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At least 541 records · Page 30

Hydrogen Risk Assessment Models (HyRAM) (V.3.1) (Technical Reference Manual)

The HyRAM software toolkit provides a basis for conducting quantitative risk assessment and consequence modeling for hydrogen infrastructure and transportation systems. HyRAM is designed to facilitate the use of state-of-the-art science and engineering models to conduct robust, repeatable assessments of hydrogen safety, hazards, and risk. HyRAM includes generic probabilities for hydrogen equipment failures, probabilistic models for the impact of heat flux on humans and structures, and experimentally validated first-order models of hydrogen release and flame physics. HyRAM integrates deterministic and probabilistic models for quantifying accident scenarios, predicting physical effects, and characterizing hydrogen hazards (thermal effects from jet res, overpressure effects from deflagrations), and assessing impact on people and structures. HyRAM is developed at Sandia National Laboratories for the U.S. Department of Energy to increase access to technical data about hydrogen safety and to enable the use of that data to support development and revision of national and international codes and standards. HyRAM is a research software in active development and thus the models and data may change. This report will be updated at appropriate developmental intervals. This document provides a description of the methodology and models contained in HyRAM version 3.1. There have been several impactful updates since version 3.0. HyRAM 3.1 contains a correction to use the volume fraction for two-phase speed of sound calculations; this only affects cryogenic releases in which two-phase ow (vapor and liquid) is predicted in the orifice. Other changes include clarifications that inputs for tank pressure should be given in absolute pressure, not gauge pressure. Additionally, the interface now rejects invalid inputs to probability distributions, and the less accurate single-point radiative source model selection was removed from the interface.

08 HYDROGEN↗

Limits to the NEP of an intracavity LiNbO3 upconverter

Limits to low noise equivalent power (NEP) operation of a lithium niobate upconverter are investigated. Upconversion is achieved inside the optical cavity of an Ar-ion laser. Limits to NEP are imposed by limits to conversion efficiency and by noise present in the upconversion process. Conversion efficiency is limited by thermal effects in the lithium niobate. Thermally induced wedging, focusing, and aberrations are caused by the lithium niobate absorption at the 514.5-nm argon pump wavelength. The primary component of noise in the upconverter is due to upconversion of thermal radiation from the lithium niobate crystal. The lowest NEP, at a wavelength of 3.4 microns, achieved in this study was 8.9 x 10 to the -14th W/(Hz to the 1/2 power).

See, Y. C.↗

Heat pipe solar receiver with thermal energy storage

An HPSR Stirling engine generator system featuring latent heat thermal energy storge, excellent thermal stability and self regulating, effective thermal transport at low system delta T is described. The system was supported by component technology testing of heat pipes and of thermal storage and energy transport models which define the expected performance of the system. Preliminary and detailed design efforts were completed and manufacturing of HPSR components has begun.

Zimmerman, W. F.↗

Thermal elastohydrodynamic lubrication of line contacts

A numerical solution to the problem of thermal elastohydrodynamic lubrication of line contacts was obtained by using a finite difference formulation. The solution procedure consists of simultaneous solution of the thermal Reynolds equation, the elasticity equation, and the energy equation subject to appropriate boundary conditions. Pressure distribution, film shape, and temperature distribution were obtained for fully flooded conjunctions, a paraffinic lubricant, and various dimensionless speed parameters while the dimensionless load and materials parameters were held constant. Reduction in the minimum film thickness due to thermal effects (as a ratio of thermal to isothermal minimum film thickness) is given by a simple formula as a function of the thermal loading parameter Q: H(min)/H(min,I) = 10/10+ Q(0.4). Plots of pressure distribution, film shape, temperature distribution, and flow are shown for some representative cases.

Ghosh, M. K.↗

Thermal elastohydrodynamic lubrication of line contacts

A numerical solution to the problem of thermal elastohydrodynamic lubrication of line contacts was obtained by using a finite difference formulation. The solution procedure consists of simultaneous solution of the thermal Reynolds equation, the elasticity equation, and the energy equation subject to appropriate boundary conditions. Pressure distribution, film shape, and temperature distribution were obtained for fully flooded conjunctions, a paraffinic lubricant, and various dimensionless speed parameters while the dimensionless load and materials parameters were held constant. Reduction in the minimum film thickness due to thermal effects (as a ratio of thermal to isothermal minimum film thickness) is given by a simple formula as a function of the thermal loading parameter Q: H(min)/H(min, I) = 10/10 + Q(0.4). Plots of pressure distribution, film shape, temperature distribution, and flow are shown for some representative cases.

