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At least 541 records · Page 30

LLM Generation of Online Courses from a Curated Set of Documents in the Nuclear Safeguards Domain

A multidisciplinary team at Argonne National Laboratory explores the application of advanced technologies to enhance knowledge transfer and retention within the nuclear safeguards domain. Specifically, it examines the feasibility of leveraging secure large language models (LLMs) to streamline the creation of e-learning modules for the U.S. National Nuclear Security Administration (NNSA) Office of International Nuclear Safeguards (NA-241). The initiative addresses the critical need for preserving institutional memory and accelerating skill development amidst the imminent retirement of senior professionals in the field in addition to supporting good knowledge management practices. The project integrates instructional design theory with cutting-edge AI technologies to transform curated document sets from the Safeguards Knowledge Repository (SKR) into modular online courses. By automating the generation of learning objectives and instructional content, the effort aims to reduce manual effort while maintaining high-quality educational outcomes. A limited measure of human supervision, however, ensures accuracy, relevance, and alignment with NNSA’s strategic priorities. Key findings highlight the potential of AI-assisted course generation to support safeguards professionals by creating structured, interactive learning experiences. The report underscores the importance of SME validation to address limitations in AI-generated content, such as terminology errors and gaps in coverage. Recommendations include adopting a structured workflow combining LLM acceleration with expert oversight to ensure accuracy, usability, and alignment with learner needs. This work demonstrates Argonne’s commitment to advancing national security and scientific excellence through innovative knowledge management solutions.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

Coupled Microbial-Conversion and Computational-Fluid-Dynamics (CFD) Models for Butanediol Production in Micro-Aerated Reactors

Microbial conversion of substrates to macromolecules has been widely used in the synthesis of value-added products in pharmaceutical and biotechnology industries. These bioreactions are also being investigated in the production of low-value commodities such as biofuels [1]. Gas-liquid mass-transfer and transport-reaction coupling are important challenges when designing and scaling up these reactor systems. Experiments in wellmixed small-scale reactors have enabled characterization of microbial reactivity, while their coupling with macroscale transport remains relatively unexplored. In this work, we use a coupled metabolic-CFD model to study the action of a genetically engineered microbe Zymomonas mobilis [2] on sugars to produce 2,3-Butanediol (BDO). BDO is an important hydrocarbon intermediate that can be catalytically upgraded to several fuels and chemicals [3]. An important aspect to this particular microbial conversion is the need for micro-aerated environments as opposed to traditional aerobic fermentation. Slight variations in oxygen concentration can result in competing reaction pathways that disable BDO production. Hence, gas-liquid mass transfer and transport need to be optimized in large-scale reactors to maximize BDO production, for which CFD is a valuable tool. The aerobic-fermentation CFD model previously developed by the authors [5] for simulating bubble-column and airlift reactors at scale was used in this study. The Reynolds-averaged mass, momentum and energy transport equations for interpenetrating gas and liquid phase are solved in this model along with the transport and interphase mass transfer of oxygen. Our previous work used a phenomenological model for microbial oxygen uptake that neglected microbial growth and other reaction pathways. In this work, a detailed metabolic model enabled prediction of product formation and inhibition pathways. In order to manage computational cost, we used a subcycling technique [6] that takes advantage of the clear separation in transport (~ 200 sec) and reaction (~ 2-3 hours) timescales. The CFD model is first solved to steady state, after which the metabolic model is advanced at every cell in the computational domain using the local oxygen concentration. The CFD model is then run to achieve a new steady state that provides a new oxygen distribution for the metabolic model. This process, where reaction and fluid updates are interleaved together, is iterated until reactants are completely exhausted. This work will examine the performance of different reactor designs such as bubble column and airlift reactors at scale (250-500 m3). Oxygen mass-transfer coefficient and distribution are critically analyzed among reactors, and optimization studies pertaining to aeration is presented. Furthermore, it has been observed in experiments that high BDO production may be achieved by manipulating the aerobic environment over the course of reaction, such that oxygen concentration is high during the growth phase, and very low as sugar is depleted. This characteristic will be addressed by our simulations for which a timedependent scheduling strategy for aeration is presented that maximizes BDO production. [1] Humbird, D., Davis, R., and McMillan, J., Aeration costs in stirred-tank and bubble column bioreactors, Biochemical Engineering Journal, 127, 161—166, 2017 [2] Yang, S., Mohagheghi, A., Franden, M. A., Chou, Y.-C., Chen, X., Dowe, N., Himmel, M. E., and Zhang, M., Metabolic engineering of zymomonas mobilis for 2, 3-butanediol production from lignocellulosic biomass sugars. Biotechnology for biofuels, 9(1):189, 2016 [3] Kim, S. J., Sim, H. J., Kim, J. W., Lee, Y. G., Park, Y. C., and Seo, J. H., Enhanced production of 2,3-butanediol from xylose by combinatorial engineering of xylose metabolic pathway and cofactor regeneration in pyruvate decarboxylase-deficient Saccharomyces cerevisiae. Bioresource Technology, 245:1551–1557, 2017 [4] Weller, H., Tabor, G., Jasak, H. and Fureby, C., A tensorial approach to computational continuum mechanics using object-oriented techniques, Computers in physics, 12, 6, 620--631, 1998

