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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 559 records · Page 31
All sourcesNASA NTRSDOE OSTI
NASA NTRS1996

Observations of Colliding Winds in O-Type Binaries

Stellar winds will collide in a bow shock in close binary systems of O-type stars. The presence of this boundary will truncate the full spatial extent of the two individual winds, and thus the spectral lines formed in the wind will appear differently when viewed from different orientations. Here I discuss the orbital variations of the UV wind lines in a large sample of O-binaries that have been observed with the International Ultraviolet Explorer Satellite (IUE). High density regions in the wind (near the photospheres and bow shock) will produce optical emission lines, and I describe the He emission properties of several systems. The physical characteristics of the component stars can now be better estimated through Doppler tomography, a numerical method to extract the individual primary and secondary spectra.

Gies, Douglas R.↗
NASA NTRS1997

Laser Flash Photolysis Studies of Radical-Radical Reaction Kinetics: The O((sup 3)P(sub J)) + BrO Reaction

A novel dual laser flash photolysis-long path absorption-resonance fluorescence technique has been employed to study the kinetics of the important stratospheric reaction 0((sup 3)P(sub j)) + Br yields(k1) BrO((sup 2)P(sub J)) + O2 as a function of temperature (231-328 K) and pressure (25-150 Torr) in N2 buffer gas. The experimental approach preserves the principal advantages of the flash photolysis method, i.e., complete absence of surface reactions and a wide range of accessible pressures, but also employs techniques which are characteristic of the discharge flow method, namely chemical titration as a means for deducing the absolute concentration of a radical reactant and use of multiple detection axes. We find that k1 is independent of pressure, and that the temperature dependence of k1 is adequately described by the Arrhenius expression k1(T) = 1.91 x 10(exp -11)(230/J) cu cm/ molecule.s; the absolute accuracy of measured values for k1 is estimated to vary from +/- 20 percent at at T approximately 230 K to +/- 30 percent at T approximately 330 K. Our results demonstrate that the O((sup 3)P(sub j)) + BrO rate coefficient is significantly faster than previously 'guesstimated,' and suggest that the catalytic cycle with the O((sup 3)P(sub j)) + BrO reaction as its rate-limiting step is the dominant stratospheric BrO(x), odd-oxygen destruction cycle at altitudes above 24 km.

Thorn, R. P.↗
NASA NTRS1981

Detection of [O I] 63 Micron Emission from the Galactic Center

The detection of the 63 microns line of [O I] is reported for three positions in the H II region complex Sgr A at the galactic center. Velocity resolution of the line indicates that the emitting material has both rotational and radial motion of magnitude similar to that of the ionized gas in the core and that a substantial amount of the emitting material lies within the central few parsecs of the Galaxy. A model in which [O I] is collisionally excited by neutral hydrogen, either from the warm region ahead of an ionization front or behind a shock, is proposed and gives a total mass of hot, neutral gas within the central 3 pc of the Galaxy of between 10 and 10(exp 3) solar mass. A limit on the flux of this line has been set for Sgr B2.

Lester, D. F.↗
NASA NTRS1997

Mesospheric Observations and Modeling of the Zeeman Split 233.9 GHz O-18O-16 line

Observations made from Kitt Peak, AZ, of the 233.9 GHz emission line of O-18O-16 in the upper stratosphere and lower mesosphere are reported. A good model fit to the line is obtained by incorporation of pressure and temperature broadening effects, as well as a Zeeman splitting algorithm that uses a standard geomagnetic field model and a paramagnetic Hamiltonian description of the molecular energy states. These observations are used, along with the well known O-18O-16 mixing ratio, to establish absolute calibration for observations of other chemical species from Kitt Peak. Repeated measurements show no change in this absolute calibration between observation dates. The wide magnetic splitting (+/-1.8 MHz) exhibited by this line with only six Zeeman components provides a unique test of middle atmosphere Zeeman effect model calculations, supporting the use Of 02 lines by microwave atmospheric sounders to measure pressure and temperature.

Sandor, Brad J.↗
NASA NTRS1999

Detection of O VII Lambda 1522 in IUE Spectra of Planetary Nebula Nuclei and Other Hot Stars

We present the first detection of O VII lambda 1522 emission or absorption from archival IUE spectra in 14 planetary nebula nuclei and three PG 1159-type stars. The n = 5 approaching 6 transition of O VII was determined by Kruk & Werner and observed by them in the spectrum of the very hot PG 1159-type star H1504+65 from data obtained with the Hopkins Ultraviolet Telescope (HUT). Emission-line fluxes or absorption equivalent widths as well as radial velocities for the program stars are presented. The precise rest wavelength for the 5 approaching 6 transition requires further investigation.

