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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 559 records · Page 31
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Electron-ion relaxation in a dense plasma

The microscopic physics of the thermonuclear runaway in highly degenerate carbon-oxygen cores is investigated to determine if and how a detonation wave is generated. An expression for the electron-ion relaxation time is derived under the assumption of large degeneracy and extreme relativity of the electrons in a two-temperature plasma. Since the nuclear burning time proves to be several orders of magnitude shorter than the relaxation time, it is concluded that in studying the structure of the detonation wave the electrons and ions must be treated as separate fluids.

Littleton, J. E.↗
NASA NTRS1976

Double-focusing mass spectrometer

Device uses lighter, easily alined, magnet assembly to provide field required to interact with ion beam. It has no separate duct; instead, evacuated duct is formed by pole pieces which support vacuum pump. Magnetic gap and magnet assembly are reduced from 4.64 to 2.54 mm and from 2.4 to 1.5 kg, respectively.

Giffin, C. E.↗
NASA NTRS1979

Redox flow cell energy storage systems

NASA-Redox systems are electrochemical storage devices that use two fully soluble Redox couples, anode and cathode fluids, as active electrode materials separated by a highly selective ion exchange membrane. The reactants are contained in large storage tanks and pumped through a stack of Redox flow cells where the electrochemical reactions (reduction and oxidation) take place at porous carbon felt electrodes. A string or stack of these power producing cells is connected in series in a bipolar manner. Redox energy storage systems promise to be inexpensive and possess many features that provide for flexible design, long life, high reliability and minimal operation and maintenance costs. These features include independent sizing of power and storage capacity requirements and inclusion within the cell stack of a cell that monitors the state of charge of the system as a whole, and a rebalance cell which permits continuous correction to be made for minor side reactions that would tend to result in the anode fluid and cathode fluids becoming electrochemically out of balance. These system features are described and discussed.

Thaller, L. H.↗
NASA NTRS1979

Redox flow cell energy storage systems

The redox flow cell energy storage system being developed by NASA for use in remote power systems and distributed storage installations for electric utilities is presented. The system under consideration is an electrochemical storage device which utilizes the oxidation and reduction of two fully soluble redox couples (acidified chloride solutions of chromium and iron) as active electrode materials separated by a highly selective ion exchange membrane. The reactants are contained in large storage tanks and pumped through a stack of redox flow cells where the electrochemical reactions take place at porous carbon felt electrodes. Redox equipment has allowed the incorporation of state of charge readout, stack voltage control and system capacity maintenance (rebalance) devices to regulate cells in a stack jointly. A 200 W, 12 V system with a capacity of about 400 Wh has been constructed, and a 2 kW, 10kWh system is planned.

Thaller, L. H.↗
NASA NTRS1980

Hybrid polymer microspheres

Techniques have been successfully tested for bonding polymeric spheres, typically 0.1 micron in diameter, to spheres with diameter up to 100 microns. Hybrids are being developed as improved packing material for ion-exchange columns, filters, and separators.

Rembaum, A.↗
NASA NTRS1980

Physicochemical and dynamical processes in cometary ionospheres. I - The basic flow profile

The paper deals with the basic aspects of solar wind interaction with the ionosphere of a large comet and with detailed hydrodynamic models developed to describe the flow exterior to the tangential discontinuity surface that separates the outflowing purely cometary ions from the inflowing contaminated solar wind. The equation of the basic flow model and the results of a preliminary analysis of these equations are given, and the shape and structure of the shock layer are analyzed. The shock layer structure associated with fan-shaped comet emanating from the cometary nucleus in the general direction to the sun is identified.

Houpis, H. L. F.↗
NASA NTRS1984

Plasma in Saturn's magnetosphere

The spatial and compositional distribution of the thermal plasma in the magnetosphere of Saturn is described in the light of the Voyager encounters. Theoretical considerations are applied to the elucidation of the structure, including two external and two internal boundaries. The outer boundary is a magnetohydrodynamic entity, while the inner boundary of locally created thermal plasma is a result of the dissociative recombination of corotating molecular ions. The internal boundaries, which separate plasmas of different composition, are explained as a charge exchange quasi-resonance phenomenon.

