Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “oxygen diffusion”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 541 records · Page 30

Global empirical model of the Venus thermosphere

Direct measurements of neutral CO2, O, CO, N2, He, and N densities from the Pioneer Venus Orbiter Neutral Mass Spectrometer are described in terms of a spherical harmonic representation (latitude and local time coordinates) of exospheric temperature and number densities at 150 km, using modified Bates temperature profiles. The exospheric temperatures are determined from the altitude variations of atomic oxygen. A global average temperature of 228 K is derived with a first harmonic variation of 5%. The altitude profiles are extended downward to 100 km by using empirical formulas to provide a transition through the turbopause region (simulating the effect of eddy diffusion and vertical flows) and matching entry probe density data. The model reflects the observed variations of temperature and density with the 10.7 cm radio flux index. For a given change in flux at the planet, the exospheric temperature on Venus changes by only 10% of the change seen in the terrestrial thermosphere.

Hedin, A. E.↗

Cr, Mn, and Ca distributions for olivine in angritic systems: Constraints on the origins of Cr-rich and Ca-poor core olivine in angrite LEW87051

Angrite meteorites are a type of basaltic achondrites that are noted for their very old cyrstallization ages (4.55 b.y.) and unusual chemical and mineralogical properties. In spite of great interest, only four angrites have been found. LEW87051 is the smallest one which weighs 0.6 g. It is a porphyritic rock with coarse subhedral to euhedral olivines set in a fine-grained groundmass which clearly represents a crystallized melt. The largest uncertainty about the petrogenesis of LEW87051 is the relationship between the large olivine crystals and the groundmass. Prinz et al. suggests that olivines are xenocrysts, while McKay et al. proposed a fractional cyrstallization model based on experimental studies. However, the crystals have Cr-rich and Ca-poor cores which do not match experimental olivines. Although Jurewicz and McKay tried to explaine the zoning of the rim by diffusion, some features are not explained. There also exists a definite composition boundary of Fe(2+) and MnO between the core and the rim. To clarify the origin of these olivines, we have performed experiments using LEW87051 analogs to measure the effects of oxygen fugacity on distribution coefficients of various elements in an angritic system.

Mikouchi, T.↗

The neutral oxygen spectrum. 2: Pumping by hydrogen Lyman-beta under the optically thin condition: A first application to the classical novae

A calculation, employing a detailed model of neutral oxygen, is carried out to give fluorescent line intensities expected in a long-proposed photoexcitation by accidental resonance (PAR) process in which hydrogen Lyman-beta photoexcites the oxygen spectrum. The results pertain to the optically thin case but provide an upper limit to the fluorescent intensities which can be attained. They are applied to analyze line ratios involving the strong 8446 A line observed in classical novae during the diffusion-enhanced and Orion phases. Operation of the PAR process in the novae is verified. It is found that photoexcitation rates in the ejecta reach values greater than 0.1/sec, corresponding to hydrogen Lyman-beta radiation field intensities greater than 1250 ergs/cm/sec/sr.

Kastner, S. O.↗

NASA flow fields analysis

The objectives of the present research are to improve design capabilities for low thrust rocket engines through understanding the detailed mixing and combustion processes in a representative combustor. Of particular interest is a small gaseous hydrogen-oxygen thruster which is considered as a coordinated part of an on-going experimental program at NASA LERC. Detailed computational modeling involves the solution of both the two- and three-dimensional Navier Stokes equations, coupled with chemical reactions and the species diffusion equations. Computations of interest include both steady state and time-accurate flowfields and are obtained by means of LU approximate factorization in time and flux split upwinding differencing in space. The emphasis in the research is focused on using numerical analysis to understand detailed combustor flowfields, including the shear layer dynamics created between fuel film cooling and the core gas in the vicinity on the nearby combustor wall; the integrity and effectiveness of the coolant film; and three-dimensional fuel and oxidizer jet injection/mixing/combustion characteristics in the primary combustor along with their joint impacts on global engine performance.

