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Lower thermosphere composition and mean molecular weight, analyzing diurnal and latitude effects using mass spectrometric measurements
We analyzed the performance of an electrochemical desorption unit to be implemented in an electrochemically mediated amine regeneration (EMAR) process, which separates CO 2 and regenerates the amine upon modulation of a targeted species that complexes with the amine molecules. Using a simplified one-dimensional boundary layer model, we combined the kinetic expressions of the faradaic reactions with mass transfer effects to analyze the polarization behavior of the flow cell. Mass transfer limitations become dominant at high current densities, leading to increases in energy consumption. An understanding of scaling laws with key parameters, such as the Sherwood number, is required to achieve high power operation with minimal mass transfer losses. Because the EMAR chemistry is sensitive to temperature, heat distribution in the unit is also examined. Our results indicate that the desorption performance increases with addition of a high-temperature heat source. Additionally, incorporation of membrane crossover suggests energy losses because of diffusion and migration of active species. Furthermore, these findings inform on scaling laws for at-scale desorber design and provide a model for scaling up the EMAR system for larger scale operations.
Typical commercial construction inherently contains large surface areas of relatively thin mass located in the floor slabs. This research asks how effective this mass could be for passive cooling, relative to other mass depths, if it were to be exposed and used as thermal mass. Although much of the rich literature on thermal mass has been conducted with far greater mass depths, a more limited amount of research suggests that because the surface heat transfer rate is limited, the focus should be on the surface area of exposed mass, not its depth. This presents an opportunity for more buildings to behave more thermally massively, if the mass inherent in typical floor slabs contains utility, particularly over diurnal cycles. In all climates analyzed, it was found that there is a pronounced shoulder where energy savings from passive cooling of increasing mass depths was steep until roughly 7.5–10 cm, and beyond this point the achieved energy savings diminished rapidly. When considering the embodied energy of concrete, the incremental benefit of added mass beyond a typical topping slab of 10 cm does not justify the incremental embodied energy cost from a total energy standpoint alone.
A simple engineering correlation scheme is developed to predict the variable property effects on dilute species laminar forced convection mass transfer applicable to all vapor molecules or Brownian diffusing small particle, covering the surface to mainstream temperature ratio of 0.25 T sub W/T sub e 4. The accuracy of the correlation is checked against rigorous numerical forced convection laminar boundary layer calculations of flat plate and stagnation point flows of air containing trace species of Na, NaCl, NaOH, Na2SO4, K, KCl, KOH, or K2SO4 vapor species or their clusters. For the cases reported here the correlation had an average absolute error of only 1 percent (maximum 13 percent) as compared to an average absolute error of 18 percent (maximum 54 percent) one would have made by using the constant-property results.
The effects of 14 days of increased gravitational load, and the absence of adrenal stress hormones on total body bone mineral content (BMC) were examined in male Sprague-Dawley rats. Centrifugation at 2 Gs (2G) was used to increase the gravitational load, and bilateral adrenalectomy (ADX) was used to eliminate the production of adrenal stress hormones. Stationary groups at 1 G (1G) and sham operated (SHAM) animals served as controls. Thirty rats (n=6 or 8) made up the four experimental groups (1G SHAM, 1G ADX, 2G SHAM and 2G ADX). BMC was assessed by dual energy x-ray absorptiometry (DXA) which was performed to determine the total body bone mineral content, and also through bone ashing of the left femur and the left humerus. Activity was determined through biotelemetry, also body mass and food intake were measured. Multi-factorial analysis of variance (MANCOVA) and Newman Keuls post hoc tests were used to analyze significant effects (p is less than 0.05) for the primary variables. Results from both DXA and the ashed femur indicated that BMC decreased significantly with increased G for both the SHAM and ADX groups. The BMC determined by DXA for the 1G ADX group was also significantly lower than the 1G SHAM group, however the 2G SHAM and 2G ADX groups were not significantly different. However, the bone ashing results showed the femur differed significantly only between the rates of centrifugation and not between the ADX and SHAM. The humerus showed no significant difference between any of the groups. There was a significant decrease in body mass with increased G and there was no ADX effect on body mass. When DXA BMC was normalized for body mass changes, there were no significant group differences. However, with bone ashing, the femur BMC/BW still showed significant difference between rates of centrifugation, with the 2G group being lower. Activity level decreased with body mass, and food intake data showed there was significant hypophagia during the first few days of centrifugation. Urine calcium was measured and was found decrease at the start of centrifugation for the 2G groups and rise to a level higher than that of the stationary groups. Finally, the correlation between BW and BMC was determined to be highly correlated (r = .71). These results suggest that the decrease in total body BMC seen with hypergravity may be based to a large extent on the differences in body mass induced by the 2G load.
