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At least 559 records · Page 31

Chiral selection in poly(C)-directed synthesis of oligo(G)

An experimental study is reported which shows that poly(C)-directed oligomerization of activated guanosine mononucleotides proceeds readily if the monomers are of the same optical handedness as the template, and is far less efficient if the monomers are of the opposite handedness. However, in template-directed reactions with a racemic mixture, monomers of the opposite handedness to the template are incorporated as chain terminators at the 2'(3') end of the products. This inhibition raises an important problem for many theories of the origin of life.

Joyce, G. F.↗

Perpendicular Subcritical Shock Structure in a Collisional Plasma Experiment

We present a study of perpendicular subcritical shocks in a collisional laboratory plasma. Shocks are produced by placing obstacles into the supermagnetosonic outflow from an inverse wire array z pinch. We demonstrate the existence of subcritical shocks in this regime and find that secondary shocks form in the downstream. Detailed measurements of the subcritical shock structure confirm the absence of a hydrodynamic jump. We calculate the classical (Spitzer) resistive diffusion length and show that it is approximately equal to the shock width. As a result, we measure little heating across the shock (<10 % of the ion kinetic energy) which is consistent with an absence of viscous dissipation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Human mononuclear cell function after 4 degrees C storage during 1-G and microgravity conditions of spaceflight

Future space missions of long duration may require that autologous leukocytes be stored in flight for infusion to restore normal immune competence in crewmembers. Peripheral blood mononuclear cells (PBMNCs), as leukocyte concentrates in autologous plasma and 2% dextrose, were stored in the microgravity conditions provided by the U.S. Space Shuttle Columbia (Mission 61-C). Activity of PBMNC after space flight was compared with that from a series of preflight ground control experiments, which demonstrated in culture a progressive daily loss in mitogen-stimulated protein synthesis at 24 h and thymidine uptake at 72 h after storage for 7 d at 4 degrees C. Post-storage viabilities were at least 90% as determined by trypan dye exclusion. A progressive reduction in the percentage of PBMNC expressing cell-surface phenotype markers, which was similar for monocytes, B cells, and T-cell subsets, also occurred after storage. The ability of PBMNC, stored for 8 d in Columbia's middeck, to become activated and proliferate in vitro was similar to that of cells that remained in identical flight lockers on the ground as 1-G controls, thus indicating that PBMNCs were not adversely affected by storage under microgravity conditions.

NASA Discipline Number 00-00↗

Cross-shell excited configurations in the structure of 34 Si

The cross-shell excited states of 34 Si have been investigated via β decays of the 4 − ground state and the 1 + isomeric state of 34 Al. Since the valence protons and valence neutrons occupy different major shells in the ground state as well as the intruder 1 + isomeric state of 34 Al, intruder levels of 34 Si are populated via allowed β decays. Spin assignments to such intruder levels of 34 Si were established through γ-γ angular correlation analysis for the negative-parity states. The configurations of such intruder states play crucial roles in our understanding of the N = 20 shell gap evolution. A configuration interaction model derived from the FSU Hamiltonian was utilized in order to interpret the intruder states in 34 Si. Furthermore, shell model interaction derived from a more fundamental theory with the valence space in medium similarity renormalization group method was also employed to interpret the structure of 34 Si.

20 ≤ A ≤ 38↗

Advancing extreme pulsed lasers through measurements: summary of the pulsed laser metrology workshop

In this report we present consensus findings produced during the pulsed laser metrology (PLM) workshop (Boulder, CO, USA, August 2025). The workshop was a meeting of 35 scientists from private industry, academia, and U.S. government to compile a list of the metrology needs to support extreme pulsed laser development and implementation. We define ‘extreme pulsed lasers’ loosely as those with peak powers above 1 TW or multi-Joule pulse energies. Such lasers are being increasingly used and investigated for use in high energy particle acceleration, short wavelength radiation generation, laser-based fusion, etc. The rapid growth of these fields and the proliferation of extreme lasers for these applications, coupled with the extreme electric fields they generate and relative scarcity of such lasers, presents unique challenges to accuracy in their measurement. The PLM workshop was a two-day event designed to hear from users, developers, and researchers on the current state of optical metrology associated with these extreme pulsed lasers. The goal was to identify the most important measurement challenges limiting development and implementation of these lasers in practical applications. We report here the conclusions and recommendations of this workshop. The hope is that this document will become the first of many iterations which track the status of measurement needs supporting extreme pulsed lasers.

