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NASA NTRS1987

Middle atmospheric electrodynamic modification by particle precipitation at the South Atlantic magnetic anomaly

Evidence for a localized middle atmospheric electrodynamic modification at low latitudes (southern Brazilian coast) of the South Atlantic Magnetic Anomaly (SAMA), in association with enhanced geomagnetic activity, are presented in a unified way combining recent observational efforts and related numerical studies. They involve a distortion effect in the fair weather electric field at balloon altitudes. This effect is attributed to a local intensification of energetic electron precipitation through a related middle atmospheric ionization enhancement and is elucidated by numeric simulation. From the electric field measurements and the numeric simulation, the intensification of precipitation is considered to occur in fairly narrow regions at the observed low L values (around L = 1.13) of the SAMA, with horizontal extensions of the order of a few hundred kilometers. A physical mechanism that could be responsible for this sort of intensification is suggested. Furthermore, a comparison of the phenomenon of middle atmospheric electrodynamic modification at the SAMA with a similar one at auroral latitudes, in response to enhanced solar and geomagnetic activity, is also given.

Gonzalez, W. D.↗

NASA NTRS2001

The Ionization and Metallicity of the Intervening O VI Absorber at z=0.1212 in the Spectrum of H1821+643

We use high-resolution UV (ultraviolet) spectra of the radio-quiet QSO (quasi-stellar object) H1821+643 (z(sub em) = 0.297), obtained with the Space Telescope Imaging Spectrograph (STIS) and the Far Ultraviolet Spectroscopic Explorer (FUSE), to study the ionization and metallicity of an intervening O VI absorption line system at z(sub abs) = 0.1212. This absorber has the following notable properties: (1) Several galaxies are close to the sight line at the absorber redshift, including an actively star-forming galaxy at a projected distance of 144 h(sub 75)(exp -1) kpc. (2) There is a complex cluster of H I Ly(alpha) absorption lines near the O VI redshift, including at least five components spread over a velocity range of approximately 700 km s(exp -1). (3) The strongest Ly(alpha) line in the cluster appears to be composed of a mildly saturated component with a typical b-value blended with a remarkably broad component with b approximately equals 85 km s(exp -1). (4) The O VI absorption is not aligned with the strongest (saturated) H I absorption, but instead is well-aligned with the very broad component. (5) The only detected species (at the 4(sigma) level) are O VI and H I despite coverage of strong transitions of abundant elements (e.g., C II, C III, and C IV). Based on these constraints, we find that the absorption line properties can be produced in collisionally ionized gas with 10(exp 5.3) is equal to or less than T is equal to or less than 10(exp 5.6) K and -1.8 is equal to or less than [O/H] is equal to or less than -0.6. However, we find that photoionization is also viable if the pathlength l through the absorbing gas is long enough; simple photoionization models require 85 is equal to or less than l is equal to or less than 1900 kpc and -1.1 is equal to or less than [O/H] is equal to or less than -0.3. We briefly discuss how observations of X-ray absorption lines due to O VII and O VIII could be used, in principle, to break the ionization mechanism degeneracy, and we conclude with some comments regarding the nature of O VI absorbers.

Tripp, Todd M.↗

DOE OSTI2022

Hydrolysis of Acetamide on Low-Index CeO 2 Surfaces: Ceria as a Deamidation and General De-esterification Catalyst

Using DFT calculations and acetamide as the main example, we show that ceria is a potential catalyst for the hydrolysis of amide and similar bonds. The overall reaction is endergonic in the gas phase, yielding acetic acid and ammonia, but is slightly exergonic in the aqueous phase, which facilitates ionization of the products (CH 3 COO – and NH 4 + ). Neighboring Ce and O sites on the CeO 2 (111), (110), and (100) facets are conducive to the formation of an activated metastable tetrahedral intermediate (TI) complex, followed by C–N bond scission. With van der Waals and solvation effects taken into account, the overall reaction energetics is found to be most favorable on the (111) facet as desorption of acetic acid is much more uphill energetically on (110) and (100). We further suggest that the Ce–O–Ce sites on ceria surfaces can activate X(=Y)–Z type bonds in amides, amidines, and carboxylate and phosphate esters, among many others that we term “generalized esters”. A Brønsted-Evans–Polanyi relationship is identified correlating the stability of the transition and final states of the X–Z generalized ester bond scission. A simple descriptor (ΣΔχ) based on the electronegativity of the atoms that constitute the bond (X, Y, Z) versus those of the catalytic site (O, Ce, Ce) captures the trend in the stability of the transition state of generalized ester bond scission and suggests a direction for modifying ceria for targeting specific organic substrates.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2025

