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NASA NTRSDate not supplied

Use of Beacon Satellites for Efficient Uplink Transmission for Free-Space Quantum Entanglement Distribution

Efficient transmission of optical beams from ground to space is important for free-space entanglement distribution in a dual-uplink architecture in which photons from entanglement sources at two ground locations interact in an optical Bell-state measurement implemented on a satellite. Efficient transmission requires large transmitting apertures to minimize diffraction losses and high-performance adaptive optics to overcome the effects of atmospheric turbulence. Achieving good atmospheric compensation for beams transmitted to satellites is challenging because the need to point ahead of the satellite introduces anisoplanatism error that limits the effectiveness of the adaptive optics. An attractive approach for solving the point-ahead problem is to position a separate small satellite at the point-ahead location to provide a beacon source for the adaptive optics. This paper presents analysis of the requirements for the beacon source(s) for a dual-uplink entanglement-distribution demonstration. A relative performance metric is defined and evaluated for multiple beacon configurations, from a single, fixed beacon serving both ground sites to a dedicated beacon for each site continually adjusted to be at the correct point-ahead distance from the target satellite.

quantum↗
NASA NTRS1975

Superconducting quantum-interference devices

Published document discusses devices which are based on weak-link Josephson elements that join superconductors. Links can take numerous forms, and circuitry utilizing links can perform many varied functions with unprecedented sensitivity. Theoretical review of Josephson's junctions include tunneling junctions, point contact devices, microbridges, and proximity-effect devices.

Peters, P. N.↗
NASA NTRS1998

Study of Atmospheric Nitric Oxide

We investigated the contribution of energetic nitrogen atoms to the production of nitric oxide in the thermosphere and their influence on the infrared emission spectrum. The nitric oxide molecules are important contributors to the cooling of the atmosphere. We first pointed out that in determining the energy distribution of the nitrogen atoms, it is important to take into account the thermal motion of the atmospheric gases. It had been ignored in all earlier studies. The source spectra are broadened considerably by the center of mass motion of the reactants. We worked out the consequences for the production of nitric oxide at night, using as sources of energetic N atoms, NO(+) + e yield N + O, N(D-2) + O yield N + O. The high energy tail is enhanced by orders of magnitude. We had earlier suggested (Sharma et al. 1993) that the reaction of energetic nitrogen atoms with O2 was responsible for the rotationally enhanced NO identified in the infrared spectrum. Our calculations provided quantitative confirmation of the suggestion. We proceeded to explore the validity of another approximation used in earlier analyses, the hard sphere approximation for the energy loss in elastic collisions. We carried out precise quantum mechanical calculations of the elastic 2 differential scattering of nitrogen atoms in collisions with oxygen atoms and showed that although the hard sphere approximation was nowhere of high precision, reasonable results could be obtained with an effective cross section of 6 x 10(exp 15)sq cm. We also initiated a program to include inelastic energy loss processes in the determination of the energy distribution function. We began a calculation of the rotation and vibrational excitation cross sections of molecular nitrogen and nitrogen atoms and developed a method for including inelastic energy loss as a function of scattering angle in the Boltzmann equation. A procedure for obtaining the solution of the Boltzman equation was worked out.

Dalgarno, A.↗
NASA NTRS1994

Toward astrometric tracking with the infrared spatial interferometer

Infrared interferometric demonstrations with the University of California, Berkeley's infrared spatial interferometer (ISI) on Mt. Wilson explore the potential of infrared and optical astrometry for deep space tracking, reference frame development, and DSN science. Astrometric data taken and analyzed over the last five years from the ISI have shown that instrumental and atmospheric effects limit current demonstrations. The benefits of sensitivity upgrades, which were performed in 1991 and 1992, have been demonstrated by comparing point-to-point phase fluctuations for the fall 1989 and fall 1992 observing epochs. This comparison showed that point-to-point phase fluctuations due to tropospheric and quantum noise, for optimal integration times of 0.2 sec, are approaching the 0.1-cycle level needed to reliably connect the interferometric phase. The increase in sensitivity, coupled with that arising from very recent hardware upgrades, will greatly enhance phase-connection capabilities necessary for astrometry in the presence of atmospheric refractivity fluctuations. The current data set suggests that atmospheric fluctuations on Mt. Wilson during the best seeing are dominated by a low-lying component, approximately 25 m high, which may be minimized with in situ calibration in the future. During poor seeing conditions that currently prohibit the interferometric phase connection necessary for astrometry, fluctuations seem to be generated by atmospheric inhomogeneities at much higher altitudes above Mt. Wilson. Data taken over the last year suggest that the ISI will soon be able to achieve 50- to 100-nrad astrometry in a single observing session, employing current ground-based laser distance interferometer calibrations to minimize atmospheric effects.

