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At least 559 records · Page 31

Thermogravimetry system designed for use in dispersion strengthening studies.

A thermogravimetry system, designed to study the reduction of oxides in metal and alloy powders to be used in dispersion strengthened materials, is described. The apparatus was devised for use at high temperatures with controlled atmospheres. Experimental weight change and moisture evolution results for the thermal decomposition of calcium oxalate monohydrate in dry helium, and experimental weight change results for the reduction of nickel oxide in dry hydrogen and hydrogen containing 15,000 p.p.m. water vapor are presented. The system is currently being successfully applied to the evaluation of the reduction characteristics and the removal of impurities from metals and alloys to be used for dispersion strengthening.

Herbell, T. P.↗

On the elastic properties of fiber composite laminates with statistically dispersed fiber and ply orientations.

Structural application of advanced composite filamentary materials requires lamination of the basic orthotropic plies into angle-ply laminates. This article reviews the effect on elastic properties of orientation dispersion. The conventional constitutive relations are recast in a homologous form to account for uniform orientation dispersion by addition of a single parameter. Graphical results are presented to show the behavior of the most important advanced composite materials. The results are directly useful for estimating effects of manufacturing inaccuracy and for design of partially oriented reinforced structures.

Robinson, E. Y.↗

An association of magnetospheric whistler dispersion characteristics with changes in local plasma density.

We use OGO 5 measurements made within the plasmapause on May 15, 1969, to investigate the possible association between changes in lightning whistler dispersion characteristics and local density fluctuations. It is shown that groups of whistlers with relatively constant dispersions tended to be detected in regions where the local ion concentration was significantly enhanced. It is assumed that these local density fluctuations represent characteristics of large-scale field-aligned variations. The results are then compared with ray refraction estimates appropriate for low-frequency whistler mode propagation (wave components with frequencies comparable to the local lower hybrid frequency) in a nonuniform medium.

Scarf, F. L.↗

Monitoring the dispersion of ocean waste disposal plumes from ERTS-1 and Skylab

The author has identified the following significant results. About forty miles off the Delaware coast is located the disposal site for waste discharged from a plant processing titanium dioxide. The discharge is a greenish-brown; 15-20% acid liquid which consists primarily of iron chlorides and sulfates. The barge which transports this waste has a 1,000,000 gallon capacity and makes approximately three trips to the disposal site per week. ERTS-1 MSS digital tapes are being used to study the dispersion patterns and drift velocities of the iron-acid plume. Careful examination of ERTS-1 imagery disclosed a fishhook-shaped plume about 40 miles east of Cape Henlopen caused by a barge disposing acid wastes. The plume shows up more strongly in the green band than in the red band. Since some acids have a strong green component during dumping and turn slowly more brownish-reddish with age, the ratio of radiance signatures between the green and red bands may give an indication of how long before the satellite overpass the acid was dumped. Enlarged enhancements of the acid waste plumes, prepared from the ERTS-1 MSS digital tapes aided considerably in studies of the dispersion of the waste plume. Currently acid dumps are being coordinated with ERTS-1 overpasses.

Klemas, V.↗

Dispersion strengthened nickel-yttria sheet alloy produced from comminuted powders

Report on initial efforts to dispersion-strengthen nickel with Y2O3 in an attempt to replace radioactive ThO2 as the strengthening phase in dispersion-strengthened alloys. Nickel-Y2O3 powders were processed by the NASA comminution and blending (NASCAB) method and subsequently thermomechanically worked. Experimental variables included volume per cent Y2O3 (2% and 4%), powder cleaning temperature (315, 371, and 426 C), a screening step in the process, and the number (up to 23) of cold-roll-anneal cycles. Tensile strengths, determined at 1093 C, as well as some stress-rupture life data, are presented.

Sikora, P. F.↗

The effects of dispersed oxides on the oxidation characteristics of superalloys

The high-temperature oxidation behavior of thoriated nickel and chromium superalloys is discussed on the basis of scanning electron micrographs and other experimental data. The beneficial effects of dispersed oxide particles are identified as a lower chromium content needed for the formation of external scale, an increased adhesion of scale, and lower growth rates of chromia as compared with those in alloys without dispersed oxide particles.