Merkle, Charles L.↗

The effects of thermospheric winds and chemistry in the diurnal variations of thermospheric species

The reported investigation considers on the basis of a theoretical model, the diurnal variations of the thermospheric composition (H, He, O, O2, and Ar) in terms of thermal expansion with diffusive equilibrium and transport effects associated with thermospheric winds, chemistry, and exospheric flow. The theoretical results are compared with satellite composition data which indicate that the fundamental diurnal tide can be reasonably well understood. It is found that winds are only important for molecular oxygen below 180 km, while thermal expansion due to the larger mass is relatively more important for O2 than for O. Distinct from O, photodissociation and in particular photoionization of O2 are very significant for molecular oxygen.

Mayr, H. G.↗

Origin of reverse annealing in radiation-damaged silicon solar cells

The paper employs relative defect concentrations, energy levels, capture cross sections, and minority carrier diffusion lengths in order to identify the defect responsible for the reverse annealing observed in a radiation damaged n(+)/p silicon solar cell. It is reported that the responsible defect, with the energy level at +0.30 eV, has been tentatively identified as boron-oxygen-vacancy complex. In conclusion, it is shown that removal of this defect could result in significant cell recovery when annealing at temperatures well below the currently required 400 C.

Weinberg, I.↗

A model of the Venus ionosphere

Results of model calculations of the Venus ionosphere from 120 to 300 km are presented. The chemical scheme and reaction rates used are the same as given by Kumar and Hunten (1974) except that the electron temperature dependence of the dissociative recombination rates is taken into account. Calculations are made for low and high atomic oxygen models in which the O/CO2 ratios are 0.4% and 4% respectively at 140 km, and the results agree well in shape and magnitude with the Mariner 5 and 10 occultation results in the chemically controlled region. Reasonable agreement is obtained at higher altitudes if diffusive equilibrium and high vertical flow velocities (10 km/s) are assumed as upper boundaries for the Mariner 5 and 10 conditions respectively, although solar wind-ionosphere interactions are considered to be the controlling mechanism for the Mariner 10 results.

Nagy, A. F.↗

The formation of molecules in interstellar clouds from singly and multiply ionized atoms

The suggestion is considered that multiply ionized atoms produced by K- and L-shell X-ray ionization and cosmic-ray ionization can undergo ion-molecule reactions and also initiate molecule production. The role of X-rays in molecule production in general is discussed, and the contribution to molecule production of the C(+) radiative association with hydrogen is examined. Such gas-phase reactions of singly and multiply ionized atoms are used to calculate molecular abundances of carbon-, nitrogen-, and oxygen-bearing species. The column densities of the molecules are evaluated on the basis of a modified version of previously developed isobaric cloud models. It is found that reactions of multiply ionized carbon with H2 can contribute a significant fraction of the observed CH in diffuse interstellar clouds in the presence of diffuse X-ray structures or discrete X-ray sources and that substantial amounts of CH(+) can be produced under certain conditions.

Langer, W. D.↗

Ion temperature variations in the daytime high-latitude F region

The Schunk and Sojka (1981a, b) high latitude ionospheric model is improved through the inclusion of thermal conduction and diffusion terms in the ion energy equation, permitting the study of daytime, high latitude F layer temperature variations in a region poleward of the auroral oval. It is found that ion temperature variation with solar cycle, season and geomagnetic activity closely follows the neutral atomic oxygen variation, and that meridional electric fields of more than 40 mV/m can cause larger ion temperature changes than those due to solar cycle, seasonal or geomagnetic activity variations. In the presence of meridional electric fields, there is an upward flow of heat from the lower ionosphere that also acts to raise ion temperatures at high altitudes. Zonal electric fields affect ion temperature indirectly, through electron density changes.

Schunk, R. W.↗

LOX vaporization in high-pressure, hydrogen-rich gas

LOX droplet vaporization in high-pressure hydrogen-rich gas is analyzed, with special attention to thermodynamic effects which compel the surface to heat to the critical state and to supercritical vaporization processes on heating to criticality. Subcritical vaporization is modeled using a quasi-steady diffusion-controlled gas-phase transport formulation coupled to an effective-conductivity internal-energy-transport model accounting for circulation effects. It is demonstrated how the droplet surface might heat to the critical state, for ambient pressures slightly greater than the critical pressure of oxygen, such that the bulk of propellant within the droplet remains substantially below the critical mixing temperature.