Lasers↗

Design, synthesis, and characterization of vinyl-addition polynorbornenes with tunable thermal properties

Unfunctionalized vinyl-addition polynorbornene (VAPNB) possesses many outstanding properties such as high thermal, chemical, and oxidative stability. These features make VAPNB a promising candidate for many engineering applications. However, VAPNB has a small service window between its glass transition temperature (T g ) and decomposition temperature (T d ), and it cannot be readily processed in a melt state. In this work, we demonstrate that the service window of VAPNBs can be tailored through the use of norbornene monomers bearing alkyl, aryl, and aryl ether substituents. The vinyl addition homopolymerization and copolymerization of these functionalized norbornyl-based monomers yielded VAPNBs with high T' g s (>150 °C) and large service windows (T d –T g > 100 °C), which are comparable to other commercial engineering thermoplastics. To further establish the feasibility of melt processing, a functionalized VAPNB material with T g = 209 °C and a service window of 170 °C was successfully extruded and molded into bars. Subsequent characterization of the bars by dynamic mechanical analysis (DMA), nuclear magnetic resonance spectroscopy (NMR), and gel permeation chromatography (GPC) revealed only minor signs of polymer degradation. Furthermore, these studies suggest that substituted VAPNBs could be developed into a new class of engineering thermoplastics that is compatible with workhorse melt processing techniques such as extrusion and injection molding, as well as emerging techniques such as extrusion-based 3D printing.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Cryogenic liquid-jet breakup in two-fluid atomizers

A two-fluid atomizer was used to study the breakup of liquid-nitrogen jets in nitrogen, argon, and helium atomizing gas flows. A scattered-light scanner particle sizing instrument previously developed at NASA Lewis Research Center was further developed and used to determine characteristic drop diameters for the cryogenic sprays. In the breakup regime of aerodynamic-stripping, i.e., sonic-velocity conditions, the following correlation of the reciprocal Sauter mean diameter, D(sub 32)exp -1, with the atomizing-gas flowrate, W(g), was obtained: D(sub 32)exp -1 = k(sub c)(W(g)exp 1.33), where k(sub c) is a proportionality constant evaluated for each atomizing gas. Values of k(sub c) = 120, 220, and 1100 were obtained for argon, nitrogen, and helium gasflows, respectively. The reciprocal Sauter mean diameter and gas flowrate have the units of 1/cm and g/sec, respectively. In the regime of capillary-wave breakup, or subsonic conditions, it was found that D(sub 32)exp -1 = k(g)(W(g)exp 0.75), where k = 270, 390, and 880 for argon, nitrogen, and helium gasflows, respectively.

Ingebo, Robert D.↗

Discovery of Thermonuclear (Type 1) X-ray Bursts in the X-ray Binary Swift J1858.6-0814 Observed with NICER and NuSTAR

Swift J1858.6–0814 is a recently discovered X-ray binary notable for extremely strong variability (by factors of >100 in soft X-rays) in its discovery state. We present the detection of five thermonuclear (Type I) X-ray bursts from Swift J1858.6–0814, implying that the compact object in the system is a neutron star (NS). Some of the bursts show photospheric radius expansion, so their peak flux can be used to estimate the distance to the system. The peak luminosity, and hence distance, can depend on several system parameters; for the most likely values, a high inclination and a helium atmosphere, D = 12.8+0.8−0.6 kpc, although systematic effects allow a conservative range of 9–18 kpc. Before one burst, we detect a QPO at 9.6 ± 0.5 mHz with a fractional rms amplitude of 2.2 ± 0.2 per cent (0.5–10 keV), likely due to marginally stable burning of helium; similar oscillations may be present before the other bursts but the light curves are not long enough to allow their detection. We also search for burst oscillations but do not detect any, with an upper limit in the best case of 15 per cent fractional amplitude (over 1–8 keV). Finally, we discuss the implications of the NS accretor and this distance on other inferences which have been made about the system. In particular, we find that Swift J1858.6–0814 was observed at super-Eddington luminosities at least during bright flares during the variable stage of its outburst.

D J K Buisson↗

Observation of subcritical shocks in a collisional laboratory plasma: scale dependence near the resistive length