Treuhaft, R. N.↗
NASA NTRS1972

Excitation of sodium D-line radiation in collisions of sodium atoms with internally excited H2, D2 and N2.

Excitation of D-line radiation in collisions of Na atoms with vibrationally excited N2, H2, and D2 was studied in two modulated crossed-beam experiments. In both experiments, the molecular excitation was provided by heating the molecular beam to temperatures which were assumed to give populations corresponding to the Boltzmann distribution. In the first experiment, a total rate coefficient was measured as a function of molecular beam temperature. The second experiment achieved partial separation of internal vs kinetic energy transfer effects by using a velocity-selected molecular beam. The data from both experiments were used to determine parameters for the dependence of the transfer cross section upon the kinetic energy for a given change in the vibrational quantum number. Results indicate that most of the Na excitation energy comes from internal vibrational energy, with the remainder coming from kinetic energy.

Krause, H. F.↗
NASA NTRS1983

Interpretation of the 6818.9-A methane feature observed on Jupiter, Saturn, and Uranus

High-resolution (0.1-A) spectra of the 6818.9-A methane feature obtained for Jupiter, Saturn, and Uranus by Baines, Schempp, and Smith (1969) are modeled using a doubling and adding code after Hansen (1983). The feature's rotational quantum number is estimated using the relatively homogeneous atmosphere of Saturn, with only J = 0 and J = 1 fitting the observational constraints. The aerosol content within Saturn's northern temperate region is shown to be substantially less than at the equator, indicating a haze only half as optically thick. Models of Jupiter's atmosphere are consistent with the rotational quantum-number assignment. Synthetic line profiles of the 6818.9-A feature observed on Uranus reveal that a substantial haze exists at or above the methane condensation region with an optical depth eight times greater than previously reported. Seasonal effects are indicated. The methane column abundance is 5 + or - 1 km-am. The mixing ratio of methane to hydrogen within the deep unsaturated region of the planet is 0.045 + or - 0.025, based on an H2 column abundance of 240 + or - 60 km-am (Smith, Macy, and Pilcher /1980/), thus indicating that methane comprises between one-sixth and one-half of the planet's mass. However, proper reevaluation of H2 quadrupole features accounting for the haze reported here may significantly reduce the relative methane abundance.

Baines, K. H.↗
NASA NTRS1990

Speculations and inquiries regarding the possibilities for and limitations to practical interstellar travel

The existence of superluminal phenomena have now been independently confirmed by physicists working in several different laboratories, most notably by the team of Alain Aspect in Paris. The two major variants of these experiments are described and their implications for superluminal communication and superluminal travel are discussed. It is noted that while the original suggestion for these experiments is due in part to Albert Einstein (Einstein, Rosen, and Podolsky, 1935), their recent empirical validation presents a significant anomaly within the theoretical framework of the special theory of quantum mechanics. How a newly emerging paradigm broadly encompassing the empirical sciences, and informed by both the social sciences and general systems theory may resolve this theoretical crisis is discussed. With the impasse to further elaboration of these effects for possible superluminal applications removed, the discussion concludes with a research proposal.

Gardiner, William W.↗
NASA NTRS1999

Modeling of THz Lasers Based on Intersubband Transitions in Semiconductor Quantum Wells

In semiconductor quantum well structures, the intersubband energy separation can be adjusted to the terahertz (THz) frequency range by changing the well width and material combinations. The electronic and optical properties of these nanostructures can also be controlled by an applied dc electric field. These unique features lead to a large frequency tunability of the quantum well devices. In the on-going project of modeling of the THz lasers, we investigate the possibility of using optical pumping to generate THz radiation based on intersubband transitions in semiconductor quantum wells. We choose the optical pumping because in the electric current injection it is difficult to realize population inversion in the THz frequency range due to the small intersubband separation (4-40 meV). We considered both small conduction band offset (GaAs/AlGaAs) and large band offset (InGaAs/AlAsSb) quantum well structures. For GaAs/AlGaAs quantum wells, mid-infrared C02 lasers are used as pumping sources. For InGaAs/AlAsSb quantum wells, the resonant intersubband transitions can be excited by the near-infrared diode lasers. For three- and four-subband quantum wells, we solve the pumpfield-induced nonequilibrium distribution function for each subband of the quantum well system from a set of rate equations that include both intrasubband and intersubband relaxation processes. Taking into account the coherent interactions between pump and THz (signal) waves, we calculate the optical gain for the THz field. The gain arising from population inversion and stimulated Raman processes is calculated in a unified manner. A graph shows the calculated THz gain spectra for three-subband GaAs/AlGaAs quantum wells. We see that the coherent pump and signal wave interactions contribute significantly to the gain. The pump intensity dependence of the THz gain is also studied. The calculated results are shown. Because of the optical Stark effect and pump-induced population redistribution, the maximum THz gain saturates at larger pump intensities.

