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At least 559 records · Page 31

October 2025 Semiannual Composite Salt Waste Processing Facility Decontaminated Salt Solution Toxicity Characteristic Leaching Procedure Results

The aqueous waste from the Salt Waste Processing Facility is sampled semiannually for transfers to the Saltstone Disposal Facility. Salt solution is treated at the Saltstone Production Facility and disposed of in the Saltstone Disposal Facility. Per request of customer, X-TTR-Z-00027, Revision 0, one Saltstone Processing Facility Decontaminated Salt Solution and Z area premix material for the October 2025 semiannual Toxicity Characteristic Leaching Procedure sample. The sample contained 60:40 (by weight) of slag and fly ash (referred to as the “Cement-Free grout sample”). Results from the technical report support Task 2: ‘Grout Leaching Analyses’ of the Task Technical Request prepared by Savannah River Mission Completion. At 51 days cured, the Saltstone sample was collected and shipped to a certified laboratory for analysis using the Toxicity Characteristic Leaching Procedure. The October 2025 Semiannual Cement-Free grout sample met 61 79.268.48 requirements for a non-hazardous waste form with respect to the Resource Conservation and Recovery Act metals and Underlying Hazardous Constituents and met the Saltstone Production Facility Waste Acceptance Criteria that was in effect at the time of the sample collection at the Salt Waste Processing Facility.

Hsieh, Madison [Savannah River National Laboratory↗

Mesoscale convective systems in the third pole region: Characteristics, mechanisms and impact on precipitation

The climate system of the Third Pole region, including the (TP) and its surroundings, is highly sensitive to global warming. Mesoscale convective systems (MCSs) are understood to be a vital component of this climate system. Driven by the monsoon circulation, surface heating, and large-scale and local moisture supply, they frequently occur during summer and mostly over the central and eastern TP as well as in the downstream regions. Further, MCSs have been highlighted as important contributors to total precipitation as they are efficient rain producers affecting water availability (seasonal precipitation) and potential flood risk (extreme precipitation) in the densely populated downstream regions. The availability of multi-decadal satellite observations and high-resolution climate model datasets has made it possible to study the role of MCSs in the under-observed TP water balance. However, the usage of different methods for MCS identification and the different focuses on specific subregions currently hamper a systematic and consistent assessment of the role played by MCSs and their impact on precipitation over the TP headwaters and its downstream regions. Here, we review observational and model studies of MCSs in the TP region within a common framework to elucidate their main characteristics, underlying mechanisms, and impact on seasonal and extreme precipitation. We also identify major knowledge gaps and provide suggestions on how these can be addressed using recently published high-resolution model datasets. Three important identified knowledge gaps are 1) the feedback of MCSs to other components of the TP climate system, 2) the impact of the changing climate on future MCS characteristics, and 3) the basin-scale assessment of flood and drought risks associated with changes in MCS frequency and intensity. A particularly promising tool to address these knowledge gaps are convection-permitting climate simulations. Therefore, the systematic evaluation of existing historical convection-permitting climate simulations over the TP is an urgent requirement for reliable future climate change assessments.

54 ENVIRONMENTAL SCIENCES↗

Frequency and Characteristics of Inland Advecting Sea Breezes in the Southeast United States

Sea breezes have been observed to move inland over 100 km. These airmasses can be markedly different from regional airmasses, creating a shallow layer with differences in humidity, wind, temperature and aerosol characteristics. To understand their influence on boundary layer and cloud development on subsequent days, we identify their frequency and characteristics. We visually identified sea breeze fronts on radar passing over the Savannah River Site (SRS) between March and October during 2015–2019. The SRS is ~150 km from the nearest coastal location; therefore, our detection suggests further inland penetration. We also identified periods when sea breeze fronts may have passed but were not visually observed on radar due to the shallow sea breeze airmass remaining below the radar beam elevation that ranges between approximately 1–8 km depending on the beam angle and radar source (Columbia, SC or Charleston, SC). Near-surface atmospheric measurements indicate that the dew point temperature increases, the air temperature decreases, the variation in wind direction decreases and the aerosol size increases after sea breeze frontal passage. A synoptic classification procedure also identified that inland moving sea breezes are more commonly observed when the synoptic conditions include weak to moderate offshore winds with an average of 35 inland sea breezes occurring each year, focused primarily in the months of April, May and June.

