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At least 541 records · Page 30
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Structural considerations in design of lightweight glass-fiber composite pressure vessels

The development of structurally efficient, metal-lined, glass-fiber composite pressure vessels. Both the current state-of-the-art and current problems are discussed along with fracture mechanics considerations for the metal liner. The design concepts used for metal-lined, glass-fiber, composite pressure vessels are described and the structural characteristics of the composite designs are compared with each other and with homogeneous metal pressure vessels. Specific design techniques and available design data are identified. Results of a current program to evaluate flaw growth and fracture characteristics of the metal liners are reviewed and the impact of these results on composite pressure vessel designs is discussed.

Faddoul, J. R.↗
NASA NTRS1973

Friction and wear behavior of glasses and ceramics

Adhesion, friction, and wear behavior of glasses and ionic solids are reviewed. These materials are shown to behave in a manner similar to other solids with respect to adhesion. Their friction characteristics are shown to be sensitive to environmental constituents and surface films. This sensitivity can be related to a reduction in adhesive bonding and the changes in surficial mechanical behavior associated with Rehbinder and Joffe effects. Both friction and wear properties of ionic crystalline solids are highly anisotropic. With metals in contact with ionic solids the fracture strength of the ionic solid and the shear strength in the metal and those properties that determine these will dictate which of the materials undergoes adhesive wear. The chemical activity of the metal plays an important role in the nature and strength of the adhesive interfacial bond that develops between the metal and a glass or ionic solid.

Buckley, D. H.↗
NASA NTRS1974

Glass fiber addition strengthens low-density ablative compositions

Approximately 15% of E-glass fibers was added to compositions under test and greatly improved char stability. Use of these fibers also reduced thermal strains which, in turn, minimized char shrinkage and associated cracks, subsurface voids, and disbonds. Increased strength allows honeycomb core reinforcement to be replaced by equivalent amount of glass fibers.

Chandler, H. H.↗
NASA NTRS1973

Structural considerations in design of lightweight glass-fiber composite pressure vessels

The design concepts used for metal-lined glass-fiber composite pressure vessels are described, comparing the structural characteristics of the composite designs with each other and with homogeneous metal pressure vessels. Specific design techniques and available design data are identified. The discussion centers around two distinctly different design concepts, which provide the basis for defining metal lined composite vessels as either (1) thin-metal lined, or (2) glass fiber reinforced (GFR). Both concepts are described and associated development problems are identified and discussed. Relevant fabrication and testing experience from a series of NASA-Lewis Research Center development efforts is presented.

Faddoul, J. R.↗
NASA NTRS1973

Origin and characteristics of excess Fe metal in lunar glass welded aggregates

We show that the characteristic features of lunar glass welded aggregates including their irregular shapes, vesicularity, and content of submicron Fe metal in the welding glass can be explained by a model in which they are predominantly formed by micrometeorite impacts into the solar wind saturated topmost surface of the regolith. The Fe metal is reduced from silicates by the solar wind gases. Other possible mechanisms of Fe metal formation are discussed and shown to play at most minor roles. It is shown that surface tension forces control vesicularity and that the low gravity and high vacuum conditions prevailing on the moon are unimportant. Consequences of this surface tension control to possible lunar eruptive volcanism and to the Ar-40/Ar-39 dating of impact events are discussed.

Housley, R. M.↗
NASA NTRS1974

Antiferromagnetic inclusions in lunar glass

The magnetic susceptibility of eleven glass spherules from the Apollo 15, 16, and 17 fines and two specimens of a relatively large glass spherical shell were studied as a function of temperature from room temperature to liquid helium temperatures. All but one specimen showed the presence of antiferromagnetic inclusions. Closely spaced temperature measurements of the magnetic susceptibility below 77 K on five of the specimens showed antiferromagnetic temperature transitions (Neel transitions). With the exception of ilmenite in one specimen, these transitions did not correspond to any transitions in known antiferromagnetic compounds.