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Community-Informed Urban Flood Modeling for Impact Mitigation

The intensification of the hydrologic cycle due to climate change poses a threat to aging and under-designed water infrastructure systems which cannot adequately manage intense storm events. Developing a comprehensive plan for managing rain-driven flooding events is challenging due to uncertainties in the magnitude and frequency of future storm events and conflicting stakeholder objectives. In the City of Baltimore, Maryland, stormwater infrastructure is struggling to keep up with rainfall-driven (pluvial) flooding events, which regularly damage housing and disrupt transportation for residents. In this study, a hybrid of community engagement, numerical modeling, and artificial intelligence techniques are employed to explore prospective urban flooding adaptations. Community engagement drives the development of an urban flooding model (EPA Storm Water Management Model) for the Baltimore Harbor watershed. The model integrates complex surface and subsurface stormwater infrastructure data from the City, high-resolution spatial data, insights from local public works experts, and the lived experiences of City residents. This co-developed model simulates adaptations of interest to stakeholders in the city, including green and grey infrastructure and operational management strategies. Stormwater management scenarios focused on inlet cleaning and spatially concentrated green infrastructure are found to be the most effective in reducing flood depths in community priority locations. Together, these adaptations can reduce the duration of intersection inundation by more than twenty minutes, allowing for quicker emergency response and restoration of typical transportation systems. Future work will combine this community engaged flooding model with the Deep Uncertainties Pathways framework to explore tradeoffs between adaptations and develop dynamic adaptations which align with community objectives, enhance climate resilience in Baltimore, and can be adjusted in response to changing future conditions.

Ava, Spangler [Pennsylvania State University]↗

Widespread co‐occurrence of Sebacinales and arbuscular mycorrhizal fungi in switchgrass roots and soils has limited dependence on soil carbon or nutrients

Societal Impact Statement This work addresses a novel group of Sebacinales mycorrhizal fungi being considered for development as inoculants in managed ecosystems because of their potential access to nutrients in soil organic matter. By comparing the diversity, distributions, and abundances of the Sebacinales with the more common arbuscular mycorrhizal fungi in switchgrass, a biofuel crop, we demonstrate that current suggestions for a Sebacinales revolution in agriculture should be tempered by their ecology. In particular, Sebacinales are rare compared to arbuscular mycorrhizal fungi, and are only weakly associated with soil carbon, suggesting that ideas about improved soil carbon cycling associated with Sebacinales need to be sufficiently studied across a range of environmental conditions prior to their consideration for broad‐spectrum soil inoculants. Summary Arbuscular mycorrhizal (AM) fungi are widespread and important root symbionts, but recent work suggests that Sebacinales fungi may play an equally important role in both plant success and ecosystem carbon and nutrient cycling based on their worldwide occurrence and putative access to organic matter. However, the ecological impacts of Sebacinales will depend on their abundance and distribution relative to AM fungi and environmental soil carbon and nutrient patterns, which remain unexplored. We characterized Glomeromycota and Sebacinales fungi in switchgrass ( Panicum virgatum L.) roots and soils across 14 sites with diverse soil conditions. We examined group richness differences, co‐occurrence patterns, and how the relative abundance of these fungi related to soil carbon, nutrient stoichiometry, and host size. Sebacinales were widespread, but less diverse, common, and abundant than Glomeromycota. Moreover, co‐occurrences were predominantly random, suggesting relatively few interactions between these groups. Sebacinales increased relative to Glomeromycota in soils with more carbon, but explanatory power was limited. Based on our findings, we suggest that Sebacinales are likely complementary to AM fungi in roots. Expectations that Sebacinales have large effects on soil carbon and nutrient cycling may need to be reconsidered, at least based on their limited abundances relative to AM fungi in switchgrass. This is an important consideration as Sebacinales are candidates for use as inoculants in managed ecosystems.

