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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 559 records · Page 31
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

The effect of compositionally-generated elastic stresses on morphological instability during directional solidification

The effect of compositionally-generated elastic stresses on the conditions for morphological instability during directional solidification of a dilute, ideal binary alloy is investigated using the Gibbs-Thomson equations for an elastically-stressed solid with zero surface stress in equilibrium with a liquid. It is found that these stresses lead to a small stabilization of the Mullins and Sekerka cellular mode of instability. The steady mode is stabilized by a stress-induced modification to the interfacial concentration of the solid, which in turn alters the amount of solute rejected to inhibit the growth of perturbations. The presence of elastic stresses could generate a new oscillatory instability which is most likely to be found in experiments near absolute stability for materials with segregation coefficients near unity and large solute expansion coefficients.

Spencer, B. J.↗
DOE OSTI2020

Fast Determination of Lithium Content in Spent Cathodes for Direct Battery Recycling

Determination of the lithium ion content in cathode materials, which is currently performed by inductively coupled plasma mass spectrometry (ICP-MS), involves tedious procedures and error-prone preparation. This work introduces a new methodology to quickly determine the lithium content in spent cathode materials (LiNix Mny Coz O2, x + y + z = 1, NMC) using a thermalgravimetric analysis, which bypasses the use of ICP-MS and significantly reduces the cost and time required for determining the lithium content. Based on this new method, a new approach is developed to identify spent cathode materials suitable for direct relithiation recycling. Finally, these new methods have been applied to investigate the effectiveness of direct electrochemical-relithiation on recycling the spent cathodes, and provide insights for future development of direct battery materials recycling.

cathode recycling↗
NASA NTRS1987

Growth of Metastable Peritectic Alloys

Effects of directional solidification on microstructural, compositional, and magnetic properties studied. Two reports describe experiments to determine effects of directional solidification on peritectic alloys. Of particular interest were effects of gravitationally driven convection.

Larson, David J., Jr.↗
DOE OSTI2022

Superfluid effective field theory for dark matter direct detection

We develop an effective field theory (EFT) framework for superfluid 4 He to model the interactions among quasiparticles, helium atoms and probe particles. Our effective field theory approach brings together symmetry arguments and power-counting and matches to classical fluid dynamics. We then present the decay and scattering rates for the relevant processes involving quasiparticles and helium atoms. The presented EFT framework and results can be used to understand the dynamics of thermalization in the superfluid, and can be further applied to sub-GeV dark matter direct detection with superfluid 4 He.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1973

Low-speed wind tunnel investigation of the lateral-directional characterisitcs of a large-scale variable wing-sweep fighter model in the high-lift configuration

The low-speed characteristics of a large-scale model of the F-14A aircraft were studied in tests conducted in the Ames Research Center 40- by 80-Foot Wind Tunnel. The primary purpose of the present tests was the determination of lateral-directional stability levels and control effectiveness of the aircraft in its high-lift configuration. Tests were conducted at wing angles of attack between minus 2 deg and 30 deg and with sideslip angles between minus 12 deg and 12 deg. Data were taken at a Reynolds number of 8.0 million based on a wing mean aerodynamic chord of 2.24 m (7.36 ft). The model configuration was changed as required to show the effects of direct lift control (spoilers) at yaw, yaw angle with speed brake deflected, and various amounts and combinations of roll control.

Eckert, W. T.↗
DOE OSTI2025

Direct evidence of the effect of a moderate external magnetic field on stimulated Raman scattering in the kinetic regime

We present results from an experiment carried out at the OMEGA-EP laser facility that investigated the effect of a perpendicular magnetic field on stimulated Raman scattering (SRS) and report the first direct measurement of magnetic mitigation of SRS. A 13-T magnetic field generated by pulsed-power coils was imposed on a gas jet plasma, and a novel three-picket interaction beam was used to explore SRS reflectivity for several plasma conditions within single shots. The time-resolved backscattered light shows that SRS was mitigated by the external 13-T magnetic field in the kinetic regime (kλ D ∼ 0.3, where k is the electron plasma wave's wavenumber and λ D is electron Debye length) and at a density of n e /n cr ∼ 0.10. On the other hand, we also measured an enhancement of SRS reflectivity at lower density (n e /n cr < 0.08). We discuss experimental results in the context of magnetohydrodynamic and particle-in-cell simulations that scan SRS dynamics for a variety of plasma conditions. While the experimental evidence of SRS mitigation validates prior work on the kinetic simulation of SRS in an external magnetic field, we also find that other mechanisms such as SRS rescatter can lead to an enhancement of measured SRS reflectivity in simulations of parameters relevant to our experiment.

