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At least 559 records · Page 31

An intercomparison technique for measuring thermal attachment cross sections and rate constants in distinct final channels

A new technique is introduced for comparing negative-ion signal rates in which a common ion is produced by dissociative attachment in a series of molecules. Measurements are carried out at electron energies less than 100 MeV and at resolutions of 6-8 MeV (FWHM). The technique is demonstrated by detection of the Cl(-) signal in CFCl3, CCl4, CF2Cl2, 1,1,2-C2Cl3F3, 1,1,1-C2Cl3F3 and C2Cl4. Measurements for 1,1,1-C2Cl3F3 show that there is a significant open channel, other than Cl(-) formation, which accounts for about 60 percent of negative-ion formation in thermal-multiple-collision (swarm) experiments. Channel cross sections and rate constants are given for the process Cl(-)/1,1,1-Cl2Cl3F3, as well as in C2Cl4, for the separate channels Cl(-)/C2Cl4 and C2Cl4(-)/C2Cl4.

Alajajian, S. H.↗

NASA Tech Briefs, December 2005

Topics covered include: Video Mosaicking for Inspection of Gas Pipelines; Shuttle-Data-Tape XML Translator; Highly Reliable, High-Speed, Unidirectional Serial Data Links; Data-Analysis System for Entry, Descent, and Landing; Hybrid UV Imager Containing Face-Up AlGaN/GaN Photodiodes; Multiple Embedded Processors for Fault-Tolerant Computing; Hybrid Power Management; Magnetometer Based on Optoelectronic Microwave Oscillator; Program Predicts Time Courses of Human/ Computer Interactions; Chimera Grid Tools; Astronomer's Proposal Tool; Conservative Patch Algorithm and Mesh Sequencing for PAB3D; Fitting Nonlinear Curves by Use of Optimization Techniques; Tool for Viewing Faults Under Terrain; Automated Synthesis of Long Communication Delays for Testing; Solving Nonlinear Euler Equations With Arbitrary Accuracy; Self-Organizing-Map Program for Analyzing Multivariate Data; Tool for Sizing Analysis of the Advanced Life Support System; Control Software for a High-Performance Telerobot; Java Radar Analysis Tool; Architecture for Verifiable Software; Tool for Ranking Research Options; Enhanced, Partially Redundant Emergency Notification System; Close-Call Action Log Form; Task Description Language; Improved Small-Particle Powders for Plasma Spraying; Bonding-Compatible Corrosion Inhibitor for Rinsing Metals; Wipes, Coatings, and Patches for Detecting Hydrazines; Rotating Vessels for Growing Protein Crystals; Oscillating-Linear-Drive Vacuum Compressor for CO2; Mechanically Biased, Hinged Pairs of Piezoelectric Benders; Apparatus for Precise Indium-Bump Bonding of Microchips; Radiation Dosimetry via Automated Fluorescence Microscopy; Multistage Magnetic Separator of Cells and Proteins; Elastic-Tether Suits for Artificial Gravity and Exercise; Multichannel Brain-Signal-Amplifying and Digitizing System; Ester-Based Electrolytes for Low-Temperature Li-Ion Cells; Hygrometer for Detecting Water in Partially Enclosed Volumes; Radio-Frequency Plasma Cleaning of a Penning Malmberg Trap; Reduction of Flap Side Edge Noise - the Blowing Flap; and Preventing Accidental Ignition of Upper-Stage Rocket Motors.

