance, and multiple linear regressions to test how CPN and pollutant properties correlated with Langmuir adsorption model coefficients. While adsorption was, surprisingly, not influenced by mineral properties, it was influenced by CPN fabrication method, polymer functional groups, and pollutant properties. For example, among the pollutant classes, heavy metals had the highest adsorption capacity but the lowest adsorption affinity. Conversely, dyes had high adsorption affinities, as reflected by the linear correlation between adsorption affinity and pollutant molecular weight. Scaling from ‘basic research’ to ‘technological application’ requires testing CPN performance in real water, application in columns, comparison to commercial sorbents, regeneration, and cost evaluation. However, our survey indicates that of the 158 observations, only 20 compared the CPN's performance to that of a commercial sorbent. We anticipate that this review will promote the design of smart and functional CPNs, which can then evolve into an effective water treatment technology.

42 ENGINEERING↗

Ceramic–Metal (Cermet) Composites: A Review of Key Properties and Synthesis Methods Focused on Nuclear Waste Immobilization

Here this paper reviews key properties, applications, and examples of ceramic-metal composites (cermets), and metal matrix composites (MMC) with emphasis on their applicability as waste forms for immobilizing nuclear waste. While the literature is mature for vitrified and cementitious radioactive waste forms, cermet materials have not received adequate attention as potential candidates for immobilizing nuclear waste. To promulgate this effort, this review connects cermet and MMC design, such as hardened tools, with the chemistry of radioactive waste streams. A discussion on certification and qualification standards for cermet waste forms, literature gaps, and “how-to” sections on cermet processing techniques. Key parameters discussed include thermal conductivity, chemical durability, and waste loading, as well as examples for metal-containing waste forms. As cermet waste forms gain momentum within the community, this review paper aims ensure the end-of-life nuclear fuel cycle is addressed from a materials and waste disposition perspective.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Review of Computational Models for the Flow of Milled Biomass Part II: Continuum-Mechanics Models

The design of efficient material-handling systems for milled lignocellulosic biomass is challenging due to their complex particle morphologies and frictional interactions. Computational modeling, including the discrete element method (DEM) and continuum-based finite-element/volume methods, may offer scientific insight and predictive capabilities for the flow of milled biomass in hoppers and feeders. Herein, this article (Part II) presents a review of current state-of-the-art continuum models for the flow of milled biomass, whereas DEM models are reviewed in a companion article (Part I). Advances of numerical methods to solve the global governing equations are discussed first, followed by a comprehensive review of constitutive models for granular materials, including Drucker–Prager, hypoplastic, Cambridge-type, inertial-rheology, and nonlocal granular fluidity models. Specifically, we provide in-depth discussion on the suitability of those models for milled lignocellulosic biomass materials in terms of nonlinear elasticity, dependence of flow strength on pressure, density and shear rate, and compaction (dilation) associated with hardening (softening). Furthermore, our study shows that, despite the recent advances in continuum granular flow modeling, the most suitable constitutive models still need further development to account for material parametrization, multiflow regimes, and multiscale behavior before they can be reliably used to optimize the design and operation of biomass handling systems.

09 BIOMASS FUELS↗

Atmospheric Research Over the Extended Western North Atlantic Ocean Region and North American East Coast: A Review of Past Work and Challenges Ahead

Decades of atmospheric research have focused on the extended Western North Atlantic Ocean (WNAO) region, including the East Coast of North America and the island of Bermuda, because of its unique location that offers accessibility, gradients in important atmospheric parameters, and a range of meteorological regimes leading to diverse conditions that are poorly understood. This work reviews decades of scientific investigations for the extended WNAO region. Approximately 40 combined field campaigns and long-term monitoring programs, in addition to 563 peer-reviewed publications between 1950 and 2019 have provided a firm foundation of knowledge for the extended WNAO region. Of particular importance in this region has been extensive work at the island of Bermuda that is host to important time series records of oceanic and atmospheric variables. Our review categorizes WNAO research into eight major categories, with some studies fitting into multiple categories (relative %): Aerosols (26%), Gases (23%), Development/Validation of Techniques, Models, and Retrievals (17%), Meteorology and Transport (10%), Air-Sea Interactions (9%), Wet Deposition (6%), Clouds/Storms (6%), and Aerosol-Cloud Interactions (3%). These extensive works have revealed a series of major knowledge gaps. For instance, a disproportionately low number of studies have been devoted to aerosol-cloud interactions, which is identified here as one of the most pressing research needs for the extended WNAO region. Recommendations for future research are provided in the categories highlighted above. Part 2 of this paper series will summarize major spatial and temporal features for the extended WNAO region.