Gas jet↗
NASA NTRS1985

Cellular interface morphologies in directional solidification. III - The effects of heat transfer and solid diffusivity

The shape and stability of two-dimensional finite-amplitude cellular interfaces arising during directional solidification are compared for several solidification models that account differently for latent heat released at the interface, unequal thermal conductivities of melt and solid, and solute diffusivity in the solid. Finite-element analysis and computer-implemented perturbation methods are used to analyze the families of steadily growing cellular forms that evolve from the planar state. In all models a secondary bifurcation between different families of finite-amplitude cells exists that halves the spatial wavelength of the stable interface. The quantitative location of this transition is very dependent on the details of the model. Large amounts of solute diffusion in the solid retard the growth of large-amplitude cells.

Ungar, Lyle H.↗
DOE OSTI2024

Chemical control of excited-state reactivity of the anionic green fluorescent protein chromophore

Controlling excited-state reactivity is a long-standing challenge in photochemistry, as a desired pathway may be inaccessible or compete with other unwanted channels. An important example is internal conversion of the anionic green fluorescent protein (GFP) chromophore where non-selective progress along two competing torsional modes (P: phenolate and I: imidazolinone) impairs and enables Z-to-E photoisomerization, respectively. Developing strategies to promote photoisomerization could drive new areas of applications of GFP-like proteins. Motivated by the charge-transfer dichotomy of the torsional modes, we explore chemical substitution on the P-ring of the chromophore as a way to control excited-state pathways and improve photoisomerization. As demonstrated by methoxylation, selective P-twisting appears difficult to achieve because the electron-donating potential effects of the substituents are counteracted by inertial effects that directly retard the motion. Conversely, these effects act in concert to promote I-twisting when introducing electron-withdrawing groups. Specifically, 2,3,5-trifluorination leads to both pathway selectivity and a more direct approach to the I-twisted intersection which, in turn, doubles the photoisomerization quantum yield. Our results suggest P-ring engineering as an effective approach to boost photoisomerization of the anionic GFP chromophore.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2004

Theoretical and Observational Determination of Global and Regional Radiation Budget, Forcing and Feedbacks at the Top-of-Atmosphere and Surface

Report consists of: 1. List of accomplishments 2. List of publications 3. Abstracts of published or submitted papers and 4. Subject invention disclosure. The accomplishments of the grant listed are: 1. Improved the third-order turbulence closure in cloud resolving models to remove the liquid water oscillation. 2. Used the University of California-Los Angeles (UCLA) large-eddy simulation (LES) model to provide data for radiation transfer testing. 3. Revised shortwave k-distribution models based on HITRAN 2000. 4. Developed a gamma-weighted two-stream radiative transfer model for radiation budget estimate applications. 5. Estimated the effect of spherical geometry to the earth radiation budget. 6. Estimated top-of-atmosphere irradiance over snow and sea ice surfaces. 7. Estimated the aerosol direct radiative effect at the top of the atmosphere. 8. Estimated the top-of-atmosphere reflectance of the clear-sky molecular atmosphere over ocean. 9. Developed and validated new set of Angular Distribution Models for the CERES TRMM satellite instrument (tropical) 10. Developed and validated new set of Angular Distribution Models for the CERES Terra satellite instrument (global) 11. Quantified the top-of-atmosphere direct radiative effect of aerosols over global oceans from merged CERES and MODIS observations 12 Clarified the definition of TOA flux reference level for radiation budget studies 13. Developed new algorithm for unfaltering CERES measured radiances 14. Used multiangle POLDER measurements to produce narrowband angular distribution models and examine the effect of scene identification errors on TOA albedo estimates 15. Developed and validated a novel algorithm called the Multidirectional Reflectance Matching (MRM) model for inferring TOA albedos from ice clouds using multi-angle satellite measurements. 16. Developed and validated a novel algorithm called the Multidirectional Polarized Reflectance Matching (MPRM) model for inferring particle shapes from ice clouds using multi-angle polarized satellite measurements. 17. Developed 4 advanced light scattering models including the three-dimensional (3D) uniaxial perfectly matched layer (UPML) finite-difference time-domain (FDTD) model. 18. Develop sunglint in situ measurement and study reflectance distribution in the sunglint area. 19. Lead a balloon-borne radiometer TOA albedo validation effort. 20. Developed a CERES surface UVB, UVA, and UV index product.

