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At least 559 records · Page 31

Removal of sodium chloride from human urine via batch recirculation electrodialysis at constant applied voltage

The removal of sodium chloride (NaCl) from human urine using a six-compartment electrodialysis cell with batch recirculation mode of operation for use in advanced life support systems (ALSS) was studied. From the results obtained, batch recirculation at constant applied voltage yields high values (approximately 94% of NaCl removal. Based on the results, the initial rate of NaCl removal was correlated to a power function of the applied voltage: -r=2.0 x 10(-4)E(3.8). With impedance spectroscopy methods, it was also found that the anion membranes were more affected by fouling with an increase of the ohmic resistance of almost 11% compared with 7.4% for the cationic ones.

Ecological Systems, Closed↗

Signaling in Human and Murine Lymphocytes in Microgravity: Parallels and Contrasts

Immune function in space undergoes dramatic changes, some of which are detrimental to lymphocyte function. These changes may lead to significant immune suppression. Studies with human lymphocytes both in space flight and with ground-based models (NASA in vitro ground-based microgravity analog) indicate that T cell activation is inhibited in microgravity. Other lymphocyte functions, such as locomotion, are also inhibited. There is about an 80 percent homology in the immune response of mice to that of humans. A murine model was investigated because of its ability to parallel some microgravity using hind limb suspension. In in vivo antiorthostatically (AOS)-suspended mice, T cell activation is greatly suppressed, with the majority of activation related cytokines being inhibited. PHA activation in lymphocytes derived from AOS mice (in vivo ground-based microgravity analog) is also suppressed. Calcium ionophore studies in human lymphocytes exposed to modeled microgravity indicate that the calcium pathways are probably unaffected in microgravity. IP3 (inositol triphosphate) receptor expression in both human and mouse lymphocytes cultured in modeled microgravity indicate no suppression of calcium signaling. In the human system, microgravity seems to inhibit signaling cascades either at the level of, or up-stream of, Protein Kinase C (PKC). In particular, a membrane event, such as phospholipase C gamma 1 activity in human lymphocytes is affected, with its direct upstream effector, LAT, being deficiently expressed. In the mouse pathway, LAT is undiminished while another critical intermediate, SLP-76, is diminished significantly. This study identifies critical stages in the human and mouse immune systems and in lymphocytes as a function of microgravity.

Neal, Pellis↗

Application of Emulsified Zero-Valent Iron to Marine Environments

Contamination of marine waters and sediments with heavy metals and dense non-aqueous phase liquids (DNAPLs) including chlorinated solvents, pesticides and PCBs pose ecological and human health risks through the contaminant's potential bioaccumulation in fish, shellfish and avian populations. The contaminants enter marine environments through improper disposal techniques and storm water run-off. Current remediation technologies for application to marine environments include costly dredging and off-site treatment of the contaminated media. Emulsified zero-valent iron (EZVI) has been proven to effectively degrade dissolved-phase and DNAPL-phase contaminants in freshwater environments on both the laboratory and field-scale level. However, the application to marine environments is only just being explored. This paper discusses the potential use of EZVI in brackish and saltwater environments, with supporting laboratory data detailed. Laboratory studies were performed in 2005 to establish the effectiveness of EZVI to degrade trichloroethylene (TCE) in saltwater. Headspace vials were setup to determine the kinetic rate of TCE degradation using EZVI in seawater. The reaction vials were analyzed by Gas Chromatographic/Flame Ionization Detection (GC/FID) for ethene production after a 48 day period using a GC/FID Purge and Trap system. Analytical results showed that EZVI was very effective at degrading TCE. The reaction by-products (ethene, acetylene and ethane) were produced at 71% of the rate in seawater as in the fresh water controls. Additionally, iron within the EZVI particles was protected from oxidation of the corrosive seawater, allowing EZVI to perform in an environment where zero-valent iron alone could not compete. Laboratory studies were also performed to establish the effectiveness of emulsified zero-valent metal (EZVM) to remove dissolved-phase cadmium and lead found in seawater. EZVM is comprised of a combination of magnesium and iron metal surrounded by the same oil/surfactant membrane used in EZVI. The removal of cadmium and lead from a seawater matrix is a unique challenge. It requires a system that is resistant to the corrosive nature of seawater while removing specific ions that are in a relatively low concentration compared to naturally occurring seawater salts. Laboratory studies conducted show greater than 99% removal of lead and 96% removal of cadmium from a seawater solution spiked at 5 mg/L that was treated with an Emulsified Zero-Valent Metal (EZVM). The cadmium and lead are removed from the solution as they transport across the emulsion membrane and plate out onto the zero-valent metal surface.