Thorpe, A. N.↗
NASA NTRS1974

Microcraters formed in glass by projectiles of various densities

An experiment was conducted investigating the effect of projectile density on the structure and size of craters in soda lime glass and fused quartz. The projectiles were spheres of polystyrene-divinylbenzene (PS-DVB), aluminum, and iron with velocities between 0.5 and 15 km/sec and diameters between 0.4 and 5 microns. The projectile densities spanned the range expected for primary and secondary particles of micrometer size at the lunar surface, and the velocities spanned the lower range of micrometeoroid velocities and the upper range of secondary projectile velocities. There are changes in crater morphology as the impact velocity increases, and the transitions occur at lower velocities for the projectiles of higher density. The sequence of morphological features of the craters found for PS-DVB impacting soda lime glass for increasing impact velocity, described in a previous work (Mandeville and Vedder, 1971), also occurs in fused quartz and in both targets with the more dense aluminum and iron projectiles. Each transition in morphology occurs at impact velocities generating a certain pressure in the target. High density projectiles require a lower velocity than low-density projectiles to generate a given shock pressure.

Vedder, J. F.↗
NASA NTRS1974

Luminescence of powdered uranium glasses

Measurement of cathodoluminescence and photoluminescence efficiencies in powdered borosilicate glasses having different particle size and different uranium content. Excitation with 100 to 350 keV electrons and with 253.7 nm light was found to produce identical absolute radiant exitance spectra in powdered samples. The most efficient glass was one containing 29.4 wt% B2O3, 58.8 wt% SiO2, 9.8 wt% Na2O and 2.0 wt% UO2.

Eubanks, A. G.↗
NASA NTRS1974

EPR measurement of the effect of glass composition on the oxidation states of europium

An investigation was conducted concerning the dependence of the concentration ratio of Eu(2+) to Eu(3+) on composition for silicate liquids whose compositional end members are CaAl2Si2O8 and MgSiO3, MG2SiO4, CaMgSi2O6, CaMgSiO4, CaSiO3, or Ca2SiO4. The liquids were quenched to produce glasses. An electron paramagnetic resonance spectrometer was used to determine the concentration ratios of Eu(2+) to Eu(3+) in the glasses.

Morris, R. V.↗
NASA NTRS1974

Properties of ribulose diphosphate carboxylase immobilized on porous glass

Ribulose-1,5-diphosphate carboxylase from spinach has been bound to arylamine porous glass with a diazo linkage and to alklamine porous glass with glutaraldehyde. Stability at elevated temperatures and responses to changes of pH and ribulose-1,5-diphosphate, Mg(2+), and dithiothreitol concentrations were not significantly different from the soluble enzyme, though stability at 4 C was somewhat improved.

Shapira, J.↗
NASA NTRS1974

Orange glass - Evidence for regional deposits of pyroclastic origin on the moon

Crystallized spheres of orange glass from Shorty Crater at the Apollo 17 site are shown by spectral reflectance data to be the characteristic ingredient of the dark mantling deposit of the Taurus-Littrow region. This deposit, mapped on spectral vidicon images taken using earth-based telescopes, apparently is thickest 50 km northwest of the Apollo 17 landing area, and has a gradational contact with the surrounding materials. The irregular areal distribution of the dark-mantle deposit and the gradational borders support conclusions based on laboratory studies of the orange soils that these are volcanic pyroclastic materials. Similar deposits are identified by spectral reflectance properties near Rima Bode, Schroeter W, Fauth H, and Higinus W. The same material is likely to occur at Sulpucius Gallus based on visual and photographic observations of orange soil. The apparently restricted occurrence of the orange-glass deposits in a belt along the edges of major mare basins implies structural control of volcanic vents and a possible deep-seated origin.

Adams, J. B.↗
NASA NTRS1974

Thermal histories and crystal distributions in partly devitrified lunar glasses cooled by radiation

Calculations of the expected crystallization behavior of selected lunar compositions (60095 and 14259) are presented. Knowledge of this behavior combined with measurements of the state of crystallinity in partially devitrified lunar samples permits the determination of the thermal history of the samples. The state of crystallinity of a specimen is described by a statistical crystal distribution function psi. The heat flow problems of a plate of opaque glass quenched on an aluminum block and of a semi-transparent glass sphere cooling by radiation are analyzed. The results are combined with laboratory measurements of the crystal growth velocity and the viscosity, and with theoretical expressions for the nucleation frequency (homogeneous and heterogeneous) to obtain psi. It is found that the calculated psi is much too large in comparison with laboratory experiments on lunar samples. Possible reasons for the discrepancy are discussed, and the most likely cause is that the assumed nucleation barrier is too small. It also appears likely that these materials have relatively few nucleating heterogeneities.

