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At least 559 records · Page 31

Advances in Spectro‐Microscopy Methods and their Applications in the Characterization of Perovskite Materials

Perovskite materials are promising contenders as the active layer in light-harvesting and light-emitting applications if their long-term stability can be sufficiently increased. Chemical and structural engineering are shown to enhance long-term stability, but the increased complexity of the material system also leads to inhomogeneous functional properties across various length scales. Thus, scanning probe and high-resolution microscopy characterization techniques are needed to reveal the role of local defects and the results promise to act as the foundation for future device improvements. Here, a look at the parameter space: technique-specific sample penetration depth versus probe size highlights a gap in current methods. High spatial resolution combined with a deep penetration depth is not yet achievable. However, multimodal measurement technique may be the key to covering this parameter space. In this perspective, current advanced spectro-microscopy methods which have been applied to perovskite materials are highlighted.

Luo, Yanqi↗

Research relative to high resolution camera on the advanced X-ray astrophysics facility

The HRC (High Resolution Camera) is a photon counting instrument to be flown on the Advanced X-Ray Astrophysics Facility (AXAF). It is a large field of view, high angular resolution, detector for the x-ray telescope. The HRC consists of a CsI coated microchannel plate (MCP) acting as a soft x-ray photocathode, followed by a second MCP for high electronic gain. The MCPs are readout by a crossed grid of resistively coupled wires to provide high spatial resolution along with timing and pulse height data. The instrument will be used in two modes, as a direct imaging detector with a limiting sensitivity of 10 to the -15 ergs sq cm sec in a 10 to the 5th second exposure, and as a readout for an objective transmission grating providing spectral resolution of several hundreds to thousands.

Source record↗

Portable high speed photometry systems for observing occultations

Ring orbit studies for Uranus have been particularly fruitful because of the ability, through occultations, to obtain data of high spatial resolution at the rate of 1 to 2 times per year. The occultation program at M.I.T. involves: (1) identifying the scientific questions that can be answered by occultation events, (2) predicting the zone of visibility for the useful events, (3) maintaining and improving a set of portable high-speed photometric systems, (4) obtaining the observations, and (5) reducing the data and interpreting the results. Two stellar occultations by Uranus occurred in May 1985, and were observed with a network of large telescopes that encompassed the Northern and Southern Hemispheres. Portable quartz-oscillator time standards were used at all observatories, and were calibrated before and after each event. Observations obtained form Cerro Tololo and McDonald Observatories of the 4 May and 24 May 1985 occultations by the Uranian rings clearly show a companion to the delta ring on both the immersion and emersion traces. The occultation by Ceres that occurred on 12 November 1984 was observed. Preliminary results give a mean diameter of 933 + or - 10 km, which implies a geometric albedo, Pv = 0.07 + or - 0.01 and a density 2.7 + or - 0.3 gm cu/cm. Hence Ceres is likely composed of silicate material throughout.

Elliot, J. L.↗

The Advanced X-ray Astrophysics Facility high resolution camera

The HRC (High Resolution Camera) is a photon counting instrument to be flown on the Advanced X-Ray Astrophysics Facility (AXAF). It is a large field of view, high angular resolution, detector for the X-ray telescope. The HRC consists of a CsI coated microchannel plate (MCP) acting as a soft X-ray photocathode, followed by a second MCP for high electronic gain. The MCPs are readout by a crossed grid of resistively coupled wires to provide high spatial resolution along with timing and pulse height data. The instrument will be used in two modes, as a direct imaging detector with a limiting sensitivity of 10 to the -15th ergs/sq cm sec in a 10 to the 5th second exposure, and as a readout for an objective transmission grating providing spectral resolution of several hundreds to thousands.