Feibelman, Walter A.↗
NASA NTRS2000

POLAR Observations of Field Aligned O+ Flows at 5000 km Altitude Over the Polar Regions with Comparison to Auroral Images

Measurements of thermal 0+ ion parameters from the Thermal Ion Dynamics Experiment (TIDE) on POLAR obtained near 5000 km altitude are compared with auroral images from the Ultra Violet Imager (UVI), for southern perigee passes. Ion parameters, including parallel velocity, density, and flux are combined with multiple dayside and nightside auroral images to investigate relationships between O+ field aligned flows and the structure and brightness seen in the auroral forms. Results indicate field aligned upflowing O+ ions over regions of bright auroral activity and downward flows over dark regions. These and other relationships will be presented for several POLAR passes when both ion measurements and auroral images are observed under favorable conditions for comparison.

Stevenson, B. A.↗
NASA NTRS1991

STS-40/SLS-1 Breakfast/Suit-up/Depart O&C/Ingress/Launch with isolated Views

Live footage shows the crew members, Commander Bryan D. O'Connor, Pilot Sidney M. Gutierrez, Mission Specialists James P. Bagian, Tamara E. Jernigan, M. Rhea Seddon, and Payload Specialists F. Drew Gaffney, and Millie-Hughes Fulford, sitting down at the traditional breakfast table. The crew is also seen suiting-up, entering the elevator, leaving the Operations and Checkout Building (O&C), and getting into the Astro-van. Scenes also show the crew members entering the vehicle as well as various isolated morning launch views, and some beautiful panoramic shots of the shuttle on the launch pad.

Source record↗
NASA NTRS2001

Observations of O VI Emission from the Diffuse Interstellar Medium

We report the first Far Ultraviolet Spectroscopic Explorer (FUSE) measurements of diffuse O(VI) (lambda lambda 1032,1038) emission from the general diffuse interstellar medium outside of supernova remnants or superbubbles. We observed a 30 arcsec x 30 arcsec region of the sky centered at l = 315.0 deg and b = -41.3 deg. From the observed intensities (2930 +/- 290 (random) +/- 410 (systematic) and 1790 +/- 260 (random) +/- 250 (systematic) photons/sq cm/s/sr in the 1032 and 1038 angstrom emission lines, respectively), derived equations, and assumptions about the source location, we calculate the intrinsic intensity, electron density, thermal pressure, and emitting depth. The intensities are too large for the emission to originate solely in the Local Bubble. Thus, we conclude that the Galactic thick disk and lower halo also contribute. High velocity clouds are ruled out because there are none near the pointing direction. The calculated emitting depth is small, indicating that the O(VI)-bearing gas fills a small volume. The observations can also be used to estimate the cooling rate of the hot interstellar medium and constrain models. The data also yield the first intensity measurement of the C(II) 3s 2S(1/2) to 2p 2P(3/2) emission line at 1037 angstrom and place upper limits on the intensities of ultraviolet line emission from C(I), C(III), Si(II), S(III), S(IV), S(VI), and Fe(III).

Shelton, R. L.↗
NASA NTRS1997

Formation of Carbon Nanotube Based Gears: Quantum Chemistry and Molecular Mechanics Study of the Electrophilic Addition of o-Benzyne to Fullerenes, Graphene, and Nanotubes