Source record↗

Science Objectives and Rationale for the Radiation Belt Storm Probes Mission

The NASA Radiation Belt Storm Probes (RBSP) mission addresses how populations of high energy charged particles are created, vary, and evolve in space environments, and specifically within Earths magnetically trapped radiation belts. RBSP, with a nominal launch date of August 2012, comprises two spacecraft making in situ measurements for at least 2 years in nearly the same highly elliptical, low inclination orbits (1.1 x 5.8 RE, 10 deg.).The orbits are slightly different so that 1 spacecraft laps the other spacecraft about every 2.5 months, allowing separation of spatial from temporal effects over spatial scales ranging from 0.1 to 5 RE. The uniquely comprehensive suite of instruments, identical on the two spacecraft, measures all of the particle (electrons, ions, ion composition), fields (E and B),and wave distributions (dE and dB) that are needed to resolve the most critical science questions. Here we summarize the high level science objectives for the RBSP mission, provide historical background on studies of Earth and planetary radiation belts, present examples of the most compelling scientific mysteries of the radiation belts, present the mission design of the RBSP mission that targets these mysteries and objectives, present the observation and measurement requirements for the mission, and introduce the instrumentation that will deliver these measurements. This paper references and is followed by a number of companion papers that describe the details of the RBSP mission, spacecraft, and instruments.

magnetosphere↗

Pioneer Venus spacecraft charging model

Five environmental models were constructed to represent the solar wind and the upper, middle, and lower ionosphere of Venus. The spacecraft structure was modeled with over 140 passive electrical elements representing structural elements of the spacecraft. Electron, ion, secondary electron, and photocurrents to the spacecraft from the plasma were calculated, ignoring sheath effects. In all but one case, potentials of interest were less than 1 volt. Potential differences between widely separated points on the equipment shelf were less than 1 mV. The one area of concern is the solar panel potential when the orbiter is passing through the bowshock region.

Robinson, P. A., Jr.↗

Polar Wind in the Context of the Auroral Plasma Fountain for 2 to 8 RE

Operations of the POLAR Plasma Source Instrument have provided adequate observing time with controlled spacecraft potential to begin a 3D characterization of the polar wind as it exists in the context of the auroral plasma fountain. The principal periods of such polar wind observation to date have been 15-18 Apr. 96, 28 may 96, 14 Jun. - 6 Sep. 96, 17-29 Mar. 97, 29 May - 12 Jun. 97, 13-27 Aug. 97. Separate observations have been made near 2 RE geocentric in the south polar perigee passes and between 6-8 RE geocentric in the north polar apogee passes. Analyses of data from the Thermal Ion Dynamics Experiment during these periods are used to characterize the altitude, local time, and invariant latitude distribution of the polar wind. Data from these and other periods are used to establish the auroral plasma heating context within which the polar wind outflows exist. The available data will be used to address the temporal variability of the polar wind during the period of operations to date. Comparisons between the observations and a coupled fluid-semikinetic model are used to interpret the observed spatial structure and temporal variability.

Moore, T. E.↗

The effect of cosmic rays on thunderstorm electricity

The inflow of charges of small ions, formed by cosmic rays, into thunderstorm cells is estimated on the basis of rocket measurements of ionic concentrations below 90 km. Out of the two processes that form the thunderstorm charge (generation and separation of charges), the former is supposed to be caused by cosmic rays, and the nature of separation is assumed to be the same as in other thunderstorm theories.

Bragin, Y. A.↗

Rechargeable battery which combats shape change of the zinc anode

A rechargeable cell or battery is provided in which shape change of the zinc anode is combatted by profiling the ionic conductivity of the paths between the electrodes. The ion flow is greatest at the edges of the electrodes and least at the centers, thereby reducing migration of the zinc ions from edges to the center of the anode. A number of embodiments are disclosed in which the strength and/or amount of electrolyte, and/or the number and/or size of the paths provided by the separator between the electrodes, are varied to provide the desired ionic conductivity profile.