Murray, Stephen S.↗

Laser Doppler Velocimetry and full-field soot volume fraction

Since its introduction in the mid-sixties, Laser Doppler Velocimetry (LDV) has become one of the most widely used methods for the measurement of flows. Its remote and essentially non-intrusive nature provides an invaluable tool for a variety of difficult measurement situations which would be otherwise inaccessible. The high spatial resolution and rapid temporal response afforded by this technique are well suited to the determination of spatial and temporal details of flow fields, as well as characterization of turbulence. Advances in the understanding of the properties of LDV signals, accompanied by technological advances in coherent laser sources, detectors of high sensitivity and low noise, optical fabrication techniques and high-speed digital signal processing architectures have resulted in systems of increased accuracy and flexibility. As will be shown, recent progress in solid-state lasers and photo-detectors has been beneficial insofar as the compatibility of this method with the unique and severe constraints inherent in microgravity combustion science experiments.

Greenberg, Paul S.↗

The Stellar Content of H72.97-69.39, a Potential Super Star Cluster in the Making

Young massive clusters and super star clusters (SSCs) represent an extreme mode of star formation. Far-infrared imaging of the Magellanic Clouds has identified one potential embedded SSC, HSO BMHERICC J72.971176-69.391112 (H72.97-69.39 in short), in the southwest outskirts of the Large Magellanic Cloud. We present Gemini Flamingos 2 and GSAOI near-infrared imaging of a 3′ × 3′ region around H72.97-69.39 in order to characterize the stellar content of the cluster. The stellar content is probed down to 1.5 M {sub ⊙}. We find substantial dust extinction across the cluster region, extending up to A {sub K} of 3. Deeply embedded stars are associated with ALMA-detected molecular gas suggesting that star formation is ongoing. The high spatial resolution of the GSAOI data allows identification of the central massive object associated with the {sup 13}CO ALMA observations and detection of fainter low-mass stars around the H30α ALMA source. The morphology of the molecular gas and the nebulosity from adjacent star formation suggest they have interacted covering a region of several parsecs. The total stellar content in the cluster is estimated from the intermediate- and high-mass stellar content to be at least 10,000 M {sub ⊙}, less than R136 with up to 100,000 M {sub ⊙} within 4.7 pc radius, but places it in the regime of an SSC. Based on the extinction determination of individual stars we estimate a molecular gas mass in the vicinity of H72.97-69.39 of 6600 M {sub ⊙}, suggesting more star formation can be expected.

74 ATOMIC AND MOLECULAR PHYSICS↗

Magnetic domains and domain wall pinning in atomically thin CrBr 3 revealed by nanoscale imaging

The emergence of atomically thin van der Waals magnets provides a new platform for the studies of two-dimensional magnetism and its applications. However, the widely used measurement methods in recent studies cannot provide quantitative information of the magnetization nor achieve nanoscale spatial resolution. These capabilities are essential to explore the rich properties of magnetic domains and spin textures. Here, we employ cryogenic scanning magnetometry using a single-electron spin of a nitrogen-vacancy center in a diamond probe to unambiguously prove the existence of magnetic domains and study their dynamics in atomically thin CrBr 3 . By controlling the magnetic domain evolution as a function of magnetic field, we find that the pinning effect is a dominant coercivity mechanism and determine the magnetization of a CrBr 3 bilayer to be about 26 Bohr magnetons per square nanometer. The high spatial resolution of this technique enables imaging of magnetic domains and allows to locate the sites of defects that pin the domain walls and nucleate the reverse domains. Our work highlights scanning nitrogen-vacancy center magnetometry as a quantitative probe to explore nanoscale features in two-dimensional magnets.