Jaffee, R. I.↗

Ultrasonic dispersion (delta V/V) determined from mechanical resonance frequency shifts

With standing wave ultrasonic techniques, small changes in phase velocity which result from changes in some external parameter (e.g., temperature or magnetic field) have traditionally been determined by observing shifts in the mechanical resonance frequency of a composite resonator. Some previous investigators have assumed that the fractional change in velocity is equal to the fractional change in frequency. Substantially improved formulas for determining the dispersion are presented and one of these is shown to be much more accurate than all previous approximations. The results of simulated and actual experiments over wide ranges of dispersion, transducer loading parameter, and frequency are analyzed in order to compare the errors inherent in the various approximations.

Moerner, W. E.↗

Amplification, attenuation, and dispersion of sound in inhomogeneous flows

First order effects of gradients in nonuniform potential flows of a compressible gas are included in a dispersion relation for sound waves. Three nondimensional numbers, the ratio of the change in the kinetic energy in one wavelength to the thermal energy of the gas, the ratio of the change in the total energy in one wavelength to the thermal energy, and the ratio of the dillatation frequency (the rate of expansion per unit volume) to the acoustic frequency, play a role in the separation of the effects of flow gradients into isotropic and anisotropic effects. Dispersion and attenuation (or amplification) of sound are found to be proportional to the wavelength for small wavelength, and depend on the direction of wave propagation relative to flow gradients. Modification of ray acoustics for the effects of flow gradients is suggested, and conditions for amplification and attenuation of sound are discussed.

Kentzer, C. P.↗

The stability of liquid dispersions in low gravity

The stability of three different dispersions of oil and water prepared on Skylab 4 is compared with the same dispersions made on earth. The stability of the emulsions has been studied by two independent optical techniques. An analysis of the data indicates that all the investigated emulsions were stable over a period of 10 hr, whereas the fluids separated completely on earth in 10 sec. This experiment indicates that the rate of coalescence in low gravity is at least 3 millionths times that on earth. A knowledge of the coalescence rate in low gravity is important in the solidification of immiscible alloys in space. The parameters obtained for this experiment are compared with those of liquid metals to determine if the same stability could be achieved with immiscible alloys.

Lacy, L. L.↗

Dispersion forces at arbitrary distances

The formalism of Boehm and Yaris is used to evaluate explicitly the leading term of the London dispersion force between closed-shell atoms. Instead of using the usual multipole expansion, which breaks down at intermediate internuclear distances, an analytic representation of the Born amplitude together with a general angular momentum analysis is used. As a result, expressions are obtained which reduce to the usual dispersion forces at large distances and are finite at all distances.

Jacobi, N.↗

Ultrasonic dispersion determined from mechanical resonance frequency shifts

With standing wave ultrasonic techniques, small changes in phase velocity which result from changes in some external parameter (e.g., temperature or magnetic field) have traditionally been determined by observing shifts in the mechanical resonance frequency of a composite resonator. Some previous investigators have assumed that the fractional change in velocity is equal to the fractional change in frequency. We discuss quantitatively the errors involved in such an approach, showing that it leads to substantial inaccuracies when the loading effect of the transducer(s) cannot be neglected. Substantially improved formulas for determining the dispersion are presented and one of these is shown to be much more accurate than all previous approximations. The results of simulated and actual experiments over wide ranges of dispersion, transducer loading parameter, and frequency are analyzed in order to compare the errors inherent in the various approximations.

Moerner, W. E.↗

Structure-property relationships in thermomechanically treated beryllia dispersed nickel alloys

BeO dispersed nickel alloys, produced by powder metallurgy techniques, were studied extensively in stress rupture at 815, 982, and 1093 C (1088, 1255, and 1366 K) and by transmission electron microscopy. The alloys were subjected to a variety of thermomechanical treatments (TMT) to determine the benefits of TMT on properties. It is shown that the use of intermediate annealing treatments after 10 pct reduction steps is highly beneficial on both low and high temperature properties. It is indicated that the high temperature strength is not primarily dependent on the grain aspect ratio or texture but depends strongly on the dislocation density and distribution of dislocations in a stable substructure which is pinned by the fine oxide dispersion.