Commissioning of Extended Electron Beam Ion Source at Brookhaven National Laboratory

Here, the Extended Electron Beam Ion Source (EEBIS) has been installed and commissioned at Brookhaven National Laboratory (BNL) hadron accelerator complex in the spring of 2023. EEBIS has replaced its predecessor, RhicEBIS, which provided ions for BNL hadron facilities for over a decade since 2009. The motivations for the source upgrade are to provide higher intensities of the Au 32+ ion beam for the Relativistic Heavy Ion Collider (RHIC) and to provide of an intense source of polarized 3 He 2+ ions for the future Electron Ion Collider (EIC) at BNL. EEBIS is and will continue to be the primary source for a variety of different ion species for the NASA Space Radiation Laboratory (NSRL) at BNL. EEBIS utilizes two identical, two-meter-long unshielded 5T warm bore superconducting solenoids, and it is operated with electron beam current up to 10 A, providing a high-capacity ion traps to fulfill the requirement for high intensity ion beams. The upstream solenoid contains a “short ion trap” with a length of 95 cm, while the “long ion trap” with a length of 178 cm is located inside the downstream solenoid bore. The main features of EEBIS are: * A Gas injection and ionization cell equipped with a Lorenz pulse valve * High-capacity ZAO non-evaporable getter (NEG) custom linear pumping units * In situ apparatus for pumping speed measurements to monitor NEG activation and saturation * “External drift tube” construction with differential pumping stages to provide space for Lorentz pulse valve and 3 He high-field polarization cell * A Ba oxide electron gun cathode. The design of EEBIS as well as the results of its commissioning and first-year operation are presented and discussed.

43 PARTICLE ACCELERATORS↗

NASA NTRS1976

Ames collaborative study of cosmic ray neutrons

The results of a collaborative study to define both the neutron flux and the spectrum more precisely and to develop a dosimetry package that can be flown quickly to altitude for solar flare events are described. Instrumentation and analysis techniques were used which were developed to measure accelerator-produced radiation. The instruments were flown in the Ames Research Center high altitude aircraft. Neutron instrumentation consisted of Bonner spheres with both active and passive detector elements, threshold detectors of both prompt-counter and activation-element types, a liquid scintillation spectrometer based on pulse-shape discrimination, and a moderated BF3 counter neutron monitor. In addition, charged particles were measured with a Reuter-Stokes ionization chamber system and dose equivalent with another instrument. Preliminary results from the first series of flights at 12.5 km (41,000 ft) are presented, including estimates of total neutron flux intensity and spectral shape and of the variation of intensity with altitude and geomagnetic latitude.

Hewitt, J. E.↗

NASA NTRS1979

Evidence for continuum absorption above the quiet sun transition region

Evidence for continuum absorption in the solar transition zone in EUV spectra obtained from OSO 4, OSO 6, ATM, and full-sun measurements is reported. This absorption shortward of 912 A is manifested everywhere on the sun's disk. It is present within network cells and boundaries of the quiet sun, in coronal holes, in active regions, above the limb, and in solar prominences. Models of the upper chromosphere and the transition zone must be modified to include an admixture of neutral hydrogen (or possibly single ionized helium) with the hotter plasma.

Schmahl, E. J.↗

NASA NTRSDate not supplied

Improving Data Analyses for a Biological Mission to Deep Interplanetary Space

Onboard the Artemis 1 rocket, NASA plans to launch the first deep space bioscience mission past low Earth orbit (LEO) since 1972, BioSentinel, a 6-Unit (6U) biological CubeSat. BioSentinel’s goals are to assess the effect of deep space ionizing radiation (IR) on DNA and cell damage response, using Saccharomyces cerevisiae, or budding yeast, as a model organism. BioSentinel accomplishes this by measuring Optical Density (OD) in addition to metabolic activity using the redox dye alamarBlue, both of which will be read through light emitting diode (LED) lights of differing wavelengths. With the largest and most sophisticated energy-providing solar panels utilized on a biological CubeSat to date, BioSentinel will be equipped with an IR dosimeter to identify what doses of radiation the yeast is exposed to at any point in time, in addition to a transponder to send such data back to NASA Ames’ Multi Mission Operations Center (MMOC). Biology computational programs and data processing scripts are necessary to analyze this complex data once it is received, including automated subroutines to analyze duplication rate, alamarBlue reduction, and time periods when paired against numerous other variables. Overall, we have implemented several VisualBasic biocomputational programs to analyze such data in an organized and efficient manner so that conclusions can be made rapidly. Furthermore, we showcase why efficient analysis of particular parameters is important to better understand the risks that deep space IR poses to astronauts, especially when considering the upcoming Artemis missions.