Considerable progress has been made in recent years in chemical functionalization of fullerene molecules. In some cases, the predominant reaction products are different from those obtained (using the same reactants) from polycyclic aromatic hydrocarbons (PAHs). One such example is the cycloaddition of o-benzyne to C60. It is well established that benzyne adds across one of the rings in naphthalene, anthracene and other PAHs forming the [2+4] cycloaddition product (benzobicyclo[2.2.2.]-octatriene with naphthalene and triptycene with anthracene). However, Hoke et al demonstrated that the only reaction path for o-benzyne with C60 leads to the [2+2] cycloaddition product in which benzyne adds across one of the interpentagonal bonds (forming a cyclobutene ring in the process). Either reaction product results in a loss of aromaticity and distortion of the PAH or fullerene substrate, and in a loss of strain in the benzyne. It is not clear, however, why different products are preferred in these cases. In the current paper, we consider the stability of benzyne-nanotube adducts and the ability of Brenner's potential energy model to describe the structure and stability of these adducts. The Brenner potential has been widely used for describing diamondoid and graphitic carbon. Recently it has also been used for molecular mechanics and molecular dynamics simulations of fullerenes and nanotubes. However, it has not been tested for the case of functionalized fullerenes (especially with highly strained geometries). We use the Brenner potential for our companion nanogear simulations and believe that it should be calibrated to insure that those simulations are physically reasonable. In the present work, Density Functional theory (DFT) calculations are used to determine the preferred geometric structures and energetics for this calibration. The DFT method is a kind of ab initio quantum chemistry method for determining the electronic structure of molecules. For a given basis set expansion, it is comparable in accuracy to the MP2 method (better than Hartree Fock, but less accurate than more extensive electron correlation methods such as MP4 or CCSD). However, for systems with large numbers of basis functions it more efficient than any other methods that include electron correlation effects. In this presentation we show the results of DFT calculations for the reaction of benzyne with naphthalene, C60, and nanotube models. We compare energies for [2+2] and [2+4] cycloaddition products. The preferred products for the naphthalene and C60 reactions have been determined by experiment and, thus, these cases serve as a validation of our quantum chemical approach. We also compare the DFT and Brenner potential results. Finally we can predict the likelihood of reaction between benzyne and nanotubes.

Jaffe, Richard↗
NASA NTRS1997

Quantum Chemistry Study of Cycloaddition Pathways for the Reaction of o-Benzyne with Fullerenes and Carbon Nanotubes

Functionalization of fullerenes via the [2+2] cycloaddition reaction with o-benzyne has been demonstrated in the laboratory. In contrast, [2+4) cycloaddition products are formed when benzyne reacts with planar polycyclic aromatic hydrocarbons. Using density functional theory (DFT) calculations with Becke's hybrid functional and small contracted gaussian basis sets, we are able to reproduce these product preferences. The objective of this work is to explore the functionalization of carbon nanotubes. We have studied o-benzyne cycloaddition products with a [14,0] single-walled nanotube. We find both the [2+2] and [2+4] adducts to be stable, with the latter product being somewhat favored.

Jaffe, Richard↗
NASA NTRS1987

Determination of O2(a1 delta g) and O2(b1 sigma+ g) yields in the reaction O + ClO --> Cl + O2: implications for photochemistry in the atmosphere of Venus

A discharge flow apparatus with chemiluminescence detector has been used to study the reaction O + ClO --> Cl + O2, where O2 = O2(a1 delta g) or O2(b1 sigma+ g). The measured quantum yields for producing O2(a1 delta g) and O2(b1 sigma+ g) in the above reaction are less than 2.5 x 10(-2) and equal to (4.4 +/- 1.1) x 10(-4), respectively. The observed O2(a1 delta g) airglow of Venus cannot be explained in the context of standard photochemistry using our experimental results and those reported in recent literature. The possibility of an alternative source of O atoms derived from SO2 photolysis in the mesosphere of Venus is suggested.

Non-NASA Center↗
NASA NTRS2005

FUSE Observations of QSOs behind Galaxy Clusters and of Galactic O VI Emission

We observed five quasars located behind clusters of galaxies with the goal of detecting resonant O VI absorption from warm (T approx. 10(exp 6) K) gas in the clusters' intracluster medium. The presence of such warm gas is predicted by cosmological hydrodynamic simulations and is observationally supported by the detection of "soft excess" emission in several galaxy clusters. A second goal was the detection of diffuse O VI emission from warm gas in our own Galaxy.

Dixon, William V.↗
NASA NTRS2005

Interaction of Superconducting YBa2Cu(sub 3-x)Zn(sub x)O(sub 7-y) with MeV Radiation

When the high Tc superconductor Y-Ba-Cu-O is cooled with liquid nitrogen, the conduction holes form a macroscopic collective or entangled state. While collective effects have been observed with radiation energies up to 5 eV, no high-sensitivity experiments have previously been carried out to search for comparable effects with MeV radiation. Here an experiment using a pair of scintillation counters arranged to search for changes in the natural background of high energy radiation adjacent to a warm and cold Y-Ba-Cu-O superconductor is described. The experiment showed a shift toward higher pulse heights when the SC was cooled, with a 4 standard deviation excess of 9.12+/-2.28 events/ksec over the range of 0 to 18 MeV. The net difference spectrum shows a 5.5 standard deviation excess signal for the range of 3 to 6 MeV.

