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At least 559 records · Page 31

Large Atomic Natural Orbital Basis Sets for the First Transition Row Atoms

Large atomic natural orbital (ANO) basis sets are tabulated for the Sc to Cu. The primitive sets are taken from the large sets optimized by Partridge, namely (21s 13p 8d) for Sc and Ti and (20s 12p 9d) for V to Cu. These primitive sets are supplemented with three p, one d, six f, and four g functions. The ANO sets are derived from configuration interaction density matrices constructed as the average of the lowest states derived from the 3d(sup n)4s(sup 2) and 3d(sup n+1)4s(sup 1) occupations. For Ni, the 1S(3d(sup 10)) state is included in the averaging. The choice of basis sets for molecular calculations is discussed.

Bauschlicher, Charles W., Jr.↗

What is the Structure of FeC5H6(+)?

Calculations performed using both density functional theory (DFT) and the modified coupled-pair functional (MCPF) approach show that FeC5H6(+) is more stable than HFeC5H5(+) by about 10 kcal/mol. The ground state of FeC5H6(+) is a quartet state derived from the 3d(sup 7) occupation of Fe+. For HFeC5H6(+), the MCPF 5 approach yields a sextet ground state while DFT yields a quartet; however, these two states are close in energy at both levels of theory.

Bauschlicher, Charles W., Jr.↗

Forearm Muscle Oxygenation Decreases During Low Levels of Brief, Isometric Contraction

Regional muscle pain syndromes can be caused by repeated and sustained exertion of a specific muscle. Such exertion may elevate local tissue fluid pressure, reduce blood flow and tissue oxygenation (TO2), and cause fatigue, pain and functional deficits of the Involved muscle. Low levels (less than 20% maximum voluntary contraction (MVC)) of prolonged static contraction of the upper extremity are common In many occupational settings and May cause fatigue. The purpose of our Investigation was to determine whether TO2 decreases significantly at low levels of static contraction of the extensor carpi radialis brevis (ECRB).

Murthy Gita↗

19th JANNAF Safety and Environmental Protection Subcommittee Meeting

This volume, the first of two volumes, is a compilation of 22 unclassified/unlimited technical papers presented at the 19th Joint Army-Navy-NASA-Air Force (JANNAF) Safety & Environmental Protection Subcommittee Meeting. The meeting was held 18-21 March 2002 at the Sheraton Colorado Springs Hotel, Colorado Springs, Colorado. Topics covered include green energetic materials and life cycle pollution prevention; space launch range safety; propellant/munitions demilitarization, recycling, and reuse: and environmental and occupational health aspects of propellants and energetic materials.

Cocchiaro, J. E.↗

Design and Test of an Improved Crashworthiness Small Composite Airframe

The purpose of this small business innovative research (SBIR) program was to evaluate the feasibility of developing small composite airplanes with improved crashworthiness. A combination of analysis and half scale component tests were used to develop an energy absorbing airframe. Four full scale crash tests were conducted at the NASA Impact Dynamics Research Facility, two on a hard surface and two onto soft soil, replicating earlier NASA tests of production general aviation airplanes. Several seat designs and restraint systems including both an air bag and load limiting shoulder harnesses were tested. Tests showed that occupant loads were within survivable limits with the improved structural design and the proper combination of seats and restraint systems. There was no loss of cabin volume during the events. The analysis method developed provided design guidance but time did not allow extending the analysis to soft soil impact. This project demonstrated that survivability improvements are possible with modest weight penalties. The design methods can be readily applied by airplane designers using the examples in this report.

Terry, James E.↗

STS-113 Crew Interviews: Jim Wetherbee, Commander

STS-113 Commander Jim Wetherbee is seen during this preflight interview where he gives a quick overview of the mission before answering questions about his inspiration to become an astronaut and his career path. Wetherbee outlines his role in the mission, what his responsibilities will be, what the crew exchange will be like (transferring the Expedition 6 crew in place of the Expedition 5 crew on the International Space Station (ISS)) and what the importance of the primary payload (the P1 truss) will be. He also provides a detailed account of the three planned extravehicular activities (EVAs) and additional transfer duties. He ends by offering his thoughts on the success of the ISS as the second anniversary of continuous human occupation of the ISS approaches.

