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At least 559 records · Page 31

Laser-ion acceleration through controlled surface contamination

In laser-plasma ion accelerators, control of target contamination layers can lead to selection of accelerated ion species and enhancement of acceleration. To demonstrate this, deuterons up to 75 keV are accelerated from an intense laser interaction with a glass target simply by placing 1 ml of heavy water inside the experimental chamber prior to pumping to generate a deuterated contamination layer on the target. Using the same technique with a deuterated-polystyrene-coated target also enhances deuteron yield by a factor of 3 to 5, while increasing the maximum energy of the generated deuterons to 140 keV.

74 ATOMIC AND MOLECULAR PHYSICS↗

Inelastic scattering of electron and light ion beams in organic polymers

We have calculated the inelastic mean free path, stopping power, and energy-loss straggling of swift electron, proton, and {alpha}-particle beams in a broad incident energy range in four organic polymers: poly(methyl methacrylate) (PMMA), Kapton, polyacetylene (PA), and poly(2-vinylpyridine) (P2VP). These calculations have been done through a suitable description of their optical properties and its extension into the whole momentum and energy transfer excitation spectrum. For electrons, we take into account the exchange effect between the projectile and the target electrons, while the charge-state fractions have been considered for ions. Our results are compared with other models and with the available experimental data. An excellent agreement with experimental data is obtained in the case of proton and {alpha}-particle beams in Kapton and a reasonably good agreement has been achieved for electron beams in PMMA, Kapton, and PA. We have parameterized by means of simple analytical expressions our results for electron beams interacting with these four polymers, which can be easily implemented in Monte Carlo calculations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Positron Annihilation Studies In Polymer Nano-Composites

Positron annihilation spectroscopy coupled with a variable mono-energy positron beam has been applied to study nanoscale polymeric nanocomposites. New information about multilayer depth profiles and structures, interfacial free-volume and open space properties have been obtained in polystyrene/carbon nano fiber composites. The S parameter in Doppler Broadening Energy Spectra combined slow positron beam is used to quantitatively represent the free volume, open spaces, and interactions in the interface between polystyrene matrix and carbon nanofibers.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Positronium Formation Of Glyeisdyl Methacrylic Acid (GMA)/Styrene Grafted On PVDF Membrane For Fuel Cells

Simultaneous gamma irradiation was used effectively for grafting of glycidyl methacrylic acid and styrene onto Poly vinyldine fluoride (PVDF). Membranes were characterized by thermal gravimetric analysis (TGA) and scanning electron microscopy (SEM). The properties of the obtained membranes were evaluated in terms of proton conductivity, methanol permeability and positron annihilation lifetime (PALS) parameters. The high probability of Positronium formation enables the application of PALS to the study of free volume. Good property values approved the applicability of the membrane from the cost benefit point of view.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Physical and Chemical Changes of Polystyrene Nanospheres Irradiated with Laser

It has been reported that polymer resist such as PMMA (Poly(methyl methacrylate) which is a well known and commonly used polymer resist for fabrication of electronic devices can show zwitter characteristic due to over exposure to electron beam radiation. Overexposed PMMA tend to changes their molecular structure to either become negative or positive resist corresponded to electron beam irradiation doses. These characteristic was due to crosslinking and scissors of the PMMA molecular structures, but till now the understanding of crosslinking and scissors of the polymer resist molecular structure due to electron beam exposure were still unknown to researchers. Previously we have over exposed polystyrene nanospheres to various radiation sources, such as electron beam, solar radiation and laser, which is another compound that can act as polymer resist. We investigated the physical and chemical structures of the irradiated polystyrene nanospheres with FTIR analysis. It is found that the physical and chemical changes of the irradiated polystyrene were found to be corresponded with the radiation dosages. Later, combining Laser irradiation and Reactive Ion Etching manipulation, created a facile technique that we called as LARIEA NSL (Laser and Reactive Ion Etching Assisted Nanosphere Lithography) which can be a facile technique to fabricate controllable carbonaceous nanoparticles for applications such as lithographic mask, catalysts and heavy metal absorbers.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

UV Spectra of Amino Acid Immobilized at Nanoparticles Formation through Nanosphere Lithography (NSL) by Plasma Treatment