36 MATERIALS SCIENCE↗

Marine Boundary Layer Cloud Property Retrievals from High-Resolution ASTER Observations: Case Studies and Comparison with Terra MODIS

A research-level retrieval algorithm for cloud optical and microphysical properties is developed for the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) aboard the Terra satellite. It is based on the operational MODIS algorithm. This paper documents the technical details of this algorithm and evaluates the retrievals for selected marine boundary layer cloud scenes through comparisons with the operational MODIS Data Collection 6 (C6) cloud product. The newly developed, ASTERspecific cloud masking algorithm is evaluated through comparison with an independent algorithm reported in Zhao and Di Girolamo (2006). To validate and evaluate the cloud optical thickness (tau) and cloud effective radius (r(sub eff)) from ASTER, the high-spatial-resolution ASTER observations are first aggregated to the same 1000m resolution as MODIS. Subsequently, tau(sub aA) and r(sub eff, aA) retrieved from the aggregated ASTER radiances are compared with the collocated MODIS retrievals. For overcast pixels, the two data sets agree very well with Pearson's product-moment correlation coefficients of R greater than 0.970. However, for partially cloudy pixels there are significant differences between r(sub eff, aA) and the MODIS results which can exceed 10 micrometers. Moreover, it is shown that the numerous delicate cloud structures in the example marine boundary layer scenes, resolved by the high-resolution ASTER retrievals, are smoothed by the MODIS observations. The overall good agreement between the research-level ASTER results and the operational MODIS C6 products proves the feasibility of MODIS-like retrievals from ASTER reflectance measurements and provides the basis for future studies concerning the scale dependency of satellite observations and three-dimensional radiative effects.

marine boundary layer↗

The high energy X-ray probe (HEX-P): Galactic PeVatrons, star clusters, superbubbles, microquasar jets, and gamma-ray binaries

HEX-P is a probe-class mission concept that will combine high spatial resolution X-ray imaging (<10" FWHM) and broad spectral coverage (0.2–80 keV) with an effective area far superior to current facilities (including XMM-Newton and NuSTAR) to enable revolutionary new insights into a variety of important astrophysical problems. With the recent discoveries of over 40 ultra-high-energy gamma-ray sources (detected above 100 TeV) and neutrino emission in the Galactic Plane, we have entered a new era of multi-messenger astrophysics facing the exciting reality of Galactic PeVatrons. In the next decade, as more Galactic PeVatrons and TeV gamma-ray sources are expected to be discovered, the identification of their acceleration and emission mechanisms will be the most pressing issue in both particle and high-energy astrophysics. In this paper, along with its companion papers, we will present that HEX-P is uniquely suited to address important problems in various cosmic-ray accelerators, including Galactic PeVatrons, through investigating synchrotron X-ray emission of TeV–PeV electrons produced by both leptonic and hadronic processes. For Galactic PeVatron candidates and other TeV gamma-ray sources, HEX-P can fill in a large gap in the spectral-energy distributions (SEDs) of many objects observed in radio, soft X-rays, and gamma rays, constraining the maximum energies to which electrons can be accelerated, with implications for the nature of the Galactic PeVatrons and their contributions to the spectrum of Galactic cosmic rays beyond the knee at ~3 PeV. In particular, X-ray observation with HEX-P and TeV observation with CTAO will provide the most powerful multi-messenger diagnostics to identify Galactic PeVatrons and explore a variety of astrophysical shock mechanisms. We present simulations of each class of Galactic TeV–PeV sources, demonstrating the power of both the imaging and spectral capabilities of HEX-P to advance our knowledge of Galactic cosmic-ray accelerators. In addition, we discuss HEX-P’s unique and complementary roles to upcoming gamma-ray and neutrino observatories in the 2030s.

79 ASTRONOMY AND ASTROPHYSICS↗

The high energy X-ray probe (HEX-P): Galactic PeVatrons, star clusters, superbubbles, microquasar jets, and gamma-ray binaries