Liu, Ansheng↗
NASA NTRS2013

Trace Contaminant Control: An In-Depth Study of a Silica-Titania Composite for Photocatalytic Remediation of Closed-Environment Habitat Air

This collection of studies focuses on a PCO system for the oxidation of a model compound, ethanol, using an adsorption-enhanced silica-TiO2 composite (STC) as the photocatalyst; studies are aimed at addressing the optimization of various parameters including light source, humidity, temperature, and possible poisoning events for use as part of a system for gaseous trace-contaminant control system in closed-environment habitats. The first goal focused on distinguishing the effect of photon flux (i.e., photons per unit time reaching a surface) from that of photon energy (i.e., wavelength) of a photon source on the PCO of ethanol. Experiments were conducted in a bench-scale annular reactor packed with STC pellets and irradiated with either a UV-A fluorescent black light blue lamp O max=365 nm) at its maximum light intensity or a UV-C germicidal lamp O. max=254 nm) at three levels of light intensity. The STC-catalyzed oxidation of ethanol was found to follow zero-order kinetics with respect to CO2 production, regardless of the photon source. Increased photon flux led to increased EtOH removal, mineralization, and oxidation rate accompanied by lower intermediate concentration in the effluent. The oxidation rate was higher in the reactor irradiated by UV-C than by UV-A (38.4 vs. 31.9 nM s-1 ) at the same photon flux, with similar trends for mineralization (53.9 vs. 43.4%) and reaction quantum efficiency (i.e., photonic efficiency, 63.3 vs. 50.1 nmol C02 ~mol photons-1 ). UV-C irradiation also led to decreased intermediate concentration in the effluent compared to UV -A irradiation. These results demonstrated that STC-catalyzed oxidation is enhanced by both increased photon flux and photon energy. The effect of temperature and relative humidity on the STC-catalyzed degradation of ethanol was also determined using the UV-A light source at its maximum intensity.

Coutts, Janelle L.↗
NASA NTRS1989

Characterization of quantum well structures using a photocathode electron microscope

Present day integrated circuits pose a challenge to conventional electronic and mechanical test methods. Feature sizes in the submicron and nanometric regime require radical approaches in order to facilitate electrical contact to circuits and devices being tested. In addition, microwave operating frequencies require careful attention to distributed effects when considering the electrical signal paths within and external to the device under test. An alternative testing approach which combines the best of electrical and optical time domain testing is presented, namely photocathode electron microscope quantitative voltage contrast (PEMQVC).

Spencer, Michael G.↗
NASA NTRS1978

Passive imaging through the turbulent atmosphere - Fundamental limits on the spatial frequency resolution of a rotational shearing interferometer

The signal-to-noise (S/N) ratio to be expected when a 180 deg rotationally shearing interferometer is used for image recovery at the diffraction limit of a large telescope is computed. The variance and covariance of the irradiance fluctuations at the detector array are shown to yield measures of the high-frequency spatial spectrum of the source. Four fundamental sources of noise are considered: temporal fluctuations of the source, space-time fluctuations of the atmosphere, shot noise in the detected photocurrents, and the effects of finite sampling. S/N is found to be directly proportional to the angular resolution of the telescope, the single-frame integration time, the square root of the number of frames, the cube of the operating wavelength, the quantum efficiency of the detector, and the average spectral irradiance from the source on the pupil. It is inversely proportional to the cube of the field angle subtended by the source (or part thereof) under study.

Burke, J. J.↗
NASA NTRS1996

Coupled Structural, Thermal, Phase-change and Electromagnetic Analysis for Superconductors, Volume 2

Described are the theoretical development and computer implementation of reliable and efficient methods for the analysis of coupled mechanical problems that involve the interaction of mechanical, thermal, phase-change and electromag subproblems. The focus application has been the modeling of superconductivity and associated quantum-state phase change phenomena. In support of this objective the work has addressed the following issues: (1) development of variational principles for finite elements, (2) finite element modeling of the electromagnetic problem, (3) coupling of thermel and mechanical effects, and (4) computer implementation and solution of the superconductivity transition problem. The main accomplishments have been: (1) the development of the theory of parametrized and gauged variational principles, (2) the application of those principled to the construction of electromagnetic, thermal and mechanical finite elements, and (3) the coupling of electromagnetic finite elements with thermal and superconducting effects, and (4) the first detailed finite element simulations of bulk superconductors, in particular the Meissner effect and the nature of the normal conducting boundary layer. The theoretical development is described in two volumes. Volume 1 describes mostly formulation specific problems. Volume 2 describes generalization of those formulations.