The modifying of nanospheres structures by plasma treatments to the fabricated nanoparticles arrays by Nanosphere Lithography (NSL) techniques to create Periodic Particles Arrays (PPAs) with different size, shape and orientation. Spectra of amino acid that immobilized to the nanoparticles arrays under Ultra Violet (UV) spectrums were studied. The PPAs with different sizes, shapes and orientation were fabricated by plasma treatment of 5 sec, 7 sec and 10 sec to the Polystyrene Nanosphere (PSN). Plasma treatment will effect to the PSN including etching part of the PSN to produce a much bigger channel to the single layer template of the PSN. Metal was deposited at interstitial sites between of the polymer balls and later removed by dissolving them in organic solvent, leaving a hexagonal pattern of metal structures at the interstitial sites. The nanoparticles immobilized with the standard amino acid, which later investigated under UV spectrums. The spectrums shows the possibilities use as biosensor devices.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Polyvinylpyrrolidone/Multiwall Carbon Nanotube Composite Based 36 deg. YX LiTaO{sub 3} Surface Acoustic Wave For Hydrogen Gas Sensing Applications

Poly-vinyl-pyrrolidone (PVP)/Multiwall Carbon Nanotubes (MWNTs) based Surface Acoustic Wave (SAW) sensors are fabricated and characterized, and their performances towards hydrogen gas are investigated. The PVP/MWNTs fibers composite are prepared by electrospinning of the composite aqueous solution deposited directly onto the active area of SAW transducers. Via scanning electron microscopy (SEM), the morphology of the deposited nanostructure material is observed. From the dynamic response, frequency shifts of 530 Hz (1%H{sub 2}) and 11.322 kHz (0.25%H{sub 2}) are recorded for the sensors contain of 1.525 g and 1.025 g PVP concentrations, respectively.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Modelling Viscoelastic Behaviour of Polymer by A Mixed Velocity, Displacement Formulation - Numerical and Experimental Results

The objective of this work is to model the viscoelastic behaviour of polymer from the solid state to the liquid state. With this objective, we perform experimental tensile tests and compare with simulation results. The chosen polymer is a PMMA whose behaviour depends on its temperature. The computation simulation is based on Navier-Stokes equations where we propose a mixed finite element method with an interpolation P1+/P1 using displacement (or velocity) and pressure as principal variables. The implemented technique uses a mesh composed of triangles (2D) or tetrahedra (3D). The goal of this approach is to model the viscoelastic behaviour of polymers through a fluid-structure coupling technique with a multiphase approach.

36 MATERIALS SCIENCE↗

Study of the Thermal Behavior of Syndiotactic and Atactic Polystyrene By Raman Spectroscopy

The glass properties and semi crystalline properties of polymers are observable by X-ray diffraction. Some previous works 1, 2, 3 were about determination of degree of crystallinity of sPS by various technologies, like for example DSC, XRD and Raman spectroscopy. The purpose of this paper is to show importance of Raman spectroscopy as analytical tool for the study of amorphous and semi-crystalline phase. The polymers on which our research is achieved, is amorphous polystyrene, shortened aPS, and semi crystalline polystyrene, sPS.

36 MATERIALS SCIENCE↗

Tuneable magnetic patterning of paramagnetic Fe{sub 60}Al{sub 40} (at. %) by consecutive ion irradiation through pre-lithographed shadow masks

Arrays of ferromagnetic circular dots (with diameters ranging from 225 to 420 nm) have been prepared at the surface of atomically ordered paramagnetic Fe{sub 60}Al{sub 40} (at. %) sheets by means of ion irradiation through prelithographed poly(methyl methacrylate) (PMMA) masks. The cumulative effects of consecutive ion irradiation (using Ar{sup +} ions at 1.2 x 10{sup 14} ions/cm{sup 2} with 10, 13, 16, 19 and 22 keV incident energies) on the properties of the patterned dots have been investigated. A progressive increase in the overall magneto-optical Kerr signal is observed for increasingly larger irradiation energies, an effect which is ascribed to accumulation of atomic disorder. Conversely, the coercivity, H{sub C}, shows a maximum after irradiating at 16-19 keV and it decreases for larger irradiation energies. Such a decrease in H{sub C} is ascribed to the formation of vortex states during magnetization reversal, in agreement with results obtained from micromagnetic simulations. At the same time, the PMMA layer, with an initial thickness of 90 nm, becomes progressively thinned during the successive irradiation processes. After irradiation at 22 keV, the remaining PMMA layer is too thin to stop the incoming ions and, consequently, ferromagnetism starts to be generated underneath the nominally masked areas. These experimental results are in agreement with calculations using the Monte-Carlo simulation Stopping Range of Ions in Matter software, which show that for exceedingly thin PMMA layers Ar{sup +} ions can reach the Fe{sub 60}Al{sub 40} layer despite the presence of the mask.

