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At least 559 records · Page 31

Enhancing the Functionality of a Hollow Scaffold Solid State Bioreactor via Computer Aided Design Optimization

The concern over greenhouse gases, methane (CH 4 ) and carbon dioxide (CO 2 ), is increasing rapidly. There have been strides to find solutions to this global issue but there is not a clear path to a successful end goal. The concentration of CH 4 and CO 2 in the atmosphere has increased significantly over the last 60 years, methane is a great source of concern due to its ability to trap a high amount of heat in the atmosphere. These greenhouse gases contribute to global warming which has caused changes in the environment, including the melting of ice caps, and altered weather patterns. Solutions for these pressing challenges have led to different avenues of methane mitigation one of which is the development of solid-state bioreactors. These reactors harness the power of biological species that have evolved to use methane as an energy source. The development and optimization of Hollow Scaffold Solid State Bioreactors (HS-SSBR) has become readily available due to the advancements in additive manufacturing technology and accessibility of computer aided design (CAD) software. With laboratory scale experiments, time and effort are of great importance. Enhancing the design of the HS-SSBR to create a more user-friendly interface, but also increase the functionality of the reactor. The reactor's design improvements focus on better dispersion of methane and circulation of media.

36 MATERIALS SCIENCE↗

Hard x-ray imaging and characterization of staged z-pinch plasmas in order to exclude ion beams as cause of fusion

Prior to the start of the INFUSE project, a 1-D x-ray device had been developed to detect > 5 keV x-rays and, by using the device as a pinhole camera, determine the location of the source of these x-rays. The system was also used in a non-camera mode to measure the energy of the X-rays by having different thicknesses of attenuating material on different pixels. This dual-purpose had been used in three plasma experiments: the laboratory magnetized plasma jet at Caltech, the laboratory solar nanoflare at Caltech, and at the 500 kA staged Z-pinch (CESZAR) at UCSD. Preliminary measurements at the UCSD facility indicated that hard x-rays with energies ranging from ~27 to over 100 keV were created and that these x-rays likely originated at the Z-pinch’s anode. These preliminary data also indicated that the x-rays’ origin was coincident with the moment of peak compression. The major goal of the INFUSE proposal was to confirm these preliminary results. This confirmation was to be made by improving the imaging capability to two dimensions, increasing the time resolution of the camera, and using the x-ray diagnostic alongside time-resolved neutron detectors.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Report on the Update and Codification of Expert Knowledge into ASTM Standard Practice E521

The overall purpose of the Grand Challenge Integrated Research Project (IRP), Accelerating the Qualification of Materials to Enable Rapid Deployment of Advanced Reactors, is to fulfill several objectives. The first objective is to complete and demonstrate/establish the process for predicting the microstructure and properties of structural materials in reactor and at high doses using ion irradiation as an accurate predictive tool for assessing behavior under reactor irradiation. The second objective is for this process to be adopted as part of an ASTM standard, and to work with the US Nuclear Regulatory Commission to utilize this standard in licensing decisions on advanced reactor designs for which such data are nonexistent or impractical to achieve. The need for standardized procedures is apparent based on the outcomes of a recent round-robin experiment from laboratories using ion beams for radiation damage studies and the roadmap for ion beam technologies to address challenges for the advancement of nuclear energy technologies.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Differential Organic Carbon Mineralization Responses to Soil Moisture in Three Different Soil Orders Under Mixed Forested System

Soil microbial respiration is one of the largest sources of carbon (C) emissions to the atmosphere in terrestrial ecosystems, which is strongly dependent on multiple environmental variables including soil moisture. Soil moisture content is strongly dependent on soil texture, and the combined effects of texture and moisture on microbial respiration are complex and less explored. Therefore, this study examines the effects of soil moisture on the mineralization of soil organic C Soil organic carbon in three different soils, Ultisol, Alfisol and Vertisol, collected from mixed forests of Georgia, Missouri, and Texas, United States , respectively. A laboratory microcosm experiment was conducted for 90 days under different moisture regimes. Soil respiration was measured weekly, and destructive harvests were conducted at 1, 15, 60, and 90 days after incubation to determine extractable organic C (EOC), phospholipid fatty acid based microbial community, and C-acquiring hydrolytic extracellular enzyme activities (EEA). The highest cumulative respiration in Ultisol was observed at 50% water holding capacity (WHC), in Alfisol at 100% water holding capacity, and in Vertisol at 175% WHC. The trends in Extractable Organic Carbon were opposite to that of cumulative microbial respiration as the moisture levels showing the highest respiration showed the lowest EOC concentration in all soil types. Also, extracellular enzyme activities increased with increase in soil moisture in all soils, however, respiration and EEA showed a decoupled relationship in Ultisol and Alfisol soils. Soil moisture differences did not influence microbial community composition.