Lower thermosphere composition and mean molecular weight analyzed for diurnal and latitude effects, using mass spectrometric measurements
Hollow fiber membrane modules are used for gas purification by their selective permeation properties. Intensification of the process to minimize the retentate loss and gas pressure involves optimization at various scales. In this work, we outline a numerical investigation of the gas separation performance at the scale of fiber bundles and its impact on module performance. Flow channeling and anisotropy govern the mass-transfer coefficient in axial and cross-flow configurations. These effects are quantified in terms of a permeability tensor or an anisotropy ratio and the effective mass-transfer coefficient or the Sherwood number. The results show a trade-off between purification and recovery. While smaller fibers offer a large specific surface area to enable high purification, it comes at a huge penalty on the separation performance due to reduced penetration within bundles. Optimum performance indicators are emphasized.
The Peters formula, which tells how the coalescence time of a binary system emitting gravitational radiation is determined by the initial size and shape of the elliptic orbit, is often used in estimating the merger rate of primordial black holes and the gravitational wave background from the mergers. Valid as it is in some interesting scenarios, such as the analysis of the LIGO-Virgo events, the Peters formula fails to describe the coalescence time if the orbital period of the binary exceeds the value given by the formula. This could underestimate the event rate of mergers that occur before the cosmic time t ~ 10 13 s. As a result, the energy density spectrum of the gravitational wave background could develop a peak, which is from mergers occurring at either t ~ 10 13 s (for black holes with mass M ≳ 10 8 M ⊙ ) or t ~ 10 26 (M/M ⊙ ) -5/3 s (for 10 5 M ⊙ ≲ M ≲ 10 8 M ⊙ ). This can be used to constrain the fraction of dark matter in primordial black holes (denoted by f) if potential probes (such as SKA and U-DECIGO) do not discover such a background, with the result f ≲ 10 -6 –10 -4 for the mass range 10– 10 9 M ⊙ . Finally, we then consider the effect of mass accretion onto primordial black holes at redshift z ~ 10, and find that the merger rate could drop significantly at low redshifts. The spectrum of the gravitational wave background thus gets suppressed at the high-frequency end. This feature might be captured by future detectors such as ET and CE for initial mass M = Script $\mathcal{O}$(10–100) M ⊙ with f ≳ 10 -4 .
An analysis has been performed t o determine the effect of mass injection on heat transfer to an arbitrary surface of revolution. effective heat of ablation is determined, and the downstream effects of injection are investigated. It is found that the linear relation between heat of ablation and difference between wall and free-stream enthalpy, previously verified at the stagnation point, provides a useful approximation at any point on a surface of revolution. From the investigation of the downstream effects of injection it is found that an appreciable rate of heating may be obtained, even at points considerably downstream from the point at which injection ends. However, the radiation equilibrium temperature is proportional to the fourth root of the heating rate; therefore, except in particular cases, it will be difficult to make use of this effect in the design of thermal protection systems. Effects of radiation from a hot gas layer to the ablating surface are investigated by an approximate procedure. The efficiency of ablation is found to approach a maximum value which depends on the ratio of radiant heating to aerodynamic heating and is independent of the enthalpy difference across the boundary layer.
A typical section model is used to analytically investigate the effect of mass balancing as applied to hollow, supersonic fan blades. A procedure to determine the best configuration of an internal balancing mass to provide flutter alleviation is developed. This procedure is applied to a typical supersonic shroudless fan blade which is unstable in both the solid configuration and when it is hollow with no balancing mass. The addition of an optimized balancing mass is shown to stabilize the blade at the design condition.
A typical section model is used to analytically investigate the effect of mass balancing as applied to hollow, supersonic fan blades. A procedure to determine the best configuration of an internal balancing mass to provide flutter alleviation is developed. This procedure is applied to a typical supersonic shroudless fan blade which is unstable in both the solid configuration and when it is hollow with no balancing mass. The addition of an optimized balancing mass is shown to stabilize the blade at the design condition.
We report on our investigation of low-energy pion-nucleon scattering from lattice QCD with Wilson type fermions. Our focus is on the isospin I = 3/2 channel, which couples to the Delta resonance. We discuss our calculations aiming at the extraction of the Delta resonance mass, width and effective coupling at pion mass 250 MeV, using the Lüscher finite-volume method to extract the phase shift δ J=3/2,l=1 .