HEX-P is a probe-class mission concept that will combine high spatial resolution X-ray imaging (<10" FWHM) and broad spectral coverage (0.2–80 keV) with an effective area far superior to current facilities (including XMM-Newton and NuSTAR) to enable revolutionary new insights into a variety of important astrophysical problems. With the recent discoveries of over 40 ultra-high-energy gamma-ray sources (detected above 100 TeV) and neutrino emission in the Galactic Plane, we have entered a new era of multi-messenger astrophysics facing the exciting reality of Galactic PeVatrons. In the next decade, as more Galactic PeVatrons and TeV gamma-ray sources are expected to be discovered, the identification of their acceleration and emission mechanisms will be the most pressing issue in both particle and high-energy astrophysics. In this paper, along with its companion papers, we will present that HEX-P is uniquely suited to address important problems in various cosmic-ray accelerators, including Galactic PeVatrons, through investigating synchrotron X-ray emission of TeV–PeV electrons produced by both leptonic and hadronic processes. For Galactic PeVatron candidates and other TeV gamma-ray sources, HEX-P can fill in a large gap in the spectral-energy distributions (SEDs) of many objects observed in radio, soft X-rays, and gamma rays, constraining the maximum energies to which electrons can be accelerated, with implications for the nature of the Galactic PeVatrons and their contributions to the spectrum of Galactic cosmic rays beyond the knee at ~3 PeV. In particular, X-ray observation with HEX-P and TeV observation with CTAO will provide the most powerful multi-messenger diagnostics to identify Galactic PeVatrons and explore a variety of astrophysical shock mechanisms. We present simulations of each class of Galactic TeV–PeV sources, demonstrating the power of both the imaging and spectral capabilities of HEX-P to advance our knowledge of Galactic cosmic-ray accelerators. In addition, we discuss HEX-P’s unique and complementary roles to upcoming gamma-ray and neutrino observatories in the 2030s.

79 ASTRONOMY AND ASTROPHYSICS↗

Feasibility Study For A Spaceborne Ozone/Aerosol Lidar System

Because ozone provides a shield against harmful ultraviolet radiation, determines the temperature profile in the stratosphere, plays important roles in tropospheric chemistry and climate, and is a health risk near the surface, changes in natural ozone layers at different altitudes and their global impact are being intensively researched. Global ozone coverage is currently provided by passive optical and microwave satellite sensors that cannot deliver high spatial resolution measurements and have particular limitations in the troposphere. Vertical profiling DIfferential Absorption Lidars (DIAL) have shown excellent range-resolved capabilities, but these systems have been large, inefficient, and have required continuous technical attention for long term operations. Recently, successful, autonomous DIAL measurements have been performed from a high-altitude aircraft (LASE - Lidar Atmospheric Sensing Experiment), and a space-qualified aerosol lidar system (LITE - Laser In-space Technology Experiment) has performed well on Shuttle. Based on the above successes, NASA and the Canadian Space Agency are jointly studying the feasibility of developing ORACLE (Ozone Research with Advanced Cooperative Lidar Experiments), an autonomously operated, compact DIAL instrument to be placed in orbit using a Pegasus class launch vehicle.

Campbell, Richard E.↗

The High Energy X-Ray Probe (HEX-P): Galactic PeVatrons, Star Clusters, Superbubbles, Microquasar Jets, and Gamma-Ray Binaries

HEX-P is a probe-class mission concept that will combine high spatial resolution X-ray imaging (<10"FWHM) and broad spectral coverage (0.2--80 keV) with an effective area far superior to current facilities (including XMM-Newton and NuSTAR) to enable revolutionary new insights into a variety of important astrophysical problems. With the recent discoveries of over 40 ultra-high-energy gamma-ray sources (detected above 100 TeV) and neutrino emission in the Galactic Plane, we have entered a new era of multi-messenger astrophysics facing the exciting reality of Galactic PeVatrons. In the next decade, as more Galactic PeVatrons and TeV gamma-ray sources are expected to be discovered, the identification of their acceleration and emission mechanisms will be the most pressing issue in both particle and high-energy astrophysics. In this paper, along with its companion papers (Reynolds et al. 2023, Mori et al. 2023), we will present that HEX-P is uniquely suited to address important problems in various cosmic-ray accelerators, including Galactic PeVatrons, through investigating synchrotron X-ray emission of TeV--PeV electrons produced by both leptonic and hadronic processes. For Galactic PeVatron candidates and other TeV gamma-ray sources, HEX-P can fill in a large gap in the spectral-energy distributions (SEDs) of many objects observed in radio, soft X-rays, and gamma rays, constraining the maximum energies to which electrons can be accelerated, with implications for the nature of the Galactic PeVatrons and their contributions to the spectrum of Galactic cosmic rays beyond the knee at $\sim3$ PeV. In particular, X-ray observation with HEX-P and TeV observation with CTA will provide the most powerful multi-messenger diagnostics to identify Galactic PeVatrons and explore a variety of astrophysical shock mechanisms. We present simulations of each class of Galactic TeV--PeV sources, demonstrating the power of both the imaging and spectral capabilities of HEX-P to advance our knowledge of Galactic cosmic-ray accelerators. In addition, we discuss HEX-P’s unique and complementary roles to upcoming gamma-ray and neutrino observatories in the 2030s.

