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NASA NTRS1983

Remote measurement of trace gases with the JPL laser absorption spectrometer

Extensive data from large regions are needed as a basis for the study of anthropogenic trace gases in the troposphere. The need arises, therefore, for an instrument which is capable to monitor rapidly the atmosphere in a region. The present investigation is concerned with the results of efforts to develop an instrument which is capable of remotely measuring gases in the troposphere. The Laser Absorption Spectrometer (LAS) was designed for use in aircraft, and was employed to measure tropospheric ozone distribution since 1977. Attention is given to a description of the LAS instrument, the theoretical basis of instrument operation, LAS measurement programs, the results of the LAS development program, and future work.

Shumate, M. S.↗

NASA NTRS1983

CO2 DIAL sensitivity studies for measurements of atmospheric trace gases

An analysis is presented of the accuracy of infrared differential absorption lidar (DIAL) measurements of trace constituents in the atmosphere. Expressions are derived for the signal-to-noise ratios applicable in the detection of a signal from a scattering cell for the cases of single-detection heterodyne detection and direct detection. Results of computer simulations of the expectation value of the measured return for various measurement conditions are presented which illustrate the sensitivities of plume measurements for horizontal range-resolved and vertical content measurements of NH3 in heterodyne and direct detection. Advantages for long-range measurements of the use of rare isotope laser frequencies, tuning by collision broadening, and closely spaced on and off frequencies are pointed out.

Brockman, P.↗

NASA NTRS1983

Effects of systematic errors on the mixing ratios of trace gases obtained from occulation spectra

The influence of systematic errors in the parameters of the models describing the geometry and the atmosphere on the profiles of trace gases retrieved from simulated solar occultation spectra, collected at satellite altitudes, is investigated. Because of smearing effects and other uncertainties, it may be preferable to calibrate the spectra internally by measuring absorption lines of an atmospheric gas such as CO2 whose vertical distribution is assumed rather than to relay on externally supplied information.

Shaffer, W. A.↗

NASA NTRS1983

Enstatite chondrites - Trace element clues to their origin

Three EH and three EL chondrites have been subjected to RNAA analysis for 20 trace elements, and interelement correlations were examined in order to assess the effects of nebular fractionation and metamorphism. The refractory siderophiles Ir, Os, and Re correlate with the normal siderophiles Ni, Pd, Au, Sb, and Ge, in ELs but not in EHs. The two element groups presumably condensed on separate phases at first, but concentrated in metal during metabolism. Volatiles are consistently more depleted in ELs than EHs. Strong correlations are found for In-Tl, Tl-Bi, and Zn-Cd-In, which are equally consistent with predicted condensation curves for the solar nebula and with volatilization curves for artificially heated Abee. The three factors accounting for 93 percent of variance reflect volatile, siderophile, and chalcophile behavior.

Hertogen, J.↗

NASA NTRS1983

Aubrites and diogenites - Trace element clues to their origin

A typically igneous siderophile element pattern emerges from an RNAA analysis of 25 aubrite and nine diogenite samples for 13-29 siderophile, volatile, and lithophile trace elements, although it is noted that abundances are about 10 times higher in the case of aubrites. Se is also surprisingly abundant in aubrites. Factor analysis shows several parallel groupings for aubrites and diogenites. Several element pairs that differ greatly in volatility correlate closely in aubrites, in approximately C1-chondrite proportions, suggesting that aubrites originated by igneous processes in their parent body.

Wolf, R.↗

NASA NTRS1984

Trace elements in rims and interiors of Chainpur chondrules

Trace elements were measured in the rims and interiors of nine chondrules separated from the Chainpur LL-3 chondrite. Whole rock samples of Chainpur and samples of separated rims were also measured. Chondrule rims are moderately enriched in siderophile and volatile elements relative to the chondrule interiors. The enriched volatile elements include the lithophilic volatile element Zn. The moderate enrichment of volatiles in chondrule rims and the lack of severe depletion in chondrules can account for the complete volatile inventory in Chainpur. These results support a three-component model of chondrite formation in which metal plus sulfide, chondrules plus rims and matrix silicates are mixed to form chondrites.

