Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “phosphor”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 541 records · Page 30
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Environmental impacts of dam reservoir filling in the East Amazon

Mitigating the environmental impacts caused by hydroelectric dams is a worldwide challenge. The aquatic ecosystem is the most impacted during the reservoir filling phase, yet biogeochemical dynamics at this stage are not well-studied. Here we evaluate water quality and hydraulic parameters in the Araguari River (Amapá/Brazil) during the filling of the Ferreira Gomes Hydroelectric Power Plant reservoir (UHEFG). Five field campaigns were performed from July 2014 to August 2015 across nine sample sites within the reservoir (P1, P2, …P9) and only one downstream (P10). The following key variables were monitored: Trophic State Index (TSI), Total Coliforms (TC), E. coli (EC) and Chlorophyll-a (Chl-a), along with physical and chemical variables (Temperature, Suspended Solids, Total Dissolved Solids, Electrical Conductivity, Turbidity, Color, pH, DO, Al3+, NH4+, Cl-, Mg1+, Ca2+, total Phosphorous, NH3, NO3-, and SO42). Besides that, hydraulic-operational variables were also investigated: inflows (Qa), outflows (Qd), and variation in reservoir volume (Vol%). Multiple Regression Analyses showed that the key parameters were both significantly influenced by physio-chemical and hydraulic variables (0.46=R2adj=0.99, p<0.05). The DO showed significant spatial variation, being influenced by the turbulence from the Coaracy Nunes dam (UHECN) upstream and the UHEFG dam downstream. The Vol% influenced the TSI, which ranged from oligotrophic to hypertrophic and eventually stabilized at mesotrophic. The levels of TSI, TC, and Chl-a decreased and the level of E. coli increased (p<0.05) as a function of Vol%. A Cluster Analysis showed the formation of three spatial groups - two inside the reservoir and one downstream (P10). This suggests that in the rainy season or transition season, the hydraulic residence time in the reservoir is very low (16 = thr = 36 h) when hydrodynamic processes are dominant. In the dry season (thr ˜ 1 month), biogeochemical and hydrodynamic processes occur at similar time scales to the nutrient and microbial abundance. These results confirm the hypothesis that the filling phase has significant impacts on the key parameters of the water quality (p<0.05). We conclude that the filling phase of the UHEFG reservoir generated significant environmental impacts, which have repercussions even retrospectively.

Amazon, biogeochemistry, ecosystem, extreme event,↗
DOE OSTI2021

Impact of Primary and Secondary ZDDP and Ionic Liquid as Lubricant Oil Additives on the Performance and Physicochemical Properties of Pd-Based Three-Way Catalysts

In the present study, two industry primary and secondary zinc dialkyldithiophosphate standards, ZDDP1 and ZDDP2, respectively, are evaluated for their impact on the performance of Pd-based three-way catalyst and bench-marked against two mixed lubricant additives formed from either ZDDP1 or ZDDP2 with a second-generation oil-miscible phosphoric-containing ionic liquid (IL). The three-way catalysts (TWCs) are exposed to the lubricant additives in an engine bench under four different scenarios: a base case with no additive (NA), ZDDP1, IL+ZDDP1, ZDDP2, and IL+ZDDP2. The engine-aged TWC samples are characterized through a variety of analytical techniques, including evaluation of catalyst reactivity in a bench-flow reactor. With respect to the water–gas shift reaction and the oxygen storage capacity, the ZDDP2- and IL+ZDDP2-aged TWC samples are more degraded than the ZDDP1- and IL+ZDDP1-aged TWC samples. X-ray diffraction (XRD) patterns indicate that phosphorus in the form of CePO4 was found to be present in the washcoat of all TWC samples, with the highest amount found in the ZDDP2-aged TWC sample. The results obtained from XRD are further confirmed by those from inductively coupled plasma-optical emission spectroscopy (ICP-OES), which show that more phosphorus is detected in the washcoat of ZDDP2- and IL+ZDDP2-aged TWC samples than in the ZDDP1- and IL+ZDDP1-aged TWC samples.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Structural Assessment of Fluorine, Chlorine, Bromine, Iodine, and Hydroxide Substitutions in Lead Arsenate Apatites (Mimetites)–Pb 5 (AsO 4 ) 3 X

