Exploring Al(X)Ga(1-X)N Nanostructures Fabricated via Chemical Wet Etching.
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Phase stability and phase transformations in binary Pu alloys are critical for multiple applications. Long-term phase stability affects mechanical properties, microstructure, corrosion behavior, and structural integrity. A clear and detailed understanding of phase transformations and phase stability mechanisms is necessary to assess the behavior and response to unexpected stimuli. Gaining advanced knowledge on the behavior of Pu and Pu alloys at a variety of temperatures, pressures, and time will ensure better predictions and control on evolution outside laboratory measurements.
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The impact of moisture ingress on the surface of copper indium gallium diselenide (CIGS) solar cells was studied. While industry-scale modules are encapsulated in specialized polymers and glass, over time, the glass can break and the encapsulant can degrade. During such conditions, water can potentially degrade the interior layers and decrease performance. The first layer the water will come in contact with is the transparent conductive oxide (TCO) layer. To simulate the impact of this moisture ingress, complete devices were immersed in deionized water. To identify the potential sources of degradation, a common window layer for CIGS devices—a bilayer of intrinsic zinc oxide (i-ZnO) and conductive indium tin oxide (ITO)—was deposited. The thin films were then analyzed both pre and post water soaking. To determine the extent of ingress, dynamic secondary ion mass spectroscopy (SIMS) was performed on completed devices to analyze impurity diffusion (predominantly sodium and potassium) in the devices. The results were compared to device measurements, and indicated a degradation of device efficiency (mostly fill factor, contrary to previous studies), potentially due to a modification of the alkali profile.
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Solubility range of 75 atomic percent vanadium- gallium system to determine phases in equilibrium and ascertain presence or absence of superconductivity
Results of theoretical and applied research related to fissioning uranium plasmas. Topics examined include uranium plasma instabilities, diagnostic techniques, radiant heat transfer characteristics, nuclear pumping of lasers, and various fission engine concepts. Engineering aspects considered for open-cycle gas core engines include effects of buoyancy on fuel containment, flow and criticality problems, effects of injection conditions, and radiation hazards. The nuclear light bulb engine, the mini-cavity reactor, the dust-bed reactor, and the colloid core reactor are also examined in terms of design and control considerations. Individual items are abstracted in this issue.
The mean thermal conductivity of liquid gallium was measured as 70 (plus or minus 7) W/m/K over the range 250-550 C. For indium antimonide, Kl = 2.04Ks at the melting temperature with Kl = 9.23 W/m/K- as a reasonable absolute value.
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The results of an experimental program to develop the epitaxial growth techniques and analytical characterization techniques to fabricate graded bandgap solar cells are reported.
A double discharge technique was used in the investigation. An initial discharge established between parallel arrays of tungsten pin electrodes was followed, after a variable time delay, by a high voltage (180 kV), short duration (50 nsec) secondary discharge between two aluminum main electrodes. Metal compounds, including metal alkyls, hydrides, and halides, were used to obtain the required metal atom concentrations. Twenty-four new laser transitions involving 9 different metal atoms were observed. The observed relations are shown in a number of partial energy-level diagrams.
Interface recombination velocity in AlxGa1-xAs-GaAs and A10.85 Ga0.15As-GaAs1-ySby heterojunction systems was studied as a function of lattice mismatch. The results are applied to the design of highly efficient III-V heterojunction solar cells. A horizontal liquid-phase epitaxial growth system was used to prepare p-p-p and p-p-n double heterojunction test samples with specified values of x and y. Samples were grown at each composition, with different GaAs and GaAsSb layer thicknesses. A method was developed to obtain the lattice mismatch and lattice constants in mixed single crystals grown on (100) and (111)B oriented GaAs substrates.
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The development of a sulfur-iodine thermal water splitting cycle is described. The process features a 50% thermal efficiency, plus all liquid and gas handling. Basic chemical investigations comprised the development of multitemperature and multistage sulfuric acid boost reactors, defining the phase behavior of the HI/I2/H2O/H3PO4 mixtures, and development of a decomposition process for hydrogen iodide in the liquid phase. Initial process engineering studies have led to a 47% efficiency, improvements of 2% projected, followed by coupling high-temperature solar concentrators to the splitting processes to reduce power requirements. Conceptual flowsheets developed from bench models are provided; materials investigations have concentrated on candidates which can withstand corrosive mixtures at temperatures up to 400 deg K, with Hastelloy C-276 exhibiting the best properties for containment and heat exchange to I2.