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At least 559 records · Page 31

Multiple scattered radiation emerging from continental haze layers. 2: Ellipticity and direction of polarization

The ellipticity and the direction of polarization are calculated for radiation that has undergone multiple scattering from plane parallel layers. Both the radiation emerging from the top of the layer and that transmitted through the bottom are considered. Two different phase functions are used for the scattering layer: Rayleigh and haze L. The direction of polarization of the reflected radiation shows little variation as the optical depth of the layer increases, while there is a much larger variation for the transmitted radiation. When the optical thickness is small, the direction of polarization for haze L varies rapidly with zenith angle near those angles at which the single scattered polarization is zero. The ellipticity of the radiation from haze L layers increases at first in direct proportion to the optical thickness of the layer. In general the ellipticity of the transmitted radiation is considerably greater than that of the reflected because of the greater average number of photon collisions in the former case.

Plass, G. N.↗

Light scattering by tenuous particles - A generalization of the Rayleigh-Gans-Rocard approach

We consider scattering by arbitrarily shaped particles that satisfy two conditions: (1) that the polarizability of the particle relative to the ambient medium be small compared to 1 and (2) that the phase shift introduced by the particle be less than 2. We solve the integro-differential equation proposed by Shifrin by using the method of successive iterations and then applying a Fourier transform. For the second iteration, results are presented that accurately describe scattering by a broad class of particles. The phase function and other elements of the scattering matrix are shown to be in excellent agreement with Mie theory for spherical scatterers.

Acquista, C.↗

Radar Differential Phase Signatures of Ice Orientation for the Prediction of Lightning Initiation and Cessation

The majority of lightning-related casualties typically occur during thunderstorm initiation (e.g., first flash) or dissipation (e.g., last flash). The physics of electrification and lightning production during thunderstorm initiation is fairly well understood. As such, the literature includes a number of studies presenting various radar techniques (using reflectivity and, if available, other dual-polarimetric parameters) for the anticipation of initial electrification and first lightning flash. These radar techniques have shown considerable skill at forecasting first flash. On the other hand, electrical processes and lightning production during thunderstorm dissipation are not nearly as well understood and few, if any, successful techniques have been developed to anticipate the last flash and subsequent cessation of lightning. One promising approach involves the use of dual-polarimetric radar variables to infer the presence of oriented ice crystals in lightning producing storms. In the absence of strong vertical electric fields, ice crystals fall with their largest (semi-major) axis in the horizontal associated with gravitational and aerodynamic forces. In thunderstorms, strong vertical electric fields (100-200 kV m(sup -1)) have been shown to orient small (less than 2 mm) ice crystals such that their semi-major axis is vertical (or nearly vertical). After a lightning flash, the electric field is typically relaxed and prior radar research suggests that ice crystals rapidly resume their preferred horizontal orientation. In active thunderstorms, the vertical electric field quickly recovers and the ice crystals repeat this cycle of orientation for each nearby flash. This change in ice crystal orientation from primarily horizontal to vertical during the development of strong vertical electric fields prior to a lightning flash forms the physical basis for anticipating lightning initiation and, potentially, cessation. Research has shown that radar reflectivity (Z) and other co-polar back-scattering radar measurements like differential reflectivity (Z(sub dr)) typically measured by operational dual-polarimetric radars are not sensitive to these changes in ice crystal orientation. However, prior research has demonstrated that oriented ice crystals cause significant propagation effects that can be routinely measured by most dual-polarimetric radars from X-band (3 cm) to S-band (10 cm) wavelengths using the differential propagation phase shift (often just called differential phase, phi(sub dp)) or its range derivative, the specific differential phase (K(sub dp)). Advantages of the differential phase include independence from absolute or relative power calibration, attenuation, differential attenuation and relative insensitivity to ground clutter and partial beam occultation effects (as long as the signal remains above noise). In research mode, these sorts of techniques have been used to anticipate initial cloud electrification, lightning initiation, and cessation. In this study, we develop a simplified model of ice crystal size, shape, orientation, dielectric, and associated radar scattering and propagation effects in order to simulate various idealized scenarios of ice crystals responding to a hypothetical electric field and their dual-polarimetric radar signatures leading up to lightning initiation and particularly cessation. The sensitivity of the K(sub dp) ice orientation signature to various ice properties and radar wavelength will be explored. Since K(sub dp) is proportional to frequency in the Rayleigh- Gans scattering regime, the ice orientation signatures should be more obvious at higher (lower) frequencies (wavelengths). As a result, simulations at radar wavelengths from 10 cm down to 1 cm (Ka-band) will be conducted. Resonance effects will be considered using the T-matrix method. Since most K(sub dp) Vbased observations have been shown at S-band, we will present ice orientation signatures from C-band (UAH/NASA ARMOR) and X-bd (UAH MAX) dual-polarimetric radars located in Northern Alabama. Issues related to optimal radar scanning for the detection of oriented ice will be discussed. Preliminary suggestions on how these differential phase signatures of oriented ice could contribute to lightning initiation and cessation algorithms will be presented.