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STS-113 Crew Interviews: Paul Lockhart, Pilot

STS-113 Pilot Paul Lockhart is seen during this preflight interview, where he gives a quick overview of the mission before answering questions about his inspiration to become an astronaut and his career path. Lockhart outlines his role in the mission in general, and specifically during the docking and extravehicular activities (EVAs). He describes the primary mission payload (the P1 truss) and the crew transfer activities (Expedition 6 crew will replace the Expedition 5 Crew). Lockhart discusses the planned EVAs in detail and mentions what supplies will be left for the resident crew of the International Space Station (ISS). He ends with his thoughts about the importance of the ISS as the second anniversary of continuous human occupation of the space station approaches.

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STS-113 Crew Interviews: Michael Lopez-Alegria, Mission Specialist 1

STS-113 Mission Specialist 1 Michael Lopez-Alegria is seen during this preflight interview where he gives a quick overview of the mission before answering questions about his inspiration to become an astronaut and his career path. Lopez-Alegria outlines his role in the mission in general, and specifically during the docking and extravehicular activities (EVAs). He describes the payload (P1 truss) and the crew transfer activities (the crew of Expedition Six is replacing the crew of Expedition Five on the International Space Station (ISS)). Lopez-Alegria discusses the planned EVAs in detail and outlines what supplies will be left for the resident crew. He ends with his thoughts on the importance of the ISS as the second anniversary of human occupation of the Space Station approaches.

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Gas Analyzer

The M200 originated in the 1970's under an Ames Research Center/Stanford University contract to develop a small, lightweight gas analyzer for Viking Landers. Although the unit was not used on the spacecraft, it was further developed by The National Institute for Occupational Safety and Health (NIOSH). Three researchers from the project later formed Microsensor Technology, Inc. (MTI) to commercialize the analyzer. The original version (Micromonitor 500) was introduced in 1982, and the M200 in 1988. The M200, a more advanced version, features dual gas chromatograph which separate a gaseous mixture into components and measure concentrations of each gas. It is useful for monitoring gas leaks, chemical spills, etc. Many analyses are completed in less than 30 seconds, and a wide range of mixtures can be analyzed.

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Relaxation System

Environ Corporation's relaxation system is built around a body lounge, a kind of super easy chair that incorporates sensory devices. Computer controlled enclosure provides filtered ionized air to create a feeling of invigoration, enhanced by mood changing aromas. Occupant is also surrounded by multidimensional audio and the lighting is programmed to change colors, patterns, and intensity periodically. These and other sensory stimulators are designed to provide an environment in which the learning process is stimulated, because research has proven that while an individual is in a deep state of relaxation, the mind is more receptive to new information.

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Personal Cooling System

Cool Head, a personal cooling system for use in heat stress occupations, is a spinoff of a channeled cooling garment for space wear. It is portable and includes a heat exchanger, control display unit, liquid reservoir and temperature control unit. The user can eliminate 40 to 60 percent of his body's heat storage and lower heart rate by 50 to 80 beats a minute. The system is used by the Army, Navy, crop dusting pilots, heavy equipment operators and auto racing drivers and is marketed by Life Enhancement Technologies, LLC. Further applications are under consideration.

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Air Purification in Closed Environments: An Overview of Spacecraft Systems

The primary goal for a collective protection system and a spacecraft environmental control and life support system (ECLSS) are strikingly similar. Essentially both function to provide the occupants of a building or vehicle with a safe, habitable environment. The collective protection system shields military and civilian personnel from short-term exposure to external threats presented by toxic agents and industrial chemicals while an ECLSS sustains astronauts for extended periods within the hostile environment of space. Both have air quality control similarities with various aircraft and 'tight' buildings. This paper reviews basic similarities between air purification system requirements for collective protection and an ECLSS that define surprisingly common technological challenges and solutions. Systems developed for air revitalization on board spacecraft are discussed along with some history on their early development as well as a view of future needs. Emphasis is placed upon two systems implemented by the National Aeronautics and Space Administration (NASA) onboard the International Space Station (ISS): the trace contaminant control system (TCCS) and the molecular sieve-based carbon dioxide removal assembly (CDRA). Over its history, the NASA has developed and implemented many life support systems for astronauts. As the duration, complexity, and crew size of manned missions increased from minutes or hours for a single astronaut during Project Mercury to days and ultimately months for crews of 3 or more during the Apollo, Skylab, Shuttle, and ISS programs, these systems have become more sophisticated. Systems aboard spacecraft such as the ISS have been designed to provide long-term environmental control and life support. Challenges facing the NASA's efforts include minimizing mass, volume, and power for such systems, while maximizing their safety, reliability, and performance. This paper will highlight similarities and differences among air purification systems. Additional information is included in the original extended abstract.

