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At least 559 records · Page 31

A contactless approach for respiratory gating in PET using continuous-wave radar

Purpose: Respiratory gating is commonly used to reduce motion artifacts in positron emission tomography (PET). Clinically established methods for respiratory gating in PET require contact to the patient or a direct optical line between the sensor and the patient’s torso and time consuming preparation. In this work, a contactless method for capturing a respiratory signal during PET is presented based on continuous-wave radar. Methods: The proposed method relies on the principle of emitting an electromagnetic wave and detecting the phase shift of the reflected wave, modulated due to the respiratory movement of the patient’s torso. A 24 GHz carrier frequency was chosen allowing wave propagation through plastic and clothing with high reflections at the skin surface. A detector module and signal processing algorithms were developed to extract a quantitative respiratory signal. The sensor was validated using a high precision linear table. During volunteer measurements and [{sup 18}F] FDG PET scans, the radar sensor was positioned inside the scanner bore of a PET/computed tomography scanner. As reference, pressure belt (one volunteer), depth camera-based (two volunteers, two patients), and PET data-driven (six patients) signals were acquired simultaneously and the signal correlation was quantified. Results: The developed system demonstrated a high measurement accuracy for movement detection within the submillimeter range. With the proposed method, small displacements of 25 μm could be detected, not considerably influenced by clothing or blankets. From the patient studies, the extracted respiratory radar signals revealed high correlation (Pearson correlation coefficient) to those derived from the external pressure belt and depth camera signals (r = 0.69–0.99) and moderate correlation to those of the internal data-driven signals (r = 0.53–0.70). In some cases, a cardiac signal could be visualized, due to the representation of the mechanical heart motion on the skin. Conclusions: Accurate respiratory signals were obtained successfully by the proposed method with high spatial and temporal resolution. By working without contact and passing through clothing and blankets, this approach minimizes preparation time and increases the convenience of the patient during the scan.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Rapid Open-Air Fabrication of Perovskite Solar Modules

We report on the open-air fabrication of perovskite solar modules with key advances including scalable large-area spray deposition, new monolithic integration scribing techniques, advanced photoluminescence characterization, and reproducible high-throughput manufacturability. Perovskite deposition with linear speeds of 12 m/min without a post-anneal are demonstrated with improved device performance, luminescent yield and >10X carrier lifetimes. Manufacturability using monolithic integration of series-connected modules is accomplished with a new indirect fiber laser ablation scribing method. A stable cell and module power output of 18.0% and 15.5%, respectively, was achieved with a subcell V oc > 1.06V. A comprehensive supporting technoeconomic analysis details the entire in-line manufacturing process from the glass substrate to the junction box of the encapsulated module. Here, the module manufacturing cost, balance of system costs and levelized cost of energy for a range of module efficiencies and lifetimes provides insights for the necessary tool speeds, efficiencies, and lifetimes for utility-scale energy generation.

14 SOLAR ENERGY↗

Imaging charge carriers in potential-induced degradation defects of c-Si solar cells by scanning capacitance microscopy

We report on nm-resolution imaging of charge-carrier distribution around local potential-induced degradation (PID) shunting defects using scanning capacitance microscopy. We imaged on cross sections of heavily field-degraded module areas, cored out and selected by mm-scale photoluminescence imaging. We found localized areas with abnormal carrier behavior induced by the PID defects: the apparent n-type carrier extends vertically into the absorber to ~1-2 um from the cell surface, and laterally in similar lengths; in defect-free areas, the n-type carrier extends ~0.5 um, which is consistent with the junction depth. For comparison, we also investigated areas of the same module exhibiting the least PID stress, and we found no such heavily damaged junction area. Instead, we found slightly abnormal carrier behavior, where the carrier-type inversion in the absorber did not occur, but the p-type carrier concentration changed slightly in a much smaller lateral length of ~300 nm. These nano-electrical findings may indicate a possible mechanism that the existing extended defects, which may not be significantly harmful to cell performance, can be changed by PID to heavily damaged junction areas.

14 SOLAR ENERGY↗

Application of a Modified Gas Chromatograph to Analyze Space Experiment Combustion Gases on Space Shuttle Mission STS-94