Felippa, C. A.↗
NASA NTRS2003

Investigations of Relatively Easy To Construct Antennas With Efficiency in Receiving Schumann Resonances: Preparations for a Miniaturized Reconfigurable ELF Receiver

Relatively little is known about the cavity between the Earth and the ionosphere, which opens opportunities for technological advances and unique ideas. One effective means to study this cavity is with extremely low frequency (ELF) antennas. Possible applications of these antennas are global weather prediction, earthquake prediction, planetary exploration, communication, wireless transmission of power, or even a free energy source. The superconducting quantum interference device SQUID) and the coil antenna are the two most acceptable receivers discovered for picking up ELF magnetic fields. Both antennas have the potential for size reduction, allowing them to be portable enough for access to space and even for personal ware. With improvements of these antennas and signal processing, insightful analysis of Schumann resonance (SR) can give the science community a band of radio frequency (RF) signals for improving life here on Earth and exploring beyond.

Farmer, Brian W.↗
NASA NTRS2013

Constraints on Lorentz Invariance Violation from Fermi -Large Area Telescope Observations of Gamma-Ray Bursts

We analyze the MeV/GeV emission from four bright Gamma-Ray Bursts (GRBs) observed by the Fermi-Large Area Telescope to produce robust, stringent constraints on a dependence of the speed of light in vacuo on the photon energy (vacuum dispersion), a form of Lorentz invariance violation (LIV) allowed by some Quantum Gravity (QG) theories. First, we use three different and complementary techniques to constrain the total degree of dispersion observed in the data. Additionally, using a maximally conservative set of assumptions on possible source-intrinsic spectral-evolution effects, we constrain any vacuum dispersion solely attributed to LIV. We then derive limits on the "QG energy scale" (the energy scale that LIV-inducing QG effects become important, E(sub QG)) and the coefficients of the Standard Model Extension. For the subluminal case (where high energy photons propagate more slowly than lower energy photons) and without taking into account any source-intrinsic dispersion, our most stringent limits (at 95% CL) are obtained from GRB 090510 and are E(sub QG,1) > 7.6 times the Planck energy (E(sub Pl)) and E(sub QG,2) > 1.3×10(exp 11) GeV for linear and quadratic leading order LIV-induced vacuum dispersion, respectively. These limits improve the latest constraints by Fermi and H.E.S.S. by a factor of approx. 2. Our results disfavor any class of models requiring E(sub QG,1) < or approx. E(sub Pl)

Planck↗
NASA NTRS2017

Revised Models of Interstellar Nitrogen Isotopic Fractionation

Nitrogen-bearing molecules in cold molecular clouds exhibit a range of isotopic fractionation ratios and these molecules may be the precursors of 15N enrichments found in comets and meteorites. Chemical model calculations indicate that atom-molecular ion and ion-molecule reactions could account for most of the fractionation patterns observed. However, recent quantum-chemical computations demonstrate that several of the key processes are unlikely to occur in dense clouds. Related model calculations of dense cloud chemistry show that the revised 15N enrichments fail to match observed values. We have investigated the effects of these reaction rate modifications on the chemical model of Wirstrom et al. (2012) for which there are significant physical and chemical differences with respect to other models. We have included 15N fractionation of CN in neutral-neutral reactions and also updated rate coefficients for key reactions in the nitrogen chemistry. We find that the revised fractionation rates have the effect of suppressing 15N enrichment in ammonia at all times, while the depletion is even more pronounced, reaching 14N/15N ratios of >2000. Taking the updated nitrogen chemistry into account, no significant enrichment occurs in HCN or HNC, contrary to observational evidence in dark clouds and comets, although the 14N/15N ratio can still be below 100 in CN itself. However, such low CN abundances are predicted that the updated model falls short of explaining the bulk 15N enhancements observed in primitive materials. It is clear that alternative fractionating reactions are necessary to reproduce observations, so further laboratory and theoretical studies are urgently needed.

