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At least 559 records · Page 31

Yield Estimates of three Historical Atmospheric Nuclear Explosions at Lop Nor, from Reduced Order Models of Regionally Recorded Rayleigh Waveforms and One Seismic Station: A Brief Communication

We use a reduced order model (ROM) for Rayleigh waveforms sourced by large atmospheric explosions along with data collected from a single seismic station (TLG) to estimate the yields of three atmospheric nuclear tests with order-megaton (MT) yields. These historical tests were conducted by China between 1973 and 1980 (CHIC 15, CHIC 16, and CHIC 26). We use our ROM to estimate yields of 2.34 MT (CHIC 15), 0.51 MT (CHIC 16), and 1.15 (CHIC 26) in the 20.5 s period band that are consistent with publicly accepted values of 3 MT (CHIC 15), 0.50 MT (CHIC 16), and 0.730 MT (CHIC 26).

58 GEOSCIENCES↗

Statistical Relations among Solid Precipitation, Atmospheric Moisture and Cloud Parameters in the Arctic

Observations collected during cold-season precipitation periods at Utquagvik, Alaska and at the multidisciplinary drifting observatory for the study of Arctic climate (MOSAiC) are used to statistically analyze the relations among the atmospheric water cycle parameters including the columnar supercooled liquid and ice amounts (expressed as liquid-water and ice-water paths, i.e., LWP and IWP), the integrated water vapor (IWV) and the near-surface snowfall rate. Data come from radar and radiometer-based retrievals and from optical precipitation sensors. While the correlation between snowfall rate and LWP is rather weak, correlation coefficients between radar-derived snowfall rate and IWP are high (~0.8), which is explained, in part, by the generally low LWP/IWP ratios during significant precipitation. Correlation coefficients between snowfall rate and IWV are moderate (~0.45). Correlations are generally weaker if snowfall is estimated by optical sensors, which is, in part, due to blowing snow. Correlation coefficients between near-surface temperature and snowfall rates are low (r < 0.3). The results from the Alaska and MOSAiC sites are generally similar. These results are not very sensitive to the amount of time averaging (e.g., 15 min averaging versus daily averages). Observationally based relations among the water cycle parameters are informative about atmospheric moisture conversion processes and can be used for model evaluations.

54 ENVIRONMENTAL SCIENCES↗

A Time-Gated, Time-Correlated Single-Photon-Counting Lidar to Observe Atmospheric Clouds at Submeter Resolution

Most lidars used for cloud observations have the range resolution of about 10 m, so they are incapable of resolving submeter-scale processes that are crucial to cloud evolution. This article describes a prototype of a ground-based, vertically pointing, time-gated, time-correlated single-photon-counting lidar (referred to as the T2 lidar) developed to explore atmospheric clouds at range resolution two orders of magnitude finer than traditional atmospheric lidars. The T2 lidar emits green-light pulses (532 nm) at a repetition rate of 20.6 kHz and a pulse width of ∼650 ps, which enables the observation of aerosol and cloud layers at heights from a few hundred meters to 7.28 km above the ground level at range resolution down to 10 cm. In addition, a digital delay pulse generator controls the detector to only receive photons for a short period after each laser pulse. This time-gated technique blocks photons arriving from regions outside the target zone, thus significantly reducing the noise level and allowing observation even inside clouds. Initial observations show that the T2 lidar can detect sharp cloud boundaries and fine structures near the cloud base. Such refined measurements of cloud structure could lead to an improved understanding of microphysical processes such as droplet activation, entrainment and mixing, and precipitation.

54 ENVIRONMENTAL SCIENCES↗

High-Resolution Image Products Acquired from Mid-Sized Uncrewed Aerial Systems for Land–Atmosphere Studies

We assess the viability of deploying commercially available multispectral and thermal imagers designed for integration on small uncrewed aerial systems (sUASs, <25 kg) on a mid-size Group-3-classification UAS (weight: 25–600 kg, maximum altitude: 5486 m MSL, maximum speed: 128 m/s) for the purpose of collecting a higher spatial resolution dataset that can be used for evaluating the surface energy budget and effects of surface heterogeneity on atmospheric processes than those datasets traditionally collected by instrumentation deployed on satellites and eddy covariance towers. A MicaSense Altum multispectral imager was deployed on two very similar mid-sized UASs operated by the Atmospheric Radiation Measurement (ARM) Aviation Facility. This paper evaluates the effects of flight on imaging systems mounted on UASs flying at higher altitudes and faster speeds for extended durations. We assess optimal calibration methods, acquisition rates, and flight plans for maximizing land surface area measurements. We developed, in-house, an automated workflow to correct the raw image frames and produce final data products, which we assess against known spectral ground targets and independent sources. We intend this manuscript to be used as a reference for collecting similar datasets in the future and for the datasets described within this manuscript to be used as launching points for future research.