Lee, Marissa R.↗

Decomposition characteristics of C4F7N-based SF6-alternative gas mixtures

C4F7N [2,3,3,3-tetrafluoro-2-(trifluoromethyl)propanenitrile]/CO2 gas mixtures are being developed as an eco-friendly electrical insulator to replace SF6, the most potent greenhouse industrial gaseous dielectric. However, recent studies have reported complicated and often conflicting decomposition pathways for C4F7N/CO2 gas mixtures, which has raised concerns. In this work, the decomposition characteristics of C4F7N/CO2 gas mixtures were studied comprehensively by both designed computations and experiments. Computations were performed starting from fundamental propositions of C4F7N/CO2 decompositions, which were further experimentally verified by pyrolysis, long-term thermal aging with/without catalytic materials (industrial-grade molecular sieves 4A), and electrical decomposition by spark discharge. The results of both computations and experiments suggest that in an ideal thermal decomposition, C4F7N is likely to decompose into C2F6 and small fluoronitriles first at high temperatures. The generation of C3F6 and C2N2 from C4F7N thermal decomposition at lower temperatures appears because of the catalytic effect of incompatible materials, for example, the industrial-grade molecular sieves 4A that we tested. The electron impact dissociation of C4F7N plays an important role in C4F7N electrical decomposition, leading to additional formation of distinctive small molecules of CF4 and C2N2 of low concentrations. It was pointed out based on a real arcing test in a load disconnector that the decomposition of C4F7N gas mixtures in real applications will be at a much moderate and manageable rate than what was obtained from the highly accelerated laboratory tests presented in this work. The signatures of decomposition products extracted in this study provide invaluable guidance for developing decomposition-based diagnosis and fixation of decomposition byproducts toward SF6-free power grids.

Physics↗

Integrated End-to-end Performance Prediction and Diagnosis for Extreme Scientific Workflows

This report details recent progress for the ASCR funded project “Integrated End-to-end Performance Prediction and Diagnosis for Extreme Scientific Workflows”. We refer to the project as IPPD/2, reflecting the 2017 renewal under expanded scope and partners In IPPD/2, we increased our research scope to include data motion. We are focusing on three major aspects: a) observe how data is generated, distributed, and used; b) analyze how data is (repeatedly) consumed with a focus both on repeated patterns and anomalies; and c) explore how to optimize data motion. This new work on data motion will augment and complement IPPD/2’s research that focused on the computational aspects of tasks. We leverage and extend our existing tools and demonstrate our work on the Belle II workflow suite as well as on workflows from NSLS-II. The highlights of our work are as follows: Provenance for Workflows: Provenance is used to provide information enabling quality control, re-run computational workflows, and reproduce results. IPPD/2 has been building a scalable provenance management system that enables the capture of provenance from the high-level workflow through all relevant system levels in one integrated environment. Leveraging this work, our recent efforts have included using provenance as an enabling technique. Workload characterization: Leveraging provenance and analysis, we characterize data movement within network, storage, and memory over a variety of workloads. This characterization enables an understanding by performance analysts and application developers of the range of behaviors that could be expected. Performance Prediction for Workflows: The goal of modeling distributed workflows is to understand performance bottlenecks and enable more intelligent task scheduling to optimize selected metrics of interest (e.g., task throughput or output data rate). IPPD/2 has utilized both analytical and AI/ML modeling methodologies for performance modeling. Advanced Scheduling and Fault Modeling for Workflows: Scheduling of large-scale scientific workflows on geographically distributed resources is a challenging problem. To improve workflow throughput, we combined novel scheduling algorithms with task predictions from performance modeling and fault modeling. Dynamically Alleviating Bottlenecks in Workflows: Exploiting our provenance, analysis, and modeling efforts, we have explored and developed several techniques for dynamically detecting and alleviating bottlenecks in data movement. In particular, we have spent considerable effort demonstrating our techniques on production-like workflow configurations.