Five lead-arsenate apatites (mimetites)-Pb 5 (AsO 4 ) 3 X—where X denotes fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and hydroxide (OH)—were synthesized via precipitation from aqueous solutions. The crystal structures were determined through Rietveld refinement of powder synchrotron X-ray data. All the compounds crystallized in the hexagonal class symmetry (space group P6 3 /m). The Rietveld refinement indicated that mimetite-Cl, -Br, -I, and -OH had an anion deficiency at position X. Substitution of halogens in a mimetite structure brought about systematic changes in unit-cell parameters, interatomic distances, and metaprism twist angles φ, proportional to the substituted halogen’s ionic radius. Mimetite-OH did not follow the linear correlations determined within the series. Twist angle φ, a useful device for monitoring changes in apatite topology, ranged from 20.34° for mimetite-F to 11.42° for mimetite-I. The geometric method has been proposed for determining the diameter of hexagonal channels hosting halogens in apatites. A comparison of the results with halogenated pyromorphites showed similar systematic trends: the substitutions in mimetites have comparable effect on the interatomic distances as in their phosphorous analogues.

58 GEOSCIENCES↗
DOE OSTI2025

A Synthetic Pathway for Producing Carbon Dots for Detecting Iron Ions Using a Fiber Optic Spectrometer

Iron detection is of growing importance in the critical minerals sector, where unwanted iron ions are typically removed during the processing of target critical metals. The ideal sensor should utilize inexpensive, scalable materials along with a low-cost, robust, and easy-to-use analysis platform. Here, we demonstrate a simple acid–base synthesis of luminescent iron-responsive carbon dots by reacting ethanolamine, phosphoric acid, and m-phenylenediamine. The carbon dots exhibit selective, iron-specific emission quenching, with the ability to detect part-per-billion levels of iron ions even in 0.1 M HCl. After benchmarking the purified materials using a commercial spectrometer, a “low-cost” process is demonstrated in which carbon dots with minimal purification are coupled with a portable fiber-optic spectrometer for analyzing iron content. Carbon dot-coated paper strips are also evaluated as another convenient platform for iron analysis. Taken together, the sensing material and platforms demonstrated here are well-suited for detecting trace quantities of iron in environmentally relevant conditions, with potential applications in tracking iron removal processes during critical mineral production as one exciting area of interest.

acid mine draining↗
DOE OSTI2021

Sensitivity of Riparian Buffer Designs to Climate Change—Nutrient and Sediment Loading to Streams: A Case Study in the Albemarle-Pamlico River Basins (USA) Using HAWQS

Riparian buffer zones (RBZs) provide multiple benefits to watershed ecosystems. We aimed to conduct an extensive sensitivity analysis of the RBZ designs to climate change nutrient and sediment loadings to streams. We designed 135 simulation scenarios starting with the six baselines RBZs (grass, urban, two-zone forest, three-zone forest, wildlife, and naturalized) in three 12-digit Hydrologic Unit Code watersheds within the Albemarle-Pamlico river basin (USA). Using the hydrologic and water quality system (HAWQS), we assessed the sensitivity of the designs to five water quality indicator (WQI) parameters: dissolved oxygen (DO), total phosphorous (TP), total nitrogen (TN), sediment (SD), and biochemical oxygen demand (BD). To understand the climate mitigation potential of RBZs, we identified a subset of future climate change projection models of air temperature and precipitation using EPA’s Locating and Selecting Scenarios Online tool. Analyses revealed optimal RBZ designs for the three watersheds. In terms of watershed ecosystem services sustainability, the optimal Urban RBZ in contemporary climate (1983–2018) reduced SD from 61–96%, TN from 34–55%, TP from 9–48%, and BD from 53–99%, and raised DO from 4–10% with respect to No-RBZ in the three watersheds. The late century’s (2070–2099) extreme mean annual climate changes significantly increased the projected SD and BD; however, the addition of urban RBZs was projected to offset the climate change reducing SD from 28–94% and BD from 69–93% in the watersheds. All other types of RBZs are also projected to fully mitigate the climate change impacts on WQI parameters except three-zone RBZ.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

A global database of dissolved organic matter (DOM) concentration measurements in coastal waters (CoastDOM v1)