Cohn, E. M.↗

Pioneer Venus Sounder Probe Neutral Gas Mass Spectrometer

A neutral gas mass spectrometer was flown to Venus as part of the Pioneer Venus Multiprobe to measure the composition of its lower atmosphere. The instrument, mounted in the Sounder Probe, was activated after the probe entered the top of the atmosphere, and it obtained data during the descent from 62 km to the surface. Atmospheric gases were sampled through a pair of microleaks, the effluent from which was pumped by a combination of ion and getter pumping. A pneumatically operated valve, controlled by the ambient atmospheric pressure, maintained the ion source pressure at a nearly constant value during descent while the atmospheric pressure varied by three orders of magnitude. A single focusing magnetic sector field mass spectrometer with mass resolution sufficient to reasonably separate argon from C3H4 at 40 amu provided the mass analysis and relative abundance measurements. A microprocessor controlled the operation of the mass spectrometer through a highly efficient peak-tip stepping routine and data compression algorithm that effected a scan of the mass spectrum from 1 to 208 amu in 64 sec while requiring an information rate of only 40 bits/sec to return the data to earth. A subscale height altitude resolution was thus obtained. Weight, size, and power requirements were minimized to be consistent with interplanetary flight contraints.

Hoffman, J. H.↗

Space water electrolysis: Space Station through advance missions

Static Feed Electrolyzer (SFE) technology can satisfy the need for oxygen (O2) and Hydrogen (H2) in the Space Station Freedom and future advanced missions. The efficiency with which the SFE technology can be used to generate O2 and H2 is one of its major advantages. In fact, the SFE is baselined for the Oxygen Generation Assembly within the Space Station Freedom's Environmental Control and Life Support System (ECLSS). In the conventional SFE process an alkaline electrolyte is contained within the matrix and is sandwiched between two porous electrodes. The electrodes and matrix make up a unitized cell core. The electrolyte provides the necessary path for the transport of water and ions between the electrodes, and forms a barrier to the diffusion of O2 and H2. A hydrophobic, microporous membrane permits water vapor to diffuse from the feed water to the cell core. This membrane separates the liquid feed water from the product H2, and, therefore, avoids direct contact of the electrodes by the feed water. The feed water is also circulated through an external heat exchanger to control the temperature of the cell.

Ronald J Davenport↗

Abundance ratios of oxygen, neon, and magnesium in solar active regions and flares: The FIP effect

Relative abundances of oxygen, neon, and magnesium have been derived for a sample of nine solar active regions, flares, and an erupting prominance by combining plots of the ion differential emission measures. The observations were photographed in the 300-600 A range by the Naval Research Laboratory (NRL) spectroheliograph on Skylab. Methods for deriving the Mg/Ne abundance ratio-which measures the separation between the low- first ionization potential (FIP) and high-FIP abundnace plateaus-have been described in previous papers. In this paper we describe the spectroscopic methods for deriving the O/Ne abundance ratio, which gives the ratio between two high-FIP elements. The plot of the O/Ne ratio versus the Mg/Ne ratio in the sample of nine Skylab events is shown. The variation in the Mg/Ne ratio by a factor of 6 is associated with a much smaller range in the O/Ne ratio. This is broadly consistent with the presence of the standard FIP pattern of abundances in the outer atmosphere of the Sun. However, a real change in the relative abundances of oxygen and neon by a factor of 1.5 cannot be excluded.

Widing, K. G.↗

Two-Pulsed Technique for Ablative Laser Propulsion: Force Measurement in Vacuum

This is a continuation of studies using a two-pulsed technique for Ablative Laser Propulsion (ALP) extended to force measurements in vacuum. Aluminum samples were ablated using pairs of laser pulses, each of 100 ps width, 532 nm wavelength and 5 mJ energy. The pulses were temporally separated in the 0 - 0.67 ns range. The force imparted on Al targets was measured in situ by means of a piezoelectric force gauge. The preliminary results confirm the previously reported oscillatory behavior of ion velocity and number density observed by means of a time-of-flight energy analyzer. The uncertainties of presented measurements and future directions for the study are discussed.