36 MATERIALS SCIENCE↗

Free Volume Related Fluorescence Properties of Electron Irradiated Chalcone Doped PMMA Films

Effect of electron irradiation on free volume related fluorescence properties of chalcone doped Poly(methyl methacrylate)(PMMA) composite films have been studied using Positron Annihilation and Fluorescence spectroscopic techniques. In this polymer composite, enhancement of fluorescence at lower doses and reduction at higher doses has been observed under electron irradiation. From Positron annihilation studies suggests that at lower doses of irradiation induced crosslinking which affect the free volume properties and inturn hinders the chalcone molecular rotation. At higher doses chain scission process affect matrix relaxation. Under the restricted condition the chromophore molecules likely to emit enhanced fluorescence and its mobility is directly related to the free volume around it.

36 MATERIALS SCIENCE↗

Effect of Electric Field Alignment of MWCNT in PMMA Matrix for Hydrogen Gas Purification

The composite membranes of multi-walled carbon nanotube (MWCNT) and polymethylmethacrylate (PMMA) were prepared by solution cast method. The MWCNT was dispersing a very low concentration (0.1 wt %) in PMMA matrix. Alignment of MWCNT in PMMA matrix has been performed by inducing a DC electric field at different voltage parameter varying from 350 V/cm to 1250 V/cm. The MWCNT/PMMA composites were characterized by gas permeation and electrical measurement before and after electric field alignment. The effect of electric field alignment has been studied on gas permeation measurements for gas purification applications. These measurements indicate the enhancement in gas permeability due to the aligned of MWCNT in PMMA matix as compare to randomly dispersed MWCNT. I-V characteristics measurement also indicates that aligned MWCNT/PMMA composite membrane exhibits electron tunneling conductivity.

36 MATERIALS SCIENCE↗

Dual Gate Thin Film Transistors Based on Indium Oxide Active Layers

Polycrystalline Indium Oxide (In{sub 2}O{sub 3}) thin films were employed as an active channel layer for the fabrication of bottom and top gate thin film transistors. While conventional SiO{sub 2} served as a bottom gate dielectric, cross-linked poly-4-vinylphenol (PVP) was used a top gate dielectric. These nano-crystalline TFTs exhibited n-channel behavior with their transport behavior highly dependent on the thickness of the channel. The correlation between the thickness of the active layer and TFT parameters such as on/off ratio, field-effect mobility, threshold voltage were carried out. The optical spectra revealed a high transmittance in the entire visible region, thus making them promising candidates for the display technology.

36 MATERIALS SCIENCE↗

Observation of Phase Objects by Using an X-ray Microscope with a Foucault Knife-Edge

An x-ray microscope with a zone plate was assembled at the synchrotron radiation source of BL3C, Photon Factory. A Foucault knife-edge was set at the back focal plate of the objective zone plate and phase retrieval was tested by scanning the knife-edge. A preliminary result shows that scanning the knife-edge during exposure was effective for phase retrieval. Phase-contrast tomography was investigated using differential projection images calculated from two Schlieren images with the oppositely oriented knife-edges. Fairly good reconstruction images of polystyrene beads and spores could be obtained.