47 OTHER INSTRUMENTATION↗

Statistical Characterization of Hot Jupiter Atmospheres Using Spitzer’s Secondary Eclipses

We report 78 secondary eclipse depths for a sample of 36 transiting hot Jupiters observed at 3.6 and 4.5 μm using the Spitzer Space Telescope. Our eclipse results for 27 of these planets are new, and include highly irradiated worlds such as KELT-7b, WASP-87b, WASP-76b, and WASP-64b, and important targets for James Webb Space Telescope such as WASP-62b. We find that WASP-62b has a slightly eccentric orbit (ecos ω=0.00614±0.00064), and we confirm the eccentricity of HAT-P-13b and WASP-14b. The remainder are individually consistent with circular orbits, but we find statistical evidence for eccentricity increasing with orbital period in our range from 1 to 5 days. Our day-side brightness temperatures for the planets yield information on albedo and heat redistribution, following Cowan & Agol (2011). Planets having maximum day-side temperatures exceeding ~2200 K are consistent with having zero albedo and a distribution of stellar irradiance uniformly over the day-side hemisphere. Our most intriguing result is that we detect a systematic difference between the emergent spectra of these hot Jupiters as compared to blackbodies. The ratio of observed brightness temperatures, Tb(4.5)/Tb(3.6), increases with equilibrium temperature by 100 ± 24 parts-per-million per Kelvin, over the entire temperature range in our sample (800–2500 K). No existing model predicts this trend over such a large range of temperature. We suggest that this may be due to a structural difference in the atmospheric temperature profiles of real planetary atmospheres as compared to models.

79 ASTRONOMY AND ASTROPHYSICS↗

New Grids of Pure-hydrogen White Dwarf NLTE Model Atmospheres and the HST/STIS Flux Calibration

Nonlocal thermodynamic equilibrium (NLTE) calculations of hot white dwarf (WD) model atmospheres are the cornerstone of modern flux calibrations for the Hubble Space Telescope and for the CALSPEC database. These theoretical spectral energy distributions (SEDs) provide the relative flux versus wavelength, and only the absolute flux level remains to be set by reconciling the measured absolute flux of Vega in the visible with the Midcourse Space Experiment values for Sirius in the mid-IR. The most recent SEDs calculated by the tlusty and tmap NLTE model atmosphere codes for the primary WDs G191-B2B, GD 153, and GD 71 show improved agreement to 1% from 1500 Å to 30 μm, in comparison to the previous 1% consistency only from 2000 Å to 5 μm. These new NLTE models of hot WDs now provide consistent flux standards from the far UV to the mid-IR.

79 ASTRONOMY AND ASTROPHYSICS↗

Two Strengths of Ordinary Chondritic Meteoroids as Derived from Their Atmospheric Fragmentation Modeling

The internal structure and strength of small asteroids and large meteoroids is poorly known. Observation of bright fireballs in the Earth’s atmosphere can explore meteoroid structure by studying meteoroid fragmentation during the flight. Earlier evaluations showed that the meteoroid’s strength is significantly lower than that of the recovered meteorites. We present a detailed study of atmospheric fragmentation of seven meteorite falls, all ordinary chondrites, and 14 other fireballs, where meteorite fall was predicted but the meteorites, probably also ordinary chondrites, were not recovered. All observations were made by the autonomous observatories of the European Fireball Network and include detailed radiometric light curves. A model, called the semiempirical fragmentation model, was developed to fit the light curves and decelerations. Videos showing individual fragments were available in some cases. The results demonstrated that meteoroids do not fragment randomly but in two distinct phases. The first phase typically corresponds to low strengths of 0.04–0.12 MPa. In two-thirds of cases, the first phase was catastrophic or nearly catastrophic with at least 40% of mass lost. The second phase corresponds to 0.9–5 MPa for confirmed meteorite falls and somewhat lower strengths, from about 0.5 MPa, for smaller meteoroids. All of these strengths are lower than the tensile strengths of ordinary chondritic meteorites cited in the literature, 20–40 MPa. We interpret the second phase as being due to cracks in meteoroids and the first phase as a separation of weakly cemented fragments, which reaccumulated at the surfaces of asteroids after asteroid collisions.