Brooks, Kathleen B.↗

The Adaptable, Deployable, Entry and Placement Technology (ADEPT) Enabling Advanced Entry, Descent, and Landing Capabilities for SmallSat Missions

The Adaptable, Deployable Entry and Placement Technology (ADEPT) is a mechanically deployable low-ballistic coefficient aeroshell entry system which performs entry, descent, and landing (EDL) functions for a broad range of planetary destinations including Mars, Venus, Titan and Earth. The deployable system allows mission planners to develop an aeroshell design that is stowed like a folded umbrella, and yet prior to the EDL mission segment, transforms into a deployed, near-rigid low ballistic coefficient configuration. The ADEPT architecture is scalable from a sub-1m class to 6m diameter entry vehicles for Venus and and it has been studied at up to 15m – 20m scale for human exploration class missions. There has been growing interest in performing interplanetary missions with small spacecraft as secondary payloads and ADEPT offers small satellite mission designers the ability to consider Aeroassist technologies to expand mission applications. The ADEPT architecture introduces a new approach for entry vehicle design. It deploys a flexible 3D woven carbon fabric as the primary drag surface. It is capable of surviving high aerothermal heating during entry, while maintaining a robust impermeable membrane that provides high drag for vehicle deceleration. The ADEPT project team has advanced this decelerator technology via systems-level testing at the one meter diameter (nano-ADEPT) scale. A subsonic aeroloads test (May 2015) and a pathfinder arc-jet aeroheating test (Sept 2015) and a successful sounding rocket flight (SR-1) launch of a 0.7 meter deployed diameter ADEPT (September 2018). The SR-1 flight experiment demonstrated most of the primary end-to-end mission stages including: launch in a stowed configuration, separation and deployment in zero-g, exo-atmospheric conditions, and passive ballistic re-entry of a 70 degree half-angle cone geometry. The ADEPT SR-1 sounding rocket flight experiment had to address challenges such as stowing within the constrained payload envelope, fabric folding, and packaging concerns.

Paul Wercinski↗

Results of the Alternative Water Processor Test, A Novel Technology for Exploration Wastewater Remediation

Biologically‐based water recovery systems are a regenerative, low energy alternative to physiochemical processes to reclaim water from wastewater. This paper summarizes the results of the Alternative Water Processor (AWP) test conducted over one year. The AWP recovered 90% of water from four crewmembers using (4) membrane aerated bioreactors (MABRs) to remove carbon and nitrogen from an exploration mission wastewater, including urine, hygiene, laundry and humidity condensate. Downstream, a coupled forward and reverse osmosis system removed large organics and inorganic salts from the biological system effluent. The system exceeded the overall objectives of the test by recovering 90% of the influent wastewater processed and a 29% reduction of consumables from the current state of the art water recovery system on the International Space Station (ISS). However the biological system fell short of its test goals, failing to remove 75% and 90% of the influent ammonium and organic carbon, respectively. Despite not meeting its test goals, the BWP demonstrated the feasibility of an attachedgrowth biological system for simultaneous nitrification and denitrification, an innovative, volume and consumable‐saving design that doesn't require toxic pretreatment. This paper will explain the reasons for this and will discuss steps to optimize each subsystem to increase effluent quality from the MABRs and the FOST to advance the system.

Leticia Vega↗

Results of the Alternative Water Processor Test, A Novel Technology for Exploration Wastewater Remediation

Biologically-based water recovery systems are a regenerative, low energy alternative to physiochemical processes to reclaim water from wastewater. This paper summarizes the results of the Alternative Water Processor (AWP) test conducted over one year. The AWP recovered 90% of water from four crewmembers using (4) membrane aerated bioreactors (MABRs) to remove carbon and nitrogen from an exploration mission wastewater, including urine, hygiene, laundry and humidity condensate. Downstream, a coupled forward and reverse osmosis system removed large organics and inorganic salts from the biological system effluent. The system exceeded the overall objectives of the test by recovering 90% of the influent wastewater processed and a 29% reduction of consumables from the current state of the art water recovery system on the International Space Station (ISS). However the biological system fell short of its test goals, failing to remove 75% and 90% of the influent ammonium and organic carbon, respectively. Despite not meeting its test goals, the BWP demonstrated the feasibility of an attached-growth biological system for simultaneous nitrification and denitrification, an innovative, volume and consumable-saving design that doesn't require toxic pretreatment. This paper will explain the reasons for this and will discuss steps to optimize each subsystem to increase effluent quality from the MABRs and the FOST to advance the system.

