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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 541 records · Page 30
All sourcesNASA NTRSDOE OSTI
DOE OSTI2012

Synthesis and properties of a new quadruple perovskite: A-site ordered PbMn{sub 3}Mn{sub 4}O{sub 12}

PbMn{sub 3}Mn{sub 4}O{sub 12} a quadruple perovskite was prepared by high pressure and high temperature synthesis. Powder X-ray diffraction (PXD) and differential scanning calorimetry reveal a structural phase transition at {approx}380 K. Rietveld refinement of the synchrotron room temperature data indicate rhombohedral symmetry (R-3) with a=6.43675(4) A and {alpha}=109.556(2) Degree-Sign . Similar 423 K PXD data refined in a body centered cubic cell (Im-3) with a=7.4283(9) A. The temperature variation of magnetization, shows a magnetic field dependent antiferromagnetic-like transition at 68 K, and dynamic fluctuations indicative of magnetic frustration. The semiconducting electrical behavior indicates a large decrease in the conductivity near 68 K. The temperature dependence of the real part of the dielectric constant, {epsilon}{sub real} increases dramatically at {approx}68 K, and shows relaxor-type ferroelectric behavior as a function of frequency. The intimate coupling of magnetic, electrical and dielectric properties at 68 K in PbMn{sub 3}Mn{sub 4}O{sub 12} suggests possible multiferroic behavior. - Graphical abstract: Resistance vs. temperature plot showing drastically increasing resistances at temperatures below 68 K (a). Formation of a frequency dependency of the dielectric constant between 68 K and ambient temperature (b). Sharp cusp in the magnetic susceptibility observed at 68 K which is suppressed with increasing magnetic field (c) indicates coupling of magnetic, electric and dielectric effects. Highlights: Black-Right-Pointing-Pointer PbMn{sub 3}Mn{sub 4}O{sub 12} a quadruple perovskite was prepared at high pressure. Black-Right-Pointing-Pointer A structural transition is seen at 380 K from space group R-3-to-Im-3. Black-Right-Pointing-Pointer An antiferromagnetic transition is observed at 68 K. Black-Right-Pointing-Pointer It is semiconducting with a large decrease in the conductivity near 68 K. Black-Right-Pointing-Pointer The temperature dependence of the dielectric constant increases dramatically at 68 K. Black-Right-Pointing-Pointer Coupling of magnetic, electric and dielectric behavior suggests multiferroicity.

36 MATERIALS SCIENCE↗
DOE OSTI2023

FACsPb Triple Halide Perovskite Solar Cells with Thermal Operation over 200 °C

Formamidinium cesium (FACs) perovskites solar cells have been shown to be among the most stable metal halide perovskites. In this report high-temperature data are presented which systematically and statistically demonstrate the high thermal operation of this system to temperatures in excess of 200 degrees C. Device measurements between 250 K and 490 K show that while some loss of performance is evident at higher temperature, this is driven by reversible halide segregation with no evidence of a structural phase transition over the measurement range probed. Moreover, upon reduction of the temperature back to ambient the power conversion efficiency is retained.

14 SOLAR ENERGY↗
DOE OSTI2022

High-Fuel Loading Ignition Delay Time Characterization of Hydrogen/Natural Gas/Ammonia at Gas Turbine-Relevant Conditions Inside a High-Pressure Shock Tube

Abstract This study explores the combustion characterization of high-fuel percentage, air-diluted mixtures of H2 mixed with natural gas (NG) as well as mixtures of H2 and NH3 at temperatures and pressures relevant to turbine operating conditions (20–30 bar, 1000–1500 K). Lower temperatures (below 1070 K) exhibit preignition characteristics due to non-homogeneity. An attempt to mitigate these occurrences at high pressures is investigated using the constrained reaction volume (CRV) stage-filling technique. Due to the need to further refine the facility CRV stage-filling uncertainty, only higher temperature data will be interpreted at this time. The test conditions in this study closely replicate the temperatures, pressures, and mixtures that would be seen in hydrogen-powered gas turbines, making it the first to explore such conditions. The experimental IDTs were compared against the current state-of-the-art chemical kinetic models for mechanism validation. The current work will advance H2-powered turbines and aims to determine the optimum molecular ratio of H2 when mixed with natural gas.

