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At least 541 records · Page 30

Epoxy hydantoins as matrix resins

Tensile strength and fracture toughness of castings of the hydantoin resins cured with methylenedianiline are significantly higher than MY 720 control castings. Water absorption of an ethyl, amyl hydantoin formulation is 2.1 percent at equilibrium and Tg's are about 160 C, approximately 15 deg below the final cure temperature. Two series of urethane and ester-extended hydantoin epoxy resins were synthesized to determine the effect of crosslink density and functional groups on properties. Castings cured with methylenedianiline or with hexahydrophthalic anhydride were made from these compounds and evaluated. The glass transition temperatures, tensile strengths and moduli, and fracture toughness values were all much lower than that of the simple hydantoin epoxy resins. Using a methylene bishydantoin epoxy with a more rigid structure gave brittle, low-energy fractures, while a more flexible, ethoxy-extended hydantoin epoxy resin gave a very low Tg.

Weiss, J.↗

Evaluation of atomic constants for optical radiation, volume 1

Atomic constants for optical radiation are discussed which include transition probabilities, line strengths, and oscillator strengths for both dipole and quadrupole transitions, as well as the associated matrix elements needed for line broadening calculations. Atomic constants were computed for a wide selection of elements and lines. An existing computer program was used, with modifications to include, in an approximate manner, the effect of equivalent electrons, and to enable reordering and restructuring of the output for publication. This program is suitable for fast, low cost computation of the optical constants, using the Coulomb approximation formalism for LS coupling.

Kylstra, C. D.↗

CO 1-0 band isotopic lines as intensity standards

Fundamental band vibration-rotational line intensities are reported for the (C-12)(O-16), (C-13)(O-16), and (C-12)(O-18) molecules. The intensities were computed using numerically obtained matrix elements of a recently, determined electric dipole moment function. New intensity measurements for some of these lines obtained via high-resolution Fourier spectra are also reported. The overall consistency (approximately 2.2 percent) between calculations, which are based on recent experimental determinations of CO 1-0 band intensities, not including our own, those of the authors, and independent experimental results of the authors suggests that the lines of the fundamental band of CO can be used as absolute intensity standards.

Chackerian, C., Jr.↗

The substitution of nickel for cobalt in hot isostatically pressed powder metallurgy UDIMET 700 alloys

Nickel was substituted in various proportions for cobalt in a series of five hot-isostatically-pressed powder metallurgy alloys based on the UDIMET 700 composition. These alloys were given 5-step heat treatments appropriate for use in turbine engine disks. The resultant microstructures displayed three distinct sizes of gamma-prime particles in a gamma matrix. The higher cobalt-content alloys contained larger amounts of the finest gamma-prime particles, and had the lowest gamma-gamma-prime lattice mismatch. While all alloys had approximately the same tensile properties at 25 and 650 gamma C, the rupture lives at 650 and 760 C peaked in the alloys with cobalt contents between 12.7 and 4.3 pct. Minimum creep rates increased as cobalt contents were lowered, suggesting their correlation with the gamma-prime particle size distribution and the gamma-gamma-prime mismatch. It was also found that, on overaging at temperatures higher than suitable for turbine disk use, the high cobalt-content alloys were prone to sigma phase formation.

Harf, F. H.↗

Stability of semidiscrete approximations for hyperbolic initial-boundary-value problems: An eigenvalue analysis

A hyperbolic initial-boundary-value problem can be approximated by a system of ordinary differential equations (ODEs) by replacing the spatial derivatives by finite-difference approximations. The resulting system of ODEs is called a semidiscrete approximation. A complication is the fact that more boundary conditions are required for the spatially discrete approximation than are specified for the partial differential equation. Consequently, additional numerical boundary conditions are required and improper treatment of these additional conditions can lead to instability. For a linear initial-boundary-value problem (IBVP) with homogeneous analytical boundary conditions, the semidiscrete approximation results in a system of ODEs of the form du/dt = Au whose solution can be written as u(t) = exp(At)u(O). Lax-Richtmyer stability requires that the matrix norm of exp(At) be uniformly bounded for O less than or = t less than or = T independent of the spatial mesh size. Although the classical Lax-Richtmyer stability definition involves a conventional vector norm, there is no known algebraic test for the uniform boundedness of the matrix norm of exp(At) for hyperbolic IBVPs. An alternative but more complicated stability definition is used in the theory developed by Gustafsson, Kreiss, and Sundstrom (GKS). The two methods are compared.