Sorooshian, Armin↗

Review: Induced Seismicity During Geoenergy Development—A Hydromechanical Perspective

The basic triggering mechanism underlying induced seismicity traces back to the mid-1960s that relied on the process of pore-fluid pressure diffusion. The last decade has experienced a renaissance of induced seismicity research and data proliferation. An unprecedent opportunity is presented to us to synthesize the robust growth in knowledge. The objective of this article is to provide a concise review of the triggering mechanisms of induced earthquakes with a focus on hydro-mechanical processes. Four mechanisms are reviewed: pore-fluid pressure diffusion, poroelastic stress, Coulomb static stress transfer, and aseismic slip. For each, an introduction of the concept is presented, followed by case studies. Diving into these mechanisms sheds light on several outstanding questions. For example, why did some earthquakes occur far from fluid injection or after injection stopped? Our review converges on the following conclusions: (a) Pore-fluid pressure diffusion remains a basic mechanism for initiating inducing seismicity in the near-field. (b) Poroelastic stresses and aseismic slip play an important role in inducing seismicity in regions beyond the influence of pore-fluid pressure diffusion. (c) Coulomb static stress transfer from earlier seismicity is shown to be a viable mechanism for increasing stresses on mainshock faults. (d) Multiple mechanisms have operated concurrently or consecutively at most induced seismicity sites. (e) Carbon dioxide injection is succeeding without inducing earthquakes and much can be learned from its success. Future research opportunities exist in deepening the understanding of physical and chemical processes in the nexus of geoenergy development and fluid motion in the Earth’s crust.

58 GEOSCIENCES↗

Agrivoltaic Grazing Systems for a Sustainable Future: A Multi‐Disciplinary Review & Gap Analysis

Solar photovoltaics (PV) is the fastest growing source of electricity in the world, however, its expansion has raised concerns about the displacement of agriculture and the degradation of rangeland ecosystems. This has prompted research and development of multi-land-use systems that co-prioritize energy production alongside agriculture, commonly referred to as agrivoltaics. Currently, agrivoltaic grazing (also called solar grazing) is one of the most common forms of these systems. However, peer-reviewed research on these systems is limited. This review synthesizes research on agrivoltaic grazing systems, drawing upon literature addressing agrivoltaics broadly and considering relevant literature in adjacent fields of study. Based on this review, we identify six key gaps and priority directions for future research. These include foundational fieldwork to characterize the layered ecological impacts of solar PV and grazing and understand PV-livestock integration from both an animal welfare and a PV infrastructure perspective. This will facilitate the development of biogeochemical and economic models that improve our predictive capacity and ability to compare system designs. We also identify gaps in understanding the human aspects of these systems and emphasize the importance of utilizing collaborative research methods and increasing research on the social dimensions of agrivoltaic grazing systems.

14 SOLAR ENERGY↗

Curation of a list of chemicals in biosolids from EPA National Sewage Sludge Surveys & Biennial Review Reports

Section 405(d) of the Clean Water Act requires the US Environmental Protection Agency to review sewage sludge regulations every two years to identify any additional pollutants that may occur in biosolids and to set regulations for pollutants identified in biosolids if sufficient scientific evidence shows they may harm human health or the environment. To date, EPA has conducted eight biennial reviews to identify chemical and microbial pollutants and three national sewage sludge surveys to identify pollutants and obtain concentration data for chemicals found in biosolids. Prior to 2021, there was inconsistent reporting of chemicals identified and EPA did not cumulatively track chemicals in biosolids. Through the efforts presented here, EPA produced a list of 726 chemicals and structure-based classes found in biosolids based on biennial reviews and national sewage sludge surveys. Summary statistics of concentration data are also reported for the 484 chemicals found in the three national sewage sludge surveys. The creation of the Biosolids List supports EPA in assessing the potential risk of chemical pollutants found in biosolids.