Ghosh, M. K.↗

Non-Tidal Non-Seasonal Oceanic Mass Redistribution Estimated from the TOPEX/Poseidon Observation

Topex/Poseidon altimetry data are used to estimate the non-tidal mass redistribution as a function of space-time. The goal is to study the contribution of ocean circulations in the geodynamic effects including Earth's rotational and gravitational variations. We examine the non-seasonal anomalies at monthly sampling rate over the T/P span of eight years, concentrating especially on interannual variabilities. Since the sea-surface height data obtained from altimetry is the combined effect of steric change (primarily thermal effect) and the mass flux, and because the former has zero contribution to the geodynamic effects, one needs to do a so-called steric correction by removing from the altimetry data the steric contributions. We achieve it using multiyear monthly sea-surface temperature maps, together with monthly "climatology" for mixed-layer depth maps for mean-months of the year. We analyze both sets of the altimetry data and the steric correction data using the empirical orthogonal function/principal component analysis (in which we take care of issues associated with the area-weighting and non-zero mean), and examine the most important modes, either globally or regionally. In particular, the ENSO in the tropical Pacific/Indian Oceans exhibits the most prominent pattern. The net mass transport after the steric correction can then be compared with: (1) ocean general circulation model outputs for the same period of time (such as from POCM-4B); (2) non-atmospheric Earth rotation variations obtained from space geodesy data and atmospheric angular momentum data; (3) non-atmospheric low-degree gravitational variations from satellite-laser-ranging observations and global atmospheric data.

Chao, Benjamin F.↗

Apparent Thermal Conductivity Of Multilayer Insulation

Mathematical model of apparent or effective thermal conductivity between two successive layers of multilayer thermal insulation (MLI) offers potential for optimizing performance of insulation. One gains understanding of how each physical mechanism contributes to overall flow of heat through MLI blanket. Model helps analyze engineering tradeoffs among such parameters as number of layers, thicknesses of gaps between layers, types of spacers placed in gaps, weight, overall thickness, and effects of foregoing on apparent thermal conductivity through blanket.

Mcintosh, Glen E.↗

Thermoacoustic Effects at a Solid-Fluid Boundary: The Role of a Second-Order Thermal Expansion Coefficient

Analytical and numerical studies are to be carried out to examine time-averaged thermal effects which are induced by the interaction of strong acoustic fields with a rigid boundary (thermoacoustic streaming). Also of interest is the significance of a second-order thermal expansion coefficient that emerges from this analysis. The model problem to be considered is that of a sphere that is acoustically levitated such that it is effectively isolated in a high-intensity standing acoustic field. The solution technique involves matched asymptotic analysis along with numerical solution of the boundary layer equations. The objective of this study is to predict the thermoacoustic streaming behavior and fully understand the role of the associated second-order thermodynamic modulus.

Gopinath, Ashok↗

Thermal Inertia of Rocks and Rock Populations

The effective thermal inertia of rock populations on Mars and Earth is derived from a model of effective inertia versus rock diameter. Results allow a parameterization of the effective rock inertia versus rock abundance and bulk and fine component inertia. Additional information is contained in the original extended abstract.

Golombek, M. P.↗

Electric-Drive Vehicle Power Electronics Thermal Management: Current Status, Challenges, and Future Directions

Effective thermal management of traction-drive power electronics is critical to the advancement of electric-drive vehicles and is necessary for increasing power density and improving reliability. Replacing traditional silicon devices with more efficient, higher temperature, higher voltage, and higher frequency wide-bandgap (WBG) devices will enable increased power density but will result in higher device heat fluxes. Compact packaging of high-temperature WBG devices near low-temperature-rated components creates thermal management challenges that need to be addressed for future power-dense systems. This paper summarizes the thermal performance of on-road automotive power electronics thermal management systems and provides thermal performance and pumping-power metrics for select vehicles. Thermal analyses reveal that the package/conduction resistance dominates the total thermal resistance (for existing automotive systems). We model advanced packaging concepts and compare the results with existing packaging designs to quantify their thermal performance enhancements. Double-side-cooled configurations that do not use thermal interface materials are package concepts predicted to provide a low junction-to-fluid thermal resistance (compared to current packages). Dielectric-fluid-cooled concepts enable a redesign of the package to reduce the package resistance, can be implemented in single- and two-phase cooling approaches, and allow for cooling of passive components (e.g., capacitors) and bus bars.

