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542 records · Page 31

Evaluation of the GEOS-Chem UCX Stratosphere in the GEOS Composition Forecast System

The NASA GEOS Composition Forecast (GEOS-CF) system provides 3-dimensional atmospheric composition analyses and forecasts to the public in near-real time at the high spatial resolution of 25 km. While the main focus of this new product is on tropospheric air quality information, the GEOS-Chem chemistry model (v12) used in this system includes the UCX stratospheric chemistry mechanism. Here, we describe the GEOS-CF system and provide comparisons against remote-sensed observations for stratospheric composition, including measurements of HCl, ClO, NO2, and O3. The GEOS-CF nudges the stratospheric ozone towards the GEOS Forward Processing (GEOS FP) assimilated ozone product; as a result the stratospheric ozone analysis in theGEOS-CF agrees well with observations. Additionally, with the inclusion of the GEOS-Chem UCX stratospheric chemistry mechanism in GEOS-CF, 5-day forecasts, especially during the abnormal 2020 NH polar spring, capture the chemical and dynamical changes missed by the GEOS FP system, which tends towards climatology. The GEOS-CF is a new tool for the research community providing near-real time 3-dimensional gridded information on atmospheric composition throughout the troposphere and stratosphere.

Stratosphere↗

Barium Chloride Based Pyrotechnic Compositions for Green Color Emissions

<p style="text-align: justify;"><span style="color: black; font-family: Calibri; font-size: 12pt;">Here, we present research focusing on the green light emission using Barium chloride dihydrate (BaCl</span><sub style="color: black; font-family: Calibri; font-size: 8pt;">2</sub><span style="color: black; font-family: Calibri; font-size: 12pt;">.2H</span><sub style="color: black; font-family: Calibri; font-size: 8pt;">2</sub><span style="color: black; font-family: Calibri; font-size: 12pt;">O) as an emitter contrary to commonly used Ba(NO</span><sub style="color: black; font-family: Calibri; font-size: 8pt;">3</sub><span style="color: black; font-family: Calibri; font-size: 12pt;">)</span><sub style="color: black; font-family: Calibri; font-size: 8pt;">2</sub><span style="color: black; font-family: Calibri; font-size: 12pt;">, Ba(ClO</span><sub style="color: black; font-family: Calibri; font-size: 8pt;">3</sub><span style="color: black; font-family: Calibri; font-size: 12pt;">)</span><sub style="color: black; font-family: Calibri; font-size: 8pt;">2</sub><span style="color: black; font-family: Calibri; font-size: 12pt;">, BaCO</span><span style="color: black; font-family: Calibri; font-size: 8pt;">3</span><span style="color: black; font-family: Calibri; font-size: 12pt;">, etc. For this work, different compositions containing BaCl</span><sub style="color: black; font-family: Calibri; font-size: 8pt;">2</sub><span style="color: black; font-family: Calibri; font-size: 12pt;">.2H</span><sub style="color: black; font-family: Calibri; font-size: 8pt;">2</sub><span style="color: black; font-family: Calibri; font-size: 12pt;">O and other components acting as oxidant, fuel, etc. were made and analyzed using TGA and burning tests. The flame intensity was captured using a photocell attached with a green color filter. It was observed that the decomposition behavior and the flame intensity were strongly influenced by the ratio of barium chloride to the oxidizer and by the particle size of the pyrotechnic composition powder. Compositions having a higher amount of oxidizer were found to decompose faster and have a more intense flame color.</span>

Kanitkar, Swarom↗