Herren, Kenneth A.↗

Organic Modification of a Layered Silicate by Co-Ion Exchange of an Alkyl Ammonium and a Mono-Protonated Diamine

Co-Ion exchange of the interlayer cations of a layered silicate with a mono-protonated aromatic diamine and an alkyl ammonium ion into the silicate galleries. The presence of the alkyl ammonium ion provides low oligomer melt viscosity during processing. The presence of the diamine allows chemical reaction between the silicate surface modification and the monomers. This reaction strengthens the polymer silicate interface, and ensures irreversible separation of the individual silicate layers. Improved polymer thermal oxidative stability and mechanical properties are obtained.

Sandi G Campbell↗

Complex Chromosomal Rearrangements Induced in Vivo by Heavy Ions

It has been suggested that the ratio complex/simple exchanges can be used as a biomarker of exposure to high-LET radiation. We tested this hypothesis in vivo, by considering data from several studies that measured complex exchanges in peripheral blood from humans exposed to mixed fields of low- and high-LET radiation. In particular, we studied data from astronauts involved in long-term missions in low-Earth-orbit, and uterus cancer patients treated with accelerated carbon ions. Data from two studies of chromosomal aberrations in astronauts used blood samples obtained before and after space flight, and a third study used blood samples from patients before and after radiotherapy course. Similar methods were used in each study, where lymphocytes were stimulated to grow in vitro, and collected after incubation in either colcemid or calyculin A. Slides were painted with whole-chromosome DNA fluorescent probes (FISH), and complex and simple chromosome exchanges in the painted genome were classified separately. Complex-type exchanges were observed at low frequencies in control subjects, and in our test subjects before the treatment. No statistically significant increase in the yield of complex-type exchanges was induced by the space flight. Radiation therapy induced a high fraction of complex exchanges, but no significant differences could be detected between patients treated with accelerated carbon ions or X-rays. Complex chromosomal rearrangements do not represent a practical biomarker of radiation quality in our test subjects. Copyright 2003 S. Karger AG, Basel.

Ions/adverse effects/therapeutic use↗

Analysis of LDEF experiment AO187-2 chemical and isotopic measurements of micrometeoroids by secondary ion mass spectrometry

#Experiment AO187-2, that was flown on board the Long Duration Exposure Facility(LDEF), was designed to measure the chemical and isotopic compositions of interplanetary dust impinging on the spacecraft from outer space. Information on the nature and composition of orbital debris was also anticipated. The spacecraft maintained a constant orientation with respect to its velocity vector thereby defining leading and trailing edges that faced respectively into and away from the direction of motion. Arrays of individual capture cells each 80.8 sq cm in size and totaling 237 in number were exposed on both the leading and trailing edges of LDEF. Each cell consisted of a pure Ge target surface slightly separated from a thin (2.5 micrometers) metallized plastic 'entrance foil.' The basic concept was that incoming projectiles would penetrate the foil, strike the Ge target plate at high velocity producing a vapor-liquid cloud that would re-deposit material on the underside of the plastic foil. This material would then be analyzed using the sensitive surface analysis technique of Secondary Ion Mass Spectrometry (SIMS). In practice, most of the plastic entrance foils failed during the extended period of orbital exposure probably due to a combination of UV embrittlement, large densities of impact events and (for the leading edge) the effects of atomic oxygen erosion in orbit. However the foils failed gradually and most remained in place on the capture cells for a significant fraction of the duration of the flight . Because most of the impactors were small (less than 10 micrometers) they were heated and dispersed in traversing the entrance foils producing clouds of molten droplets and vapor that produced easily identifiable 'extended impacts' on the Ge target plates. Fortunately, it proved possible to make ion probe measurements of projectile compositions from material deposited on the Ge in the extended impact structures.

Zinner, Ernst↗

Observations of particle acceleration in solar flares

Solar flares provide several examples of nonthermal particle acceleration. The paper reviews the information gained about these processes via X-ray and gamma-ray astronomy, which can presently distinguish among three separate particle-acceleration processes at the sun: an impulsive accelerator of more than 20 keV electrons, a gradual accelerator of more than 20 keV electrons, and a gradual accelerator of more than 10 MeV ions. The acceleration energy efficiency (total particle energy divided by total flare energy) of any of these mechanisms cannot be less than about 0.1%, although the gradual acceleration does not occur in every flare. The observational material suggests that both the impulsive and gradual accelerations take place preferentially in closed magnetic-field structures, but that the electrons decay in these traps before they can escape. The ions escape very efficiently.