Pierro, Michael↗
NASA NTRS1991

Thermal environment of Mars

Thermal observations of Mars are reviewed focusing on surface and atmospheric temperatures. Data obtained indicate that the effect of increasing dust in the atmosphere is to reduce diurnal temperature variation at the surface, while enhancing atmospheric thermal variation. Atmospheric thermal effects can be induced by global dust storms even in regions of polar night. Maximum temperatures occur near the equator in summer or at local sites with sunward facing slopes, where low surface thermal inertias make it possible to achieve values up to about 310 K. Radiation and convection in the daytime affect atmospheric temperatures near the surface, which are limited by radiation at night. Results of thermal observations confirm that Mars' thermal state and climate can significantly vary from year to year, due to the variation in dust activity.

Martin, T. Z.↗
NASA NTRS1983

Frost Forecasting for Fruitgrowers

Progress in forecasting from satellite data reviewed. University study found data from satellites displayed in color and used to predict frost are valuable aid to agriculture. Study evaluated scheme to use Earth-temperature data from Geostationary Operational Environmental Satellite in computer model that determines when and where freezing temperatures endanger developing fruit crops, such as apples, peaches and cherries in spring and citrus crops in winter.

Martsolf, J. D.↗
NASA NTRSDate not supplied

3D Material Response of the MSL Heatshield Using NuSil-Coated PICA

The Mars Science Laboratory (MSL) was protected during its atmospheric entry by an instrumented heatshield that used NASA's Phenolic Impregnated Carbon Ablator (PICA) material [1]. PICA is a lightweight carbon fiber/polymeric resin material that offers outstanding performance for protecting probes during planetary entry. Data from the Mars Entry Descent and Landing Instrument (MEDLI) suite on MSL offers unique in-flight validation data for models of material response and atmospheric entry. MEDLI recorded, among other things, time-resolved in-depth temperature data of PICA using thermocouple sensors assembled in the MEDLI Integrated Sensor Plugs (MISP) [2]. A space-grade silicone-based coating commercially known as NuSil CV-1144-0 [3] was applied to the entire MSL heatshield, including the MEDLI plugs, to mitigate the spread of dust from PICA. Modeling the thermal response of PICA-NuSil (PICA-N) system is still an open challenge. Ground testing of PICA-N models exhibited surface temperature jumps of the order of 150 K due to oxide scale formation and sub-sequent NuSil burn-off. It is therefore critical to include a validated model for the material response of the coating in engineering codes. A test campaign has been conducted at the NASA’s Langley HyMETS [4] facility to screen the response of PICA-N and gather detailed data on its behavior [5]. A first model of PICA-N thermal response has been developed using the Hy-METS experiments [6]. The objective of this work is to analyze the material response of the latest PICA-N model compared to the engineering model used to simulate the entry of MSL. The environment and material response around the MSL aeroshell during Mars atmospheric entry is simulated using a collection of tools. The Direct Simulation Monte Carlo SPARTA code [7] is used in the rarefied regime, the Data Parallel Line Relaxation (DPLR) code [8] is used in the continuum regime and radiative heating conditions are provided by the Nonequilibrium air radiation (NEQAIR) code [9] to estimate the environmental conditions. The thermal response inside the material is computed using the Porous material Analysis Toolbox based on Open-FOAM (PATO) [10,11,12]. Thermodynamic and chemistry properties are estimated using the Mutation++ library [13]. The approach implemented in PATO as a first cut PICA-N thermal response model is outlined in Figure 1. While the recession is less than the coating thickness, the Surface mass and energy balance Boundary Condition (SBC) uses the NuSil B’ tables. Once the recession removes the coating, the usual PICA B’ tables are used for the SBC. The B’ tables are computed using an equilibrium solver implemented in Mutation++, given the temperature, pressure, blowing rate, composition of the pyrolysis and environment gases, and the condensed species at the surface. Preliminary results of the 3D material response of the MSL heat-shield at the peak heating (80 sec after Entry Interface) are shown in Figure 2. Current NASA’s mission to Mars, Mars 2020, used the spare heatshield of MSL for thermal protection during entry, descent, and landing. In preparation for Mars 2020 post-flight analysis, the PATO high-fidelity material response capability was benchmarked against flight data from MEDLI. This effort represents an important milestone toward the development of validated predictive capabilities for designing thermal protection systems for planetary probes. This bench-marking is awaiting the final release of the MEDLI-2 data.