54 ENVIRONMENTAL SCIENCES↗

Angular Distribution of Characteristic Radiation Following the Excitation of He-Like Uranium in Relativistic Collisions

In this paper, we present an experimental and theoretical study of excitation processes for the heaviest stable helium-like ion, that is, He-like uranium occurring in relativistic collisions with hydrogen and argon targets. In particular, we concentrate on angular distributions of the characteristic Kα radiation following the K → L excitation of He-like uranium. We pay special attention to the magnetic sub-level population of the excited 1s2lj states, which is directly related to the angular distribution of the characteristic Kα radiation. We show that the experimental data can be well described by calculations taking into account the excitation by the target nucleus as well as by the target electrons. Moreover, we demonstrate for the first time an important influence of the electron-impact excitation process on the angular distributions of the Kα radiation produced by excitation of He-like uranium in collisions with different targets.

74 ATOMIC AND MOLECULAR PHYSICS↗

N-Doped Graphene (N-G)/MOF(ZIF-8)-Based/Derived Materials for Electrochemical Energy Applications: Synthesis, Characteristics, and Functionality

In recent years, graphene-type materials originating from metal–organic frameworks (MOFs) or integrated with MOFs have exhibited notable performances across various applications. However, a comprehensive understanding of these complex materials and their functionalities remains obscure. While some studies have reviewed graphene/MOF composites from different perspectives, due to their structural–functional intricacies, it is crucial to conduct more in-depth reviews focusing on specific sets of graphene/MOF composites designed for particular applications. In this review, we thoroughly investigate the syntheses, characteristics, and performances of N-G/MOF(ZIF-8)-based/derived materials employed in electrochemical energy conversion and storage systems. Special attention is given to realizing their fundamental functionalities. The discussions are divided into three segments based on the application of N-G/ZIF-8-based/derived materials as electrode materials for batteries, electrodes for electrochemical capacitors, and electrocatalysts. As electrodes for batteries, N-G/MOF(ZIF-8) materials can mitigate issues like an electrode volume expansion for Li-ion batteries and the ‘shuttle effect’ for Li-S batteries. As electrodes for electrochemical capacitors, these materials can considerably improve the ion transfer rate and electronic conductivity, thereby enhancing the specific capacitance while maintaining the structural stability. Also, it was observed that these materials could occasionally outperform standard platinum-based catalysts for the electrochemical oxygen reduction reaction (ORR). The reported electrochemical performances and structural parameters of these materials were carefully tabulated in uniform units and scales. Through a critical analysis of the present synthesis trends, characteristics, and functionalities of these materials, specific aspects were identified that required further exploration to fully utilize their inherent capabilities.

Electrochemistry↗

Predicting Water Cycle Characteristics from Percolation Theory and Observational Data

The fate of water and water-soluble toxic wastes in the subsurface is of high importance for many scientific and practical applications. Although solute transport is proportional to water flow rates, theoretical and experimental studies show that heavy-tailed (power-law) solute transport distribution can cause chemical transport retardation, prolonging clean-up time-scales greatly. However, no consensus exists as to the physical basis of such transport laws. In percolation theory, the scaling behavior of such transport rarely relates to specific medium characteristics, but strongly to the dimensionality of the connectivity of the flow paths (for example, two- or three-dimensional, as in fractured-porous media or heterogeneous sediments), as well as to the saturation characteristics (i.e., wetting, drying, and entrapped air). In accordance with the proposed relevance of percolation models of solute transport to environmental clean-up, these predictions also prove relevant to transport-limited chemical weathering and soil formation, where the heavy-tailed distributions slow chemical weathering over time. The predictions of percolation theory have been tested in laboratory and field experiments on reactive solute transport, chemical weathering, and soil formation and found accurate. Recently, this theoretical framework has also been applied to the water partitioning at the Earth’s surface between evapotranspiration, ET, and run-off, Q, known as the water balance. A well-known phenomenological model by Budyko addressed the relationship between the ratio of the actual evapotranspiration (ET) and precipitation, ET/P, versus the aridity index, ET 0 /P, with P being the precipitation and ET 0 being the potential evapotranspiration. Existing work was able to predict the global fractions of P represented by Q and ET through an optimization of plant productivity, in which downward water fluxes affect soil depth, and upward fluxes plant growth. In the present work, based likewise on the concepts of percolation theory, we extend Budyko’s model, and address the partitioning of run-off Q into its surface and subsurface components, as well as the contribution of interception to ET. Using various published data sources on the magnitudes of interception and information regarding the partitioning of Q, we address the variability in ET resulting from these processes. The global success of this prediction demonstrated here provides additional support for the universal applicability of percolation theory for solute transport as well as guidance in predicting the component of subsurface run-off, important for predicting natural flow rates through contaminated aquifers.