54 ENVIRONMENTAL SCIENCES↗

Tidal Turbine Benchmarking Project: Stage I - Steady Flow Blind Predictions: Preprint

This paper presents the first blind prediction stage of the Tidal Turbine Benchmarking Project being conducted and funded by the UK's EPSRC and Supergen ORE Hub. In this first stage, only steady flow conditions, at low and elevated turbulence (3.1%) levels, were considered. Prior to the blind prediction stage, a large laboratory scale experiment was conducted in which a highly instrumented 1.6m diameter tidal rotor was towed through a large towing tank in well-defined flow conditions with and without an upstream turbulence grid. Details of the test campaign and rotor design were released as part of this community blind prediction exercise. Participants were invited to use a range of engineering modelling approaches to simulate the performance and loads of the turbine. 26 submissions were received from 12 groups from across academia and industry using solution techniques ranging from blade resolved computational fluid dynamics through actuator line, boundary integral element methods, vortex methods to engineering Blade Element Momentum methods. The comparisons between experiments and blind predictions were extremely positive helping to provide validation and uncertainty estimates for the models, but also validating the experimental tests themselves. The exercise demonstrated that the experimental turbine data provides a robust data set against which researchers and design engineers can test their models and implementations to ensure robustness in their processes, helping to reduce uncertainty and provide increased confidence in engineering processes. Furthermore, the data set provides the basis by which modellers can evaluate and refine approaches.

benchmarking↗

Observations of gas-phase products from the nitrate-radical-initiated oxidation of four monoterpenes

Abstract. Chemical ionization mass spectrometry with the nitrate reagent ion (NO3- CIMS) was used to investigate the products of the nitrate radical (NO3) initiated oxidation of four monoterpenes in laboratory chamber experiments. α-Pinene, β-pinene, Δ-3-carene, and α-thujene were studied. The major gas-phase species produced in each system were distinctly different, showing the effect of monoterpene structure on the oxidation mechanism and further elucidating the contributions of these species to particle formation and growth. By comparing groupings of products based on the ratios of elements in the general formula CwHxNyOz, the relative importance of specific mechanistic pathways (fragmentation, termination, and radical rearrangement) can be assessed for each system. Additionally, the measured time series of the highly oxidized reaction products provide insights into the ratio of relative production and loss rates of the high-molecular-weight products of the Δ-3-carene system. The measured effective O:C ratios of reaction products were anticorrelated with new particle formation intensity and number concentration for each system; however, the monomer : dimer ratios of products had a small positive trend. Gas-phase yields of oxidation products measured by NO3- CIMS correlated with particle number concentrations for each monoterpene system, with the exception of α-thujene, which produced a considerable amount of low-volatility products but no particles. Species-resolved wall loss was measured with NO3- CIMS and found to be highly variable among oxidized reaction products in our stainless steel chamber.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Radiation Shielding Analysis for the PIP-II Linac at Fermilab

The Proton Improvement Plan-II (PIP-II) [1] has been developed at Fermilab to provide powerful proton beams to the laboratory’s experiments. An 800-MeV superconducting linear accelerator—a centerpiece of the project—is currently under construction in Batavia, Illinois (USA). After completion, the superconducting linac will be the starting point for the 1.2 MW (Phase 1) and 2.4-MW (Phase 2) proton beam that is needed for the Long-Baseline Neutrino Facility (LBNF) at Fermilab [2]. Due to unavoidable loss of a fraction of the beam in the accelerator components, a certain level of radiation will be generated in the accelerator tunnel both during normal operation and at accidents. This work deals with radiation shielding design for the accelerator facility.