Aerospace↗
NASA NTRS2000

System Being Developed to Measure the Rotordynamic Characteristics of Air Foil Bearings

Because of the many possible advantages of oil-free engine operation, interest in using air lubricated foil-bearing technology in advanced oil-free engine concepts has recently increased. The Oil-Free Turbomachinery Program at the NASA Glenn Research Center at Lewis Field has partially driven this recent push for oil-free technology. The program's goal of developing an innovative, practical, oil-free gas turbine engine for aeropropulsion began with the development of NASA's high-temperature solid-lubricant coating, PS304. This coating virtually eliminates the life-limiting wear that occurs during the startup and shutdown of the bearings. With practically unlimited life, foil air bearings are now very attractive to rotating machinery designers for use in turbomachinery. Unfortunately, the current knowledge base of these types of bearings is limited. In particular, the understanding of how these types of bearings contribute to the rotordynamic stability of turbomachinery is insufficient for designers to design with confidence. Recent work in oil-free turbomachinery has concentrated on advancing the understanding of foil bearings. A high-temperature fiber-optic displacement probe system and measurement method were developed to study the effects of speed, load, temperature, and other environmental issues on the stiffness characteristics of air foil bearings. Since high temperature data are to be collected in future testing, the testing method was intentionally simplified to minimize the need for expensive test hardware. The method measures the displacement induced upon a bearing in response to an applied perturbation load. The early results of these studies, which are shown in the accompanying figure, indicate trends in steady state stiffness that suggest stiffness increases with load and decreases with speed. It can be seen, even from these data, that stiffness is not expected to change by orders of magnitude over the normal operating range of most turbomachinery; a promising sign for their eventual integration into oil-free turbomachines. Planned future testing will generate similar plots for stiffness changes with temperature and geometry, as well as damping data. The data collected by this method represent a critical step toward understanding how to successfully apply foil air bearings to future oil-free turbomachinery systems.

Howard, Samuel A.↗
DOE OSTI2016

Development of an interatomic potential for the simulation of defects, plasticity, and phase transformations in titanium

New interatomic potentials describing defects, plasticity, and high temperature phase transitions for Ti are presented. Fitting the martensitic hcp-bcc phase transformation temperature requires an efficient and accurate method to determine it. We apply a molecular dynamics method based on determination of the melting temperature of competing solid phases, and Gibbs-Helmholtz integration, and a lattice-switch Monte Carlo method: these agree on the hcp-bcc transformation temperatures to within 2 K. We were able to develop embedded atom potentials which give a good fit to either low or high temperature data, but not both. The first developed potential (Ti1) reproduces the hcp-bcc transformation and melting temperatures and is suitable for the simulation of phase transitions and bcc Ti. Two other potentials (Ti2 and Ti3) correctly describe defect properties and can be used to simulate plasticity or radiation damage in hcp Ti. The fact that a single embedded atom method potential cannot describe both low and high temperature phases may be attributed to neglect of electronic degrees of freedom, notably bcc has a much higher electronic entropy. As a result, a temperature-dependent potential obtained from the combination of potentials Ti1 and Ti2 may be used to simulate Ti properties at any temperature.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Thermal stress in degraded forests in the Brazilian Amazon Arc of Deforestation