Grewal, M. S.↗

Amplification, attenuation, and dispersion of sound in inhomogeneous flows

First order effects of gradients in nonuniform potential flows of a compressible gas are included in a dispersion relation for sound waves. Three nondimensional numbers, the ratio of the change in the kinetic energy in one wavelength to the thermal energy of the gas, the ratio of the change in the total energy in one wavelength to the thermal energy, and the ratio of the dilatation frequency (the rate of expansion per unit volume) to the acoustic frequency, play the dominant role permitting the separation of the effects of flow gradients into isotropic and anisotropic effects. Dispersion and attenuation (or amplification) of sound are proportional to the wavelength for small wavelength and depend on the direction of wave propagation relative to flow gradients. Modification of ray acoustics for the effects of flow gradients is suggested and conditions for amplification and attenuation of sound are discussed.

Kentzer, C. P.↗

Preliminary study of oxide-dispersion-strengthened B-1900 prepared by mechanical alloys

An experimental oxide dispersion strengthened (ODS) alloy based on the B-1900 composition was produced by the mechanical alloying process. Without optimization of the processing for the alloy or the alloy for the processing, recrystallization of the extruded product to large elongated grains was achieved. Materials having grain length-width ratios of 3 and 5.5 were tested in tension and stress-rupture. The ODS B-1900 exhibited tensile strength similar to that of cast B-1900. Its stress-rupture life was lower than that of cast B-1900 at 760 C. At 1095 C the ODS B-1900 with the higher grain length-width ratio (5.5) had stress-rupture life superior to that of cast B-1900. It was concluded that, with optimization, oxide dispersion strengthening of B-1900 and other complex cast nickel-base alloys has potential for improving high temperature properties over those of the cast alloy counterparts.

Glasgow, T. K.↗

ASTP (SA-210) launch vehicle operational flight trajectory dispersion analysis, volume 1

In order to establish realistic deviation limits for the ASTP (SA-210) Launch Vehicle Operational Flight Trajectory, a dispersion analysis was conducted. The nominal trajectory prescribed for this analysis is the ASTP (SA-210) Launch Vehicle 500 Pound Launch Window Opening OT. The error sources considered are those associated with predictions of vehicle characteristics, vehicle systems performance, and flight environment. The nominal vehicle, the boost trajectory simulations, the error sources, the analytic procedures utilized, and the results are discussed. Launch vehicle guidance system inaccuracies were determined from the guidance error analysis. These data are composed of individual error source trajectory parameter dispersion envelopes.

Williams, N. D.↗

The influence of coastal fronts on the movement and dispersion of oil slicks

The author has identified the following significant results. LANDSAT, aircraft, and boats were used successfully to study estuarine and coastal fronts or boundaries. Horizontal salinity gradients of 4% in one meter and convergence velocities of the order of 0.1 m/sec were observed. Visibility improved from one meter to two meters as certain boundaries were crossed. Fronts near the mouth of the bay are associated with the tidal exchange with shelf water. By capturing and holding oil slicks, these frontal systems also significantly influence the movement and dispersion of oil slicks in Delaware Bay. Recent oil slick tracking experiments conducted to verify a predictive oil dispersion and movement model have shown that during certain parts of the tidal cycle the oil slicks tend to line up along boundaries.

Klemas, V.↗

An oxide dispersion strengthened Ni-W-Al alloy with superior high temperature strength

An experimental oxide dispersion strengthened (ODS) alloy, WAZ-D, derived from the WAZ-20 composition was produced by the mechanical alloying process. Cast WAZ-20 is strengthened by both a high refractory metal content, and 70 volume percent of gamma prime. The ODS alloy WAZ-D was responsive to variables of alloy content, of attritor processing, of consolidation by extrusion, and of heat treatment. The best material produced had large highly elongated grains. It exhibited tensile strengths generally superior to a comparable cast alloy. The ODS alloy exhibited high temperature stress rupture life considerably superior to any known cast superalloy. Tensile and rupture ductility were low, as was intermediate temperature rupture life. Very low creep rates were noted and some specimens failed with essentially no third stage creep. Also the benefit derived from the oxide dispersion, far out-weighed that from the elongated microstructure alone.

Glasgow, T. K.↗

Dispersion analysis for baseline reference mission 3A with 400,000 foot entry interface altitude

A dispersion analysis considering 3 beta uncertainties in platform, vehicle, and environmental parameters is described. Powered explicit guidance used to develop closed loop steering commands, the nominal profile, and entry interface conditions are discussed. The groundrules and assumptions for the analysis are reviewed. The results presented include dispersion data at specific time slices from liftoff to entry interface, covariance matrices, summary data, and exchange ratios.

Snow, L. S.↗