Rakhno, Igor↗

Recent Radioactive Material Package Testing Experiences at Oak Ridge National Laboratory

Oak Ridge National Laboratory (ORNL) was a pioneer in the testing of radioactive material shipping packages and has been performing such tests for over 50 years. Currently, except for Type B thermal tests, testing is performed at the purpose-built Packaging Research Facility that is located at the National Transportation Research Center - a U.S. Department of Energy User Facility. Packages used for the transportation of Type B quantities of radioactive materials must be capable of meeting normal conditions of transportation (NCT) requirements and hypothetical accident conditions (HAC) requirements as defined in Title 10 Code of Federal Regulations (CFR) Part 71. Evaluation of package designs to these criteria typically involves a combination of analysis and physical testing. Required physical tests include free drop, crush, puncture, penetration, compression, vibration, water spray, water immersion, and thermal. The Oak Ridge National Laboratory (ORNL) Packaging Evaluation Facility (PEF) at the National Transportation Research Center (NTRC) provides an inclusive testing capability for a wide variety of packages needed for shipment of radioactive materials. Since PATRAM 2019, ORNL has performed several sets of tests including testing of two designs of the Defense Program Package (DPP-3 and DPP-1) and several Special Form Capsules. This paper provides an overview of the testing performed as well as a summary of advancements made to the ORNL package testing program during that time.

Martinez, Oscar↗

Numerical study of proppant transport and settling processes in fractures

Reservoir stimulation by creating hydraulically conductive fractures is the key step for enabling enhanced geothermal systems (EGS). The effectiveness of stimulation is significantly influenced by the deposition of proppant inside induced fractures. The transportation and settling of proppant in a propagating fracture is controlled by a multitude of operational and physical parameters, including the fracturing fluid rheology, injection rate, proppant concentration, fracture length/aperture evolution, proppant size/density/shape, etc. A numerical tool that robustly and efficiently accounts for all important attributes can facilitate the design and optimization of reservoir stimulation. This study presents the novel computational tool ELK (ELectrical fracKing) developed for the numerical simulation of proppant-fluid mixture circulation in a fractured geothermal reservoir. We enriched the MOOSE-based PorousFlow module with a suite of equations to consider the fluid-proppant mixture with particle-particle/fluid interactions, which include gravitational settling, particle convection, particle hampering, and strong density and viscosity contrasts. The computational tool is validated by comparing the predicted proppant bed evolution against two different laboratory scale experiments of proppant transport in a fixed aperture channel. Further parameter studies were performed, and the modeling results show that the proppant deposition is determined by the mixing characteristics and settling of the particles from the slurry. Concentration-dependent density and viscosity lead to an inhomogeneous distribution of the proppant, particle collision, and enhanced settling at the bottom of the fractures. Preliminary coupling with dynamic fracture propagation shows promising results and will be further developed to simulate hydraulic stimulation at high fidelity.

15 GEOTHERMAL ENERGY↗

ASMS 2024 Investigation of Uranyl Perchlorate Anion Complexes in the Gas Phase via Infrared Multiphoton Dissociation and Collision Induced Dissociation

Investigation of Uranyl Perchlorate Anion Complexes in the Gas Phase via Infrared Multiphoton Dissociation and Collision Induced Dissociation Brittany D. M. Hodges, Christopher A. Zarzana, JungSoo Kim, Jonathan Martens, and W. C. M. Berden Introduction (120 words max) Effects of electronic structure on chemical bonding and reactivity play critical roles shaping the chemical bonding and reactivity behaviors of heavy elements. Understanding the role of f electrons in bond formation between the actinide-series elements like uranium with other ligands is critical for solving technical challenges associated with these heavy elements, important to nuclear fuel cycles, efficient separations of rare earth metals, and understanding the chemistry of stored nuclear fuels and related environmental management sites. In this study, we further examine the interactions between uranyl and the perchlorate ion in order to understand the structures of these ions through the use of IRMPD. Here we report the IRMPD spectra of [UO2(ClO4)3]-, [UO3(ClO4)2]-, and a proposed transition state. Methods (120 word max) IRMPD spectra and CID spectra were acquired using a Bruker amaZon QIT/MS instrument at the Free-Electron Lasers for Infrared eXperiments (FELIX) laboratory at Radboud University. The FELIX QIT/MS is modified to allow for the high-intensity tunable IR beam from FELIX to be directed into the ion packet, resulting in multiphoton dissociation that is measured only when the IR frequency is in resonance with an adequately high absorption vibrational mode of the mass-selected complex. DFT geometry optimizations and frequency calculations using the Gaussian suite of programs were performed using B3LYP, TPSSh, and PBE0 level of theory with 6-31+G(d) basis for the O, C, H, and N atoms and the SDD basis set for U. The SDD basis set employs the Stuttgart/Dresden effective core potential. Preliminary Data or Plenary Speakers Abstract (300 words max) Metal ion clusters of uranyl perchlorate were formed via direct electrospray ionization. For each metal ligand complex of interest, the parent ion was isolated and collision induced dissociation fragmentation and Infrared Multiphoton Dissociation (IRMPD) fragmentation spectra were acquired. Results presented here are the first look at the IRMPD spectra of [UO3(ClO4)2]-, [UO2(ClO4)3]-. Structures were examined using Gaussian at different levels of theory B3LYP level of theory, TPPSh and PBE0 levels, to reflect the behaviors of uranium metal ligand complexes most accurately. In these structures, we identified an overlap between each of these uranyl stretches resulting in their largely being obscured by a perchlorate mode. The CID product spectra agree with similar structures reported by Groenewold for uranyl nitrate in 2006 (10.1021/ja058106n).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Overview of the Neutron Radiography Reactor (NRAD) for Neutron Imaging and In-Core Experiment Capabilities at Idaho National Laboratory