Bijan Harandi↗

NASA NTRSDate not supplied

Pinned in Microgravity: How Colloidal Suspensions Inhibit Droplet Motion

Understanding the fundamental behavior of colloidal fluids in microgravity is critical for advancing material science, manufacturing, and biological processes. In this study we investigate the dynamics of a droplet containing colloidal suspension when ejected in short term microgravity. These conditions are generated using a 2.2 second drop tower. A custom droplet generator was designed to produce consistent size-controlled droplets containing passive colloidal particles. The particles are suspended in water and subsequently ejected out of a hydrophobic wedge under microgravity conditions, where the droplet ejection time can be predicted [Torres & Weislogel, 2021]. The ejection times will be compared with de-ionized water ejected from the same system to investigate the effects of change in density and surface tension caused by the colloids. Successful passive colloidal ejection will lay the foundation for active colloid research in the future.

colloids↗

NASA NTRS1999

ASCA Observations of "Type 2" LINERs Evidence for a Stellar Source of Ionization

We present ASCA observations of LINERs without broad H.alpha emission in their optical spectra. The sample of "type 2" LINERs consists of NGC 404, 4111, 4192, 4457, and 4569. We have detected X-ray emission from all the objects except for NGC 404; among the detected objects are two so-called transition objects (NGC 4192 and NGC 4569), which have been postulated to be composite nuclei having both an H II region and a LINER component. The images of NGC 4111 and NGC 4569 in the soft (0.5-2 keV) and hard (2-7 keV) X-ray bands are extended on scales of several kpc. The X-ray spectra of NGC 4111, NGC 4457 and NGC 4569 are well fitted by a two-component model that consists of soft thermal emission with kT approximately 0.65 keV and a hard component represented by a power law (photon index approximately 2) or by thermal bremsstrahlung emission (kT approximately several keV). The extended hard X-rays probably come from discrete sources, while the soft emission most likely originates from hot gas produced by active star formation in the host galaxy. We have found no clear evidence for the presence of active galactic nuclei (AGNs) in the sample. Using black hole masses estimated from host galaxy bulge luminosities, we obtain an upper limit on the implied Eddington ratios less than 5 x 10(exp -5). If an AGN component is the primary ionization source of the optical emission lines, then it must be heavily obscured with a column density significantly larger than 10(exp 23)/sq cm, since the observed X-ray luminosity is insufficient to drive the luminosities of the optical emission lines. Alternatively, the optical emission could be ionized by a population of exceptionally hot stars. This interpretation is consistent with the small [O I] lambda6300/H.alpha ratios observed in these sources, the ultraviolet spectral characteristics in the cases where such information exists, and the X-ray results reported here. We also analyze the X-ray properties of NGC 4117, a low-luminosity Seyfert 2 galaxy serendipitously observed in the field of NGC 4111.

Terashima, Yuichi↗

DOE OSTI2022

Impact of hydronium ions on the Pd-catalyzed furfural hydrogenation

Abstract In aqueous mediums, the chemical environment for catalytic reactions is not only comprised of water molecules but also of corresponding ionized species, i.e., hydronium ions, which can impact the mechanism and kinetics of a reaction. Here we show that in aqueous-phase hydrogenation of furfural on Pd/C, increasing the hydronium ion activities by five orders of magnitude (from pH 7 to pH 1.6) leads to an increase of less than one order of magnitude in the reaction rate. Instead of a proton-coupled electron transfer pathway, our results show that a Langmuir-Hinshelwood mechanism describes the rate-limiting hydrogen addition step, where hydrogen atom adsorbed on Pd is transferred to the carbonyl C atom of the reactant. As such, the strength of hydrogen binding on Pd, which decreases with increasing hydronium ion concentration (i.e., 2 kJ mol H2 −1 per unit pH), is a decisive factor in hydrogenation kinetics (rate constant +270%). In comparison, furfural adsorption on Pd is pH-independent, maintaining a tilted geometry that favors hydrogen attack at the carbonyl group over the furan ring.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2023