Understanding thermal stress in tropical forests has taken on new urgency in light of accelerating climate change and expansion of deforestation and forest degradation. Degraded tropical forests in particular may be approaching critical temperature thresholds even more rapidly than intact forests, with implications for tree survival and ecosystem recovery. We investigate thermal stress in degraded tropical forests within the Brazilian Amazon Arc of Deforestation. Using land surface temperature data from the ECOsystem Spaceborne Thermal Radiometer Experiment on the international Space Station (ECOSTRESS), we compared canopy temperatures of intact, selectively logged, and burned forests in Feliz Natal, Mato Grosso, Brazil. Upper canopy temperatures in previously burned forests were 4.1% higher (mean = 36.5 °C) and 50.9% more variable compared to intact and logged forests, which showed remarkably similar temperature distributions (means of 34.9 °C and 35.1 °C, respectively). Modeled leaf temperature distributions based on canopy temperature measurements from one of the warmest days in a 2 year dry season record indicated that 87% of leaves in the warmest burned forest patches exceeded the temperature threshold where respiration surpasses photosynthesis, compared to approximately 72%–74% in intact and logged forests, respectively, in the same time period. After controlling for environmental factors, burned forests were predicted to be 2.6 °C warmer on average [1.39 °C–3.96 °C, 95% credible interval] than intact forests across a 5–40 m canopy height range. Burned forests showed modest thermal recovery over time, with temperatures decreasing by approximately 1.2 °C over a 30 year recovery period. In contrast, logged forests showed minimal thermal differences from intact forests (−0.353 on average, [−1.125–0.274, 95% credible interval]) and negligible change (0.15 °C) over the same timeframe. While the absolute probabilities of exceeding damaging thermal thresholds remain low across all forest types under current climate conditions, the probability of leaves exceeding temperatures that cause permanent leaf damage was ten times higher in burned forests, with implications for the future of burned forest regeneration in water-limited regions of the Amazon basin. In particular, the combination of higher mean temperatures, greater temperature variability, and more frequent exposure to damaging thermal thresholds implies that burned tropical forests will experience substantially higher mortality rates and slower biomass recovery compared to intact and selectively logged forests, especially in water-limited regions where trees cannot rely on evaporative cooling to moderate canopy temperatures.

Brazilian Amazon Arc of Deforestation↗
NASA NTRS1991

Pressure dependence of the melting temperature of solids - Rare-gas solids

A method presented by Schlosser et al. (1989) for analyzing the pressure dependence of experimental melting-temperature data is applied to rare-gas solids. The plots of the logarithm of the reduced melting temperature vs that of the reduced pressure are straight lines in the absence of phase transitions. The plots of the reduced melting temperatures for Ar, Kr, and Xe are shown to be approximately straight lines.

Schlosser, Herbert↗
NASA NTRS1992

A comparison of Nimbus 7 limb infrared monitor of the stratosphere and radiosonde temperatures in the lower stratosphere poleward of 60N

The quality of the more widely used, mapped version of the LIMS temperature data set (LAMAT) is assessed for the polar lower stratosphere by comparison with lower stratospheric radiosonde (RAOB) temperatures at a set of 22 stations. Average LIMS minus uncorrected RAOB values are within +/-0.3 K at 30, 50, and 70 hPa, and -1.2 +/-2.2 K at 100 hPa. The generally excellent LIMS/RAOB temperature comparisons at 10 to 70 hPa support the contention that there are no significant temperature bias errors in the LIMS constituent distributions for polar regions. LIMS minus RAOB differences at 100 hPa are slightly negative for the present station set, in agreement with that found by Grose et al. (1988). The month-by-month LIMS minus RAOB analysis at 100 hPa showed that LIMS is -1.9 +/-1.8 K too cold in November and December.