33 ADVANCED PROPULSION SYSTEMS↗

A One-dimensional Heat Transfer Model for a Cooled Airfoil in a Direct-fired Supercritical CO 2 Turbine

A one-dimensional (1-D) heat transfer model was developed to predict the performance of a cooled airfoil for a supercritical carbon dioxide (sCO 2 ) turbine. The model included the effects of film cooling effectiveness, thermal barrier coating thickness, and internal Nusselt number augmentation. Trends for overall cooling effectiveness versus heat load parameter were obtained for over twelve unique thermal management schemes. The study found that adding a thermal barrier coating was the most effective scheme for increasing the airfoil overall cooling effectiveness. Internal cooling technologies have diminishing returns as the heat transfer coefficient augmentation increases past a factor of five, however the sensitivity of overall cooling effectiveness to heat transfer augmentation scales by a factor of 1.3 when a thermal barrier coating is introduced. Film cooling is seen as a long-term research area which will be inevitably explored as direct sCO 2 systems develop a market presence. However, the model indicates that realizable film cooling effectiveness levels yield a smaller improvement in overall cooling effectiveness than a thermal barrier coating.

42 ENGINEERING↗

Evaluating Brightness and Stability of Cathodoluminescence from Colloidal Semiconductor Nanocrystals

Cathodoluminescence offers promise as a technique for correlation of atomic structure with electronic structure at the level of individual nanoparticles or even defects, with the ability to analyze complex nanostructures at length-scales far below those typically available to optical spectroscopy. Unlike other forms of electron microscopy, cathodoluminescence offers direct insights into the electronic structure of the visualized sample. Despite reports more than 10 years ago of individual nanoparticle cathodoluminescence, effective cathodoluminescence collection from colloidal semiconductor materials is relatively rare and remains challenging due to the instability of materials under the conditions of electron beam irradiation. In this work, to clarify the roadblocks for cathodoluminescence analysis of colloidal nanocrystals, we attempt a comprehensive study of the cathodoluminescence properties of semiconductor quantum shells, which have a thin concentric CdSe shell surrounding CdS nanoparticles, then surrounded by a further concentric CdS shell. These same materials were recently demonstrated to show promising scintillation performance in radioluminescence measurements, including high brightness (up to 100 ph/keV) and excellent durability. Comparative quantum yield measurements are designed to assess the brightness of semiconductor nanocrystal films, which show that the quantum shells are much less bright under electron irradiation compared to X-ray photons. Instability of CL emission is assigned to charging effects on the samples—and not thermal effects—through a series of voltage, current, dwell time, and atmospheric pressure experiments.

cathodoluminescence↗

Self-shadowing of orbiting trusses

The approach used to assess shadowing reductions on the heating of orbiting trusses involves determining the heating rates with slender member shadowing effects included and then obtaining the thermal response of the shadowed member. Steps taken to identify shadowers, find locations where shadowing occurs and calculate shadow intensity are listed. The finite element thermal structural analysis of cable stiffened space structure is delineated and the exact solution of the caternary problem is given. Typical cable surface heating rates are plotted. The structural analysis includes large deformation (nonlinear), thermal effect, and the pretension effect. Displacements and stresses are computed at different orbital positions for an orbit.

Mahaney, J.↗

Corrosion evaluation of metal foams in eutectic molten salts for high temperature latent heat energy storage application