Wirstrom, E. S.↗
NASA NTRS2016

Computing Highly Accurate Spectroscopic Line Lists for Characterization of Planetary Atmospheres: CO2 and SO2 Line Lists Needed for Modeling Venus

Over the last decade, it has become apparent that the most effective approach for determining highly accurate rotational and rovibrational line lists for molecules of interest in planetary atmospheres and other astrophysical environments is through a combination of highresolution laboratory experiments coupled with state-of-the art ab initio quantum chemistry methods. The approach involves computing the most accurate potential energy surface (PES) possible using state-of-the art electronic structure methods, followed by computing rotational and rovibrational energy levels using an exact variational method to solve the nuclear Schrödinger equation. Then, reliable experimental data from high-resolution experiments is used to refine the ab initio PES in order to improve the accuracy of the computed energy levels and transition energies. From the refinement step, we have been able to achieve an accuracy of approximately 0.015 cm-1 for rovibrational transition energies, and even better for purely rotational transitions. This combined "experiment / theory" approach allows for determination of essentially a complete line list, with hundreds of millions of transitions, and having the transition energies and intensities be highly accurate. Our group has successfully applied this approach to determine highly accurate line lists for NH3, CO2 and isotopologues, and SO2 and isotopologues. Here I will report our latest results for CO2 and SO2 including all isotopologues. Comparisons to the available data in HITRAN2012 and other available databases will be shown, though we note that our line lists for SO2 are significantly more complete than any other databases. Since it is important to span a large temperature range in order to model the spectral signature of Venus as well as exoplanets, we will demonstrate how the spectra change on going from low temperatures (100 K) to higher temperatures (500 K to 1500 K).

potential energy surface (PES)5405 PLANETARY SCIEN↗
NASA NTRS2017

Revised Models of Interstellar Nitrogen Isotopic Fractionation

Nitrogen-bearing molecules in cold molecular clouds exhibit a range of isotopic fractionation ratios and these molecules may be the precursors of 15N enrichments found in comets and meteorites. Chemical model calculations indicate that atom–molecular ion and ion–molecule reactions could account for most of the fractionation patterns observed. However, recent quantum-chemical computations demonstrate that several of the key processes are unlikely to occur in dense clouds. Related model calculations of dense cloud chemistry show that the revised 15N enrichments fail to match observed values. We have investigated the effects of these reaction rate modifications on the chemical model of Wirström et al. (2012) for which there are significant physical and chemical differences with respect to other models. We have included 15N fractionation of CN in neutral–neutral reactions and also updated rate coefficients for key reactions in the nitrogen chemistry. We find that the revised fractionation rates have the effect of suppressing 15N enrichment in ammonia at all times, while the depletion is even more pronounced, reaching 14N/15N ratios of >2000. Taking the updated nitrogen chemistry into account, no significant enrichment occurs in HCN or HNC, contrary to observational evidence in dark clouds and comets, although the 14N/15N ratio can still be below 100 in CN itself. However, such low CN abundances are predicted that the updated model falls short of explaining the bulk 15N enhancements observed in primitive materials. It is clear that alternative fractionating reactions are necessary to reproduce observations, so further laboratory and theoretical studies are urgently needed.

astrochemistry – molecular processes – comets: gen↗
NASA NTRS2017

Revised Models of Interstellar Nitrogen Isotopic Fractionation

Nitrogen-bearing molecules in cold molecular clouds exhibit a range of isotopic fractionation ratios and these molecules may be the precursors of 15N enrichments found in comets and meteorites. Chemical model calculations indicate that atom–molecular ion and ion–molecule reactions could account for most of the fractionation patterns observed. However, recent quantum-chemical computations demonstrate that several of the key processes are unlikely to occur in dense clouds. Related model calculations of dense cloud chemistry show that the revised 15N enrichments fail to match observed values. We have investigated the effects of these reaction rate modifications on the chemical model of Wirström et al. (2012) for which there are significant physical and chemical differences with respect to other models. We have included 15N fractionation of CN in neutral–neutral reactions and also updated rate coefficients for key reactions in the nitrogen chemistry. We find that the revised fractionation rates have the effect of suppressing 15N enrichment in ammonia at all times, while the depletion is even more pronounced, reaching 14N/15N ratios of >2000. Taking the updated nitrogen chemistry into account, no significant enrichment occurs in HCN or HNC, contrary to observational evidence in dark clouds and comets, although the 14N/15N ratio can still be below 100 in CN itself. However, such low CN abundances are predicted that the updated model falls short of explaining the bulk 15N enhancements observed in primitive materials. It is clear that alternative fractionating reactions are necessary to reproduce observations, so further laboratory and theoretical studies are urgently needed.

astrochemistry – molecular processes – comets: gen↗