Carey, L.D.↗

Multiple scattered radiation emerging from continental haze layers. 1: Radiance, polarization, and neutral points

The complete radiation field is calculated for scattering layers of various optical thicknesses. Results obtained for Rayleigh and haze scattering are compared. Calculated radiances show differences as large as 23% compared to the approximate scalar theory of radiative transfer, while the same differences are approximately 0.1% for a continental haze phase function. The polarization of reflected and transmitted radiation is given for various optical thicknesses, solar zenith angles, and surface albedos. Two types of neutral points occur for aerosol phase functions. Rayleigh-like neutral points arise from zero polarization that occurs at scattering angles of 0 deg and 180 deg. For Rayleigh phase functions, the position of these points varies with the optical thickness of the scattering layer. Non-Rayleigh neutral points are associated with the zeros of polarization which occur between the end points of the single scattering curve, and are found over a wide range of azimuthal angles.

Kattawar, G. W.↗

In situ detection and characterization of alkali-silica reaction damage in concrete using contactless ultrasonic wavefield imaging

Here we present work to characterize cracking damage in concrete caused by alkali-silica reactivity distress. We apply contactless ultrasonic scan inspection, exploiting Rayleigh wave scattering from concrete inhomogeneities. The scanning system utilizes a multi-channel MEMS sensor array to collect ultrasonic wavefield data from concrete subjected to ASR-promoting environments. The location and extent of ASR damage are established by internal expansion measurements from embedded strain gauges, scanning electron microscope images of cored samples, and expansion measurements from companion samples. A wavefield data processing method extracts oscillatory fields from the ultrasonic wavefield data to detect distinct zones of ASR damage. A damage index is proposed to further characterize the extent of ASR damage. The results confirm the feasibility and accuracy of the approach to characterize ASR damage in concrete. The fully contactless ultrasonic scanning measurement system does not require separate material samples and enables in situ characterization of ASR damage within concrete structures.

36 MATERIALS SCIENCE↗

Dopant, coating, and grating effects in silica optical fibers under extreme neutron irradiation

Radiation effects on fiber Bragg gratings (FBGs) have been studied but data gaps related to the effects of displacement damage resulting from high fast neutron fluence remain. In this work, Type-I and Type-II FBGs inscribed in optical fibers with various core dopants (Ge and F) and fiber coatings (acrylate, polyimide) were monitored in situ during 75 days of neutron irradiation to a peak fast (>0.1 MeV) neutron fluence of 3 X 10 21 n fast /cm 2 . Further, the reflected intensity of the Type-I FBGs inscribed in a Ge-doped core fiber decreased by > 30 dB within 7 h of irradiation (10 19 n fast /cm 2 ), whereas Type-II FBGs inscribed in a pure silica core fiber eventually approached >40 dB attenuation after accumulating a fast neutron fluence on the order of 10 20 n fast /cm 2 . Type-II FBGs inscribed in F-doped core fiber improved stability: the attenuation approached an equilibrium value in the range of 10 to 20 dB.