Wilkening, L. L.↗

NASA NTRS1984

The geochemical behavior of refractory noble metals and lithophile trace elements in refractory inclusions in carbonaceous chondrites

Recent models of Ca, Al-rich (CAI) inclusion petrogenesis, and the recent availability of thermodynamic data have led to the reexamination of the geochemical behavior of the refractory noble metals (RNM) and several lithophile refractory trace elements in CAI's in the context of distillation models. Here, pertinent chemical and mineralogical properties of the various classes of refractory inclusions are reviewed, and calculations of the stability of LRTE-RNM alloys and several LRTE oxides under nebular conditions are presented. The calculations, observations and experimental results are applied to a new model of the origin of refractory metal nuggets, and a specific mechanism is identified for producing Group II chemical patterns in a cold star nebula by fractionating interstellar dust at low temperature on the basis of physical differences between different populations of pre-solar grains.

Fegley, B., Jr.↗

NASA NTRS1984

Effects of systematic errors on the mixing ratios of trace gases obtained from occultation spectra

Shaffer, W. A.↗

NASA NTRS1985

Monitoring Trace Gases in the Atmosphere

Tunable laser spectrometer uses reflections from ordinary objects. Topographic target (ordinary feature of surroundings) returns enough energy to receiver so absorption by trace gases detected. Chopping laser beam allows return to be compared with original signal. Amplifier locks in on chopping frequency or laser modulation frequency. In laboratory simulations, spectrometer detected nitrogen dioxide in concentrations of only few parts per million.

Webster, C. R.↗

NASA NTRS1986

Detecting Trace Contaminants in the Atmosphere

Sensitive instrument uses two low-energy electron beams to detect certain molecules. Experimental instrument identifies and measures trace contaminants in atmosphere. When fully developed, portable instrument expected to measure contaminant concentrations of certain halogen containing molecules as low as one part per trillion. Instrument employs electron beams to ionize contaminant molecules by dissociative attachment of electrons.

Srivastava, S. K.↗

NASA NTRS1986

Solid-State Detector for Trace Materials

Detector for trace chemicals senses as few as 10 to the 12th power molecules of given material on surface. Contains no moving parts, amenable to large-scale integration, and operates at room temperature. Potential applications in industrial process control and in environmental analysis. Characteristic signals indicate presence of certain chemicals.

Lambe, J. J.↗

NASA NTRS1984

The 'North American shale composite' - Its compilation, major and trace element characteristics

North American shale composite (NASC) major element composition and compilation are presented, together with rare earth element (REE) redeterminations obtained by high precision analytical methods. The major element composition of the NASC compares closely with other average shale compositions, and significant portions of the REE and some other trace elements are contained in minor phases. The uneven REE distribution in NASC powder appears to yield the heterogeneity in analyzed aliquants. REE distributions of detrital sediments may to some extent be dependent on their minor mineral assemblages and the sedimentological factors controlling these assemblages.

Gromet, L. P.↗

NASA NTRS1985

H-chondrites - Trace element clues to their origin

RNAA is used to determine the abundances of 20 trace elements in four H4, two H3, two H5, and two H6 chondrites from the British Museum, as a contribution to a multiple-method study of these objects. The results are presented in tables and graphs and analyzed in terms of the inhomogeneity of the parent bodies and the depletion of volatiles in the higher petrologic types. Features observed include siderophile depletion in H3 chondrites; systematic variation of siderophile abundance pattern with petrologic type; volatile depletion as a primary feature; mineralogy consistent with accretion at 420-500 K; and the factor-analysis groupings siderophiles (Os, Re, Ir, Ni, Pd, Au, and Ge), volatiles (Ag, Br, In, Cd, Bi, and Tl), and alkalis (Rb and Cs).