54 ENVIRONMENTAL SCIENCES↗

Core Physics Characteristics of Extended Enrichment and High Burnup Boiling Water Reactor Fuel

This paper presents the highlights of boiling water reactor (BWR) core physics studies performed at Oak Ridge National Laboratory as part of a series of studies conducted to compare low-enriched uranium (LEU) with LEU+ fuel. The studies analyzed isotopic fuel content, lattice parameters (Phase 1), and core physics (Phase 2) to identify challenges in operation, storage, and transportation for BWRs and pressurized water reactors (PWRs). Because of a lack of publicly available lattice and core designs for modern BWR fuel assemblies and reactor cores, several optimized lattice designs were generated, and different core loading strategies were investigated. Twelve optimized lattice designs with 235 U enrichments ranging from 1.6% to 9% and gadolinia loadings ranging from 3 to 8 wt% were used to model axial enrichment and geometry variations in fuel assemblies for core designs. Each core shares a common set of approximations in design and analysis to allow for consistent comparisons between LEU and LEU+ fuel. The objective is to highlight anticipated changes in core behavior with respect to the reference LEU core. The results of this study show that the differences in LEU and LEU+ core reactor physics characteristics are less significant than the differences in lattice physics characteristics reported in the Phase 1 studies.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Charge Transport Characteristics of Molecular Electronic Junctions Studied by Transition Voltage Spectroscopy

The field of molecular electronics is prompted by tremendous opportunities for using a single-molecule and molecular monolayers as active components in integrated circuits. Until now, a wide range of molecular devices exhibiting characteristic functions, such as diodes, transistors, switches, and memory, have been demonstrated. However, a full understanding of the crucial factors that affect charge transport through molecular electronic junctions should yet be accomplished. Remarkably, recent advances in transition voltage spectroscopy (TVS) elucidate that it can provide key quantities for probing the transport characteristics of the junctions, including, for example, the position of the frontier molecular orbital energy relative to the electrode Fermi level and the strength of the molecule–electrode interactions. These parameters are known to be highly associated with charge transport behaviors in molecular systems and can then be used in the design of molecule-based devices with rationally tuned electronic properties. This article highlights the fundamental principle of TVS and then demonstrates its major applications to study the charge transport properties of molecular electronic junctions.

36 MATERIALS SCIENCE↗

Contrasting characteristics of open- and closed-cellular stratocumulus cloud in the eastern North Atlantic

Abstract. Extensive regions of marine boundary layer cloud impact the radiative balance through their significant shortwave albedo while having little impact on outgoing longwave radiation. Despite this importance, these cloud systems remain poorly represented in large-scale models due to difficulty in representing the processes that drive their life cycle and coverage. In particular, the mesoscale organization and cellular structure of marine boundary clouds have important implications for the subsequent cloud feedbacks. In this study, we use long-term (2013–2018) observations from the Atmospheric Radiation Measurement (ARM) Facility's Eastern North Atlantic (ENA) site on Graciosa Island, Azores, Portugal, to identify cloud cases with open- or closed-cellular organization. More than 500 h of each organization type are identified. The ARM observations are combined with reanalysis and satellite products to quantify the cloud, precipitation, aerosol, thermodynamic, and large-scale synoptic characteristics associated with these cloud types. Our analysis shows that both cloud organization populations occur during similar sea surface temperature conditions, but the open-cell cases are distinguished by stronger cold-air advection and large-scale subsidence compared to the closed-cell cases, consistent with their formation during cold-air outbreaks. We also find that the open-cell cases were associated with deeper boundary layers, stronger low-level winds, and higher rain rates compared to their closed-cell counterparts. Finally, raindrops with diameters larger than 1 mm were routinely recorded at the surface during both populations, with a higher number of large drops during the open-cellular cases. The similarities and differences noted herein provide important insights into the environmental and cloud characteristics during varying marine boundary layer cloud mesoscale organization and will be useful for the evaluation of model simulations for ENA marine clouds.

54 ENVIRONMENTAL SCIENCES↗

Shallow- and deep-convection characteristics in the greater Houston, Texas, area using cell tracking methodology

The convective lifecycle, from initiation to maturity and dissipation, is driven by a combination of kinematic, thermodynamic, microphysical, and radiative processes that are strongly coupled and variable in time and space. Weather radars have been traditionally used to provide various convective-cloud characteristics. Here, we analyzed climatological convective-cell radar characteristics to obtain and assess the diurnal cycles of three convective-cell types – shallow, modest deep, and vigorous deep convective cells – that formed in the greater Houston area, using the National Weather Service radar from Houston, Texas, and a multi-cell identification and tracking algorithm. The examined dataset spans 4 years (2018–2021) and covers the warm-season months (June to September) in those years. The analysis showed clear diurnal cycles in cell initiation (CI) consistent with the sea breeze circulation and showed diurnal and normalized lifetime relationships in cell evolution parameters (e.g., maximum reflectivity, echo-top height, Geostationary Operational Environmental Satellite-16 (GOES-16) channel 13 brightness temperature, and the height of maximum reflectivity). The cell evolution is well represented by relationships between (1) the height and value of the maximum radar reflectivity, (2) the minimum GOES-16 channel 13 brightness temperature and the maximum vertically integrated liquid, (3) the maximum reflectivity and columnar-average reflectivity, and (4) the echo-top ascent rate and cell lifetime. The relationships presented herein help to identify the cell lifecycle stages such as early shallow convection, vigorous vertical development, anvil development, and convective core dissipation. GOES-16 Aerosol Optical Depth values are also used as a proxy for cell initiation aerosol concentrations to investigate any potential relationships between initiation location and aerosol concentration. Overall, no significant relationships between initiation location and aerosol concentration were found for the three cell types investigated, but there are some minor differences in the pre-CI aerosol optical depth for vigorous deep convective cells.