We present a study of subcritical shocks in a highly collisional laboratory plasma with a dynamically significant magnetic field. Shocks were produced by placing cylindrical obstacles into the supermagnetosonic ( $M_{{\rm MS}} \sim 1.9$ ) outflow from an inverse wire array z-pinch at the MAGPIE pulsed power facility ( $n_{e} \sim 8.5 \times 10^{17}\,{\rm cm}^{-3}$ , $v \sim 45\,{\rm km}\,{\rm s}^{-1}$ ). We demonstrate the existence of subcritical shocks in this regime and find that secondary stagnation shocks form in the downstream which we infer from interferometry and optical Thomson scattering measurements are hydrodynamic in nature. The subcritical shock width is found to be approximately equal to the resistive diffusion length and we demonstrate the absence of a jump in hydrodynamic parameters. Temperature measurements by collective optical Thomson scattering showed little temperature change across the subcritical shock ( ${<}10\,\%$ of the ion kinetic energy) which is consistent with a balance between adiabatic and Ohmic heating and radiative cooling. We demonstrate the absence of subcritical shocks when the obstacle diameter is less than the resistive diffusion length due to decoupling of the magnetic field from the plasma. These findings are supported by magnetohydrodynamic simulations using the Gorgon and AstroBEAR codes and discrepancies between the simulations and experiment are discussed.

Physics↗

Molecular branching ratio method for intensity calibration of optical systems in the vacuum ultraviolet

A state-of-the-art review is given of the molecular branching ratio method for intensity calibration in the vacuum ultraviolet. Ways are described for determining both relative and quantitative responses in the wavelength range 1000 A to 3000 A. The molecular band systems which are discussed are the following: H2(B 1 Sigma u +)-(X 1 Sigma g +), H2(C 1 Pi u)-(X 1 Sigma g +), N2(A 1 Pi g)-(X 1 Sigma g +), CO(A 1 Pi)-(X 1 Sigma +), NO(A 2 Sigma +)-(X 2 Pi r), and NO(+) (A 1 Pi)-(X 1 Sigma +).

Mumma, M. J.↗

Nimbus-7 TOMS Version 7 Calibration

This report describes an improved instrument characterization used for the Version 7 processing of the Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) data record. An improved internal calibration technique referred to as spectral discrimination is used to provide long-term calibration precision of +/- 1%/decade in total column ozone amount. A revised wavelength scale results in a day one calibration that agrees with other satellite and ground-based measurements of total ozone, while a wavelength independent adjustment of the initial radiometric calibration constants provides good agreement with surface reflectivity measured by other satellite-borne ultraviolet measurements. The impact of other aspects of the Nimbus-7 TOMS instrument performance are also discussed. The Version 7 data should be used in all future studies involving the Nimbus-7 TOMS measurements of ozone. The data are available through the NASA Goddard Space Flight Center's Distributive Active Archive Center (DAAC).

Wellemeyer, C. G.↗

Atmosphere-biosphere exchange flux of carbon dioxide in a tallgrass prairie modeled with satellite spectral data

The estimation of the rate of net CO2 uptake of vegetated land surfaces is essential for studies of global carbon cycle. The present paper demonstrates the use of spectral reflectance data from satellite remote sensing to model net CO2 flux (NCF) of a tallgrass canopy at the Konza prairie, Kansas. A bidirectional reflectance canopy model was used to estimate seasonal changes in canopy leaf area index (LAI) from surface reflectances remotely sensed by SPOT 1 and Landsat 5 satellites. The radiation model was also coupled with leaf conductance-photosynthesis models to scale up stomatal conductance and NCF from individual leaves to canopy level according to radiation distribution inside the canopy. The satellite-data-driven model was able to closely simulate the seasonal change in LAI as well as the short-term variation of canopy LAI caused by the dry period during late July and early August in the area. Modeled canopy stomatal conductance (g(sub c)) and NCF agree with measurements within 0.16 cm/s and 0.28 mg m(exp -2)/s, respectively, during the growth season from late May to late August. In October both measured and modeled NCF turned to small negative values as canopy photosynthesis diminished and predicted LAI approached zero. In addition to data scatter, some of the differences between modeled and measured g(sub c) and NCF may be attributed to uncertainties in seasonal changes of plant physiological status that were not detected by satellite data; some of the differences were caused by inadequate description of the dependence of nighttime CO2 flux of soil respiration on near-surface turbulent mixing.

Gao, W.↗

Local structure of zinc–indium–tin oxide films via grazing-incidence x-ray pair-distribution functions and theoretical methods