Leticia Vega↗

Soft ionization device with characterization systems and methods of manufacture

Various configurations of characterization systems such as ion mobility spectrometers and mass spectrometers are disclosed that are coupled to an ionization device. The ionization device is formed of a membrane that houses electrodes therein that are located closer to one another than the mean free path of the gas being ionized. Small voltages across the electrodes generate large electric fields which act to ionize substantially all molecules passing therethrough without fracture. Methods to manufacture the mass spectrometer and ion mobility spectrometer systems are also described.

Hartley, Frank T.↗

Mechanism of Pinhole Formation in Membrane Electrode Assemblies for PEM Fuel Cells

The pinhole formation mechanism was studied with a variety of MEAs using ex-situ and in-situ methods. The ex-situ tests included the MEA aging in oxygen and MEA heat of ignition. In-situ durability tests were performed in fuel cells at different operating conditions with hydrogen and oxygen. After the in-situ failure, MEAs were analyzed with an Olympus BX 60 optical microscope and Cambridge 120 scanning electron microscope. MEA chemical analysis was performed with an IXRF EDS microanalysis system. The MEA failure analyses showed that pinholes and tears were the MEA failure modes. The pinholes appeared in MEA areas where the membrane thickness was drastically reduced. Their location coincided with the stress concentration points, indicating that membrane creep was responsible for their formation. Some of the pinholes detected had contaminant particles precipitated within the membrane. This mechanism of pinhole formation was correlated to the polymer blistering.

Stanic, Vesna↗

PEM regenerative fuel cells

This paper will update the progress in developing electrocatalyst systems and electrode structures primarily for the positive electrode of single-unit solid polymer proton exchange membrane (PEM) regenerative fuel cells. The work was done with DuPont Nafion 117 in complete fuel cells (40 sq cm electrodes). The cells were operated alternately in fuel cell mode and electrolysis mode at 80 C. In fuel cell mode, humidified hydrogen and oxygen were supplied at 207 kPa (30 psi); in electrolysis mode, water was pumped over the positive electrode and the gases were evolved at ambient pressure. Cycling data will be presented for Pt-Ir catalysts and limited bifunctional data will be presented for Pt, Ir, Ru, Rh, and Na(x)Pt3O4 catalysts as well as for electrode structure variations.

Swette, Larry L.↗

Thermomechanical Postbuckling of Shells

A number of issues involving the postbuckling of doubly-curved panels exposed to a non-uniform temperature field and subjected to a system of mechanical loads are considered in this paper. Effects played by transverse shear, initial geometric imperfections, membrane and thickness-wise temperature gradient, tangential edge constraints, linear/non-linear elastic foundation are incorporated and their implications on the non-linear response behavior of shells are discussed. Issues related with the delay of the occurrence of the snap-through buckling, alleviation of its intensity and even with its removal are addressed and remarks on conditions rendering a curved panel insensitive to initial geometric imperfections are included. Results on small vibration of shells about sub- and post-critical ranges are provided and structural modeling issues playing a non-negligible role towards a reliable prediction of the postbuckling behavior of shells under complex loading conditions are discussed. Results on non-linear response of flat reinforced panels subjected to thermomechanical loads are also presented. Finally, problems not covered by this article are briefly indicated.

Librescu, Liviu↗

Wavefront Sensing and Control Technology for Submillimeter and Far-Infrared Space Telescopes

The NGST wavefront sensing and control system will be developed to TRL6 over the next few years, including testing in a cryogenic vacuum environment with traceable hardware. Doing this in the far-infrared and submillimeter is probably easier, as some aspects of the problem scale with wavelength, and the telescope is likely to have a more stable environment; however, detectors may present small complications. Since this is a new system approach, it warrants a new look. For instance, a large space telescope based on the DART membrane mirror design requires a new actuation approach. Other mirror and actuation technologies may prove useful as well.

Redding, Dave↗

Design and test of a prototype DART system

A 1.2-meter prototype Dual Anamorphic Reflector Telescope (DART) system has been build and tested. The key design feature of the telescope is a pair of membrane mirrors stretched to single curvature parabolic cylindrical sections. The parabolic figure of the mirrors is controlled by a pair of edge rails at two opposing ends of the membrane. The flexible edge rails are adjusted to parabolic to very high accuracy and can potentially be easily refigured on-orbit. The prototype telescope is lightweight and has demonstrated excellent optical performance for the farIR. The design is readily scalable to larger apertures and for operation at shorter wavelengths. Design and test results are discussed.