particle accelerators↗

Hybrid chemical characterization of latent images in EUV resist with 12 nm half-pitch features

With the advancement of high numerical aperture extreme ultraviolet (EUV) lithography, the new platform will enable chipmakers to achieve critical dimensions of 8 nm. However, resist materials face significant challenges in delivering increased sensitivity while managing rising stochastic variations. We aim to develop comprehensive techniques to characterize the chemical profile of latent images, stored in EUV resists after exposure and postexposure baking, which is essential for understanding the origin of stochastic effects. Infrared photo-induced force microscopy (IR PiFM) is a bimodal atomic force microscopy technique combined with an infrared light source, allowing for simultaneous sub-5 nm topographic and chemical characterization within a localized environment. Critical-dimension resonant soft X-ray scatterometry (CD-RSoXS) provides statistical data that reveal structural and chemical information for comparative analysis. For the first time, IR PiFM has been used to chemically map the latent images of EUV resists (after exposure and postexposure baking) at a record high resolution of 12 nm half-pitch, enabling nondestructive analysis of patterns prior to development. Furthermore, CD-RSoXS offers direct experimental observation and comparison of exposed, postexposure baked, and developed patterns, which align with the IR PiFM results. We demonstrate that the IR PiFM technique offers valuable insights into both high spatial resolution and local chemical information simultaneously. In addition, CD-RSoXS provides statistical results that support our main findings. This hybrid metrology approach leverages a multifaceted dataset by combining the most reliable information from each source, which is essential for a comprehensive understanding of the stochastic effects in EUV lithography processes.

O’Reilly, Padraic↗

Extraction of Vibration Data with Imaging

To date, the primary sensing technology used to measure the vibration response has been accelerometers and strain gages mounted directly to the structure and using either wired or, more recently, wireless telemetry. Cost issues with these sensors and the associated data acquisition systems typically limit the numbers that are deployed on in situ structures. Although there are a few structures with larger sensing counts that in some cases exceed over 1000 sensors, more typical numbers range from ten to one hundred sensors resulting in low spatial resolution when they are applied to physically large systems. When one considers that nuclear power plant structures usually have complex geometries, material properties, connectivity and boundary conditions, it is clear these current approaches to vibration measurements can only provide limited information about a system’s dynamics response characteristics. As an alternative, many non-contact measurement technologies have emerged, including point wise measurement methods such as Global Positioning System (GPS), microwave interferometry, and laser Doppler vibrometry (LDV), as well as simultaneous full-field measurement methods such as electronic speckle pattern interferometry, holography interferometry, and muon tomography, some of which can provide high spatial resolution measurements. Among these methods, digital video imaging techniques have emerged as a feasible solution for full-field vibration measurements that provide significantly more detailed dynamic response information because every pixel becomes a measurement point. Furthermore, recent advances in image processing and computer vision algorithms have been successfully used to process video data for experimental and operational modal analysis. Such full-field measurements have the potential to significantly improve many current structural assessment procedures including system identification (modal parameter estimation), structural health monitoring, load reconstruction, model validation, and model updating. Furthermore, more recent full-field imaging techniques can be accomplished with relatively low-cost, commercially-available off-the-shelf cameras. However, these measurement procedures have other limitations that must be considered such as the ability to only measure visibly accessible points on a structure and a more limited dynamic range and bandwidth than can be achieved with accelerometers or strain gages.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Thinking Outside of the Blue Marble: Novel Ocean Applications Using the VIIRS Sensor