79 ASTRONOMY AND ASTROPHYSICS↗

Utilizing a Database of Simulated Geometric Albedo Spectra for Photometric Characterization of Rocky Exoplanet Atmospheres

In anticipation of future flagship missions focused on the goal of achieving direct imaging of rocky exoplanets, we have developed a database of models to help the community examine the potential spectral characteristics of a broad range of rocky planet atmospheres. Using the publicly available Planetary Spectrum Generator, we have computed a grid of 141,600 rocky exoplanet geometric albedo spectra across a seven-dimensional parameter space. Using this grid, we have performed a color–color analysis seeking to identify the most useful near-UV and red or near-infrared photometric follow-up channels to combine with a green-optical (discovery) spectral channel. We found that a combination of filters at 0.4, 0.58, and ∼0.8 μm were able to distinguish between atmospheres with moderate-to-high concentrations of four different dominant absorbing constituents, given at least 10 hr of observation on a star at 10 parsec with a 15 m class space telescope; however, more moderate abundances similar to those of solar system rocky bodies would be more challenging to detect. We recommend that future missions seeking to characterize directly imaged rocky exoplanets by colors alone further consider multiband photometry as a first discriminator for planetary characteristics.

79 ASTRONOMY AND ASTROPHYSICS↗

ACCESS: Confirmation of No Potassium in the Atmosphere of WASP-31b

We present a new optical (400–950 nm) transmission spectrum of the hot Jupiter WASP-31b (M = 0.48 M {sub J}; R = 1.54 R {sub J}; P = 3.41 days), obtained by combining four transit observations. These transits were observed with IMACS on the Magellan Baade Telescope at Las Campanas Observatory as part of the ACCESS project. We investigate the presence of clouds/hazes in the upper atmosphere of this planet, as well as the contribution of stellar activity on the observed features. In addition, we search for absorption features of the alkali elements Na i and K i, with particular focus on K i, for which there have been two previously published disagreeing results. Observations with Hubble Space Telescope (HST)/STIS detected K i, whereas ground-based low- and high-resolution observations did not. We use equilibrium and nonequilibrium chemistry retrievals to explore the planetary and stellar parameter space of the system with our optical data combined with existing near-IR observations. Our best-fit model is that with a scattering slope consistent with a Rayleigh slope (α=5.3{sub −3.1}{sup +2.9}), high-altitude clouds at a log cloud top pressure of −3.6{sub −2.1}{sup +2.7} bars, and possible muted H{sub 2}O features. We find that our observations support other ground-based claims of no K i. Clouds are likely why signals like H{sub 2}O are extremely muted and Na or K cannot be detected. We then juxtapose our Magellan/IMACS transmission spectrum with existing VLT/FORS2, HST/WFC3, HST/STIS, and Spitzer observations to further constrain the optical-to-infrared atmospheric features of the planet. We find that a steeper scattering slope (α = 8.3 ± 1.5) is anchored by STIS wavelengths blueward of 400 nm and only the original STIS observations show significant potassium signal.

79 ASTRONOMY AND ASTROPHYSICS↗

Estimating Atmospheric Parameters of DA White Dwarf Stars with Deep Learning

The determination of atmospheric parameters of white dwarf stars (WDs) is crucial for researches on them. Traditional methodology is to fit the model spectra to observed absorption lines and report the parameters with the lowest χ 2 error, which strongly relies on theoretical models that are not always publicly accessible. In this work, we construct a deep learning network to model-independently estimate T eff and log g of DA stars (DAs), corresponding to WDs with hydrogen-dominated atmospheres. The network is directly trained and tested on the normalized flux pixels of full optical wavelength range of DAs spectroscopically confirmed in the Sloan Digital Sky Survey. Experiments in test yield that the rms error for T eff and log g approaches 900 K and 0.1 dex, respectively. This technique is applicable for those DAs with T eff from 5000 to 40,000 K and log g from 7.0 to 9.0 dex. Furthermore, the applicability of this method is verified for the spectra with degraded resolution of ~200. So it is also practical for the analysis of DAs that will be detected by the Chinese Space Station Telescope.