54 ENVIRONMENTAL SCIENCES↗

Impacts of wind field characteristics and non-steady deterministic wind events on time-varying main-bearing loads

Abstract. This work considers the characteristics and drivers of the loads experienced by wind turbine main bearings. Simplified load response models of two different hub and main-bearing configurations are presented, representative of both inverting direct-drive and four-point-mounted geared drivetrains. The influences of deterministic wind field characteristics, such as wind speed, shear, yaw offset, and veer, on the bearing load patterns are then investigated for similarity scaled 5, 7.5, and 10 MW reference wind turbine models. Main-bearing load response in cases of deterministic gusts and extreme changes in wind direction are also considered for the 5 MW model. Perhaps surprisingly, veer is identified as an important driver of main-bearing load fluctuations. Upscaling results indicate that similar behaviour holds as turbines become larger, but with mean loads and load fluctuation levels increasing at least cubically with the turbine rotor radius. Strong links between turbine control and main-bearing load response are also observed.

17 WIND ENERGY↗

Absorption and Emission Characteristics of Diffuse Spherical Enclosures

The thermal radiation characteristics of spherical cavities are of practical interest in connection with the absorption of radiant energy for both space-vehicle and terrestrial applications. Also, spherical cavities are of potential use as sources of black-body energy. The purpose of this brief paper is to determine both the absorption and emission characteristics of spherical cavities which are diffuse reflectors and emitters.

EMISSION↗

DRAG CHARACTERISTICS AND DYNAMIC STABILITY IN DESCENT OF A ROTARY PARACHUTE TESTED IN A VERTICAL TUNNEL

An investigation was conducted in the Langley 20-foot free-spinning tunnel at low speeds to determine the drag characteristics and dynamic stability in descent of a 64-inch-diameter rotary parachute. The drag coefficient of the basic rotary parachute was approximately 1.7 based on total cloth area_ cutting cloth away from the tips of the parachute permitted it to rotate faster and gave a somewhat higher drag coefficient of about 2.1. In general, the rotary parachute was extremely stable in descent, with oscillations of probably less than 1°. Small changes in rigging had no appreciable effect on the performance of the parachute. Accompanying zip folder contains video of the experimental process completed for this document and the related records for the Experimental aerodynamic performance characteristics of a rotor entry vehicle configuration. 1-3.

WIND TUNNEL↗

The Effect of Blunt-Trailing-Edge Modifications on the High-Speed Stability and Control Characteristics of a Swept-Wing Fighter Airplane

An investigation was conducted on a 35 deg swept-wing fighter airplane to determine the effects of several blunt-trailing-edge modifications to the wing and tail on the high-speed stability and control characteristics and tracking performance. The results indicated significant improvement in the pitch-up characteristics for the blunt-aileron configuration at Mach numbers around 0.90. As a result of increased effectiveness of the blunt-trailing-edge aileron, the roll-off, customarily experienced with the unmodified airplane in wings-level flight between Mach numbers of about 0.9 and 1.0 was eliminated, The results also indicated that the increased effectiveness of the blunt aileron more than offset the large associated aileron hinge moment, resulting in significant improvement in the rolling performance at Mach numbers between 0.85 and 1.0. It appeared from these results that the tracking performance with the blunt-aileron configuration in the pitch-up and buffeting flight region at high Mach numbers was considerably improved over that of the unmodified airplane; however, the tracking errors of 8 to 15 mils were definitely unsatisfactory. A drag increment of about O.OOl5 due to the blunt ailerons was noted at Mach numbers to about 0.85. The drag increment was 0 at Mach numbers above 0.90.

Sadoff, Melvin↗

Pump simulator provides variable pressure-flow characteristics

Pump simulator with variable pressure flow characteristics permits ready experimental determination of optimum pump-load matching. It has been successfully used to investigate the effect of feed pump characteristics on the stability of a Rankine system boiler.

Packe, D. R.↗