While planning for future space-borne sensors will increase the quality, quantity, and duration of ocean observations in the years to come, efforts to extend the limits of sensors currently in orbit can help shed light on future scientific gains as well as associated uncertainties. Here, we present several applications that are unique to the polar orbiting Visual Infrared Imaging Radiometer Suite (VIIRS), each of which challenge the threshold capabilities of the sensor and provide lessons for future missions. For instance, while moderate resolution polar orbiters typically have a one day revisit time, we are able to obtain multiple looks of the same area by focusing on the extreme zenith angles where orbital views overlap, and pair these observations with those from other sensors to create pseudo-geostationary data sets. Or, by exploiting high spatial resolution (imaging) channels and analyzing patterns of synoptic covariance across the visible spectrum, we can obtain higher spatial resolution bio-optical products. Alternatively, non-traditional products can illuminate important biological interactions in the ocean, such as the use of the Day-Night-Band to provide some quantification of phototactic behavior of marine life along light polluted beaches, as well as track the location of marine fishing vessel fleets along ocean fronts. In this talk, we explore ways to take full advantage of the capabilities of existing sensors in order to maximize insights for future missions.

ocean color↗

Direct nanoscale mapping of open circuit voltages at local back surface fields for PERC solar cells

The open circuit voltage (V OC) is a critical and common indicator of solar cell performance as well as degradation, for panel down to lab-scale photovoltaics. Detecting V OC at the nanoscale is much more challenging, however, due to experimental limitations on spatial resolution, voltage resolution, and/or measurement times. Accordingly, in this work an approach based on Conductive Atomic Force Microscopy is implemented to directly detect the local V OC , notably for monocrystalline Passivated Emitter Rear Contact (PERC) cells which are the most common industrial-scale solar panel technology in production worldwide. This is demonstrated with cross-sectioned monocrystalline PERC cells around the entire circumference of a poly-Aluminum-Silicide via through the rear emitter. The V OC maps reveal a local Back Surface Field extending ~2 μm into the underlying p-type Si absorber due to Al in-diffusion as designed. Such high spatial resolution methods for photovoltaic performance mapping are especially promising for directly visualizing the effects of processing parameters, as well as identifying signatures of degradation for silicon and other solar cell technologies.

14 SOLAR ENERGY↗

Spatially Resolved Mapping of Three-Dimensional Molecular Orientations with ~2 nm Spatial Resolution through Tip-Enhanced Raman Scattering

We record local optical field images of silver nanocubes (75 nm) using tip-enhanced Raman (TER) spectral imaging. The images that we observe are consistent with several recent reports from our group, but here, we demonstrate sub-2 nm spatial resolution in local optical field nanoimaging under ambient laboratory conditions. This is achieved by scanning the substrate (nanocube on Si) relative to a 4-thiobenzonitrile (TBN)-functionalized Ag-coated TER probe. The spatial resolution that we obtain necessitates that only a few molecules govern the recorded optical response; molecular orientation becomes an important consideration in such measurements. We model the orientation through geometry optimization of a TBN molecule chemisorbed onto an Ag79 cluster (sphere with a ~1 nm diameter). Using the computed orientation of the cluster-bound molecule, we then model the optical response using formalism that accounts for the orientation of the molecule relative to vector components of the local optical fields. We find optimal agreement between experiment and theory. In effect, this work reveals the parallels between single-molecule Raman scattering and high-spatial-resolution TER spectroscopy, even when the images themselves cannot be used to visualize a single molecule in real space.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