Abstract. Measurements of dissolved organic carbon (DOC), nitrogen (DON), and phosphorus (DOP) concentrations are used to characterize the dissolved organic matter (DOM) pool and are important components of biogeochemical cycling in the coastal ocean. Here, we present the first edition of a global database (CoastDOM v1; available at https://doi.org/10.1594/PANGAEA.964012, Lønborg et al., 2023) compiling previously published and unpublished measurements of DOC, DON, and DOP in coastal waters. These data are complemented by hydrographic data such as temperature and salinity and, to the extent possible, other biogeochemical variables (e.g. chlorophyll a, inorganic nutrients) and the inorganic carbon system (e.g. dissolved inorganic carbon and total alkalinity). Overall, CoastDOM v1 includes observations of concentrations from all continents. However, most data were collected in the Northern Hemisphere, with a clear gap in DOM measurements from the Southern Hemisphere. The data included were collected from 1978 to 2022 and consist of 62 338 data points for DOC, 20 356 for DON, and 13 533 for DOP. The number of measurements decreases progressively in the sequence DOC > DON > DOP, reflecting both differences in the maturity of the analytical methods and the greater focus on carbon cycling by the aquatic science community. The global database shows that the average DOC concentration in coastal waters (average ± standard deviation (SD): 182±314 µmol C L−1; median: 103 µmol C L−1) is 13-fold higher than the average coastal DON concentration (13.6±30.4 µmol N L−1; median: 8.0 µmol N L−1), which is itself 39-fold higher than the average coastal DOP concentration (0.34±1.11 µmol P L−1; median: 0.18 µmol P L−1). This dataset will be useful for identifying global spatial and temporal patterns in DOM and will help facilitate the reuse of DOC, DON, and DOP data in studies aimed at better characterizing local biogeochemical processes; closing nutrient budgets; estimating carbon, nitrogen, and phosphorous pools; and establishing a baseline for modelling future changes in coastal waters.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Pressure-Induced Insulator–Metal Transition in Two-Dimensional Mott Insulator NiPS 3

The pressure-induced insulator to metal transition (IMT) of layered magnetic nickel phosphorous tri-sulfide NiPS 3 was studied in-situ under quasi-uniaxial conditions by means of electrical resistance (R) and X-ray diffraction (XRD) measurements. This sluggish transition is shown to occur at 35 GPa. Transport measurements show no evidence of superconductivity to the lowest measured temperature (~2 K). The structure results presented here differ from earlier in-situ work that subjected the sample to a different pressure state, suggesting that in NiPS 3 the phase stability fields are highly dependent on strain. Furthermore, it is suggested that careful control of the strain is essential when studying the electronic and magnetic properties of layered van der Waals solids.

36 MATERIALS SCIENCE↗
NASA NTRS1965

A slow-scan television film recorder.

Slow-scan television film recorder designed for Mariner Mars 1964 noting scope phosphors, film types and processing

PHOTOGRAPHIC RECORDING INSTRUMENT↗
NASA NTRS1967

Practical new method of measuring thermal-neutron fluence

Thermoluminescence dosimeter technique measures thermal-neutron fluence by encapsulating lithium flouride phosphor powder and exposing it to a neutron environment. The capsule is heated in a dosimeter reader, which results in light emission proportional to the neutron fluence.

Siebold, J. R.↗
NASA NTRS1967

Reparable, high-density microelectronic module provides effective heat sink

Reparable modular system is used for packaging microelectronic flat packs and miniature discrete components. This three-dimensional compartmented structure incorporates etched phosphor bronze sheets and frames with etched wire conductors. It provides an effective heat sink for electric power dissipation in the absence of convective cooling means.

Carlson, K. J.↗
NASA NTRS1968

Luminescent screen composition for cathode ray tubes

Screen composition for cathode ray tubes exhibits differential color of emission as a function of beam current variation at a constant accelerating voltage. The screen consists of a mixture of phosphors which emit different hues, have different current saturation values and exhibit a nonlinear current-brightness characteristic.

Hilborn, E. H.↗
NASA NTRS1968

Method for removing surface-damaged layers from nickel alloys

Electrical discharge machining /EDM/ damaged layer can be effectively removed from Rene 41, Inconel 625, Inconel 718, and Monel K-500 by abrasive-grit blasting or electropolishing /at room temperature/ at a current density of 5A/inches squared in a water solution of phosphoric and sulfuric acids.

Fawley, R. W.↗
NASA NTRS1969

Improved inorganic ion exchange membranes

New method makes solid ion exchange membrane electrolytes for use in hydrocarbon-oxygen and hydrogen-oxygen fuel cells. The membrane is a sintered composite of zirconia, phosphoric acid, and zeolite.

Arrance, F. C.↗