Eviatar, A.↗
NASA NTRS1987

Effects on H(-) production in a multicusp ion source by mixture of H2 with H2O, NH3, CH4, N2H4, and SF6

Effects of H(-) production in a multicusp ion source are measured by separately mixing with hydrogen small amounts (0.33-10 percent) of water, ammonia, methane, and hydrazine these are molecules which produce large amounts of H(-) via dissociative attachment (DA) resonances at higher electron energies. The mixing was done in a separate reservoir, with careful measurement of individual pressures. Experimental enhancements of 1.4 and less were observed, whereas calculated enhancements, using accurate DA cross sections for ground-state H2, should have produced factors of 1.5, 3.0, 1.3, and 2.4 enhancements for water, ammonia methane, and hydrazine, respectively, at a mean electron energy of 1.0 eV in the extraction region. The difference is accounted for by including, in the enhancement calculation, vibrationally and rotationally excited H2 molecules, with v-double prime = 5-11, and J-double prime = 0-5, and the large DA cross sections for the excited H2 (v-double prime, J-double prime). The relative populations of H2 (v-double prime, J-double prime) thus obtained are found to be substantially smaller than those predicted by theoretical calculations. The effect on H(-) current was also studied by mixing small amounts of SF6 with H2. A 1.5 percent mixture was found to reduce the H(-) output by one half.

Orient, O. J.↗
NASA NTRS1999

FAST Observations of Lower Hybrid Waves in the Cusp Regions

The Fast Auroral Snapshot (FAST) spacecraft has encountered the Earth's cusp regions on numerous occasions during its first few years of operations. Intense plasma waves are consistent features of these cusp encounters which are characterized by localized keV dispersed ion "Injections". Emissions observed near the lower hybrid frequency are frequently, though not always, observed in conjunction with the precipitating cusp ions. The waves are clearly electrostatic and often exhibit a bifuncation in frequency about the lower hybrid frequency. In some cases, numerous ion Bernstein waves are present, separated in frequency at harmonics near the local proton cyclotron frequency. An analysis of the measurements of the electric field components of the plasma waves gathered with FAST's spaced receivers (or interferometers) reveals their short wavelength characteristics. We examine several examples of such waves in detail in order to understand their growth mechanisms and to relate them with the cusp energetic particle populations.

Pfaff, R. F.↗
NASA NTRS2005

Rod-Coil Block Polyimide Copolymers

This invention is a series of rod-coil block polyimide copolymers that are easy to fabricate into mechanically resilient films with acceptable ionic or protonic conductivity at a variety of temperatures. The copolymers consist of short-rigid polyimide rod segments alternating with polyether coil segments. The rods and coil segments can be linear, branched or mixtures of linear and branched segments. The highly incompatible rods and coil segments phase separate, providing nanoscale channels for ion conduction. The polyimide segments provide dimensional and mechanical stability and can be functionalized in a number of ways to provide specialized functions for a given application. These rod-coil black polyimide copolymers are particularly useful in the preparation of ion conductive membranes for use in the manufacture of fuel cells and lithium based polymer batteries.

Mary Ann B Meador↗
NASA NTRS2007

Observations of a Newly "Captured" Magnetosheath Field Line: Evidence for "Double Reconnection"

We have begun an investigation of the nature of the low-latitude boundary layer in the mid-altitude cusp region using data from the Polar spacecraft. This region has been routinely sampled for about three months each year for the periods 1999-2001 and 2004-2006. The low-to-mid-energy ion instruments frequently observed dense, magnetosheath-like plasma deep (in terms of distance from the magnetopause and in invariant latitude) in the magnetosphere. One such case, taken during a period of northward interplanetary magnetic field (IMF), shows magnetosheath ions within the magnetosphere with velocity distributions resulting from two separate merging sites along the same field lines. Cold ionospheric ions were also observed counterstreaming along the field lines, evidence that these field lines were closed. These results are consistent with the hypothesis that double merging can produce closed field .lines populated by solar wind plasma. Through the use of individual cases such as this and statistical studies of a broader database we seek to understand the morphology of the LLBL as it projects from the sub-solar region into the cusp. We will present preliminary results of our ongoing study.

Chandler, Michael O.↗
NASA NTRS2007

Recent Plasma Observations Related to Dayside Magnetic Merging and the Low-latitude Boundary Layer

We have begun an investigation of the nature of the low-latitude boundary layer in the mid-altitude cusp region using data from the Polar spacecraft. This region has been routinely sampled for about three months each year for the periods 1999-2001 and 2004-2006. The low-to-mid-energy ion instruments frequently observed dense, magnetosheath-like plasma deep (in terms of distance from the magnetopause and in invariant latitude) in the magnetosphere. One such case, taken during a period of northward interplanetary magnetic field (IMF), shows magnetosheath ions within the magnetosphere with velocity distributions resulting from two separate merging sites along the same field lines. Cold ionospheric ions were also observed counterstreaming along the field lines, evidence that these field lines were closed. These results are consistent with the hypothesis that double merging can produce closed field lines populated by solar wind plasma. Through the use of individual cases such as this and statistical studies of a broader database we seek to understand the morphology of the LLBL as it projects from the sub-solar region into the cusp. We will present preliminary results of our ongoing study.

