Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “formate”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 541 records · Page 30

Formation of nuclei during precipitation in metallic mixed crystals

Assuming that the energy of a mixed crystal can be calculated by simple addition of neighboring bonds, the nuclear formation energy is calculated for precipation in a super-saturated binary mixed crystal. From this can be determined the frequency of the formation of nuclei. From the calculation of a numerical example we can obtain, for the degree of sub-cooling at which the frequency of the formation of nuclei reaches its maximum, satisfactory agreement with available measurements of the rate of precipitation.

Becker, R.↗

Star formation and molecular clouds

Several differnt stages can be discerned within the star formation process. Star formation can be considered to start when a molecular cloud fragments into many clumps. Many different physical processes are likely to play an important role in star formation, including self-gravity, magnetic fields, rotation, winds, and radiation transport. The current knowledge on some of these processes are reviewed.

Tielens, Alexander G. G. M.↗

Terrestrial versus giant planet formation

Given a solar nebular surrounding the early protosun, containing dust grains that have already undergone growth through collisions to about centimeter-size, the question of the formation of the terrestrial and giant planets is considered. In contrast to the usual approach of emphasizing how well a problem is understood, the uncertainties and areas where more work needs to be done will be accentuated. Also, the emphasis will be on the dynamics of planetary formation, because profound problems still exist in this area, and because it seems most logical to concentrate first on the dynamical questions involved with assembling the planets before putting too much effort into the detailed chemical and geological consequences of certain formation mechanisms.

Boss, Alan P.↗

Theoretical investigation of the role of clay edges in prebiotic peptide bond formation. II - Structures and thermodynamics of the activated complex species

Molecular orbital calculations are used to study amino acid activation by anhydride formation in neutral phosphates and in tetrahedral silicate and aluminate sites on clay edges. The results agree with previous ab initio studies of Luke et al. (1984) on the reactant species. Relative heats of formation of the anhydrides indicate the extent of anhydride formation to be the greatest for Al and the least for phosphate, which is the same order as the stability of hydrolysis.

Collins, Jack R.↗

Excimer laser annealing: A gold process for CZ silicon junction formation

A cold process using an excimer laser for junction formation in silicon has been evaluated as a way to avoid problems associated with thermal diffusion. Conventional thermal diffusion can cause bulk precipitation of SiOx and SiC or fail to completely activate the dopant, leaving a degenerate layer at the surface. Experiments were conducted to determine the feasibility of fabricating high quality p-n junctions using a pulsed excimer laser for junction formation at remelt temperature with ion-implanted surfaces. Solar-cell efficiency exceeding 16 percent was obtained using Czochralski single-crystal silicon without benefit of back surface field or surface passivation. Characterization shows that the formation of uniform, shallow junctions (approximately 0.25 micron) by excimer laser scanning preserves the minority carrier lifetime that leads to high current collection. However, the process is sensitive to initial surface conditions and handling parameters that drive the cost up.

Wong, David C.↗

Binary stars - Formation by fragmentation

Theories of binary star formation by capture, separate nuclei, fission and fragmentation are compared, assessing the success of theoretical attempts to explain the observed properties of main-sequence binary stars. The theory of formation by fragmentation is examined, discussing the prospects for checking the theory against observations of binary premain-sequence stars. It is concluded that formation by fragmentation is successful at explaining many of the key properties of main-sequence binary stars.

Boss, Alan P.↗

Arch filaments associated with the formation of sunspots by umbral merging

The formation of a sunspot during the emergence of a new group is described. The spot forms from a cluster of small umbrae that do not converge. Rather, the individual umbrae enlarge and merge into a spot covering the same area. The formation of each umbra is accompanied by an intensification of the arch filament anchored in it. The formation of the sunspot produces no apparent change in the total field.

Zirin, Harold↗

Enthalpies of formation of CaAl4O7 and CaAl12O19 (hibonite) by high temperature, alkali borate solution calorimetry

Enthalpies of formation were determined for two calcium aluminate phases, CaAl4O7 and CaAl12O19, using high-temperature alkali borate solution calorimetry. The aluminates were synthesized by multiple-cycle heating and grinding stoichiometric mixtures of CaCO3 and Al2O3, and the products were characteized by X-ray diffraction and SEM microbeam analysis. The data on impurities (CaAl4O7 was found to be about 89.00 percent pure by weight and the CaAl12O19 samples about 91.48 percent pure) were used to correct the heat of solution values of the synthetic products. The enthalpies of formation, at 1063 K, from oxides, were found to be equal to -(25.6 + or - 4.7) kJ/g.f.w. for CaAl4O7 and -(33.0 + or - 9.7) kJ/g.f.w. for CaAl12O19; the respective standard enthalpies of formation from elements, at 298 K, were estimated to be -4007 + or - 5.2 kJ/g.f.w. and -10,722 + or - 12 kJ/g.f.w.

Geiger, C. A.↗

Simulation of GaAs cluster formation on GaAs(00-1), AlAs(00-1), Si(001), and As1/Si(001) surfaces

Recently developed semiempirical potential energy functions for the Ga-As-Si and Ga-As-Al systems have been applied here to determine the excess formation energy for GaAs clusters on GaAs(00-1), AlAs(00-1), Si(001), and one atomic layer As-covered Si(001) substrates as a function of cluster size and cluster shape by the Monte Carlo technique. Pyramidal type ledges on the GaAs clusters are found to be the favored ledge for the first three layers while an inverted-pyramidal type ledge is also favored in certain cases for the As1/Si(001) substrate. Cluster formation at ledges is compared with cluster formation on a flat terrace for the Si(001) and the As1/Si(001) substrates.