NRAD is a 250-kilowatt TRIGA research reactor that first went online at INL in 1977. (TRIGA stands for Training, Research, Isotopes, General Atomics.) Historically, NRAD was utilized as a neutron radiography reactor that provides comprehensive, non-destructive information about the internal condition of irradiated nuclear fuel. Idaho National Laboratory (INL) has multiple nuclear fuels research and development programs that routinely evaluate irradiated fuels using neutron radiography at NRAD. In recent years, NRAD has gone through a transformation from the single purpose radiography reactor for which it was designed into a multipurpose research reactor, and expanding its in-core irradiation capabilities to support a broader mission for the US Department of Energy (DOE) Nuclear Energy (NE) programs, Basic Energy Science (BES) Programs, as well as Fusion Energy programs. NRAD is a designated user facility under the DOE Nuclear Science User Facility (NSUF) program, and is available for access for general public via a competitive proposal process. More information about NSUF and NRAD are available from the website: https://nsuf.inl.gov/Home/Facility/654.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

IER-501 CED-3b: Experiment Execution Summary for the Pulsed-Neutron Die-Away Experimental Testbed for Thermal Scattering Law Benchmarks (PNDA)

This report summarizes the experiments done for IER-501, a testbed for pulsed-neutron die-away (PNDA) experiments at Lawrence Livermore National Laboratory (LLNL). The PNDA experiments were conducted in two separate two-day campaigns: one campaign for high-density polyethylene and another for Lucite. All experiments were performed at Lawrence Livermore Laboratory. They will become high-quality benchmarks that serve to optimize and validate thermal neutron scattering laws (TSLs), which are high priority nuclear data for the Department of Energy’s Nuclear Criticality Safety Program (NCSP). The report presents the PNDA design and its equipment, and it documents the experimental die-away curves. It presents the characterization measurements that have been performed to-date. Importantly, mass spectrometry measurements to determine sample impurities were not yet completed. These will be included in the final benchmark. The report gives the fitted decay constants for the die-away curves of each target sample. It also provides the data for the die-away curves in the appendices. The HDPE experiments examined twelve targets of varying size. The Lucite measurements included ten targets of varying size. Experimenters in the campaign were Daniel Siefman, William Zywiec, and Ruby Araj.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Integral Experiment Request 523 CED-2 Report

This report documents the final design phase of the Critical Experiment Design (CED-2) conducted as part of integral experiment request (IER) 523. The purpose of IER 523 is to determine critical configurations of 35 weight percent (wt%) enriched uranium dioxide beryllium oxide (UO 2 -BeO) material driven by an annular ring of Seven Percent Critical Experiment (7uPCX) fuel rods at Sandia National Laboratories (Sandia). The experiments will provide benchmark data on water moderated, intermediately enriched UO2 systems as well as Be nuclear data. The experiment will also provide partial validation for the beryllium oxide (BeO) thermal neutron scattering law (TSL) in the thermal energy range. Experiment design concepts, neutronic analysis results, and proposed paths for continuing the CED process are presented. This report builds on the feasibility and justification of experimental need report (CED-0) and preliminary experiment design report (CED-1) completed in December 2021 and September 2023, respectively [1, 2].