97 MATHEMATICS AND COMPUTING↗

Smart Charge Management

This session will discuss "on-board" electric vehicle (EV) technology, its availability, and benefits. Learn about how these tools can empower agencies to further adopt EVs and aid in fleet electrification efforts. We will explore the evolving advancements of managed charging, available telematics, on-board technology and how to incorporate them into your overall EV adoption strategy. Furthermore, we'll discuss what to expect in the near future; and how to future proof your investments to make the technology work for you.

ADVANCED PROPULSION SYSTEMS,ENGINEERING↗

Accelerating Scientific Workflows on HPC Platforms with In Situ Processing

Scientific workflows drive most modern large-scale science breakthroughs by allowing scientists to define their computations as a set of jobs executed in a given order based on their data dependencies. Workflow management systems (WMSs) have become key to automating scientific workflows-executing computational jobs and orchestrating data transfers between those jobs running on complex high-performance computing (HPC) platforms. Traditionally, WMSs use files to communicate between jobs: a job writes out files that are read by other jobs. However, HPC machines face a growing gap between their storage and compute capabilities. To address that concern, the scientific community has adopted a new approach called in situ, which bypasses costly parallel filesystem I/O operations with faster in-memory or in-network communications. When using in situ approaches, communication and computations can be interleaved. In this work, we leverage the Decaf in situ dataflow framework to accelerate task-based scientific workflows managed by the Pegasus WMS, by replacing file communications with faster MPI messaging. We propose a new execution engine that uses Decaf to manage communications within a sub-workflow (i.e., set of jobs) to optimize inter-job communications. We consider two workflows in this study: (i) a synthetic workflow that benchmarks and compares file- and MPI-based communication; and (ii) a realistic bioinformatics workflow that computes mu-tational overlaps in the human genome. Experiments show that in situ communication can improve the bioinformatics workflow execution time by 22% to 30% compared with file communication. Our results motivate further opportunities and challenges for bridging traditional WMSs with in situ frameworks.

Decaf↗

Better management practices for environmentally sustainable production of microalgae and algal biofuels

The commercialization of biofuels produced from microalgae is in its infancy; therefore, many resource-management practices and production processes are still flexible. The purpose of this paper is to guide development of supply chains toward more environmentally sustainable practices. Furthermore, in this work, we review current and projected technologies and practices for autotrophic microalgae cultivation that promote environmental sustainability. We develop a framework that leverages these studies to propose better management practices (BMPs) for water quality and quantity, biodiversity, or greenhouse gas emissions in concert with productivity and profitability considerations. Some proposed BMPs are linked to numerical environmental targets, such as percent reductions in nutrient loadings to streams, whereas others seek to avoid thresholds leading to adverse health or ecological effects. Still others involve using the best available technologies, developed iteratively through life-cycle and techno-economic analyses. Proposed BMPs for microalgae cultivation focus on water quality and quantity, as well as improving greenhouse gas (GHG) emissions to obtain advanced biofuel designation. BMPs must allow producers to meet productivity and profitability targets, as well as environmental targets. These example BMPs characterize the state of science and engineering; thus, they will change over time.