47 OTHER INSTRUMENTATION↗

Excited-State Dynamics and Nonlinear Optical Properties of Hyperpolarizable Chromophores Based on Conjugated Bis(terpyridyl)Ru(II) and Palladium and Platinum Porphyrinic Components: Impact of Heavy Metals upon Supermolecular Electro-Optic Properties

A new series of strongly coupled oscillators based upon (porphinato)Pd, (porphinato)Pt, and bis(terpyridyl)-ruthenium(II) building blocks is described. These RuPPd, RuPPt, RuPPdRu, and RuPPtRu chromophores feature bis- (terpyridyl)Ru(II) moieties connected to the (porphinato)metal unit via an ethyne linker that bridges the 4!-terpyridyl and porphyrin macrocycle meso-carbon positions. Pump–probe transient optical data demonstrate sub-picosecond excited singlet-to-triplet-state relaxation. The relaxed lowest-energy triplet (T 1 ) excited states of these chromophores feature absorption manifolds that span the 800–1200 nm spectral region, microsecond triplet-state lifetimes, and large absorptive extinction coefficients [ε(T 1 → T n ) > 4 × 10 4 M –1 cm –1 ]. Dynamic hyperpolarizability (β λ ) values were determined from hyper-Rayleigh light scattering (HRS) measurements carried out at several incident irradiation wavelengths over the 800–1500 nm spectral region. Relative to benchmark RuPZn and RuPZnRu chromophores which showed large βHRS values over the 1200–1600 nm range, RuPPd, RuPPt, RuPPdRu, and RuPPtRu displayed large βHRS values over the 850–1200 nm region. Generalized Thomas–Kuhn sum (TKS) rules and experimental hyperpolarizability values were utilized to determine excited state-to-excited state transition dipole terms from experimental electronic absorption data and thus assessed frequency-dependent β λ values, including two- and three-level contributions for both β zzz and β xzx tensor components to the RuPPd, RuPPt, RuPPdRu, and RuPPtRu hyperpolarizability spectra. Furthermore, these analyses qualitatively rationalize how the βzzz and βxzx tensor elements influence the observed irradiation wavelength-dependent hyperpolarizability magnitudes. The TKS analysis suggests that supermolecules related to RuPPd, RuPPt, RuPPdRu, and RuPPtRu will likely feature intricate dependences of experimentally determined βHRS values as a function of irradiation wavelength that derive from substantial singlet–triplet mixing, and complex interactions among multiple different β tensor components that modulate the long wavelength regime of the nonlinear optical response.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Tuning Hybrid exciton–Photon Fano Resonances in Two-Dimensional Organic–Inorganic Perovskite Thin Films

As easy-to-grow quantum wells with narrow excitonic features at room temperature, two-dimensional (2D) Ruddleson–Popper perovskites are promising for realizing novel nanophotonic devices based on exciton–photon interactions. Here, we demonstrate a distinct hybrid exciton–photon Fano resonance in (C 4 H 9 NH 3 ) 2 PbI 4 thin films prepared via spin coating. Using a classical coupled-oscillator model and finite-difference time-domain simulations, we link the Fano interference to the coupling of the exciton with the Rayleigh-like scattering of the film microstructure. Combining colloidal plasmonic cavities with the 2D perovskite films, we demonstrate tuning of the Fano resonance. In combination with silver nanoparticles, the exciton–photon Fano interference couples to the in-plane plasmonic modes with indications of Rabi splitting. By creating a nanoparticle on mirror geometry, we address the out-of-plane excitonic component, reaching an intermediate coupling regime. Furthermore, these structures suggest possible photonic targets for biomolecular self-assembly applications.

2D perovskites↗

Distributed Temperature Monitoring of Tundish Refractory Lining Using Optical Fiber Sensors

Distributed temperature monitoring can provide useful insights into the thermal conditions in the continuous caster tundish that can affect operating stability and cast quality, such as preheat conditions, superheat uniformity, fill height, and refractory wear. In the current study, fiber optic sensors were embedded into the refractory lining of a lab-scale tundish to record the temperature profiles during dry-out, preheating, and direct molten steel exposure to demonstrate sensor performance. Additional trials were performed with fiber optic sensors embedded in an industrial tundish used in production. Furthermore, the results demonstrate that fiber optic sensors using Rayleigh technology can provide accurate distributed temperature measurements in refractory lined vessels and provide useful information about the process.