Perry, Jay L.↗

Analysis of Salinity Intrusion in the San Francisco Bay-Delta using a GA- Optimized Neural Net, and Application of the Model to Prediction in the Elkhorn Slough Habitat

The San Francisco Bay Delta is a large hydrodynamic complex that incorporates the Sacramento and San Joaquin Estuaries, the Burman Marsh, and the San Francisco Bay proper. Competition exists for the use of this extensive water system both from the fisheries industry, the agricultural industry, and from the marine and estuarine animal species within the Delta. As tidal fluctuations occur, more saline water pushes upstream allowing fish to migrate beyond the Burman Marsh for breeding and habitat occupation. However, the agriculture industry does not want extensive salinity intrusion to impact water quality for human and plant consumption. The balance is regulated by pumping stations located alone the estuaries and reservoirs whereby flushing of fresh water keeps the saline intrusion at bay. The pumping schedule is driven by data collected at various locations within the Bay Delta and by numerical models that predict the salinity intrusion as part of a larger model of the system. The Interagency Ecological Program (IEP) for the San Francisco Bay/Sacramento-San Joaquin Estuary collects, monitors, and archives the data, and the Department of Water Resources provides a numerical model simulation (DSM2) from which predictions are made that drive the pumping schedule. A problem with this procedure is that the numerical simulation takes roughly 16 hours to complete a C:~ prediction. We have created a neural net, optimized with a genetic algorithm, that takes as input the archived data from multiple stations and predicts stage, salinity, and flow at the Carquinez Straits (at the downstream end of the Burman Marsh). This model seems to be robust in its predictions and operates much faster than the current numerical DSM2 model. Because the system is strongly tidal driven, we used both Principal Component Analysis and Fast Fourier Transforms to discover dominant features within the IEP data. We then filtered out the dominant tidal forcing to discover non-primary tidal effects, and used this to enhance the neural network by mapping input-output relationships in a more efficient manner. Furthermore, the neural network implicitly incorporates both the hydrodynamic and water quality models into a single predictive system. Although our model has not yet been enhanced to demonstrate improve pumping schedules, it has the possibility to support better decision-making procedures that may then be implemented by State agencies if desired. Our intention is now to use this model in the smaller Elkhorn Slough complex near Monterey Bay where no such hydrodynamic model currently exists. At the Elkhorn Slough, we are fusing the neural net model of tidally-driven flow with in situ flow data and airborne and satellite remote sensation data. These further constrain the behavior of the model in predicting the longer-term health and future of this vital estuary.

Thompson, David E.↗

Gas Analyzer

A miniature gas chromatograph, a system which separates a gaseous mixture into its components and measures the concentration of the individual gases, was designed for the Viking Lander. The technology was further developed under National Institute for Occupational Safety and Health (NIOSH) and funded by Ames Research Center/Stanford as a toxic gas leak detection device. Three researchers on the project later formed Microsensor Technology, Inc. to commercialize the product. It is a battery-powered system consisting of a sensing wand connected to a computerized analyzer. Marketed as the Michromonitor 500, it has a wide range of applications.

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Self Righting Life Raft

The Givens Buoy Raft was designed and manufactured for inventor Jim Givens of Givens Marine Survival Co. Inc., by RPR Industries, Inc. The Raft consists of a canopied topside and an underwater hemispheric ballast chamber. It has a heavy ballast stabilization system, adopted from NASA technology, which negates the capsizing problem. A "flapper valve" admits large amounts of water to the hemisphere chamber providing ballast to keep the center of gravity constant; stabilization system compensates for changes in wave angle and weight shifting of raft occupants. Mr. Givens has an exclusive patent license for use of the NASA technology. Produced in various sizes, capacities range from six to 20 persons. Raft is housed in a canister, available in several configurations. A pull on a line triggers the automatic inflation process, which takes 12 seconds. The raft has been credited with saving 230 lives in the last five years. It has found wide acceptance with operators of fishing boats, pleasure craft and other vessels. The Coast Guard is purchasing the rafts for use on its rescue helicopters and the Navy has a development program to adapt the system. The Coast Guard last year announced a proposed amendment of its regulations that would require large ballast chambers on inflatable life rafts.