Hopper, R. W.↗
NASA NTRS1974

The formation of lunar glasses

The work investigates experimentally the conditions required to form glasses out of a number of lunar compositions. Viscous flow and crystallization behavior of several compositions were studied over a wide range of temperature. These data exhibit the form generally found for glass-forming liquids. Combining growth rate with viscosity data, the fraction of preferred growth sites on the crystal-liquid interfaces is found to increase with increasing undercooling for all lunar compositions. The detailed forms of the kinetic data are predicted by recent computer simulations of crystal growth. Calorimetry studies indicate that lunar orange soil was formed under conditions of much slower cooling rate than 1000 deg K per sec.

Uhlmann, D. R.↗
NASA NTRS1975

Glass-Si heterojunction solar cells

An increase in efficiency from 2% to over 7% was achieved by a solar cell that used polycrystal silicon heterojunction with SnO2 glass. For Single crystal substrates, efficiencies close to 10% were measured. These cells had the same structures as polycrystalline cells. Work on p+/n heterojunction using In2O3 glass resulted in cells of 3% efficiency on polycrystalline material and 4% efficiency on single crystal material.

Ahrons, R. W.↗
NASA NTRS1976

Three synthetic lunar glasses

Glasses have been synthesized that have the approximate compositions of lunar rocks 61156, 68415, and 77135, respectively. The glasses have been analyzed by conventional analytical and electron microprobe techniques and have been found to be highly homogeneous. They have been used successfully as electron microprobe standards and for experimental studies of crystallization and solar-wind implantation. Small amounts of these materials can be provided to investigators who would find them useful.

Minkin, J. A.↗
NASA NTRS1976

Manufacturing unique glasses in space

An air suspension melting technique is described for making glasses from substances which to date have been observed only in the crystalline condition. A laminar flow vertical wind tunnel was constructed for suspending oxide melts that were melted using the energy from a carbon dioxide laser beam. By this method it is possible to melt many high-melting-point materials without interaction between the melt and crucible material. In addition, space melting permits cooling to suppress crystal growth. If a sufficient amount of under cooling is accompanied by a sufficient increase in viscosity, crystallization will be avoided entirely and glass will result.

Happe, R. P.↗
NASA NTRS1977

Study of diffusion coefficients of glasses under Zero-G

A diffusion experiment for glasses was formulated, such theoretical and earth bound results as were available were outlined, and the preliminary earth based experimental work in preparation for a weightless experiment was done. The fundamental premise of the work was that diffusion studies of the glass forming ion can be conducted in zero-g environments, and diffusion data obtained from these experiments are unique and valuable because of earth based experimental difficulties.

Kinser, D. L.↗
NASA NTRS1977

Thermal expansion of an epoxy-glass microsphere composite

The thermal expansion of a composite of epoxy (diglycidyl ether of bisphenol A) and solid glass microspheres was investigated. The microspheres had surfaces which were either untreated or treated with a silicone release agent, an epoxy coupling agent, or a general purpose silane coupling agent. Both room temperature (about 300 K) and elevated temperature (about 475 K) cures were used for the epoxy. Two microsphere size ranges were used, about 50 microns, which is applicable in filled moldings, and about 125 microns, which is applicable as bond line spacers. The thermal expansion of the composites was measured from 300 to 350 K or from 300 to 500 K, depending on the epoxy cure temperature. Measurements were made on composites containing up to .6 volume fraction microspheres. Two predictive models, which required only the values of thermal expansion of the polymer and glass and their specific gravities, were tested against the experimental data. A finite element analysis was made of the thermal strain of a composite cell containing a single microsphere surrounded by a finite-thickness interface.

Price, H. L.↗