Chandler, Michael O.↗
NASA NTRS2007

Recent Plasma Observations Related to Magnetic Merging and the Low-Latitude Boundary Layer. Case Study by Polar, March 18, 2006

We have begun an investigation of the nature of the low-latitude boundary layer in the mid-altitude cusp region using data from the Polar spacecraft. Magnetosheath-like plasma is frequently observed deep (in terms of distance from the magnetopause and in invariant latitude) in the magnetosphere. One such case, taken during a long period of northward interplanetary magnetic field (IMP) on March 18, 2006, shows injected magnetosheath ions within the magnetosphere with velocity distributions resulting from two separate merging sites along the same field lines. Cold ionospheric ions were also observed counterstreaming along the field lines, evidence that these field lines were closed. Our results support the idea of double reconnection under northward IMP on the same group of field lines can provide a source for the LLBL. However, the flow direction of the accelerated magnetosheath ions antiparallel to the local magnetic field and given location of the spacecraft suggest that these two injection sites are located northward of the spacecraft position. Observed convection velocities of the magnetic field lines are inconsistent with those expected for double post-cusp reconnection in both hemispheres. These observations favor a scenario in which a group of newly closed field lines was created by a combination of high shear merging at high latitudes in the northern hemisphere and low shear merging at lower latitudes at the dayside magnetopause.

Chandler, M.↗
DOE OSTI2020

Sodium-halogen secondary cell

An intermediate temperature sodium-halogen secondary cell that includes a negative electrode compartment housing a negative, molten sodium-based electrode and a positive electrode compartment housing a current collector disposed in a highly conductive molten positive electrolyte. A sodium halide (NaX) positive electrode is disposed in a molten positive electrolyte comprising one or more AlX3 salts, wherein X may be the same or different halogen selected from Cl, Br, and I, wherein the ratio of NaX to AlX3 is greater than or equal to one. A sodium ion conductive solid electrolyte membrane separates the molten sodium negative electrode from the molten positive electrolyte. The secondary cell operates at a temperature in the range from about 80° C. to 210° C.

Bhavaraju, Sai↗
DOE OSTI2021

Molten fluid electrode apparatus

A battery includes negative electrode material and positive electrode material where the materials are in a solid phase except for selected portions that are heated to transform the selected portions into a fluid. The fluid portion of negative electrode material is directed to a negative electrode region of a reaction chamber and the fluid portion of positive electrode material is directed to a positive electrode region of the reaction chamber where a solid electrolyte containing ions of the negative electrode separates the positive electrode region from the negative electrode region.

Vissers, Daniel R.↗
DOE OSTI2023

Electrospinning of PVdF-HFP: novel composite polymer electrolytes (CPES) with enhanced ionic conductivities for lithium-sulfur batteries

The invention relates to lithium ion batteries and, more particularly, to lithium ion conducting composite polymer electrolyte separators. The separators include a nanofiber mat composed of electrospun nanofibers. The nanofibers include a polymer having one or more polar halogen groups, a lithium-containing solid or liquid electrolyte and nanoparticle filler. The polymer, electrolyte and filler are combined to form a solution that is subjected to the electro-spinning process to produce electrospun nanofibers in the form of the mat.

Kumta, Prashant N.↗
DOE OSTI2020

Stabilization of Photocatalytically Active Uranyl Species in a Uranyl–Organic Framework for Heterogeneous Alkane Fluorination Driven by Visible Light

When photoactivated, the uranyl ion is a robust oxidant capable of abstracting hydrogen atoms from nonactivated C–H bonds. Yet, the highly reactive singly reduced [U V O 2 ] + intermediate is unstable with respect to disproportionation to the uranyl dication and insoluble tetravalent uranium phases, which limits the usage of uranyl ions as robust photocatalysts. Herein, we demonstrate that photoactivated uranyl ions can be stabilized by immobilizing and separating them spatially in a uranyl–organic framework heterogeneous catalyst, NU-1301. The visible-light-photoactivated uranyl ions in NU-1301 demonstrated longer-lived U(V) and radicals than those in homogeneous counterparts, as evidenced by X-ray photoelectron spectroscopy and time-dependent electron paramagnetic resonance, leading to higher turnovers and enhanced stability for the fluorination of nonactivated alkanes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