A detailed experimental and theoretical study on the local (r ≤ 4.5 Å) atomic structure of amorphous and crystalline zinc–indium–tin oxide (ZITO) thin films using grazing-incidence x-ray Pair-Distribution Functions (PDFs), ab initio Molecular Dynamics (MD), and Empirical Potential Structure Refinement (EPSR) Monte Carlo simulations is presented. High-energy synchrotron x rays, a two-dimensional detector, and different incident angles were used to probe the depth uniformity of five (ZnO) 0.15 (In 2 O 3 ) 0.70 (SnO 2 ) 0.15 films that were deposited via pulsed-laser deposition at growth temperatures (T G ) ranging from 25 to 300 °C. Films deposited at T G ≤ 150 °C were amorphous. The partially crystalline (T G = 200 °C) and fully crystalline (T G = 300 °C) films were highly textured. Both crystalline and amorphous structures were investigated using ab initio MD and EPSR Monte Carlo simulations. The density of the amorphous films determined from the experimental data agreed with MD calculations. Coordination numbers, bond lengths, and distortion for metal–oxygen and for both the edge- and corner-shared In–metal shells up to 4.5 Å obtained from PDF analysis closely agreed with MD and EPSR simulations. There is a pronounced decrease in the edge- and corner-shared In–Zn distances arising from the shorter Zn–O bond length, Zn–O tetrahedral coordination, and In–O–Zn angle in amorphous ZITO compared to its crystalline counterpart. A maximum in electrical mobility was observed for the amorphous film just before crystallization occurred. While the peak is broad, consistent with nearly unchanged overall cation–oxygen coordination in the amorphous films, ESPR results indicate that the tetrahedral coordination follows the conductivity trend.

Grazing Incidence X-ray↗

Scanning tunneling microscopy and spectroscopy characterization of Nb films for quantum applications

Niobium thin films are key components of superconducting microwave resonators. Interest in these devices has increased dramatically because of their application in quantum systems. Despite tremendous effort to improve their performance, loss mechanisms are still not well understood. Nb/substrate and Nb/air interfaces are likely culprits in contributing to decoherence and ultimately limiting the performance of superconducting devices. Here, we investigate the Nb/substrate interface by studying the effect of hydrogen-passivated H:Si(111) substrates on the local superconducting properties of ∼40 nm thick Nb films compared to Nb films grown on typical Si(001) substrates. Specifically, low-temperature scanning tunneling microscopy and spectroscopy are employed to compare nanoscale material properties. Further, the atomically flat monohydride H:Si(111) substrates are found to yield a smoother and less defective interface with the Nb film. Correspondingly, the Nb films grown on H:Si(111) substrates present more uniform superconducting properties and exhibit less quasiparticle broadening.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Bent crystal spectrometer for solar X-ray spectroscopy

A bent crystal spectrometer employs a collimated beam of X-rays incident on the crystal over a range of Bragg angles determined by the orientation and curvature of the crystal surface. It provides continuous and simultaneous coverage of all X-ray wavelengths within its spectral range. In-flight testing for solar X-ray spectroscopy was performed using a small instrument to supplement the wavelength coverage of several scanning spectrometers used to study solar active regions in the 9-24 A range. Later testing included modifications to alleviate problems caused by ultraviolet radiation. Future usage of the device will include studies of time variable emission from solar flares or discrete galactic X-ray sources, and the first major experiment to utilize bent crystal spectrometers will be the Solar Maximum Mission satellite in 1979.

Rapley, C. G.↗

Measurements of B-mode polarization of the cosmic microwave background from 500 square degrees of SPTpol data

We report a B-mode power spectrum measurement from the cosmic microwave background (CMB) polarization anisotropy observations made using the SPTpol instrument on the South Pole Telescope. This work uses 500 deg 2 of SPTpol data, a five-fold increase over the last SPTpol B-mode release. As a result, the bandpower uncertainties have been reduced by more than a factor of two, and the measurement extends to lower multipoles: 52 < ` < 2301. Data from both 95 and 150 GHz are used, allowing for three cross-spectra: 95 GHz x 95 GHz, 95 GHz x 150 GHz, and 150 GHz x 150 GHz. B-mode power is detected at very high significance; we find P(BB < 0) = 5.8 × 10 -71 , corresponding to a 18.1 σ detection of power. With a prior on the galactic dust from Planck, WMAP and BICEP2/Keck observations, the SPTpol B-mode data can be used to set an upper limit on the tensor-to-scalar ratio, r < 0.44 at 95% confidence (the expected 1 σ constraint on r given the measurement uncertainties is 0.22). We find the measured B-mode power is consistent with the Planck best-fit ΛCDM model predictions. Scaling the predicted lensing B-mode power in this model by a factor A lens , the data prefer A lens = 1.17 ± 0.13. These data are currently the most precise measurements of B-mode power at ℓ > 320.

79 ASTRONOMY AND ASTROPHYSICS↗

Infrared Linear Imaging Array

Photodiodes, multiplexer, and preamp reside in hybrid ceramic package. Hybrid microcircuit produces 128-element line images of infrared scenes. Each picture element is 0.008-in. (0.2-mm) square. Even without image data processing, microcircuit resolves temperature differences as small as 0.05 degrees C in infrared images.

Bailey, G. C.↗