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Surface soil temperature and water content from warming experiment located at the Rocky Mountain Biological Laboratory, Colorado, 2015 to 2019

This data package consists of soil temperature and soil water content sensor data from the warming experiment near the Rocky Mountain Biological Laboratory. Data range is from summer 2015 to summer 2019, when the warming manipulation was terminated. The location of the warming experiment is in the upper montane life zone and consists of meadow vegetation with a mixture of sagebrush (Artemisia tridentata), forb species (Erigeron speciosus, Helianthella quinquenervis, Lathyrus lanszwertii), and graminoid species (Festuca thurberi, Carex spps). Early studies showed that the heating treatment led to earlier snowmelt as well as warmer and drier surface soils, and changes in the functional composition of aboveground biomass favoring sagebrush over forb species (Harte and Shaw, 1995). These changes were mainly observed in the upper, naturally drier zone for the experimental plots. More recent observations of aboveground biomass, soil carbon, and microbial composition require concurrent information about the abiotic environment for interpretation and extrapolation to process-based models. This data package provides the plot- and zone-level abiotic context for the final years of the experiment and consists of csv files with hourly soil temperature (WM_ST.csv) and soil water content (WM_SWC.csv).

54 ENVIRONMENTAL SCIENCES↗

A 15-Year Retrospective on Immersive Visualization Lessons from the Applied Visualization Laboratory

This article shares the experiences of operating an immersive visualization laboratory over a 15-year period. The paper discusses valuable insights into the lessons learned from various projects, including the challenges they faced, such as technical difficulties, user adoption, and opportunities, and practical solutions for overcoming them. One crucial element for successful immersive visualization projects is interdisciplinary collaboration. The paper presents the advantages of immersive visualization technology, such as improved data comprehension, enhanced communication, and increased engagement in complex scenarios. We present the dynamic realm of virtual and augmented truth (VR/AR) technology in the context of a immersive laboratory system. We spotlight rising trends inside the integration of VR/AR tools for visualization. We also present our experience in dealing with the hardware and software additives in an immersive VR/AR labs, dropping light on the demanding situations and successes encountered throughout everyday operations. Furthermore, it offers practical knowledge and guidance based on years of experience in the field, which can help you overcome challenges and achieve success in your project.

99 GENERAL AND MISCELLANEOUS↗

Preliminary Design of a New Pulsed-Neutron Die-Away Experimental Testbed for Thermal Scattering Law Benchmarks (PNDA) (IER-501 CED-1)

This report presents the preliminary design (CED-1) of IER-501, a new testbed for pulsed-neutron die-away (PNDA) experiments at Lawrence Livermore National Laboratory (LLNL). The PNDA experiments will be high-quality benchmarks that serve to optimize and validate thermal scattering laws (TSLs), which are high-priority nuclear data for the Department of Energy’s Criticality Safety Program (NCSP). PNDA experiments can be used to generate nuclear data validation benchmarks quickly and cheaply, as they do not require fissile material or a nuclear facility to conduct them.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Final Design of a New Pulsed-Neutron Die-Away Experimental Testbed for Thermal Scattering Law Benchmarks (PNDA) (IER-501 CED-2)

This report presents the final design (CED-2) of IER-501, a testbed for pulsed-neutron die-away (PNDA) experiments at Lawrence Livermore National Laboratory (LLNL). The PNDA experiments will be high-quality benchmarks that serve to optimize and validate thermal neutron scattering laws (TSLs), which are high-priority nuclear data for the Department of Energy’s Nuclear Criticality Safety Program (NCSP). This CED-2 was guided by experimental results gathered from a prototype experimental set-up rather than with detailed simulations as is typically done for criticality experiments. The report presents the PNDA design and its equipment, and it documents the methodology used to postprocess the measured data. It discusses how experimental configurations influenced the decay-constant eigenvalue, or the integral parameter, of the experiment. The studied variations included the distance from the target to the generator, the orientation of the generator relative to the box, the orientation of the target to the generator, the effect of HDPE lining in the shielding box, the settings of the generator, and finally the benefits of using a low-scatter facility. From these results, a final configuration for the target, detectors, shielding box, and neutron generator was chosen. Two factors particularly influenced the chosen configuration: the reproducibility of the experiment’s geometry for benchmark modeling, and the minimization of measured neutrons scattered off the shielding box.

42 ENGINEERING↗