Litchford, Ron J.↗

VUV-induced degradation of FEP Teflon aboard LDEF

Examination of fluorinated ethylene propylene (FEP) copolymer materials recovered from the Long Duration Exposure Facility (LDEF) reveals differing damage characteristics on leading edge (ram-facing) versus trailing edge (wake-facing surfaces). Silver/Teflon (Ag/FEP) thermal control materials on ram facing surfaces of the LDEF exhibited obvious degradation, with an apparent increase in diffuse light scattering, whereas identical materials on the wake facing surfaces showed little apparent damage with cursory inspection. Microscopic examination of both types of surfaces reveals the nature and extent of environment induced degradation of materials. The ram facing surfaces were clearly eroded by atomic oxygen impingement, while the wake facing material developed a thin, highly embrittled surface layer.

Brinza, David E.↗

Smoldering Combustion Experiments in Microgravity

The Microgravity Smoldering Combustion (MSC) experiment is part of a study of the smolder characteristics of porous combustible materials in a microgravity environment. Smoldering is a non-flaming form of combustion that takes place in the interior of porous materials and takes place in a number of processes ranging from smoldering of porous insulation materials to high temperature synthesis of metals. The objective of the study is to provide a better understanding of the controlling mechanisms of smolder, both in microgravity and normal-gravity. As with many forms of combustion, gravity affects the availability of oxidizer and transport of heat, and therefore the rate of combustion. Microgravity smolder experiments, in both a quiescent oxidizing environment, and in a forced oxidizing flow have been conducted aboard the NASA Space Shuttle (STS-69 and STS-77 missions) to determine the effect of the ambient oxygen concentration and oxidizer forced flow velocity on smolder combustion in microgravity. The experimental apparatus is contained within the NASA Get Away Special Canister (GAS-CAN) Payload. These two sets of experiments investigate the propagation of smolder along the polyurethane foam sample under both diffusion driven and forced flow driven smoldering. The results of the microgravity experiments are compared with identical ones carried out in normal gravity, and are used to verify present theories of smolder combustion. The results of this study will provide new insights into the smoldering combustion process. Thermocouple histories show that the microgravity smolder reaction temperatures (Ts) and propagation velocities (Us) lie between those of identical normal-gravity upward and downward tests. These observations indicate the effect of buoyancy on the transport of oxidizer to the reaction front.

Walther, David C.↗

Planar Strain-Rate-Free Diffusion Flames: Initiation, Properties, and Extinction

An effectively strain-rate-free diffusion flame constitutes the most vigorous laminar combustion of initially unmixed reactive gases. Such a diffusion flame is characterized by a relatively long residence time and by a relatively large characteristic length scale. If such a flame were also planar, providing high symmetry, it would be particularly suitable for experimental and theoretical investigations of key combustion phenomena, such as multicomponent diffusion, chemical kinetics, and soot inception, growth, and oxidation. Unfortunately, a planar strain-rate-free diffusion flame is highly disrupted in earth-gravity (e.g., in a counterflow-diffusion-flame apparatus) because of the very rapid onset (approx. 100 ms) of gravity-induced instability. Accordingly, a specially dedicated apparatus was designed, fabricated, and initially checked out for the examination of a planar strain-rate-free diffusion flame in microgravity. Such a diffusion flame may be formed within a hollowed-out squat container (initially configured as 25 cm x 25 cm x 9 cm), with isothermal, noncatalytic, impervious walls. At test initiation, a thin metallic sheet (approx. 1 mm in thickness) that separates the internal volume into two equal portions, each of dimensions 25 cm x 25 cm x 4.5 cm, is withdrawn, by uniform translation (approx. 50 cm/s) in its own plane, through a tightly fitting slit in one side wall. Thereupon, diluted fuel vapor (initially confined to one half-volume of the container) gains access to diluted oxygen (initially with the same pressure, density, and temperature as the fuel, but initially confined to the other half-volume). After a brief delay (approx. 10 ms), to permit limited but sufficient-for-flammability diffusional interpenetration of fuel vapor and oxidizer, burning is initiated by discharge of a line igniter, located along that side wall from which the trailing edge of the separator withdraws. The ignition spawns a triple-flame propagation across the 25 cm x 25 cm centerplane. When a diffusion flame is emplaced in the centerplane, any subsequent travel, and change in temperature, of that planar diffusion flame may be tracked, along with the effectively spatially uniform but temporally evolving pressure within the container. Eventually, nearly complete depletion of the stoichiometrically deficient reactant, along with heat loss to the container surfaces, effects extinction. These data afford an opportunity to check theoretical models of diffusion and chemical kinetics under conditions ranging from intense burning to flame out, or, alternatively, to evolve simple empirical representations of these phenomena. Thus, the project sought to utilize microgravity testing to elucidate commonly encountered phenomenology, arising in the commonly-encountered mode of combustion (whether related to heating, manufacturing, boiling, and propulsion, or to uncontrolled, free-burning fire in structures and wildland vegetation), of those commonly utilized fuels usually categorized as gaseous fuels (such as hydrogen, natural gas, and propane, which are gaseous under atmospheric conditions).