Loeb, Norman G.↗
NASA NTRS2011

Simulated Seasonal Spatio-Temporal Patterns of Soil Moisture, Temperature, and Net Radiation in a Deciduous Forest

The temperature and moisture regimes in a forest are key components in the forest ecosystem dynamics. Observations and studies indicate that the internal temperature distribution and moisture content of the tree influence not only growth and development, but onset and cessation of cambial activity [1], resistance to insect predation[2], and even affect the population dynamics of the insects [3]. Moreover, temperature directly affects the uptake and metabolism of population from the soil into the tree tissue [4]. Additional studies show that soil and atmospheric temperatures are significant parameters that limit the growth of trees and impose treeline elevation limitation [5]. Directional thermal infrared radiance effects have long been observed in natural backgrounds [6]. In earlier work, we illustrated the use of physically-based models to simulate directional effects in thermal imaging [7-8]. In this paper, we illustrated the use of physically-based models to simulate directional effects in thermal, and net radiation in a adeciduous forest using our recently developed three-dimensional, macro-scale computational tool that simulates the heat and mass transfer interaction in a soil-root-stem systems (SRSS). The SRSS model includes the coupling of existing heat and mass transport tools to stimulate the diurnal internal and external temperatures, internal fluid flow and moisture distribution, and heat flow in the system.

Ballard, Jerrell R., Jr.↗
NASA NTRS1981

Experiment K-313: Rat and quail ontogenesis

The potential effects of spaceflight on the processes of mammalian fertilizaton, implantation and embryonic development are investigated. Five female and two male rats were placed together on Day 2 of the flight. By R+17, it was determined that both flight and synchronous females were not carrying normal pregnancies and three of the flight animals were laparotomized. The uterus and ovaries were processed for microscopic analyses. The two remaining flight females were allowed to recover from the exploratory operation, rebred with flight males and delivered normal litters. As a control for potential transplacental effects that might be interpreted as direct spaceflight effects, a series of fertilized Japanese quail (Coturnix japonica) eggs was flown on Cosmos 1129. Although all of the eggs were adversely impacted by an inflight failure of the incubator humidifier on flight Day 13, several embryos were able to progress to a developmental stage equivalent to that of a control 10-12 Day embryo.

Keefe, J. R.↗
NASA NTRS2008

MESSENGER Observation of Mercury's Magnetopause: Structure and Dynamics

MESSENGER'S 14 January 2008 encounter with Mercury has provided new observations of the magnetopause of this small magnetosphere, particularly concerning the effect of the direction of the interplanetary magnetic field (IMF) on the structure and dynamics of this boundary. The IMF was northward immediately prior to and following the passage of the MESSENGER spacecraft through Mercury's magnetosphere. However, several-minute episodes of southward IMF were observed in the magnetosheath during the inbound portion of the encounter. Evidence for reconnection at the dayside magnetopause in the form of well-developed flux transfer events (FTEs) was observed in the magnetosheath following some of these southward-B, intervals. The inbound magnetopause crossing seen in the magnetic field measurements is consistent with a transition from the magnetosheath into the plasma sheet. Immediately following MESSENGER'S entry into the magnetosphere, rotational perturbations in the magnetic field similar to those seen at the Earth in association with large-scale plasma sheet vortices driven by Kelvin-Helmholtz waves along the magnetotail boundary at the Earth were observed. The outbound magnetopause occurred during northward IMF B(sub z) and had the characteristics of a tangential discontinuity. These new observations by MESSENGER may be combined and compared with the magnetopause measurements collected by Mariner 10 to derive new understanding of the response of Mercury's magnetopause to IMF direction and its effect on the rate of solar wind energy and mass input to this small magnetosphere.

Slavin, J. A.↗
DOE OSTI2025

Propylamine Functionalized Porous Fiber Sorbents with High Oxidation Stability for Direct Air Capture

Amine-based sorbents are highly effective for direct air capture (DAC) due to their excellent CO2 capture efficiency under ultra-dilute conditions. However, these sorbents can suffer degradation when exposed to combinations of heat, oxygen, and other atmospheric components, indicating a need for improved sorbent stability. In this study, we developed amidoxime functionalized polymer of intrinsic microporosity (PIM-1-AO) fibers with tethered amines, specifically tris(2-aminoethyl)amine (TAEA) and tris(3-aminopropyl)amine (TAPA), denoted as PIM-1-AO-TAEA and PIM-1-AO-TAPA, respectively. In addition, large scale sorbent fiber spinning has been successfully performed by producing meters of fibers in the lab. We demonstrated that substituting TAEA with TAPA, which has propyl chains instead of ethyl chains, reduces oxidative degradation under regeneration conditions. The findings revealed that PIM-1-AO-TAPA not only significantly outperforms PIM-1-AO-TAEA after accelerated aging process, but also outperforms any other sorbent used in DAC aged under similar conditions. Moreover, PIM-1-AO-TAPA sorbent fibers showed one of the highest amine efficiencies (0.25) considering the low amine loading (21%) coupled with robust CO2 uptake performance (1.12 mmol/g) under DAC conditions.