Continuous Caster↗

Ultraviolet photometry from the Orbiting Astronomical Observatory. XIII - The albedos of Jupiter, Uranus, and Neptune

Presentation of OAO-2 broad-band ultraviolet photometry data for Jupiter, Uranus, and Neptune. These data have been combined with observations of 23 late-type stars to derive planetary albedos over the region 2000-4300 A. The new broad-band albedo for Jupiter agrees well with a previous measurement based on OAO-2 spectrometer data. The albedos for Uranus and Neptune are in good agreement with ground measurements in the region of overlap. The results for Uranus and Neptune have been compared with theoretical calculations for semiinfinite and finite pure H2 Rayleigh-Raman scattering atmospheres. Except for the shortest wavelengths, the measurements lie below the semiinfinite theoretical calculations. The calculations for the finite atmospheres suggest that an additional absorbing constituent will be needed to explain the observed albedos.

Savage, B. D.↗

Ultraviolet albedos of Uranus and Neptune

Observations on Uranus, Neptune, and four G-type stars which were obtained with the five channel ultraviolet spectrometer aboard the Astronomical Netherlands Satellite are reported. The paper uses these data to derive geometric albedos between 1800 and 3300 A for Uranus and between 2200 and 3300 A for Neptune. It is shown that the albedos are in good agreement with ground measurements near 3300 A and with OAO 2 measurements near 2500 A. In addition, it is noted that the albedos are smaller than theoretical predictions for deep pure H2 Rayleigh-Raman scattering atmospheres, which confirms earlier predictions that additional sources of ultraviolet absorption are required in the upper atmosphere of these planets. Consideration is given to the possibility that the Uranian atmosphere contains an extra absorber, noting that the identification of this absorber is difficult from broad-band spectrophotometric measurements.

Savage, B. D.↗

Observations of Uranus, Neptune, and Titan by the International Ultraviolet Explorer

The ultraviolet spectra of Uranus, Neptune, and Titan do not reveal absorption features at 7-A resolution from 2100 to 3200 A. Upper limits of from 1 to 3 A are set for the equivalent widths of narrow absorptions, which corresponds to a CO/H2 mixing ratio less than 2 x 10 to the -4th in the case of Uranus. The slopes of the continuum reflectivities of Uranus and Neptune are consistent with the semi-infinite Rayleigh-Raman scattering model of Cochran, while the absolute levels are matched only if solar photometry is modified within acceptable limits. An alternative, but less satisfactory explanation of the new data is that the UV reflectivities of both Uranus and Neptune are depressed uniformly by a continuum absorber. The suggestion by Savage et al (1980) that the albedo of Uranus decreases by approximately 20% from 2200 to 1800 A is not confirmed. For Titan, the albedo decreases monotonically toward shorter wavelengths down to 2300 A. New limits are set for the pressure level in the atmosphere of Titan up to which the real, but presently unidentified, UV absorber there must extend, and for the fraction of Titan that must be covered by this absorber

Caldwell, J.↗

Homogeneous nucleation of ethanol and n-propanol in a shock tube

The condensation by homogeneous nucleation of ethanol (200 proof) and of n-propanol (99.98%) carried at small mole fraction in dry air (99.995%) was studied in the unsteady, isentropic expansion of a shock tube. Samples of the vapor at different partial pressures in dry air at room temperature were expanded into the liquid coexistence regime of the condensing species. A Kristler pressure transducer and Rayleigh light scattering were used to measure the pressure in the expansion and the onset of condensation. Condensation was observed at different locations between 0.15 and 1 m upstream of the diaphragm location, which correspond to different cooling rates of of the vapor samples about 50 to 10 C/ms.