Remsberg, Ellis E.↗
NASA NTRS1994

Temperature variations in the middle and upper stratosphere: 1979-1992

Temperature variations in the stratosphere from 1979 to 1992 are investigated using 365-day running mean of the National Meteorological Center gridded analysis temperature data. Significant variations are seen at all levels between 70 and 1 mbar. The middle stratosphere shows temperature peaks during 1982 and 1983. The upper stratosphere has significant temperature declines between 1 and 10 mbar from 1981 to 1984. Temperatures at all levels recover to near their prior values after 1984, with the 5-mbar temperatures requiring the greatest time to fully recover. The temperature declines at 1 mbar occur in both hemispheres, over all longitudes, and in every month of the year. The decreases are largest in the middle latitudes and the polar regions and during the fall and the winter months. Such temperature variations, which appear to be of natural origin, must be taken into consideration when searching for temperature trends caused by the increase of CO2 or other greenhouse gases which affect the radiative balance of the Earth-atmosphere system or stratospheric ozone.

Lambeth, James D.↗
NASA NTRS2013

Datacasting V3.0

Datacasting V3.0 provides an RSSbased feed mechanism for publishing the availability of Earth science data records in real time. It also provides a utility for subscribing to these feeds and sifting through all the items in an automatic manner to identify and download the data records that are required for a specific application. Datacasting is a method by which multiple data providers can publish the availability of new Earth science data and users download those files that meet a predefined need; for example, to only download data files related to a specific earthquake or region on the globe. Datacasting is a server-client architecture. The server-side software is used by data providers to create and publish the metadata about recently available data according to the Datacasting RSS (Really Simple Syndication) specification. The client software subscribes to the Datacasting RSS and other RSS-based feeds. By configuring filters associated with feeds, data consumers can use the client to identify and automatically download files that meet a specific need. On the client side, a Datacasting feed reader monitors the server for new feeds. The feed reader will be tuned by the user, via a graphical user interface (GUI), to examine the content of the feeds and initiate a data pull after some criteria are satisfied. The criteria might be, for example, to download sea surface temperature data for a particular region that has cloud cover less than 50% and during daylight hours. After the granule is downloaded to the client, the user will have the ability to visualize the data in the GUI. Based on the popular concept of podcasting, which gives listeners the capability to download only those MP3 files that match their preference, Earth science Datacasting will give users a method to download only the Earth science data files that are required for a particular application.

Bingham, Andrew W.↗
NASA NTRS1972

The thermodynamic properties of oxygen and nitrogen. Part 1: Thermodynamic properties of nitrogen from 115 R to 3500 R with pressures to 150000 psia

An equation of state is presented for liquid and gaseous nitrogen for temperatures from 115 R to 3500 R and pressures to 150,000 psia. All of the pressure-density-temperature data available from the published literature have been reviewed, and appropriate corrections have been identified and applied to bring experimental temperatures into accord with the International Practical Temperature Scale of 1968. Comparisons of property values calculated from the equation of state to measured values are included to illustrate the accuracy of the equation in representing the data. The coefficients of the equation of state were determined by a weighted least squares fit to selected published data and, simultaneously, to constant volume data determined by corresponding states analysis from oxygen data, and to data which define the phase equilibrium criteria for the saturated liquid and saturated vapor. The methods of weighting the various data for simultaneous fitting are presented and discussed. The equation of state is estimated to be accurate to within 0.5 percent in the liquid region, to within 0.1 percent for supercritical isotherms up to 15,000 psia, and to within 0.3 percent from 15,000 to 150,000 psia.

Stewart, R. B.↗
DOE OSTI2024

Local-scale heterogeneity of soil thermal dynamics and controlling factors in a discontinuous permafrost region