79 ASTRONOMY AND ASTROPHYSICS↗

Modeling Competing Line-broadening Mechanisms in Neutron Star Atmospheres: Interference between Motional Stark and Ion Broadening

Neutron star surfaces have extremely high magnetic fields. In the atmosphere, the broadening of spectral lines will be substantial from the dense plasma as well as from the magnetic field. One broadening mechanism of note is due to the motional Stark effect (MSE)—an additional electric field that arises from the motion of the atom in the magnetic field. However, approximate formulae are often used to construct atmosphere models, and the MSE is assumed to be the dominant line-broadening mechanism even in ions. Detailed pressure-broadening models in these extreme magnetic fields are now currently being developed. In these more detailed models, it was suggested that the MSE may not be as large as previously predicted. If correct, this hypothesis implies that neutron star line widths might be dominated by pressure broadening rather than by motional Stark broadening. We find that, in the absence of plasma perturbations, for typical magnetic fields (B = 10 12 G), mid-Z elements, such as oxygen, have motional Stark widths of order 1 eV for transitions between dipole-allowed transitions from the ground state, though higher temperatures and transitions to higher-energy states are expected to have more broadening. The MSE also breaks down selection rules, giving rise to forbidden transitions, which have much larger widths. When plasma perturbations are included, we find that the plasma perturbation and motional Stark processes are not independent and, as a result, the spectral lines become narrow in a nontrivial way and display harmonics of the ion cyclotron frequency.

74 ATOMIC AND MOLECULAR PHYSICS↗

Reconstructing atmospheric H 2 over the past century from bi-polar firn air records

Abstract. Historical atmospheric H2 levels were reconstructed using firn air measurements from two sites in Greenland (NEEM and Summit) and two sites in Antarctica (South Pole and Megadunes). A joint reconstruction based on the two Antarctic sites yields H2 levels monotonically increasing from about 330 ppb in 1900 to 550 ppb in the late 1990s, leveling off thereafter. These results are similar to individual reconstructions published previously (Patterson et al., 2020, 2021). Interpretation of the Greenland firn air measurements is complicated by challenges in modeling enrichment induced by pore close-off at these sites. We used observations of neon enrichment at NEEM and Summit to tune the parameterization of enrichment induced by pore close-off in our firn air model. The joint reconstruction from the Greenland data shows H2 levels rising 30 % between 1950 and the late 1980s, reaching a maximum of 530 ppb. After 1990, reconstructed atmospheric H2 levels over Greenland are roughly constant, with a small decline of 3 % over the next 25 years. The reconstruction shows good agreement with the available flask measurements of H2 at high northern latitudes.

Geology↗

University of Colorado and Black Swift Technologies RPAS-based measurements of the lower atmosphere during LAPSE-RATE

Abstract. Between 14 and 20 July 2018, small remotely piloted aircraft systems (RPASs) were deployed to the San Luis Valley of Colorado (USA) together with a variety of surface-based remote and in situ sensors as well as radiosonde systems as part of the Lower Atmospheric Profiling Studies at Elevation – a Remotely-piloted Aircraft Team Experiment (LAPSE-RATE). The observations from LAPSE-RATE were aimed at improving our understanding of boundary layer structure, cloud and aerosol properties, and surface–atmosphere exchange and provide detailed information to support model evaluation and improvement work. The current paper describes the observations obtained using four different types of RPASs deployed by the University of Colorado Boulder and Black Swift Technologies. These included the DataHawk2, the Talon and the TTwistor (University of Colorado), and the S1 (Black Swift Technologies). Together, these aircraft collected over 30 h of data throughout the northern half of the San Luis Valley, sampling altitudes between the surface and 914 m a.g.l. Data from these platforms are publicly available through the Zenodo archive and are co-located with other LAPSE-RATE data as part of the Zenodo LAPSE-RATE community (https://zenodo.org/communities/lapse-rate/, last access: 27 May 2021). The primary DOIs for these datasets are https://doi.org/10.5281/zenodo.3891620 (DataHawk2, de Boer et al., 2020a, e), https://doi.org/10.5281/zenodo.4096451 (Talon, de Boer et al., 2020d), https://doi.org/10.5281/zenodo.4110626 (TTwistor, de Boer et al., 2020b), and https://doi.org/10.5281/zenodo.3861831 (S1, Elston and Stachura, 2020).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Modulations of Atmospheric River Climatology by the Stratospheric Quasi‐Biennial Oscillation