Warming, Robert F.↗

1200 to 1400 K slow strain rate compressive properties of NiAl/Ni2AlTi-base materials

An attempt to apply the Martin Marietta Corporation's XD technology to the fabrication of NiAl-Ni2AlTi materials with improved creep properties is presented. Composite materials, containing from 0 to 30 vol pct of nominally 1-micron-diameter TiB2 particles in the intermetallic matrix have been produced by the XD process and compacted by hot pressing. Such composites demonstrated significant strength increases, approaching 3-fold for the 20 vol pct materials, in comparison to the unreinforced aluminide. This behavior was accomplished without deleterious side effects as the grain boundaries and particle-matrix interfaces were intact after compressive deformation to 10 percent or more strain. Typical true compressive stress-strain diagrams for materials tested in air between 1200 and 1400 K at approximate strain rates of 1.7 x 10 to the -6th/sec are presented.

Whittenberger, J. Daniel↗

Fresh look at floating shock fitting

A fast implicit upwind procedure for the two-dimensional Euler equations is described that allows accurate computations of shocked flows on nonadapted meshes. Away from shocks, the second-order accurate upwinding is based on the split-coefficient-matrix (SCM) method. In the presence of shocks, the difference stencils are modified using a floating shock fitting technique. Rapid convergence to steady-state solutions is attained with a diagonalized approximate factorization (AF) algorithm. Results are presented for Riemann's problem, for a regular shock reflection at an inviscid wall, for supersonic flow past a cylinder, and for a transonic airfoil. All computed shocks are ideally sharp and in excellent agreement with other numerical results or 'exact' solutions. Most importantly, this has been accomplished on unusually crude meshes without any attempt to align grid lines with shock fronts or to cluster grid lines around shocks.

Hartwich, PETER-M.↗

An approximately factored incremental strategy for calculating consistent discrete aerodynamic sensitivity derivatives

An incremental strategy is presented for iteratively solving very large systems of linear equations, which are associated with aerodynamic sensitivity derivatives for advanced CFD codes. It is shown that the left-hand side matrix operator and the well-known factorization algorithm used to solve the nonlinear flow equations can also be used to efficiently solve the linear sensitivity equations. Two airfoil problems are considered as an example: subsonic low Reynolds number laminar flow and transonic high Reynolds number turbulent flow.

Korivi, V. M.↗

Optics of Water Cloud Droplets Mixed with Black-Carbon Aerosols

We use the recently extended superposition T-matrix method to calculate scattering and absorption properties of micrometer-sized water droplets contaminated by black carbon. Our numerically exact results reveal that, depending on the mode of soot-water mixing, the soot specific absorption can vary by a factor exceeding 6.5. The specific absorption is maximized when the soot material is quasi-uniformly distributed throughout the droplet interior in the form of numerous small monomers. The range of mixing scenarios captured by our computations implies a wide range of remote sensing and radiation budget implications of the presence of black carbon in liquid-water clouds. We show that the popular Maxwell-Garnett effective-medium approximation can be used to calculate the optical cross sections, single-scattering albedo, and asymmetry parameter for the quasi-uniform mixing scenario, but is likely to fail in application to other mixing scenarios and in computations of the elements of the scattering matrix.

soot↗

Gust alleviation - Criteria and control laws

The relationships between criteria specified for aircraft gust alleviation and the form of the control laws that result from the criteria are considered. Open-loop gust alleviation based on the linearized, small perturbation equations of aircraft motion is discussed, and an approximate solution of the open-loop control law is presented for the case in which the number of degrees of freedom of the aircraft exceeds the rank of the control effectiveness matrix. Excessive actuator lag is compensated for by taking into account actuator dynamics in the equations of motion, resulting in the specification of a general load network. Criteria for gust alleviation when output motions are gust alleviated and the closed-loop control law derived from them are examined and linear optimal control law is derived. Comparisons of the control laws reveal that the effectiveness of an open-loop control law is greatest at low aircraft frequencies but deteriorates as the natural frequency of the actuators is approached, while closed-loop methods are found to be more effective at higher frequencies.