amine-based sorbent↗
DOE OSTI2022

Effect of dust on rainfall over the Red Sea coast based on WRF-Chem model simulations

Water is the single most important element of life. Rainfall plays an important role in the spatial and temporal distribution of this precious natural resource, and it has a direct impact on agricultural production, daily life activities, and human health. One of the important elements that govern rainfall formation and distribution is atmospheric aerosol, which also affects the Earth's radiation balance and climate. Therefore, understanding how dust compositions and distributions affect the regional rainfall pattern is crucial, particularly in regions with high atmospheric dust loads such as the Middle East. Although aerosol and rainfall research has garnered increasing attention as both an independent and interdisciplinary topic in the last few decades, the details of various direct and indirect pathways by which dust affects rainfall are not yet fully understood. Here, we explored the effects of dust on rainfall formation and distribution as well as the physical mechanisms that govern these phenomena, using high-resolution WRF-Chem simulations (~1.5 km × 1.5 km) configured with an advanced double-moment cloud microphysics scheme coupled with a sectional eight-bin aerosol scheme. Our model-simulated results were realistic, as evaluated from multiple perspectives including vertical profiles of aerosol concentrations, aerosol size distributions, vertical profiles of air temperature, diurnal wind cycles, and spatio-temporal rainfall patterns. Rainfall over the Red Sea coast is mainly caused by warm rain processes, which are typically confined within a height of ~6 km over the Sarawat mountains and exhibit a strong diurnal cycle that peaks in the evening at approximately 18:00 local time under the influence of sea breezes. Numerical experiments indicated that dust could both suppress or enhance rainfall. The effect of dust on rainfall was calculated as total, indirect, and direct effects, based on 10-year August-average daily-accumulated rainfall over the study domain covering the eastern Red Sea coast. For extreme rainfall events (domain-average daily-accumulated rainfall of ≥ 1.33 mm), the net effect of dust on rainfall was positive or enhancement (6.05 %), with the indirect effect (4.54 %) and direct effect (1.51 %) both causing rainfall increase. At a 5 % significance level, the total and indirect effects were statistically significant whereas the direct effect was not. For normal rainfall events (domain-average daily-accumulated rainfall < 1.33 mm), the indirect effect enhanced rainfall (4.76 %) whereas the direct effect suppressed rainfall (-5.78 %), resulting in a negative net suppressing effect (-1.02 %), all of which were statistically significant. We investigated the possible physical mechanisms of the effects and found that the rainfall suppression by dust direct effects was mainly caused by the scattering of solar radiation by dust. The surface cooling induced by dust weakens the sea breeze circulation, which decreases the associated landward moisture transport, ultimately suppressing rainfall. For extreme rainfall events, dust causes net rainfall enhancement through indirect effects as the high dust concentration facilitates raindrops to grow when the water vapor is sufficiently available. Our results have broader scientific and environmental implications. Specifically, although dust is considered a problem from an air quality perspective, our results highlight the important role of dust on sea breeze circulation and associated rainfall over the Red Sea coastal regions. Our results also have implications for cloud seeding and water resource management.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2010

A Global Modeling Study on Carbonaceous Aerosol Microphysical Characteristics and Radiative Effects

Recently, attention has been drawn towards black carbon aerosols as a short-term climate warming mitigation candidate. However the global and regional impacts of the direct, indirect and semi-direct aerosol effects are highly uncertain, due to the complex nature of aerosol evolution and the way that mixed, aged aerosols interact with clouds and radiation. A detailed aerosol microphysical scheme, MATRIX, embedded within the GISS climate model is used in this study to present a quantitative assessment of the impact of microphysical processes involving black carbon, such as emission size distributions and optical properties on aerosol cloud activation and radiative effects. Our best estimate for net direct and indirect aerosol radiative flux change between 1750 and 2000 is -0.56 W/m2. However, the direct and indirect aerosol effects are quite sensitive to the black and organic carbon size distribution and consequential mixing state. The net radiative flux change can vary between -0.32 to -0.75 W/m2 depending on these carbonaceous particle properties at emission. Taking into account internally mixed black carbon particles let us simulate correct aerosol absorption. Absorption of black carbon aerosols is amplified by sulfate and nitrate coatings and, even more strongly, by organic coatings. Black carbon mitigation scenarios generally showed reduced radiative fluxeswhen sources with a large proportion of black carbon, such as diesel, are reduced; however reducing sources with a larger organic carbon component as well, such as bio-fuels, does not necessarily lead to a reduction in positive radiative flux.

Bauer, S. E.↗