Peters, F.↗

The geometric albedos of Uranus and Neptune between 2100 and 3350 A

Results are reported from large aperture IUE observations of the stratospheres of Uranus and Neptune. The data were collected using 16 Cyg A and B as solar analog stars. The spectra observed were similar to geometric albedos of the predicted in terms of Rayleigh-Raman scattering in the 2200-2800 A region. A falloff was observed near visible wavelengths, a factor which might be attributable to low-altitude haze absorbing in the 3000-4000 A interval. The data also indicated that the Uranus stratosphere does not strongly absorb UV radiation, and is not a good heating source. The stratospheric haze constituents over Uranus could therefore be condensates of CH4 and H2 photochemistry.

Wagener, R.↗

Mid infrared LHS system packaging using flexible waveguides

As mid IR fiber optic systems are rapidly approaching a reality, so is the feasibility of fiber optic laser heterodyne systems. Laser heterodyne spectroscopy for high resolution monitoring of atmospheric gaseous pollutants is necessarily in the mid IR, the region in which the absorption signature of gaseous species is most prominent. It so happens that the lowest theoretical loss due to Rayleigh-Brillouin scattering also lies in the mid IR. Prospects of highly efficient laser heterodyne systems are thus very good. Such fibers are now beginning to be commercially available, and a test program is being conducted for such fibers with ambient temperature ranging from cryogenic to above room, and stringest mechanical flexibility requirements. Preliminary results are encouraging. A program is being started to explore the possibility of mid IR fiber optic device applications, by taking advantage of this phonon rich region. The potential long interaction length in fibers coupled with predicted extremely low losses point to stimulated Brillouin scattering based devices in the mW range. The generation of backscattered sBs at low laser powers is significant not only as an ultimate power limiting factor for laser transmission in fibers in the mid IR, but also the presence of frequency-shifted multiple order sBs Stokes and antiStokes lines will certainly have severe effect on the laser beats crucial in high resolution heterodyne spectroscopy.

Yu, Chung↗

The dependence of electroglow on the solar flux

Data from Voyager 2 UV spectrometer observations of electroglow at wavelengths below 110 nm in the atmospheres of Saturn, Jupiter, and Uranus are presented in extensive tables and graphs, analyzed statistically, and compared with the predictions of theoretical models. Findings reported include (1) a dependence (to within 10 percent) of electroglow intensity on the inverse square of heliocentric distance, (2) Uranian electroglow spectra consistent with Rayleigh-Raman scattering of sunlight, and (3) local-time electroglow variations suggesting a solar-flux-dependent excitation mechanism. Mechanisms involving the fluorescence of solar UV radiation in the H2 Lyman and Werner bands or H(-) photolysis are discussed.

Yelle, Roger V.↗

Satellite Estimates of Single Scattering Albedo and Optical Depth of Biomass Burning Carbonaceous Aerosols

Satellite based estimates of aerosol single scattering albedo (ssa), over both land and water surfaces, have been obtained for the first time using measurements of backscattered radiation in the near ultraviolet by the Total Ozone Mapping Spectrometer (TOMS). The retrieval of ssa and aerosol optical depth is based on the strong spectral contrast in the near-UV resulting from the interaction between the particle absorption and scattering (both Rayleigh and Mie) processes. We use the multi-year data set on backscattered radiances by the TOMS family of instruments to analyze the time and space variability of biomass burning generated carbonaceous aerosols. Results of a comparative analysis of satellite derived optical depth and available sunphotometer measurements will also be presented.

Torres, O.↗

Rayleigh-Sommerfield Diffraction vs Fresnel-Kirchhoff, Fourier Propagation and Poisson's Spot

The boundary conditions imposed on the diffraction problem in order to obtain the Fresnel-Kirchhoff (FK) solution are well-known to be mathematically inconsistent and to be violated by the solution when the observation point is close to the diffracting screen 1-3. These problems are absent in the Rayleigh-Sommerfeld (RS) solution. The difference between RS and FK is in the inclination factor and is usually immaterial because the inclination factor is approximated by unity. But when this approximation is not valid, FK can lead to unacceptable answers. Calculating the on-axis intensity of Poisson s spot provides a critical test, a test passed by RS and failed by FK. FK fails because (a) convergence of the integral depends on how it is evaluated and (b) when the convergence problem is xed, the predicted amplitude at points near the obscuring disk is not consistent with the assumed boundary conditions.

RS (RAYLEIGH SOMMERFELD)↗