A space experiment designed to study the behavior of combustion without the gravitational effects of buoyancy was launched aboard the Space Shuttle Columbia on July 1, 1997. The space experiment, designated as Combustion Module-1 (CM-1), was one of several manifested on the Microgravity Sciences Laboratory - 1 (MSL-1) mission. The launch, designated STS-94, had the Spacelab Module as the payload, in which the MSL-1 experiments were conducted by the Shuttle crewmembers. CM-1 was designed to accommodate two different combustion experiments during MSL-1. One experiment, the Structure of Flame Balls at Low Lewis-number experiment (SOFBALL), required gas chromatography analysis to verify the composition of the known, premixed gases prior to combustion, and to determine the remaining reactant and the products resulting from the combustion process in microgravity. A commercial, off-the-shelf, dual-channel micro gas chromatograph was procured and modified to interface with the CM-1 Fluids Supply Package and the CM-1 Combustion Chamber, to accommodate two different carrier gases, each flowing through its own independent column module, to withstand the launch environment of the Space Shuttle, to accept Spacelab electrical power, and to meet the Spacelab flight requirements for electromagnetic interference (EMI) and offgassing. The GC data was down linked to the Marshall Space Flight Center for near-real time analysis, and stored on-orbit for post-flight analysis. The gas chromatograph operated successfully during the entire SOFBALL experiment and collected 309 runs. Because of the constraints imposed upon the gas chromatograph by the CM-1 hardware, system and operations, it was unable to measure the gases to the required accuracy. Future improvements to the system for a re-flight of the SOFBALL experiment are expected to enable the gas chromatograph to meet all the requirements.

Coho, William K.↗

Modulation of intersubband light absorption and interband photoluminescence in double GaAs/AlGaAs quantum wells under strong lateral electric fields

The effect of a lateral electric field on the mid-infrared absorption and interband photoluminescence spectra in double tunnel-coupled GaAs/AlGaAs quantum wells is studied. The results obtained are explained by the redistribution of hot electrons between quantum wells and changes in the space charge in the structure. The hot carrier temperature is determined by analyzing the intersubband light absorption and interband photoluminescence modulation spectra under strong lateral electric fields.

36 MATERIALS SCIENCE↗

Improved Measurement of Dispersion in an Optical Fiber

An improved method of measuring chromatic dispersion in an optical fiber or other device affords a lower (relative to prior such methods) limit of measurable dispersion. This method is a modified version of the amplitude-modulation (AM) method, which is one of the prior methods. In comparison with the other prior methods, the AM method is less complex. However, the AM method is limited to dispersion levels . 160 ps/nm and cannot be used to measure the symbol of the dispersion. In contrast, the present modified version of the AM method can be used to measure the symbol of the symbol of the dispersion and affords a measurement range from about 2 ps/nm to several thousand ps/nm with a resolution of 0.27 ps/nm or finer. The figure schematically depicts the measurement apparatus. The source of light for the measurement is a laser, the wavelength of which is monitored by an optical spectrum analyzer. A light-component analyzer amplitude-modulates the light with a scanning radio-frequency signal. The modulated light is passed through a buffer (described below) and through the device under test (e.g., an optical fiber, the dispersion of which one seeks to measure), then back to the light-component analyzer for spectrum analysis. Dispersion in the device under test gives rise to phase shifts among the carrier and the upper and lower sideband components of the modulated signal. These phase shifts affect the modulation-frequency component of the output of a photodetector exposed to the signal that emerges from the device under test. One of the effects is that this component goes to zero periodically as the modulation frequency is varied.

Huang, Shouhua↗

A method of obtaining signal components of residual carrier signal with their power content and computer simulation

A novel algorithm to obtain all signal components of a residual carrier signal with any number of channels is presented. The phase modulation type may be NRZ-L or split phase (Manchester). The algorithm also provides a simple way to obtain the power contents of the signal components. Steps to recognize the signal components that influence the carrier tracking loop and the data tracking loop at the receiver are given. A computer program for numerical computation is also provided.

Kantak, Anil V.↗

Nanometer-Scale Carrier Imaging of Potential-Induced Degradation in c-Si Solar Cells

We report on nm-resolution imaging of chargecarrier distribution around local potential-induced degradation (PID) defects using scanning capacitance microscopy. We imaged cross sections of heavily field-degraded module areas as cored out and selected by mm-scale photoluminescence imaging. Localized areas with abnormal carrier behavior or junction damage were found: the apparent n-type carrier extends vertically into the absorber to ~1-2 um from the cell surface, and laterally in similar lengths; in defect-free areas, the n-type carrier extends ~0.5 um, which is consistent with the junction depth. For comparison, we also investigated areas of the same module exhibiting less PID stress, and did not find any such heavily damaged junction area. Instead, we found slightly abnormal carrier behavior, where the carrier-type inversion in the absorber did not occur, but the p-type carrier concentration changed slightly in a much smaller lateral length of ~300 nm. These nanoelectrical findings suggest that the existing extended defects, which may not be significantly harmful to cell performance, were changed by PID to heavily damaged junction areas.