Rynaski, E. G.↗

Possible isotopic fractionation effects in sputtered minerals

A model which makes definite predictions for the fractionation of isotopes in sputtered material is discussed. The fractionation patterns are nonlinear, and the pattern for a particular set of isotopes depends on the chemical matrix within which those isotopes are contained. Calculations are presented for all nonmonoisotopic elements contained in the minerals perovskite, anorthite, ackermanite, enstatite, and troilite. All isotopes are fractionated at the level of approximately 4-6 deg/o per atomic mass unit. Oxygen is always positively fractionated (heavier isotopes sputtered preferentially), and heavier elements are generally negatively fractioned (light isotopes sputtered preferentially). The value of Delta (O-18:O-16) is always less by about 1.8 deg/o than a linear extrapolation based upon the calculated delta (O-17:O-16) value would suggest. The phenomenon of both negative and positive fractionation patterns from a single target mineral are used to make an experimental test of the proposed model.

Haff, P. K.↗

Deformation and failure of transversely loaded composite plates

Quasi-isotropic graphite/epoxy clamped circular plates were loaded under control point loading. Deflections and strains at various locations were monitored up to failure. Various damage mechanisms, such as intralaminar matrix cracking, delaminations and fiber breaks, are correlated with the strain records. The damage at various stages of deformation was characterized by means of X-radiography. Results are compared with an approximate isotropic plate theory.

Daniel, I. M.↗

A superlinear interior points algorithm for engineering design optimization

We present a quasi-Newton interior points algorithm for nonlinear constrained optimization. It is based on a general approach consisting of the iterative solution in the primal and dual spaces of the equalities in Karush-Kuhn-Tucker optimality conditions. This is done in such a way to have primal and dual feasibility at each iteration, which ensures satisfaction of those optimality conditions at the limit points. This approach is very strong and efficient, since at each iteration it only requires the solution of two linear systems with the same matrix, instead of quadratic programming subproblems. It is also particularly appropriate for engineering design optimization inasmuch at each iteration a feasible design is obtained. The present algorithm uses a quasi-Newton approximation of the second derivative of the Lagrangian function in order to have superlinear asymptotic convergence. We discuss theoretical aspects of the algorithm and its computer implementation.

Herskovits, J.↗

The dust in the hydrogen-poor ejecta of Abell 30

We present new optical and near-infrared images of the hydrogen-poor planetary nebula Abell 30 and produce detailed models that account for the major observed morphological and IR properties. By imaging the nebula in the K band, we confirm the presence of hot dust in an expanding equatorial ring of H-poor gas. No emission was detected from the H-poor polar knots, suggesting a dust deficiency htere relative to the equatorial ring. The near-IR emission is attributed to small carbonaceous dust grains which are stochastically heated by stellar ultraviolet photons. Using an adaptive version of a matrix method devised by Guhathakurta & Draine (1989) to model stochastic heating, we find that the near-IR spectrum observed by Dinerstein & Lester (1984) requires the presence of dust grains down to approximately 0.0007 microns in radius. This minimum grain radius is in excellent agreement with our calculations of the grain destruction by energetic stellar UV photons: we find that carbon clusters with less than approximately 140 atoms (0.0007 microns in radius) are destroyed by stellar UV photons in approximately 1000 yr, the kinematic age of H-poor ejecta. Modeling of the far-IR dust emission implies that the bulk of the dust mass in A30 must reside at distances several times greater than the distance of the equatorial ring from the central star. This spatial dust distribution is attributed to the interaction of the stellar wind with the inhomogeneous H-poor ejecta. Most of the H-poor gas and dust has been apparently carried outward by the stellar wind, leaving behing dense, H-poor knots with prominent wind-blown tails in the equatorial ring and in the polar knots. This picture is supported by the presence of a stellar wind-blown bubble within the H-rich envelope in our optical images.