Abstract This study reveals the significant Quasi‐Biennial Oscillation (QBO) influences on the seasonal atmospheric river (AR) climatology around the globe. The North Pacific (NP) AR climatology in the boreal winter to early fall seasons in a QBO easterly (QBOE) phase is systematically shifted poleward compared with those in a QBO westerly (QBOW) phase, and such difference peaks in the local late spring season. We also find the similar poleward shift for the AR climatology over the South Pacific (SP) in the austral winter seasons in the QBOE phase. A significant equatorward shift and an overall enhancement of the AR climatology over the SP are observed in the QBOE phase during local spring and summer seasons, respectively. The QBO impacts on the AR climatology over the Atlantic Ocean are less organized. Strong QBO impacts exist in almost all seasons for the North Atlantic AR but only in the austral spring season for the South Atlantic AR. These QBO modulations of the AR climatology over the ocean basins also change the season‐mean AR frequencies around coastal regions, suggesting significant QBO impacts on the local land‐falling AR events. The QBO modulations of the seasonal background mean states and the MJO‐teleconnections are two potential mechanisms mostly over the north hemisphere. The QBOE modulation of the Madden‐Julian Oscillation (MJO)‐teleconnection over the northern hemisphere is asymmetric between the MJO convection over the Indian Ocean and that over the Pacific Ocean, which is the key to explain the QBO influences on the AR activity on the seasonal timescale.

Huang, Kai [U.S. National Science Foundation Natio↗

Atmospheric Composition and Radiative Forcing Effects due to UN International Ship Emissions Regulations (ACRUISE) Field Campaign Report

Aerosols, or atmospheric particulates, are long known to be able to seed clouds and modify their characteristics (e.g., cloud brightness, coverage, lifetime). However, the impact of aerosols on clouds is highly complex and non-linear. As a result, aerosol-cloud interaction remains the largest uncertainty in our understanding of the Earth’s radiative balance and in any future climate projections. Aerosols are also a principal component of air pollution and are known to adversely affect respiratory and cardiovascular health.

54 ENVIRONMENTAL SCIENCES↗

GNSS Installation at the Eastern North Atlantic (ENA) Atmospheric Observatory Field Campaign Report

GRUAN, the Global Climate Observing System (GCOS) Reference Upper Air Network, is an international reference observing network of sites measuring essential climate variables above Earth's surface, designed to fill an important gap in the current global observing system. GRUAN’s objectives are to (1) provide long-term, high-quality climate records, (2) constrain and calibrate data from more spatially comprehensive global observing systems (including satellites and current radiosonde networks), and (3) fully characterize the properties of the atmospheric column.

54 ENVIRONMENTAL SCIENCES↗

AI‐Driven Robot Enables Synthesis‐Property Relation Prediction for Metal Halide Perovskites in Humid Atmosphere

Materials Acceleration Platforms (MAPs) – also known as self-driving laboratories– present a new paradigm for materials science and promise an order of magnitude accelerated materials discovery compared to the traditional trial-and-error approach. Metal halide perovskites (MHPs) are an emerging class of materials for optoelectronic applications but are plagued by irreproducible optoelectronic quality, particularly for films fabricated in a humid atmosphere. Here, in this work, a machine learning (ML)-guided closed-loop platform is developed with a multimodal data fusion approach to predict synthesis–property relations for the optical quality of MHP thin films in relative humidities (RHs) ranging from 5–55%. The efficiency of this approach is confirmed by the fast-dropping learning rate to 2% after experimentally sampling less than 1% of the possible 5,000+ combinations. The prediction of synthesis–property relations is done by optical and imaging characterizations. In situ photoluminescence characterization revealed the origin of thin film quality variation at different RH. These insights provide an avenue for controlling the MHP crystallization by fine-tuning the synthesis parameters and RH for a given chemistry, thus lifting the need for stringent atmosphere control. The MAP enables an accelerated screening and understanding of the synthesis design space, facilitating rational synthesis recipe choice for a wide range of materials.

AI-driven robot↗

Effect of using a nitrogen atmosphere on enzyme hydrolysis at high corn stover loadings in an agitated reactor

A comprehensive review of the literature shows that enzyme hydrolysis efficiency decreases with increased solids loadings at constant enzyme:cellulose ratios for pretreated lignocellulosic substrates. In seeking a mechanistic explanation for this phenomenon, we found that a nitrogen atmosphere enhances enzyme hydrolysis and minimizes the decrease in glucose yields as solids loadings are increased in an agitated bioreactor. Further, for liquid hot water pretreated corn stover, at solids loadings of both 100 and 200 g/L and hydrolyzed for 72 hr in a 1 L bioreactor at pH 5.0 with 3.6 mg protein per g biomass, glucose yields were 55% in a nitrogen atmosphere versus 45% in air with agitation and about 34% without agitation. While mixing promotes biomass/enzyme contact and disperses sugars released during hydrolysis that would otherwise cause product inhibition, nitrogen gas displaces air, avoiding deactivation of cellulases by oxygen. The nitrogen effect points to a facile approach of enhancing hydrolysis at high solids loadings.

09 BIOMASS FUELS↗