14 SOLAR ENERGY↗

Ultrafast infrared plasmon switching in aligned carbon-nanotube optical resonators

Reconfigurable plasmonic materials are crucial components in active photonic devices for optical communication, signal processing, and sensing applications. Certain candidates including transparent conducting oxides, small-bandgap semiconductors (i.e. Ge, InSb), and conducting polymers can exhibit switchable free carrier concentrations triggered by optical, electrical or thermal excitations. Here, we show that aligned films of single-walled carbon nanotubes (SWCNTs) can serve as all-optically tunable plasmonic material in the mid-infrared range, thereby adding them to the library of switchable plasmonic materials. Interband optical pumping with femtosecond laser pulses results in the photoexcitation of free charge carriers, which transiently blueshifts the plasmon resonances of patterned, periodic SWCNT nano-resonators spanning the mid-infrared spectral range from 1700 to 2700 cm -1 . Furthermore. the ultrafast plasmon modulation exhibits a nearly single-picosecond decay time, attributed to interband carrier relaxation and inter-tube charge transfer. Given that aligned films of SWCNTs have high thermal stability, excellent photostability, epsilon-near-zero property, and extremely large optical anisotropy, their dynamic tunability represents a promising pathway towards active optical devices in the technologically important mid-infrared range.

single-walled carbon nanotubes↗

RAM - A concept for reducing space payload costs.

The post-Apollo era in manned space flight will be dominated in the short term by development of the space shuttle as an economical transportation system for payloads to low earth orbit. Research and Applications Modules (RAM) are a related group of shuttle-launched carriers for such payloads which can be used many times over, thus effecting great savings over currently conventional methods of implementing a program of this type. In order to maximize the potential savings, development and unit costs of the RAM vehicles must be minimized. All of the mission and operating modes can be covered in an economical fashion by the use of only three basic RAM elements - a pressurized module, an unpressurized pallet, and a pressurizable free-flying unit utilized in several combinations. These have been developed as a least cost approach through the consideration of such cost/weight related drivers as available crew size, separability of costly subsystems for multiple use, easy accessibility for maintenance/refurbishment for reuse, and a maximum commonality of hardware with existing and projected space projects.

Powell, D. J.↗

Rate 3/4 coded 16-QAM for uplink applications

First phase development of an advanced modulation technology which synergistically combines coding and modulation to achieve 2 bits per second per Hertz bandwidth efficiency in satellite demodulators is nearing completion. A proof-of-concept model is being developed to demonstrate technology feasibility, establish practical bandwidth efficiency limitations, and provide a data base for the design and development of engineering model satellite demodulators. The basic considerations leading to the choice of 4 x 4 quadrature amplitude modulation (16-QAM) and its associated coding format are discussed, along with the basic implementation of the carrier and clock recovery, automatic gain control, and decoding process. Preliminary performance results are presented. Spectra for the modulated signal shows the effects of the square root Nyquist filters in the modulation. Bit error rate (BER) results for the encoder/decoder subsystem show near ideal results, although power consumption is high and baseband BER performance of the Nyquist filter set is poor. Recommendations regarding the present system to improve BER performance and acquisition speed are given.

Mrozek, Eric M.↗

Phase-stable self-modulation of an electron-beam in a magnetic wiggler

Electron-beams with a sinusoidal energy modulation have the potential to emit sub-femtosecond x-ray pulses in a free-electron laser. The energy modulation can be generated by overlapping a powerful infrared laser with an electron-beam in a magnetic wiggler. Here we report on a new infrared source for this modulation, coherent radiation from the electron-beam itself. In this self-modulation process, the current spike on the tail of the electron-beam radiates coherently at the resonant wavelength of the wiggler, producing a six-period carrier-envelope-phase (CEP) stable infrared field with gigawatt power. This field creates a few MeV, phase-stable modulation in the electron-beam core. The modulated electron-beam is immediately useful for generating sub-femtosecond x-ray pulses at any machine repetition rate, and the CEP-stable infrared field may find application as an experimental pump or timing diagnostic.

wiggler↗

Hybrid metal–organic chalcogenide nanowires with electrically conductive inorganic core through diamondoid-directed assembly

Controlling inorganic structure and dimensionality through structure-directing agents is a versatile approach for new materials synthesis that has been used extensively for metal–organic frameworks and coordination polymers. However, the lack of ‘solid’ inorganic cores requires charge transport through single-atom chains and/or organic groups, limiting their electronic properties. Here, we report that strongly interacting diamondoid structure-directing agents guide the growth of hybrid metal–organic chalcogenide nanowires with solid inorganic cores having three-atom cross-sections, representing the smallest possible nanowires. The strong van der Waals attraction between diamondoids overcomes steric repulsion leading to a cis configuration at the active growth front, enabling face-on addition of precursors for nanowire elongation. These nanowires have band-like electronic properties, low effective carrier masses and three orders-of-magnitude conductivity modulation by hole doping. Furthermore, this discovery highlights a previously unexplored regime of structure-directing agents compared with traditional surfactant, block copolymer or metal–organic framework linkers.