Borkowski, Kazimierz J.↗

ATIC Experiment: Elemental Spectra from the Flight in 2000

The Advanced Thin Ionization Calorimeter (ATIC) had successful Long Duration Balloon flights from McMurdo, Antarctica in both 2000 and 2002. The instrument consists of a silicon matrix charge detector, a 0.75 nuclear interaction length graphite target, 3 scintillator strip hodoscopes, and an 18 radiation length thick BGO calorimeter to measure the cosmic ray composition and energy spectra from approximately 30 GeV to near 100 TeV. In this paper, we present preliminary results from the first flight, which was a test flight that lasted for 16 days, starting on 12/28/00.

Ahn, H. S.↗

Implicit/Multigrid Algorithms for Incompressible Turbulent Flows on Unstructured Grids

An implicit code for computing inviscid and viscous incompressible flows on unstructured grids is described. The foundation of the code is a backward Euler time discretization for which the linear system is approximately solved at each time step with either a point implicit method or a preconditioned Generalized Minimal Residual (GMRES) technique. For the GMRES calculations, several techniques are investigated for forming the matrix-vector product. Convergence acceleration is achieved through a multigrid scheme that uses non-nested coarse grids that are generated using a technique described in the present paper. Convergence characteristics are investigated and results are compared with an exact solution for the inviscid flow over a four-element airfoil. Viscous results, which are compared with experimental data, include the turbulent flow over a NACA 4412 airfoil, a three-element airfoil for which Mach number effects are investigated, and three-dimensional flow over a wing with a partial-span flap.

Anderson, W. Kyle↗

A recurrence matrix solution for the dynamic response of aircraft in gusts

A systematic procedure developed for the calculation of the structural response of aircraft flying through a gust by use of difference equations in the solution of dynamic problems is first illustrated by means of a simple-damped-oscillator example. A detailed analysis is then given which leads to a recurrence matrix equation for the determination of the response of an airplane in a gust. The method takes into account wing bending and twisting deformations, fuselage deflection, vertical and pitching motion of the airplane, and some tail forces. The method is based on aerodynamic strip theory, but compressibility and three-dimensional aerodynamic effects can be taken into account approximately by means of over-all corrections. Either a sharp-edge gust or a gust of arbitrary shape in the spanwise or flight directions may be treated. In order to aid in the application of the method to any specific case, a suggested computational procedure is included. The possibilities of applying the method to a variety of transient aircraft problems, such as landing, are brought out. A brief review of matrix algebra, covering the extent to which it is used in the analysis, is also included. (author)

Houbolt, John C↗

Composite materials for space applications

The objectives of the program were to: generate mechanical, thermal, and physical property test data for as-fabricated advanced materials; design and fabricate an accelerated thermal cycling chamber; and determine the effect of thermal cycling on thermomechanical properties and dimensional stability of composites. In the current program, extensive mechanical and thermophysical property tests of various organic matrix, metal matrix, glass matrix, and carbon-carbon composites were conducted, and a reliable database was constructed for spacecraft material selection. Material property results for the majority of the as-fabricated composites were consistent with the predicted values, providing a measure of consolidation integrity attained during fabrication. To determine the effect of thermal cycling on mechanical properties, microcracking, and thermal expansion behavior, approximately 500 composite specimens were exposed to 10,000 cycles between -150 and +150 F. These specimens were placed in a large (18 cu ft work space) thermal cycling chamber that was specially designed and fabricated to simulate one year low earth orbital (LEO) thermal cycling in 20 days. With this rate of thermal cycling, this is the largest thermal cycling unit in the country. Material property measurements of the thermal cycled organic matrix composite laminate specimens exhibited less than 24 percent decrease in strength, whereas, the remaining materials exhibited less than 8 percent decrease in strength. The thermal expansion response of each of the thermal cycled specimens revealed significant reduction in hysteresis and residual strain, and the average CTE values were close to the predicted values.

Rawal, Suraj P.↗