Hudson, H. S.↗

Ion extraction capabilities of two-grid accelerator systems

An experimental investigation into the ion extraction capabilities of two-grid accelerator systems common to electrostatic ion thrusters is described. This work resulted in a large body of experimental data which facilitates the selection of the accelerator system geometries and operating parameters necessary to maximize the extracted ion current. Results suggest that the impingement-limited perveance is not dramatically affected by reductions in screen hole diameter to 0.5 mm. Impingement-limited performance is shown to depend most strongly on grid separation distance, accelerator hole diameter ratio, the discharge-to-total accelerating voltage ratio, and the net-to-total accelerating voltage ratio. Results obtained at small grid separation ratios suggest a new grid operating condition where high beam current per hole levels are achieved at a specified net accelerating voltage. It is shown that this operating condition is realized at an optimum ratio of net-to-total accelerating voltage ratio which is typically quite high. The apparatus developed for this study is also shown to be well suited measuring the electron backstreaming and electrical breakdown characteristics of two-grid accelerator systems.

Rovang, D. C.↗

A silicone column for GC analysis of polar and nonpolar chemicals

The investigation of the Saturnian System is being proposed jointly by NASA and the European Space Agency (ESA). The mission is scheduled for a launch in 1996. The mission provides an opportunity for close observation and exploration of Saturn's atmosphere, the complex Saturnian System of satellites and rings, Titan (Saturn's planet-sized moon), and Saturn's magnetosphere. The mission gives special attention to Titan which is blanketed by a thick, opaque atmosphere. An atmospheric probe will be deposited into the Titan Atmosphere for in situ measurement during a slow, three hour descent to the surface. The results from this analysis may provide the information which is important to the research of chemical evolution, and the origin of life. An analytical system was developed as a part of the Titan Aerosol Gas Experiment (TAGEX), a proposed experiment for the Cassini Mission. This system will use two highly sensitive detectors, the Metastable Ionization Detector (MID) and the Ion Mobility Spectrometer (IMS). Unfortunately, when commercial columns are utilized with these highly sensitive detectors, volatile components continuously bleed from the column and interfere with the detector. In addition, light columns must be able to separate polar and nonpolar organic chemicals within 10-15 minutes under isothermal conditions for the Titan Mission. Therefore, a highly crosslinked silicone polymeric packed column was developed which is able to efficiently separate amines, alcohols, and hydrocarbons with retention times less that 15 minutes at 100 C isothermal condition.

Shen, T. C.↗

Characterization of GTP binding and hydrolysis in plasma membranes of zucchini

We have investigated the possibility that G-protein-like entities may be present in the plasma membrane (PM) of zucchini (Cucurbita pepo L.) hypocotyls by examining a number of criteria common to animal and yeast G-proteins. The GTP binding and hydrolysis characteristics of purified zucchini PM are similar to the characteristics of a number of known G-proteins. Our results demonstrate GTP binding to a single PM site having a Kd value between 16-31 nM. This binding has a high specificity for guanine nucleotides, and is stimulated by Mg2+, detergents, and fluoride or aluminium ions. The GTPase activity (Km = 0.49 micromole) of zucchini PM shows a sensitivity to NaF similar to that seen for other G-proteins. Localization of GTP mu 35S binding to nitrocellulose blots of proteins separated by SDS-PAGE indicates a 30-kDa protein as the predominant GTP-binding species in zucchini PM. Taken together, these data indicate that plant PM contains proteins which are biochemically similar to previously characterized G-proteins.

NASA Discipline Plant Biology↗