DART↗

Ground-based Design of a Test System to Evaluate Static Vapor Feed Electrolysis for Oxygen Generation

NASA designed a test facility to evaluate the performance of a Static Vapor Feed Electrolysis (SVFE) cell stack to determine its viability as an alternative technology to the state-of-the-art Oxygen Generation Assembly (OGA) to generate oxygen for habitable spacecraft environments. Static Vapor Feed Electrolysis differs from the liquid cathode-feed process utilized by the OGA in that the electrolysis process occurs entirely in the gas phase, operates at a higher pressure than OGA, and potentially requires a simpler balance-of-plant system. Pressurized liquid water is statically-fed, i.e. dead-headed, through a vapor-permeable membrane into the electrolysis chamber of the cell stack. The water vapor is then electrolyzed into hydrogen and oxygen in the cathode and anode chambers, respectively, all the while maintaining above-ambient pressures to eliminate water condensation in the oxygen and hydrogen product streams. This paper presents the design of the test facility and accompanying required balance-of-plant that will be used to test the SVFE cell stack.

Zeeshan Khawar↗

Analytical Review of Exploration Extravehicular Mobility Unit Heat Rejection Performance

The Primary Thermal Control Loop (PTCL) in the Exploration Extravehicular Mobility Unit (xEMU) uses a Spacesuit Water Membrane Evaporator (SWME) to provide cooling for the crew member and spacesuit avionics. A secondary emergency cooling system, the Auxiliary Thermal Control Loop (ATCL), also uses a smaller version of the SWME, called the Mini-ME, in the event of a failure in the primary system. These are integral to the comfort of the crew member (through heat rejection) during an Extravehicular Activity (EVA). This paper examines the effectiveness of the heat rejection of the PTCL and the ATCL during thermal vacuum testing and the absolute limit of heat rejection to maintain an approximately 10C outlet temperature. During this thermal vacuum test, the PTCL was taken from a heat input of 0W up to 900W, far past the design point, and the ATCL was tested from 0W to 300W. Testing showed that the PTCL and the ATCL can maintain crew member outlet temperature throughout an entire 8-hour thermally controlled EVA environment (hot and cold). The results and effectiveness of the test will be detailed throughout this paper for all EVAs (whether a full mapping profile or a standard continuous heat load).

PLSS↗

Regulation of cyclic nucleotide-gated channels and membrane excitability in olfactory receptor cells by carbon monoxide

1. The effect of the putative neural messenger carbon monoxide (CO) and the role of the cGMP second-messenger system for olfactory signal generation was examined in isolated olfactory receptor neurons (ORNs) of the tiger salamander. 2. With the use of whole cell voltage-clamp recordings in combination with a series of ionic and pharmological tests, it is demonstrated that exogenously applied CO is a potent activator (K1/2 = 2.9 microM) of cyclic nucleotide-gated (CNG) channels previously described to mediate odor transduction. 3. Several lines of evidence suggest that CO mediates its effect through stimulation of a soluble guanylyl cyclase (sGC) leading to formation of the second-messenger cGMP. This conclusion is based on the findings that CO responses show an absolute requirement for guanosine 5'-triphosphate (GTP) in the internal solution, that no direct effect of CO on CNG currents in the absence of GTP is detectable, and that a blocker of sGC activation, LY85383 (10 microM), completely inhibits the CO response. 4. The dose-response curve for cGMP at CNG channels is used as a calibration to provide a quantitative estimate of the CO-stimulated cGMP formation. This analysis implies that CO is a potent activator of olfactory sGC. 5. Perforated patch recordings using amphotericin B demonstrate that low micromolar doses of CO effectively depolarize the membrane potential of ORNs through tonic activation of CNG channels. This effect in turn regulates excitable and adaptive properties of ORNs and modulates neuronal responsiveness. 6. These data argue for an important role of the cGMP pathway in olfactory signaling and support the idea that CO may function as a diffusible messenger in the olfactory system.