Fendell, Francis↗

Time analysis of volcanic activity on Io by means of plasma observations

A model of Io volcanism in which the probability of activity obeys a binomial distribution is presented. Observed values of the electron density obtained over a 3-year period by ground-based spectroscopy are fitted to such a distribution. The best fit is found for a total number of 15 volcanoes with a probability of individual activity at any time of 0.143. The Pioneer 10 ultraviolet observations are reinterpreted as emissions of sulfur and oxygen ions and are found to be consistent with a plasma much less dense than that observed by the Voyager spacecraft. Late 1978 and the first half of 1979 are shown to be periods of anomalous volcanicity. Rapid variations in electron density are related to enhanced radial diffusion.

Mekler, Y.↗

Radiation damage annealing mechanisms and possible low temperature annealing in silicon solar cells

The defect responsible for reverse annealing in 2 ohm/cm n(+)/p silicon solar cells was identified. This defect, with energy level at e sub v + 0.30 eV was tentatively identified as a boron oxygen-vacancy complex. Results indicate that its removal could result in significant annealing for 2 ohm/cm and lower resistivity cells at temperatures as low as 200 C. These results were obtained by use of an expression derived from the Shockley-Read-Hall recombination theory which relates measured diffusion length ratios to relative defect concentrations and electron capture cross sections. The relative defect concentrations and one of the required capture cross sections are obtained from Deep Level Transient Spectroscopy. Four additional capture cross sections are obtained using diffusion length data and data from temperature dependent lifetime studied. These calculated results are in reasonable agreement with experimental data.

Weinberg, I.↗

Plasma dynamics in the rapidly rotating magnetosphere of Jupiter

The major Voyager findings concerning the low energy plasma in the Jovian magnetosphere are reviewed. The magnetosphere of Jupiter is unique in the solar system because of its large extent and rapid rotation, and because of the prodigious source of plasma provided by the satellite Io. Io injects 10 to the 29th power AMU/sec of freshly ionized material into the Jovian magnetosphere, producing a plasma dominated by heavy ions which are mostly various ionization states of oxygen and sulfur. This injected material is the source for the Io plasma torus, which is centered at Io's L-shell with a scale height of 1 Jovian radii and a mass of approximately 10 to the 36th power AMU. Ninety percent of the injected plasma diffuses outward, forming the Jovian magnetodisk. Io interacts with the plasma torus via the generation of an Alfven wave which propagates from Io into the ionosphere of Jupiter, carrying an energy flux of approximately 10 to the 12th power watts.

Belcher, J. W.↗

Thermal and wind-induced variations in thermospheric molecular oxygen as measured on AE-D

Simultaneous measurements of ambient O2 and N2 concentrations and temperature were made near winter solstice 1975 by the open source neutral mass spectrometer on Atmosphere Explorer-D. The data, taken at midmorning and all latitudes, are analyzed using scatter plots and correlation coefficients. Results indicate that O2 concentrations at about 200 km is controlled both by temperature variations and wind-induced diffusion. Since the winds are most effective in controlling O2 at lower altitudes, it is reasonable to expect that temperature effects will dominate over wind effects at higher altitudes.

Potter, W. E.↗

Sounding-rocket experiment to study the diffuse soft X-ray background using a Si(Li) detector

Soft X-ray background in the energy range 0.4 to 10 keV was studied. A payload was developed which uses a wide angle, windowless, cooled, Si(Li) semiconductor detector system. With a resolution of less than 150 eV between 0.3 and 2.0 keV, the system is sensitive to an emission equivalent width of about 10 eV. Carbon and oxygen line emission were detected from the vicinity of the North Galactic Pole and the North Polar Spur.

Delvaille, J. P.↗