High-temperature Thermal Energy Storage (TES) has drawn great attention as a technology that can increase the role and profitability of micro nuclear reactors in the decentralized clean energy market. Various research needs have been proposed by Idaho National Laboratory (INL) in "the Integrated Energy Systems: 2020 Roadmap" with the goal of utilizing the high temperature of 550 degrees or more generated in the 4th generation reactor to industrial purposes from the standpoint of integrated energy systems [1]. With the recent development of the 4th generation nuclear power plant, including micro nuclear reactor, there is a great deal of interest in researching how to efficiently couple a heat source to an industrial process through thermal processing. Texas A&M University (TAMU) and INL are currently collaborating to develop a novel latent heat storage design called HITB (Heat pipe-Integrated Thermal Battery). As part of the small-scale experimental demonstration research for HITB, a study for storage medium selection was conducted at TAMU. Eutectic salts have attracted interest as high-temperature heat storage medium for HITB. Especially, chloride molten salts and fluoride molten salts are considered promising candidates due to their high melting temperature, thermal stability, and high latent heat of fusion. Since eutectic salts have poor thermal conductivity in general, it is critical to distribute materials with high thermal conductivity evenly to facilitate the charging and discharging of heat. In this study, metal foam was considered in the HITB system to overcome the poor heat transfer characteristics of eutectic salts. In order to improve heat transfer, it is necessary to study materials with high thermal conductivity, corrosion resistant to molten salts, such as fins, extended surfaces, particles, microcapsulation, or foam structure. Porous structure of copper or aluminum can increase heat transfer area, form a thermal transfer network, and increase the effective thermal conductivity of thermal storage medium [2]. Since the melting temperature is required to be at least 450? in the current HITB design, various eutectic salts are being considered. FLiNaK and FLiBe, which are famous for fluoride salts, are good candidates, but due to the sharp rise in the price of LiF recently, they are excluded for economic reasons to be applied to large-capacity thermal energy storage. On the other hand, chloride salts are very cheap and easy to obtain, have a high melting temperature, and have a high latent heat of fusion, so they are recently in the spotlight as a phase change material. However, because of the hygroscopic nature of chloride salts, HCl gas due to impurity is easy to be released and is particularly vulnerable to corrosion. Chloride eutectic salts have been tested and suggested for metal alloys that are particularly resistant to corrosion, such as SS304, SS316, Hastelloy, Inconel 625, Incoloy 800H, which has low thermal conductivity, and is very expensive [3-6]. Porous materials with high thermal conductivity such as copper and aluminum have been tested for stability in fluids such as paraffin or water as metal foam or metal fin structures, but high temperature corrosion tests were not performed on various eutectic salts yet. Therefore, this study investigated the high temperature corrosion characteristics of metal alloys, such as C10100 foam, C10100 plate, 6101 alloy foam, and SS316 plate, while immersed in the candidate eutectic salts. A total of 20 tests for SS316 coupons and 10 tests for C10100 coupons were performed to ensure the repeatability of the present measurements. Since it is difficult to completely remove the salt inside metal foam due to the complex inner structure of the metal foam, only the surface condition was observed with a microscopy and scanning electron microscopy (SEM) image, except for measuring the corrosion rate and average mass loss.

25 ENERGY STORAGE↗

Treating Fibrous Insulation to Reduce Thermal Conductivity

A chemical treatment reduces the convective and radiative contributions to the effective thermal conductivity of porous fibrous thermal-insulation tile. The net effect of the treatment is to coat the surfaces of fibers with a mixture of transition-metal oxides (TMOs) without filling the pores. The TMO coats reduce the cross-sectional areas available for convection while absorbing and scattering thermal radiation in the pores, thereby rendering the tile largely opaque to thermal radiation. The treatment involves a sol-gel process: A solution containing a mixture of transition-metal-oxide-precursor salts plus a gelling agent (e.g., tetraethylorthosilicate) is partially cured, then, before it visibly gels, is used to impregnate the tile. The solution in the tile is gelled, then dried, and then the tile is fired to convert the precursor salts to the desired mixed TMO phases. The amounts of the various TMOs ultimately incorporated into the tile can be tailored via the concentrations of salts in the solution, and the impregnation depth can be tailored via the viscosity of the solution and/or the volume of the solution relative to that of the tile. The amounts of the TMOs determine the absorption and scattering spectra.

Zinn, Alfred↗

Ground Based Studies of Thermocapillary Flows in Levitated Drops: Analytical Part

The main objectives of the analytical part of this investigation are to study the fluid flow phenomena together with the thermal effects on drops levitated in an acoustic field. To a large extent, experimentation on ground requires a strong acoustic field that has a significant interference with other thermal-fluid effects. While most of the work has been directed towards particles in strong acoustic fields to overcome gravity, some results for microgravity have been obtained. One of the objectives was to obtain the thermocapillary flow in a spot-heated drop, and set up a model for the prediction of thermophysical properties. In addition, for acoustically levitated particles, a clear understanding of the underlying fluid mechanics was required. Also, the interaction of acoustics with steady and pulsating thermal stimuli was required to be analyzed. The experimental part of the work was funded through JPL, and has been reported separately.

Sadhal, S. S.↗