In permafrost regions, the strong spatial and temporal variability in soil temperature cannot be explained by the weather forcing only. Understanding the local heterogeneity of soil thermal dynamics and their controls is essential to understand how permafrost systems respond to climate change and to develop process-based models or remote sensing products for predicting soil temperature. In this study, we analyzed soil temperature dynamics and their controls in a discontinuous permafrost region on the Seward Peninsula, Alaska. We acquired one-year temperature time series at multiple depths (at 5 or 10 cm intervals up to 85 cm depth) at 45 discrete locations across a 2.3 km 2 watershed. We observed a larger spatial variability in winter temperatures than that in summer temperatures at all depths, with the former controlling most of the spatial variability in mean annual temperatures. We also observed a strong correlation between mean annual ground temperature at a depth of 85 cm and mean annual or winter season ground surface temperature across the 45 locations. We demonstrate that soils classified as cold, intermediate, or warm using hierarchical clustering of full-year temperature data closely match their co-located vegetation (graminoid tundra, dwarf shrub tundra, and tall shrub tundra, respectively). We show that the spatial heterogeneity in soil temperature is primarily driven by spatial heterogeneity in snow cover, which induces variable winter insulation and soil thermal diffusivity. These effects further extend to the subsequent summer by causing variable latent heat exchanges. Finally, we discuss the challenges of predicting soil temperatures from snow depth and vegetation height alone by considering the complexity observed in the field data and reproduced in a model sensitivity analysis.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2003

Investigation of Tropical Dynamics and Transport with UARS Data

Our research focused on Kelvin waves in the tropical lower stratosphere, and resulted in three papers published or submitted to the Journal of Geophysical Research. The first of these, published in 2002, used temperature data from the Microwave Limb Sounder to examine the amplitude, frequency, phase, and spatial structure of leading modes of Kelvin waves. The second and third, submitted late in 2002 and currently in revision, described the response to Kelvin waves of various trace constituents measured by MLS and CLAES (methane, nitrous oxide, CFC-12, and ozone in the second paper; water vapor in the third paper). Water vapor is a special case because the vertical structure induced by Kelvin waves is convolved with water vapor's seasonally varying vertical profile induced by seasonal variations in temperature at the tropical tropopause. Forward modeling indicated that the vertical resolution of MLS was indeed adequate to capture this complicated structure, yet it was not visible in the MLS data, though the Kelvin wave signature was clear on certain UARS levels. The effects of Kelvin waves on the tropical tropopause and on stratosphere- troposphere exchange cannot be quantified from UARS data because of poor vertical resolution and sensitivity in that region. It is recommended that this analysis be repeated using data from the new MLS and HIRDLS instruments aboard Aura, and that priority be given to fine-scale retrievals of temperature, water vapor, and ozone in the tropical tropopause region.

Jackman, Charles↗
DOE OSTI2023

Data and scripts associated with "Coupled primary production and respiration in a large river contrasts with smaller rivers and streams."

This data package is associated with the publication "Coupled primary production and respiration in a large river contrasts with smaller rivers and streams." in review at Limnology and Oceanography (Roley et al. 2023). This study focuses on understanding ecosystem metabolism for the Hanford Reach of the Columbia River in Washington state, a free-flowing stretch with a substantial discharge. Large rivers have been overlooked compared to small and medium rivers due to the challenges associated with measurements. Our study presents novel ways to address these challenges and highlights that metabolism patterns in large rivers differ from those observed in small-medium rivers and requires the application of knowledge and tools beyond those implemented for smaller rivers.This data package includes the data and R scripts for the analyses described in Roley et al. 2023. It includes dissolved oxygen and temperature data from a dissolved oxygen HOBO sensor, light data collected from the National Solar Radiation Database (https://nsrdb.nrel.gov/) and hydrologic variables estimated from the MASS-1 model (Niehus et al.; 2014). It also includes metabolism estimates (gross primary production, ecosystem respiration, and net ecosystem production) estimated via streamMetabolizer (Appling et al.; 2018). All analyses in the paper can be replicated with these data and scripts.The data package is comprised of one main data folder. The folder includes (1) file-level metadata (flmd); (2) a data dictionary (dd) for each data file; (3) data files; and (4) R scripts for metabolism estimates and data analysis. All files are .R, .csv, or .pdf.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Utah FORGE: Well 58-32 Stimulation Data

Pressure, temperature, and flow data from open-hole, upper perforation, and lower perforation well stimulations gathered from various tools collected at well 58-32 during phase 2C.

15 GEOTHERMAL ENERGY↗