54 ENVIRONMENTAL SCIENCES↗

The inorganic chemist's guide to actinide radiation chemistry: a review

This review aims to provide an overview of the current state of radiation chemistry with respect to the actinide elements, thorium through californium. Despite the inherent radioactivity of the actinides, only a few studies explore the effects of ionizing radiation on their redox chemistry and surrounding environment. This fundamental knowledge gap, coupled with the current renaissance in actinide-based technologies such as nuclear power, space exploration, and medicine, underscores the importance of research in this interdisciplinary area. This review will focus on the interactions between reactive species formed by radiolysis with actinides and their complexes, offering an inorganic chemist's perspective on research in radiation chemistry. In addition, a thorough discussion of our current understanding of radiation-induced changes in actinide speciation in both aqueous solution and the solid-state will be provided, focusing on changes in oxidation state distribution, complexation, and secondary coordination effects within inorganic materials. Finally, this review will discuss challenges and opportunities for inorganic chemists to explore this unique intersection of fields.

Actinides↗

A review on nanomechanical resonators and their applications in sensors and molecular transportation

Nanotechnology has opened a new area in science and engineering, leading to the development of novel nano-electromechanical systems such as nanoresonators with ultra-high resonant frequencies. The ultra-high-frequency resonators facilitate wide-ranging applications such as ultra-high sensitive sensing, molecular transportation, molecular separation, high-frequency signal processing, and biological imaging. This paper reviews recent studies on dynamic characteristics of nanoresonators. A variety of theoretical approaches, i.e., continuum modeling, molecular simulations, and multiscale methods, in modeling of nanoresonators are reviewed. The potential application of nanoresonators in design of sensor devices and molecular transportation systems is introduced. The essence of nanoresonator sensors for detection of atoms and molecules with vibration and wave propagation analyses is outlined. The sensitivity of the resonator sensors and their feasibility in detecting different atoms and molecules are particularly discussed. Furthermore, the applicability of molecular transportation using the propagation of mechanical waves in nanoresonators is presented. An extended application of the transportation methods for building nanofiltering systems with ultra-high selectivity is surveyed. The article aims to provide an up-to-date review on the mechanical properties and applications of nanoresonators, and inspire additional potential of the resonators.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Distributed optical fiber sensing: Review and perspective

Over the past few decades, optical fibers have been widely deployed to implement various applications in high-speed long-distance telecommunication, optical imaging, ultrafast lasers, and optical sensors. Distributed optical fiber sensors characterized by spatially resolved measurements along a single continuous strand of optical fiber have undergone significant improvements in underlying technologies and application scenarios, representing the highest state of the art in optical sensing. This work is focused on a review of three types of distributed optical fiber sensors which are based on Rayleigh, Brillouin, and Raman scattering, and use various demodulation schemes, including optical time-domain reflectometry, optical frequency-domain reflectometry, and related schemes. Recent developments of various distributed optical fiber sensors to provide simultaneous measurements of multiple parameters are analyzed based on their sensing performance, revealing an inherent trade-off between performance parameters such as sensing range, spatial resolution, and sensing resolution. This review highlights the latest progress in distributed optical fiber sensors with an emphasis on energy applications such as energy infrastructure monitoring, power generation system monitoring, oil and gas pipeline monitoring, and geothermal process monitoring. This review aims to clarify challenges and limitations of distributed optical fiber sensors with the goal of providing a pathway to push the limits in distributed optical fiber sensing for practical applications.

Lu, Ping (ORCID:0000000292010956)↗

Review of radiation-induced defects in GaAs

Radiation-resilient optoelectronic materials are highly desired in space and nuclear applications, and understanding the relevant defects and electronic processes in those materials is crucial for both current and next-generation applications. GaAs is a prototypical semiconductor that serves as a foundational system for describing and understanding optoelectronic devices. In this review, both experimental studies and molecular dynamics (MD) simulations of irradiated GaAs are reviewed, with particular emphasis on the deep-level transient spectroscopy, irradiation-induced amorphization zones, and MD predictions of damage structures. The MD results are also compared to predictions of the non-ionized energy-loss model. Recent theoretical studies, in particular, density functional theory based calculations on the simple intrinsic defects and defect clusters in GaAs, are also reviewed. These defects have an important role in dictating the evolution of GaAs in radiation damage environments, as they impact the coupled dynamics of charge carriers. Finally, possible gaps and challenges toward the general understanding of defect evolution in GaAs are discussed.

36 MATERIALS SCIENCE↗