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The Effect of Microgravity on the Smallest Space Travelers: Bacterial Physiology and Virulence on Earth and in Microgravity

Since the first human flights outside of Earth's gravity, crew health and well-being have been major concerns. Exposure to microgravity during spaceflight is known to affect the human immune response, possibly making the crew members more vulnerable to infectious disease. In addition, biological experiments previously flown in space have shown that bacteria grow faster in microgravity than they do on Earth. The ability of certain antibiotics to control bacterial infections may also differ greatly in microgravity. It is therefore critical to understand how spaceflight and microgravity affect bacterial virulence, which is their ability to cause disease. By utilizing spaceflight hardware provided by the European Space Agency (ESA), Dr. Barry Pyle and his team at Montana State University, Bozeman, will be performing an experiment to study the effects of microgravity on the virulence of a common soil and water bacterium, Pseudomonas aeruginosa. Importantly, these bacteria have been detected in the water supplies of previous Space Shuttle flights. The experiment will examine the effects of microgravity exposure on bacterial growth and on the bacterium's ability to form a toxin called Exotoxin A. Another goal is to evaluate the effects of microgravity on the physiology of the bacteria by analyzing their ability to respire (produce energy), by studying the condition of the plasma membrane surrounding the cell, and by determining if specific enzymes remain active. Proteins produced by the bacteria will also be assayed to see if the normal functions of the bacteria are affected. In the context of human life support in spaceflight, the results of this experiment will offer guidance in providing the highest possible water quality for the Shuttle in order to limit the risk of infection to human occupants and to minimize water system and spacecraft deterioration.

Pyle, Barry↗

Energy Requirements of Hydrogen-Utilizing Microbes: Boundary Condition for Subsurface Life

For planetary bodies with surface conditions that are too harsh to permit continuous occupation by life, the deep subsurface offers a potentially stable and habitable niche. For organisms occupying this niche, the spectrum of possible metabolisms must be limited to those which do not include sunlight as an energy source or oxygen as a chemical reagent - generally, low-energy anaerobic oxidation-reduction processes. The quantity of energy released in such processes is critical, because currently understood mechanisms of biological energy conservation indicate that energy is only 'useful' to an organism when it is available at a certain minimum level - the 'biological energy quantum'. The mere existence of a BEQ implies that a significant fraction of the chemical energy present in the environment cannot be exploited by life; similarly, the absolute magnitude of the BEQ must be a key variable in determining the potential viability and distribution of subsurface microbial communities. Laboratory culture studies suggest that organisms require an energy of about -20 kJ/mol to grow. However, we find that hydrogen-utilizing microorganisms in an energy-limited natural ecosystem are active with energy yields as low as -10 kJ/mol. A lower BEQ would mean a significantly expanded range of energetically viable subsurface habitat for life.

Hoehler, Tori M.↗

Overview of Atmospheric Ionizing Radiation (AIR) Research: SST - Present

The Supersonic Transport (SST) program, proposed in 1961, first raised concern for the exposure of pregnant occupants by solar energetic particles (SEP), and neutrons were suspected to have a main role in particle propagation deep into the atmosphere. An eight-year flight program confirmed the role of SEP as a significant hazard and of the neutrons as contributing over half of the galactic cosmic ray (GCR) exposures, with the largest contribution from neutrons above 10 MeV. The FAA Advisory Committee on the Radiobiological Aspects of the SST provided operational requirements. The more recent (1990) lowering of recommended exposure limits by the International Commission on Radiological Protection with the classification of aircrew as "radiation workers" renewed interest in GCR background exposures at commercial flight altitudes and stimulated epidemiological studies in Europe, Japan, Canada and the USA. The proposed development of a High Speed Civil Transport (HSCT) required validation of the role of high-energy neutrons, and this resulted in ER-2 flights at solar minimum (June 1997) and studies on effects of aircraft materials on interior exposures. Recent evaluation of health outcomes of DOE nuclear workers resulted in legislation for health compensation in year 2000 and recent European aircrew epidemiological studies of health outcomes bring renewed interest in aircraft radiation exposures. As improved radiation models become available, it is imperative that a corresponding epidemiological program of US aircrew be implemented.

Wilson, J. W.↗