36 MATERIALS SCIENCE↗

Extrinsic ion migration in perovskite solar cells

In this study, the migration of intrinsic ions (e.g., MA + , Pb 2+ , I – ) in organic–inorganic hybrid perovskites has received significant attention with respect to the critical roles of these ions in the hysteresis and degradation in perovskite solar cells (PSCs). Here, we demonstrate that extrinsic ions (e.g., Li + , H + , Na + ), when used in the contact layers in PSCs, can migrate across the perovskite layer and strongly impact PSC operation. In a TiO 2 /perovskite/spiro-OMeTAD-based PSC, Li + -ion migration from spiro-OMeTAD to the perovskite and TiO 2 layer is illustrated by time-of-flight secondary-ion mass spectrometry. The movement of Li + ions in PSCs plays an important role in modulating the solar cell performance, tuning TiO 2 carrier-extraction properties, and affecting hysteresis in PSCs. The influence of Li + -ion migration was investigated using time-resolved photoluminescence, Kelvin probe force microscopy, and external quantum efficiency spectra. Other extrinsic ions such as H + and Na + also show a clear impact on the performance and hysteresis in PSCs. Understanding the impacts of extrinsic ions in perovskite-based devices could lead to new material and device designs to further advance perovskite technology for various applications.

14 SOLAR ENERGY↗

DNA origami protection and molecular interfacing through engineered sequence-defined peptoids

DNA nanotechnology has established approaches for designing programmable and precisely controlled nanoscale architectures through specific Watson−Crick base-pairing, molecular plasticity, and intermolecular connectivity. In particular, superior control over DNA origami structures could be beneficial for biomedical applications, including biosensing, in vivo imaging, and drug and gene delivery. However, protecting DNA origami structures in complex biological fluids while preserving their structural characteristics remains a major challenge for enabling these applications. Here, we developed a class of structurally well-defined peptoids to protect DNA origamis in ionic and bioactive conditions and systematically explored the effects of peptoid architecture and sequence dependency on DNA origami stability. The applicability of this approach for drug delivery, bioimaging, and cell targeting was also demonstrated. A series of peptoids (PE1–9) with two types of architectures, termed as “brush” and “block,” were built from positively charged monomers and neutral oligo-ethyleneoxy monomers, where certain designs were found to greatly enhance the stability of DNA origami. Through experimental and molecular dynamics studies, we demonstrated the role of sequence-dependent electrostatic interactions of peptoids with the DNA backbone. We showed that octahedral DNA origamis coated with peptoid (PE2) can be used as carriers for anticancer drug and protein, where the peptoid modulated the rate of drug release and prolonged protein stability against proteolytic hydrolysis. Finally, we synthesized two alkyne-modified peptoids (PE8 and PE9), conjugated with fluorophore and antibody, to make stable DNA origamis with imaging and cell-targeting capabilities. Our results demonstrate an approach toward functional and physiologically stable DNA origami for biomedical applications.

36 MATERIALS SCIENCE↗

Robot for Investigations and Assessments of Nuclear Areas

RIANA is a remote controlled Robot dedicated for Investigations and Assessments of Nuclear Areas. The development of RIANA is motivated by the need to have at disposal a proven robot, tested in hot cells; a robot capable of remotely investigate and characterise the inside of nuclear facilities in order to collect efficiently all the required data in the shortest possible time. It is based on a wireless medium sized remote carrier that may carry a wide variety of interchangeable modules, sensors and tools. It is easily customised to match specific requirements and quickly configured depending on the mission and the operator's preferences. RIANA integrates localisation and navigation systems. The robot will be able to generate / update a 2D map of its surrounding and exploring areas. The position of the robot is given accurately on the map. Furthermore, the robot will be able to autonomously calculate, define and follow a trajectory between 2 points taking into account its environment and obstacles. The robot is configurable to manage obstacles and restrict access to forbidden areas. RIANA allows an advanced control of modules, sensors and tools; all collected data (radiological and measured data) are displayed in real time in different format (chart, on the generated map...) and stored in a single place so that may be exported in a convenient format for data processing. This modular design gives RIANA the flexibility to perform multiple investigation missions where humans cannot work such as: visual inspections, dynamic localization and 2D mapping, characterizations and nuclear measurements of floor and walls, non destructive testing, samples collection: solid and liquid. The benefits of using RIANA are: - reducing the personnel exposures by limiting the manual intervention time, - minimizing the time and reducing the cost of investigation operations, - providing critical inputs to set up and optimize cleanup and dismantling operations. (authors)

42 ENGINEERING↗

Design of communication systems using short-constraint-length convolutional codes.

A method is presented for calculating the effect of carrier-phase reference error in a receiver phase-locked loop on bit error rates in convolutionally coded data, for the practical design of systems using short-constraint-length convolutional codes. A set of design curves shows the relation between design bit error rate, uplink carrier tracking loop SNR, downlink total SNR, and downlink modulation index. These curves make possible rapid and simple system optimization.

Merrill, H. M.↗