An apparatus to stabilize a fine platform that carries a parabolic reflecting dish, utilized in connection with the large aperture, multichannel microwave radiometer, is discussed. It provides compensation for dynamic unbalance imparted to a fixed body by a shaft about which the rotating body rotates. Force components exerted on the fixed body by the rotating body in a plane at right angles to the axis are determined. In response to the determined force components, the rotational speed and effective direction of mass means mounted on the rotating body are controlled. The mass means has an effective axis of rotation in a plane at right angles to the longitudinal axis.
Sedimentary activity (erosion, transportation and deposition) is a major landscape-shaping process on many icy worlds of the outer solar system for which an understanding of this process is central to their geologic characterizations. Several recent studies, lead by the authors, have identified the effects of sedimentary activity on icy satellite landforms and recognized the role of mass wasting and volatile loss and redistribution in the evolution of these features. We apply state of the art, physics based, landform evolution modeling to icy satellite sedimentary landforms in order to fully quantitatively characterize how their morphologies change with time, and what their present appearances imply for the initial abundance and distribution of loose material, volatiles, and refractories in original pristine landforms. We will present results of our landform evolution modeling to the development of the landscapes of the Saturnian moons of Hyperion and Helene. Our current conclusions for Hyperion are that its unique appearance can be explained in part by the loss to space of ballistic ejecta during impact events. In order to create the smooth surfaces and the reticulate, honeycomb pattern of narrow divides between old craters, appreciable subsequent modification of crater morphology must occur through mass-wasting processes accompanied by sublimation, probably facilitated by the loss of CO2 as a component of the relief-supporting matrix of the bedrock. This mass wasting effectively destroys small craters, at least in part accounting for the paucity of sub-kilometer craters on Hyperion. Helene’s unusual morphology consists of broad depressions (modified large craters) and a generally smooth surface patterned with streaks and grooves. The streaks appear to be oriented down-gradient, as are the grooves. This pattern suggests intensive mass-wasting as a dominant process. Our initial modeling of this surface suggests a Bingham-like rheological behavior for the loose down-slope moving material. Interestingly, as a Bingham flow, the models indicate that aperiodic "intermittent" behavior to be present, suggesting that periods of quiet steady landform evolution are punctuated short periods of active surface readjustment.
Gradients in the stellar populations (SP) of galaxies – e.g. in age, metallicity, stellar initial mass function (IMF) – can result in gradients in the stellar-mass-to-light ratio, M * / L . Such gradients imply that the distribution of the stellar mass and light is different. For old SPs, e.g. in early-type galaxies at z ∼ 0, the M * / L gradients are weak if driven by variations in age and metallicity, but significantly larger if driven by the IMF. A gradient which has larger M * / L in the centre increases the estimated total stellar mass ( M * ) and reduces the scale which contains half this mass ( R e,* ), compared to when the gradient is ignored. For the IMF gradients inferred from fitting MILES simple SP models to the H β, 〈Fe〉, [MgFe], and TiO 2SDSS absorption lines measured in spatially resolved spectra of early-type galaxies in the MaNGA survey, the fractional change in R e,* can be significantly larger than that in M * , especially when the light is more centrally concentrated. The R e,* – M * correlation which results from accounting for IMF gradients is offset to smaller sizes by 0.3 dex compared to when these gradients are ignored. Comparisons with ‘quiescent’ galaxies at higher z must account for evolution in SP gradients (especially age and IMF) and in the light profile before drawing conclusions about how R e,* and M * evolve. Here, the implied merging between higher z and the present is less contrived if R e,* / R e at z ∼ 0 is closer to our IMF-driven gradient calibration than to unity.
Surface property effects on effectiveness of mass transfer cooling in laminar boundary layers with hydrogen injected into free stream of nitrogen or carbon dioxide
Two global ocean general circulation models have been used to compute the angular momentum of nontidal oceanic current and sea level height variations: (1) the Princeton Modular Ocean Model (MOM) having 22 vertical layers and a rigid lid, and (2) the Miami Isopycnic-Coordinate Ocean Model (MICOM) having 11 vertical layers with a mixed layer and a free surface. Both models were run on the same 2 degree longitude by 1 degree latitude grid spanning 80 S to 80 N latitude. Following a 10-year spin-up with climatological air-sea fluxes, both models were forced during 1992-1994 with daily wind and heat flux from the NCEP operational analysis and sea surface salinity restoring to Levitus climatology. After correcting for the effects of mass non-conservation in these models, they are shown to predict similar effects on polar motion excitation of sea level height variations, but the effect of currents predicted by MOM is much larger than that predicted by MICOM.