Choi, D. K.↗

SIRTF and star formation

Four problems in the field of star formation that can be attacked to advantage with SIRTF are discussed: (1) the patterns of star formation in spiral galaxies, (2) the physical mechanism for bimodal star formation, (3) the nature of bipolar outflows from young stellar objects, and (4) the birth of brown dwarfs. In each case, SIRTF can provide the crucial combination of high angular resolution with great sensitivity over a broad range of wavelengths that is needed to address the relevant issues.

Shu, Frank H.↗

Enhanced star formation and infrared emission in the centers of galaxies

The IR properties of galaxies with star-formation-dominated central IR luminosity are discussed, summarizing the results of recent observational investigations. Consideration is given to the constituents of star-forming galaxies (dust in emission, photoionized gas, and shock-heated gas), the IR morphology (IR luminosity and young stars and NIR mapping to see beyond dust), the relationship between IR and radio emission, M82 as a typical object, and the implications of the observations for theoretical models of star formation. It is concluded that star formation in these galaxies will exhaust the available gas supply in much less than a Hubble time. Diagrams, graphs, sample images, and tables of numerical data are provided.

Telesco, Charles M.↗

Some possible mechanisms for the formation of large scale structures in the universe

Three mechanisms for the formation of large voids are discussed: (1) the disruption of condensation due to unstable dark matter, (2) the disruption of condensation due to annihilating dark matter, and (3) the evolution of condensates into low luminosity sources. It is concluded that the extremely large sizes of the voids and their rough spherical shape and sharply defined edges suggest that some event occurred which inhibited galaxy formation in these regions (and/or triggered galaxy formation in the regions exterior to the voids), and this event may have been hydrodynamic in nature.

Daly, Ruth A.↗

Star formation

Observational studies of star formation are reviewed. The structure and properties of molecular clouds are discussed. The conditions for gravitational collapse are presented, including the thermal, rotational, and magnetic limits. Both high- and low-mass star formation are examined. A model for molecular clouds is given, which includes photoionization-regulated star formation.

Mckee, Christopher F.↗

Molecular gas, the interstellar medium, and star formation in S0 and Sa galaxies

The results are presented of a survey for CO J = 1 - 0 emission from S0 and S0/a galaxies. The results show that molecular gas is abundant within some early-type disk galaxies, and that the range in the ratio of molecular gas to atomic gas mass is similar to those in other disk galaxies. In the S0 and S0/a galaxies studied, estimated rates of star formation are substantially smaller than, but efficiencies of star formation are roughly the same as, those in Sb or Sc galaxies. Although the rate of cooling of the hot, X-ray emitting gas may be close to the estimated stellar mass return rate in the sample, the star formation rate probably exceeds both by a significant factor.

Thronson, Harley A., Jr.↗

A head up display format for application to V/STOL aircraft approach and landing

A head up display (HUD) format developed at NASA Ames Research Center to provide pilots of V/STOL aircraft with complete flight guidance and control information for category-3C terminal-area flight operations, is described in detail. These flight operations cover a large spectrum, from STOL operations on land-based runways to VTOL operations on small ships in high seas. Included in this description is a complete geometrical specification of the HUD elements and their drive laws. The principal features of this display format are the integration of the flightpath and pursuit guidance information into a narrow field of view, easily assimilated by the pilot with a single glance, and the superposition of vertical and horizontal situation information. The display is a derivative of a successful design developed for conventional transport aircraft. The design is the outcome of many piloted simulations conducted over a four-year period. Whereas the concepts on which the display format rests could not be fully exploited because of field-of-view restrictions, and some reservations remain about the acceptability of superimposing vertical and horizontal situation information, the design successfully fulfilled its intended objectives.

Merrick, Vernon K.↗

Oligomerization reactions of deoxyribonucleotides on montmorillonite clay - The effect of mononucleotide structure on phosphodiester bond formation

The formation of oligomers from deoxynucleotides, catalyzed by Na(+)-montmorillonite, was investigated with special attention given to the effect of the monomer structure on the phosphodiester bond formation. It was found that adenine deoxynucleotides bind more strongly to montmorillonite than do the corresponding ribonucleotides and thymidine nucleotides. Tetramers of 2-prime-dpA were detected in the reaction of 2-prime-d-5-prime-AMP with a water-soluble carbodiimide EDAC in the presence of Na(+)-montmorillonite, illustrating the possible role of minerals in the formation of biopolymers on the primitive earth.

Ferris, James P.↗

The physics of planetesimal formation

Physical processes involved in the planetesimal formation are discussed with special attention given to the nature of aerodynamic interactions between solid bodies and gas in the solar nebula. It is emphasized that the model of planetesimal formation by gravitational instability of a dust layer yields predictions that are simple but almost certainly wrong. It is suggested instead that the formation of planetesimals began with the process of coagulation of grains into larger aggregates, and that gravitational forces became more important than gas drag only after objects as large as many meters in diameter had formed.

Weidenschilling, Stuart J.↗

Digital interpolators for polar format processing

The polar format approach to SAR image formation requires data to be interpolated from a warped grid onto a Cartesian lattice. In general, this requires that data be interpolated between varying sampling rates. In this paper, frequency-domain optimality criteria for polar format interpolators are defined and justified, and an approach to designing the corresponding digital filters is described.

Adams, John W.↗