09 BIOMASS FUELS↗

Simulation-based analysis of different curb space type allocations on curb performance

Curbspace is a limited resource in urban areas. Delivery, ridehailing and passenger vehicles must compete for spaces at the curb. Cities are increasingly adjusting curb rules and allocating curb spaces for uses other than short-term paid parking, yet they lack the tools or data needed to make informed decisions. In this research, we analyze and quantify the impacts of different curb use allocations on curb performance through simulation, covering various mixes of curbspace uses (bus stops, paid parking, passenger pick-up/drop-off zones, and commercial vehicle loading zones), parking rules, and driver rule compliance. Three metrics (including two new ones) are developed to evaluate the performance of the curb, covering productivity and accessibility of passengers and goods, and CO 2 emissions. The metrics are calculated for each scenario across a wide range of input parameters (traffic volume, parking demand rate, vehicle dwell time, and street design speed) and compared to each other and to a baseline scenario. This work can inform policy decisions by providing municipalities a tool to analyze various curb management strategies and choose the ones that produce results more in line with their policy goals.

99 GENERAL AND MISCELLANEOUS↗

Assessment of Training Performance, Degradation and Robustness of Paraffin-Wax Impregnated Nb 3 Sn Demonstrator Under High Magnetic Field

In the context of high-energy physics, the use of Nb 3 Sn superconducting magnets as a cost-effective and reliable technology depends on improvements in the following areas: long development and manufacturing cycles, conductor degradation after thermal cycling, long training, as well as a demonstration in accelerator magnets with a beam aperture of the full potential of modern Nb 3 Sn conductors. In short, performance, robustness, and cost are the three issues to be addressed. The Magnet Development project (MagDev) of the Swiss Accelerator Research and Technology initiative (CHART) at the Paul Scherrer Institute (PSI) aims to contribute to the solutions to each of these issues, re-thinking the manufacturing and design process. Here in our program, every innovation is to be validated by means of a panoply of fast-turnaround tools: from non-powered and powered samples and coils, tested under background field, to low-field subscale magnets and high field short prototypes. This work presents one element in this panoply of R&D vehicles: a stress-managed Nb 3 Sn coil called BigBOX, impregnated with paraffin wax, and tested, through a collaboration with the Magnet Development Program of the United States (US-MDP), in the background field of Brookhaven National Laboratory (BNL)’s common coils dipole DCC17.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Stewardship Considerations for Nevada FFACO Corrective Action Units Closed through the EM NV Soils Activity based on Monitoring of Radionuclide Transport

This report summarizes the EM NV/DRI work with the intent of conveying this information to the long-term land managers who will assume responsibility as EM NV completes its environmental restoration mission. A brief description of each of the six evaluated Soils Activity sites is provided, which is followed by a discussion of the findings regarding radionuclide transport learned at the sites. The implications of these findings are examined for site management, routine monitoring, and monitoring during potentially adverse events. Possible mitigation actions are also identified. The appendices provide a more detailed examination of the conditions under which radionuclide transport occurs at these sites.

54 ENVIRONMENTAL SCIENCES↗

Evaluation of Guardbanding Methods for Calibration and Product Acceptance

The Primary Standards Lab employs guardbanding methods to reduce risk of false acceptance in calibration when test uncertainty ratios are low. Similarly, production agencies guardband their requirements to reduce false accept rates in product acceptance. The root-sum-square guardbanding method is recommended by PSL, but many other guardbanding methods have been proposed in literature or implemented in commercial software. This report analyzes the false accept and reject rates resulting from the most common guardbanding methods. It is shown that the root-sum-square method and the Dobbert Managed Guardband strategy are similar and both are suitable for calibration and product acceptance work in the NSE.

42 ENGINEERING↗

Computed Tomography Scanning and Geophysical Measurements of the Fayetteville Shale Formation from the Nixon B #1-7 Well

The computed tomography (CT) facilities and the Multi-Sensor Core Logger (MSCL) at the National Energy Technology Laboratory (NETL) in Morgantown, West Virginia were used to characterize core from the Fayetteville and Pitkin formations. This core came from a vertical well drilled by Southwestern Energy (Nixon B #1-7 well) and characterized as part of the U.S. Department of Energy’s (DOE) Fossil Energy and Carbon Management Onshore portfolio’s focus on unconventional shale plays. The primary impetus of this work is to characterize Fayetteville Shale core, from an unconventional shale play in Northwestern Arkansas, that is relatively under-reported on when compared to larger unconventional resources in the continental U.S.