Migration of Ga vacancies and interstitials in β – Ga 2 O 3

Pathways and energy barriers for the migration of Ga vacancies (V Ga ) and Ga interstitials (Ga i ) in β–Ga 2 O 3 are explored using hybrid functional calculations and the nudged elastic band method. Considering β–Ga 2 O 3 as primarily being an n-type semiconductor, we focus on defect charge states relevant under such conditions: $V^{3 –}_{Ga}$, Ga$^{3+}_{i}$, and Ga$^{+}_{i}$. Notably, we describe a mechanism by which V Ga can transform between its different split configurations. In all cases, the intermediate state consists of a vacancy split between three Ga sites—a three-split vacancy—which enables passage over a significantly lower energy barrier. This is because it avoids the unfavorable simple vacancy at the tetrahedral Ga site. The proposed mechanism lowers the overall barrier for $V^{3–}_{Ga}$ diffusion along the [001] crystal direction from 1.73 to 0.97 eV, whereas the 2.08 eV barrier for the [100] and [010] directions is unaffected. For Ga$^{3+}_{i}$, we obtain similar overall migration barriers of 0.72, 0.80, and 1.02 eV for the [010], [001], and [100] directions, respectively. Ga$^{+}_{i}$ exhibits a strong preference for diffusion within the large eight-sided channel; the overall migration barrier is 0.92 eV for the [010] direction, and 2.16 eV for the [001] and [100] directions. The limiting step for the two latter directions involves ionization of Ga$^{+}_{i}$ followed by a jump to an adjacent large eight-sided channel as Ga$^{3+}_{i}$. Finally, our results are discussed in light of experimental observations of thermally activated recovery processes in irradiated material.

36 MATERIALS SCIENCE↗

NASA NTRS1983

Ionized cluster beam deposition

Ionized Cluster Beam (ICB) deposition, a new technique originated by Takagi of Kyoto University in Japan, offers a number of unique capabilities for thin film metallization as well as for deposition of active semiconductor materials. ICB allows average energy per deposited atom to be controlled and involves impact kinetics which result in high diffusion energies of atoms on the growth surface. To a greater degree than in other techniques, ICB involves quantitative process parameters which can be utilized to strongly control the characteristics of films being deposited. In the ICB deposition process, material to be deposited is vaporized into a vacuum chamber from a confinement crucible at high temperature. Crucible nozzle configuration and operating temperature are such that emerging vapor undergoes supercondensation following adiabatic expansion through the nozzle.

Kirkpatrick, A. R.↗

NASA NTRS1985

Observation of soft X-ray spectra from a Seyfert 1 and a narrow emission-line galaxy

The 0.2-40 keV X-ray spectra of the Seyfert 1 galaxy Mrk 509 and the narrow emission-line galaxy NGC 2992 are analyzed. The results suggest the presence of a steep soft X-ray component in Mrk 509 in addition to the well-known Gamma = 1.7 component found in other active galactic nuclei in the 2-40 keV energy range. The soft X-ray component is interpreted as due to thermal emission from a hot gas, probably associated with the highly ionized gas observed to be outflowing from the galaxy. The X-ray spectrum of NGC 2992 does not show any steepening in the soft X-ray band and is consistent with a single power law (Gamma = 1.78) with very low absorbing column density of 4 x 10 to the 21st/sq cm. A model with partial covering of the nuclear X-ray source is preferred, however, to a simple model with a single power law and absorption.

Singh, K. P.↗

NASA NTRS1988

Critical velocity experiments in space

Published data from active space experiments designed to demonstrate the Alfven critical-velocity effect are compiled in graphs and compared with the predictions of numerical simulations. It is found that the discrepancies in the ionization yields obtained in shaped-charge releases of alkali metals are related to the macroscopic limits of time and energy in such releases. It is argued that the total ionization yield is an inadequate measure of the critical-velocity effect, and a new criterion based on eta, the efficiency of energy transfer from the recently ionized neutrals to a heated electron population, is proposed: the effect would be verified if eta values of 10 percent or greater were observed.