Morgan, J. W.↗

NASA NTRS1985

High sensitivity detection of trace gases at atmospheric pressure using tunable diode lasers

A detailed study of the detection of trace gases at atmospheric pressure using tunable diode lasers is described. The influence of multipass cells, retroreflectors and topographical targets is examined. The minimum detectable infrared absorption ranges from 0.1 percent for a pathlength of 1.2 km to 0.01 percent over short pathlengths. The factors which limit this sensitivity are discussed, and the techniques are illustrated by monitoring atmospehric CO2 and CH4.

Reid, J.↗

NASA NTRS1985

Mobile trace element contents in Jilin chondrite

A determination is conducted of ppm-ppt levels of Co, Se, Ga, Rb, Cs, Te, Bi, Ag, In, Tl, Zn and Cd (arranged empirically in order of increasing mobility at 1000 C) by radiochemical neutron activation analysis in eight Jilin samples of known Ar-40 content and a large vein from one of these. The trace element contents of the vein do not differ markedly from those of Jilin whole-rock samples. Only Rb correlates with Ar-40, possibly due to chance. All elements but Cd are present at levels similar to thdse in H4-6 chondrites with long K/Ar age (i.e., presumably mildly shocked). These levels are low relative to those in analogous L4-6 chondrites suggesting that H chondrites formed and/or evolved under higher pre-shock temperatures than did mildly shocked L chondrites. Time-temperature conditions during shock-loading of Jilin parent material were mild relative to those in strongly shocked L chondrites, being sufficient at most only to mobilize Cd.

Sakuragi, Y.↗

NASA NTRS1985

Ray tracing of Z-mode emissions from source regions in the high-altitude auroral zone

Two-dimensional ray tracing of Z-mode radiation from sources in the auroral zone has been performed. The Z-mode waves are assumed to be excited by the cyclotron maser mechanism at frequencies near the electron gyrofrequency and at wave normal angles near 90 deg. The emission is found to propagate primarily perpendicular to the magnetic field line (horizontal propagation) for all sources considered, and thus not to substantially lower altitudes. The frequency bandwidth estimated from the ray paths is much less than that observed by DE-1. It is suggested that the wave source needs to be in the region of field-aligned current in order for the cyclotron maser mechanism to explain the broad frequency bandwidth of Z-mode emissions.

Menietti, J. D.↗

NASA NTRS1985

A ray tracing model of gravity wave propagation and breakdown in the middle atmosphere

Lindzen (1981, 1984) has considered the effects of monochromatic, steady gravity waves propagating into the upper atmosphere. These waves reach such large amplitudes in the mesosphere that they become convectively unstable. The wave is effectively dissipated by the convection, and the pseudomomentum carried by the wave is transferred to the basic flow. The net effect is to accelerate the background flow to the phase speed of the breaking gravity wave. Schoeberl et al. (1983) have discussed modifications to Lindzen's parameterization. The present paper has the objective to develop a type of parameterization scheme for wave breaking that, in principle, can handle lateral wave propagation. Ray tracing is used to follow the gravity wave packets through varying wind conditions. The theory considered uses both the propagation properties of the wave packet and the concept of the conservation of wave action density to determine the local amplitude and position of the wave packet.

Schoeberl, M. R.↗

NASA NTRS1985

Improved aqueous scrubber for collection of soluble atmospheric trace gases

A new concentration technique for the extraction and enrichment of water-soluble atmospheric trace gases has been developed. The gas scrubbing technique efficiently extracts soluble gases from a large volume flow rate of air sample into a small volume of refluxed trapping solution. The gas scrubber utilizes a small nebulizing nozzle that mixes the incoming air with an aqueous extracting solution to form an air/droplet mist. The mist provides excellent interfacial surface areas for mass transfer. The resulting mist sprays upward through the reaction chamber until it impinges upon a hydrophobic membrane that virtually blocks the passage of droplets but offers little resistance to the existing gas flow. Droplets containing the scrubbed gases coalesce on the membrane and drip back into the reservoir for further refluxing. After a suitable concentration period, the extracting solution containing the analyte can be withdrawn for analysis. The nebulization-reflex concentration technique is more efficient (maximum flow of gas through the minimum volume of extractant) than conventional bubbler/impinger gas extraction techniques and is offered as an alternative method.

Cofer, W. R., III↗