58 GEOSCIENCES↗

Technical Characterization and Benefit Evaluation of 5G-Enabled Grid Data Transport and Applications

This report summarizes the Year 1 work of Pacific Northwest National Laboratory’s (PNNL’s) 5G Fabricated Resource and Asset Management Encompassment for energy infrastructure (Energy FRAME) project funded by the Department of Energy Office of Science’s Advanced Scientific Computing Research Program. 5G is a breakthrough technology that enables a fully mobile and connected society, and a 5G-enabled digital continuum will be one of the critical foundations for a clean energy economy and grid modernization. In collaboration with PNNL’s Advanced Wireless Communication team and Center for Advanced Technology Evaluation team, the project team has been evaluating the system performance of 5G testbeds in the PNNL 5G Innovation Studio, and has formulated a co-simulation test case of power system transmission, distribution, and communication (T&D&C) networks considering 5G technology and high penetration of distributed energy resources. The methodology developed in the 5G Energy FRAME project can be customized to fit different future grid scenarios to evaluate multiple (dynamic) configurations (computing, sensing, communication, environment) for different stakeholders. In summary, our main technical highlights in project Year 1 are as follows: 1) Technical characterization of 5G standalone architectures, 2) Formulation of co-simulation test case of T&D&C networks embedded with 5G, 3) Initial benefit evaluation of 5G communication platform for grid use cases, and 4) Additional extended discussions on edge computing, artificial intelligence and machine learning, and high-performance computing and cloud computing adoptions. In addition, a collection of system performance data is shared through the publicly available weblink, https://www.pnnl.gov/projects/5g-energy-frame/publications

24 POWER TRANSMISSION AND DISTRIBUTION↗

Zero-Emission Vehicle Adoption Resource Guide for Government Fleets in Jackson County, Illinois

As part of Communities LEAP (Local Energy Action Program), the National Renewable Energy Laboratory (NREL) provided technical assistance to Jackson County, Illinois to help develop their clean energy transition roadmap. Fleet electrification was identified as a potential pathway that could address the environmental injustices, high energy burden, and local pollution experienced by this former coal community. NREL worked with Jackson County, Illinois to develop a resource guide that can assist fleet managers considering a transition to electric light-duty fleet vehicles. To further understand the unique challenges of fleet electrification in Jackson County, NREL met with three leaders within the county who either managed current fleets or were responsible for fleet purchases. This resource guide includes best practices and resources that address many of the frequently asked questions that arose during these discussions. Interested fleets can then use this resource guide to help identify the initial steps needed to plan for vehicle electrification. The resource guide summarizes the basics of electric vehicle (EV) adoption for fleets, funding and incentive pathways, total cost of ownership in comparison to conventional internal combustion engine (ICE) vehicles, charging infrastructure, and pilot programs.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

International Nuclear Security Nuclear Material Accounting and Control Kit Participant Guides

You work at a facility that stores large amounts of nuclear material in varying containerizations. Management has just approved the establishment of a tamper indicating device program in order to cut down on the effort required to conduct inventories, and to enhance overall control of nuclear materials within the site boundary. You have been assigned, along with your colleagues, to conduct an initial assessment to determine the ideal TID types to be used at your facility. You will apply TIDs to a variety of apparatuses that are representative of the closure mechanisms on different containers and entry points to rooms and vaults onsite.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Polyphosphate kinase deletion increases laboratory productivity in cyanobacteria

Identification and manipulation of cellular energy regulation mechanisms may be a strategy to increase productivity in photosynthetic organisms. This work tests the hypothesis that polyphosphate synthesis and degradation play a role in energy management by storing or dissipating energy in the form of ATP. A polyphosphate kinase ( ppk ) knock-out strain unable to synthesize polyphosphate was generated in the cyanobacterium Synechocystis sp. PCC 6803. This mutant strain demonstrated higher ATP levels and faster growth than the wildtype strain in high-carbon conditions and had a growth defect under multiple stress conditions. In a strain that combined ppk deletion with heterologous expression of ethylene-forming enzyme, higher ethylene productivity was observed than in the wildtype background. These results support the role of polyphosphate synthesis and degradation as an energy regulation mechanism and suggest that such mechanisms may be effective targets in biocontainment design.

59 BASIC BIOLOGICAL SCIENCES↗