Lewis, R. A.↗
NASA NTRS2006

Fundamental Properties of O-Type Stars

We present a comprehensive analysis of high-resolution, far-ultraviolet HST STIS, FUSE, and optical spectra of 18 O stars in the Small Magellanic Cloud. Our analysis is based on the OSTAR2002 grid of NLTE metal-line-blanketed model atmospheres calculated with our code TLUSTY. We systematically explore and present the sensitivity of various UV and optical lines to different stellar parameters. We have obtained consistent fits of the UV and the optical spectrum to derive the effective temperature, surface gravity, surface composition, and microturbulent velocity of each star. Stellar radii, masses, and luminosities follow directly. For stars of the same spectral subtype, we find a general good agreement between effective temperature determinations obtained with TLUSTY, CMFGEN, and FASTWIND models, which are all lower than the standard T(sub eff) calibration of O stars. We propose a new calibration between the spectral type and effective temperature based on our results from UV metal lines, as well as optical hydrogen and helium lines. The lower effective temperatures translate into ionizing luminosities that are smaller by a factor of 3 compared to luminosities inferred from previous standard calibrations. The chemical composition analysis reveals that the surface of about 80% of the program stars is moderately to strongly enriched in nitrogen, while showing the original helium, carbon, and oxygen abundances. Our results support the new stellar evolution models that predict that the surface of fast rotating stars becomes nitrogen-rich during the main-sequence phase because of rotationally induced mixing. Enrichment factors are, however, larger than predicted by stellar evolution models. Most stars exhibit the "mass discrepancy" problem, which we interpret as a result of fast rotation that lowers the measured effective gravity. Nitrogen enrichment and low spectroscopic masses are therefore two manifestations of fast rotation. Our study thus emphasizes the importance of rotation in our understanding of the properties of massive stars and provides a framework for investigating populations of low-metallicity massive stars at low and high redshifts.

Heap, Sara R.↗
NASA NTRS1996

Validation of UARS MLS 183 GHz H(sub 2)O Measurements

We provide a validation of MLS H(sub 2)O by analyzing the integrity of the measurements, by providing an error characterization and by comparison with data from other instruments. This paper concerns the data validation of middle atmosphere distributions of H(sub 2)O as measured by the Midrowave Limb Sounder (MLS).

thermal emission UARS energy balance of the middle↗
NASA NTRS2008

Fe, O, and C Charge States Associated with Quiescent Versus Active Current Sheets in the Solar Wind

Ulysses MAG data were used to locate the heliospheric current sheet in data from 1991 through 2006. The purpose was to characterize typical charge states for Fe, O, and C in the vicinity of the current sheet and provide insight into the physical sources for these charge states in the corona. A study of He/H around the current sheets has led to a clear distinction between quiescent current sheets at times of low solar activity and active current sheets associated with magnetic clouds (and, presumably, ICMES). It has been shown that high ionization state Fe is produced in the corona in current sheets associated with CMEs through spectroscopic observations of the corona and through in situ detection at Ulysses. Here we show that the ionization state of Fe is typically only enhanced around active current sheets while the ionization states of O and C are commonly enhanced around both quiescent and active current sheets. This is consistent with UV coronal spectroscopy, which has shown that reconnection in current sheets behind CMEs leads to high temperatures not typically seen above quiet streamers.

Suess, S. T.↗
NASA NTRS2009

Covariant C and O Isotope Trends in Arctic Carbonate Crusts and ALH 84001: Potential Biomarker or Indicator of Cryogenic Formation Environment?

This work seeks to use the chemical, isotopic, and mineralogical characteristics of secondary carbonate minerals produced during brief aqueous events to identify the conditions of the aqueous environment in which they formed. Liquid water near the surface of Mars is subject to either rapid freezing and/or evaporation. These processes are also active on Earth, and produce secondary minerals that have complex chemical, mineralogical, and isotopic textures and compositions that can include covariant relationships between Delta C-13 (sub VPDB) and delta O-18 (sub VSMOW). The extremely well studied four billion year old carbonates preserved in martian meteorite ALH 84001 also show covariant delta C-13 and delta O-18 compositions, but these variations are manifested on a micro-scale in a single thin section while the variation observed so far in terrestrial carbonates is seen between different hand samples.

Socki, Richard A.↗