43 PARTICLE ACCELERATORS↗

Influence of Al/CuO reactive multilayer films additives on exploding foil initiator

An investigation on the influence of Al/CuO reactive multilayer films (RMFs) additives on exploding foil initiator was performed in this paper. Cu film and Cu/Al/CuO RMFs were produced by using standard microsystem technology and RF magnetron sputtering technology, respectively. Scanning electron microscopy characterization revealed the distinct layer structure of the as-deposited Al/CuO RMFs. Differential scanning calorimetry was employed to ascertain the amount of heat released in the thermite reaction between Al films and CuO films, which was found to be 2024 J/g. Electrical explosion tests showed that 600 V was the most matching voltage for our set of apparatus. The explosion process of two types of films was observed by high speed camera and revealed that compared with Cu film, an extra distinct combustion phenomenon was detected with large numbers of product particles fiercely ejected to a distance of about six millimeters for Cu/Al/CuO RMFs. By using the atomic emission spectroscopy double line technique, the reaction temperature was determined to be about 6000-7000 K and 8000-9000 K for Cu film and Cu/Al/CuO RMFs, respectively. The piezoelectricity of polyvinylidene fluoride film was employed to measure the average velocity of the slapper accelerated by the explosion of the films. The average velocities of the slappers were calculated to be 381 m/s and 326 m/s for Cu film and Cu/Al/CuO RMFs, respectively, and some probable reasons were discussed with a few suggestions put forward for further work.

36 MATERIALS SCIENCE↗

Poly (vinylidene fluoride-trifluoroethylene)/barium titanate nanocomposite for ferroelectric nonvolatile memory devices

The effect of barium titanate (BaTiO{sub 3}) nanoparticles (particle size <100 nm) on the ferroelectric properties of poly (vinylidenefluoride-trifluoroethylene) P(VDF-TrFE) copolymer has been studied. Different concentrations of nanoparticles were added to P(VDF-TrFE) using probe sonication, and uniform thin films were made. Polarisation - Electric field (P-E) hysteresis analysis shows an increase in remnant polarization (P{sub r}) and decrease in coercive voltage (V{sub c}). Piezo-response force microscopy analysis shows the switching capability of the polymer composite. The topography and surface roughness was studied using atomic force microscopy. It has been observed that this nanocomposite can be used for the fabrication of non-volatile ferroelectric memory devices.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

The influence of self-assembly behavior of nanoparticles on the dielectric polymer composites

To clearify the influence of the distribution of the conductive nanoparticles on the dielectric properties of the corresponding polymer composites, the microstructure and dielectric character of the composites based on the oleic acid modified ferroferric oxide and polyvinylidene fluoride (PVDF) polymer have been studied experimentally. It is found that these composites exhibit a normal percolative phase transition over the filler content from insulator to conductor, consistent with the classical percolation theory. However, when the percentage of fillers is at a certain value which is below the percolation threshold, these nanoparticles can assemble into a special porous structure in the PVDF matrix, associated with the enhancement of dielectric constant at low frequency. In addition, the controllable dispersion of conducting nanoparticles in a polymer matrix can prevent premature agglomeration at low filling fractions and avoid the appearance of anomalously early percolation. Therefore, the self-assembly behavior of nanoparticles can be beneficial to preparation of the high dielectric constant and low loss composites for the application of electric energy storage.

36 MATERIALS SCIENCE↗

Magnetic, dielectric and magnetodielectric properties of PVDF-La{sub 0.7}Sr{sub 0.3}MnO{sub 3} polymer nanocomposite film

We have investigated the structure, magnetic and dielectric properties of PVDF-La{sub 0.7}Sr{sub 0.3}MnO{sub 3} polymer nanocomposite thick film fabricated by dip coating technique along with the magnetodielectric effect. The structure and dielectric properties show the enhanced β phase in the composite compared to the PVDF film. The coupling between the ferroelectric and magnetic phases in the composite is revealed in the form of dielectric anomaly at the ferromagnetic Curie temperature. We observed 1.9% magnetodielectric effect at 300 K with the possibility of enhanced effect near the transition temperature. In addition, the analysis of the electric modulus indicates that the composite exhibits interfacial related relaxation and it follows Arrhenius Law. Our study suggests that the ac conductivity of the PVDF-La{sub 0.7}Sr{sub 0.3}MnO{sub 3} composite could be explained by correlated barrier hopping mechanism.

36 MATERIALS SCIENCE↗