Torbert, R. B.↗

NASA NTRS1991

Origins of the 12-200 micron flux in NGC 6946 - Starlight and continuum dust emission from AN Sc galaxy

Infrared maps and optical CCD images of NGC 6946, a nearly face-on spiral with evidence of active star formation, are presented. Consideration is given, at 1-3 kpc spatial scales, to the relationship of the infrared continuum to spiral and radial structure, tracers of the interstellar medium, and ionizing and nonionizing sources of stellar radiation. Two infrared components were revealed - one with surface brightnesses of 20-60 Jy per 45 arcsec aperture at 160 microns, and the other with a surface brightness of less than 20 Jy. Various continuum distributions show discrete sources coinciding with giant H II regions superposed on a smooth unresolved disk background which decreases exponentially with the radius. The optical and spectral properties of the nuclear source and the disk are described. Dust properties and heating conditions, and far-infrared emitting phases are discussed.

Engargiola, G.↗

NASA NTRS1995

Predictions of LDEF radioactivity and comparison with measurements

As part of the program to utilize LDEF data for evaluation and improvement of current ionizing radiation environmental models and related predictive methods for future LEO missions, calculations have been carried out to compare with the induced radioactivity measured in metal samples placed on LDEF. The predicted activation is about a factor of two lower than observed, which is attributed to deficiencies in the AP8 trapped proton model. It is shown that this finding based on activation sample data is consistent with comparisons made with other LDEF activation and dose data. Plans for confirming these results utilizing additional LDEF data sets, and plans for model modifications to improve the agreement with LDEF data, are discussed.

Armstrong, T. W.↗

NASA NTRS2002

Detection of High Energy Cosmic Rays with Advanced Thin Ionization Calorimeter, ATIC

The author presents preliminary results of the first flight of the Advanced Thin Ionization Calorimeter (ATIC). ATIC is a multiple, long duration balloon flight, investigation for the study of cosmic ray spectra from below 50 GeV to near 100 TeV total energy, using a fully active Bismuth Germanate (BGO) calorimeter. It is equipped with the first large area mosaic of small fully depleted silicon detector pads capable of charge identification of cosmic rays from H to Fe. As a redundancy check for the charge identification and a coarse particle tracking system, three projective layers of x-y scintillator hodoscopes were employed, above, in the center and below a Carbon interaction 'target'.

Adams, J. H.↗

NASA NTRS2012

Inverse Compton X-Ray Halos Around High-z Radio Galaxies: A Feedback Mechanism Powered by Far-Infrared Starbursts or the Cosmic Microwave Background?

We report the detection of extended X-ray emission around two powerful radio galaxies at z approx. 3.6 (4C 03.24 and 4C 19.71) and use these to investigate the origin of extended, inverse Compton (IC) powered X-ray halos at high redshifts. The halos have X-ray luminosities of L(sub X) approx. 3 x 10(exp 44) erg/s and sizes of approx.60 kpc. Their morphologies are broadly similar to the approx.60 kpc long radio lobes around these galaxies suggesting they are formed from IC scattering by relativistic electrons in the radio lobes, of either cosmic microwave background (CMB) photons or far-infrared photons from the dust-obscured starbursts in these galaxies. These observations double the number of z > 3 radio galaxies with X-ray-detected IC halos. We compare the IC X-ray-to-radio luminosity ratios for the two new detections to the two previously detected z approx. 3.8 radio galaxies. Given the similar redshifts, we would expect comparable X-ray IC luminosities if millimeter photons from the CMB are the dominant seed field for the IC emission (assuming all four galaxies have similar ages and jet powers). Instead we see that the two z approx. 3.6 radio galaxies, which are 4 fainter in the far-infrared than those at z 3.8, also have approx.4x fainter X-ray IC emission. Including data for a further six z > or approx. 2 radio sources with detected IC X-ray halos from the literature, we suggest that in the more compact, majority of radio sources, those with lobe sizes < or approx.100-200 kpc, the bulk of the IC emission may be driven by scattering of locally produced far-infrared photons from luminous, dust-obscured starbursts within these galaxies, rather than millimeter photons from the CMB. The resulting X-ray emission appears sufficient to ionize the gas on approx.100-200 kpc scales around these systems and thus helps form the extended, kinematically quiescent Ly(alpha) emission line halos found around some of these systems. The starburst and active galactic nucleus activity in these galaxies are thus combining to produce an even more effective and widespread "feedback" process, acting on the long-term gas reservoir for the galaxy, than either individually could achieve. If episodic radio activity and co-eval starbursts are common in massive, high-redshift galaxies, then this IC-feedback mechanism may play a role in affecting the star formation histories of the most massive galaxies at the present day.

Small, Ian↗