NASA Discipline Neuroscience↗

Advanced CO2 Removal Technology Development

The Advanced CO2 Removal Technical Task Agreement covers three active areas of research and development. These include a study of the economic viability of a hybrid membrane/adsorption CO2 removal system, sorbent materials development, and construction of a database of adsorption properties of important fixed gases on several adsorbent material that may be used in CO2 removal systems. The membrane/adsorption CO2 removal system was proposed as a possible way to reduce the energy consumption of the four-bed molecular sieve system now in use. Much of the energy used by the 4BMS is used to desorb water removed in the device s desiccant beds. These beds might be replaced by a desiccating membrane that moves the water from [he incoming stream directly into the outlet stream. The approach may allow the CO2 removal beds to operate at a lower temperature. A comparison between models of the 4BMS and hybrid systems is underway at Vanderbilt University. NASA Ames Research Center has been investigating a Ag-exchanged zeolites as a possible improvement over currently used Ca and Na zeolites for CO2 removal. Silver ions will complex with n:-bonds in hydrocarbons such as ethylene, giving remarkably improved selectivity for adsorption of those materials. Bonds with n: character are also present in carbon oxides. NASA Ames is also continuing to build a database for adsorption isotherms of CO2, N2, O2, CH4, and Ar on a variety of sorbents. This information is useful for analysis of existing hardware and design of new processes.

Finn, John E.↗

Development of a Modeling Framework to Support Control Investigations of Sailcraft Missions A First Cut: ABLE Sailcraft Dynamics Model

Solar Sailcraft, the stuff of dreams of the H.G. Wells generation, is now a rapidly maturing reality. The promise of unlimited propulsive power by harnessing stellar radiation is close to realization. Currently, efforts are underway to build, prototype and test two configurations. These sails are designed to meet a 20m sail requirement, under guidance of the In-Space Propulsion (ISP) technology program office at MSFC. While these sails will not fly , they are the first steps in improving our understanding of the processes and phenomena at work. As part of the New Millennium Program (NMP) the ST9 technology validation mission hopes to launch and fly a solar sail by 2010 or sooner. Though the Solar Sail community has been studying and validating various concepts over two decades, it was not until recent breakthroughs in structural and material technology, has made possible to build sails that could be launched. With real sails that can be tested (albeit under earth conditions), the real task of engineering a viable spacecraft has finally commenced. Since it is not possible to accurately or practically recreate the actual operating conditions of the sailcraft (zero-G, vacuum and extremely low temperatures), much of the work has focused on developing accurate models that can be used to predict behavior in space, and for sails that are 6-10 times the size of currently existing sails. Since these models can be validated only with real test data under "earth" conditions, the process of modeling and the identification of uncertainty due to model assumptions and scope need to be closely considered. Sailcraft models that exist currently, are primarily focused on detailed physical representations at the component level, these are intended to support prototyping efforts. System level models that cut across different sail configurations and control concepts while maintaining a consistent approach are non-existent. Much effort has been focused on the areas of thrust performance, solar radiation prediction, and sail membrane behavior vis-a-vis their reflective geometry, such as wrinkling/folding/furling as it pertains to thrust prediction. A parallel effort has been conducted on developing usable models for developing attitude control systems (ACS), for different sail configurations in different regimes. There has been very little by way of a system wide exploration of the impact of the various control schemes, thrust prediction models for different sail configurations being considered.

Sarathy, Sriprakash↗

Design and Flight Testing of an Inflatable Sunshield for the NGST

The Next Generation Space Telescope (NGST) mission is scheduled to launch in 2007 and be stationed at L2 for a mission life of ten years. The large aperture mirror and optical detectors aboard NGST require shielding from the constant solar energy seen at this orbit. The government reference NGST design, called the Yardstick, baselined a sunshield using an inflation deployment system. During the formulation phase, NGST is spending approximately 25% of the overall budget to foster the development of new technology. The goal is to develop and demonstrate enabling or enhancing technology and provide innovative solutions for the design of the NGST observatory. Inflatable technology falls in the category of enhancing technology due to its advantages in weight, stowed volume and cost. The Inflatable Sunshield in Space (ISIS) flight experiment will provide a realistic space flight demonstration of an inflatable sunshield. The supporting technology development program will provide an information base for the design, manufacture, assembly and testing of large thin membranes and inflatable structural elements for space structures. The ISIS experiment will demonstrate the feasibility of using inflatable technology to passively cool optical systems for NGST and provide correlation between analytical predictions and on orbit results. The experiment will be performed on a Hitchhiker/Space Shuttle mission in late 2001. The ISIS mission is an effort to address several major technical challenges of the NGST inflatable sunshield, namely controlled inflation deployment, plenarity and separation of large stretched membranes, space rigidization of inflatable booms, and dynamic modeling and simulation. This paper will describe the design of the flight experiment and the testing to be performed on-orbit.

Adams, Michael L.↗