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At least 541 records · Page 30

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NASA NTRS1982

Fluorescence yields from photodissociation of SO2 at 1060-1330 A

The absorption and fluorescence cross sections of SO2 were measured in the 1060-1330 A region using synchrotron radiation as the light source. Several absorption bands were observed and assigned tentatively to the Rydberg states converging to the SO2(+) states. It is shown that the apparent quantum yields for excitation wavelengths longer than 1200 A are small, and are presumably emitted from the O(1S) and S(1S) metastable species. At shorter excitation wavelengths, the fluorescence cross sections increase at the threshold wavelengths of possible SO2 dissociation processes.

Suto, M.↗

NASA NTRS1982

A semiclassical study of laser-induced atomic fluorescence from Na2, K2 and NaK

A semiclassical treatment of laser-induced atomic fluorescence for the alkali-dimer systems Na2, K2 and NaK is presented. The variation of the fluorescence intensity with the frequency of the exciting laser photon is studied and a comparison of theoretical results with a set of experimental data is presented.

Yuan, J.-M.↗

NASA NTRS1983

Separation of time-averaged turbulence components by laser-induced fluorescence

A resonant Doppler velocimeter technique is introduced for time averaged gas flow turbulence fluctuation measurements. A monochrome laser beam is shone through a flow seeded with an atomic or molecular species that has an absorption frequency to which the laser is tuned. The resulting fluorescence is recorded by a detector, and the Doppler shift of the absorption frequency yields the velocity component of the flow in the direction of the beam. Static temperature and pressure data are available from the spectroscopic absoption line broadening. An analytical formulation of the laser-induced fluorescence intensity is defined and related to the velocity, temperature, and pressure. Comparison with data from a Na-seeded laminar supersonic jet demonstrates the accuracy of both the technique and model. Varying the pump laser frequency allows determination of the mean square velocity, temperature, and pressure fluctuations.

Cheng, S.↗

NASA NTRS1983

Laser-induced fluorescence technique for velocity field measurements in subsonic gas flows

A nonintrusive optical technique is reported for multiple-point velocity measurements in subsonic flows. The technique is based on the detection of fluorescence from a Doppler-shifted absorption line of seeded iodine molecules excited at a laser frequency fixed in the wing of the line. Counterpropagating laser sheets are used to illuminate the flow, in the present case a nitrogen round jet, thereby eliminating the need for an unshifted reference signal. The fluorescence is detected simultaneously at 10,000 points in a plane of the flow using a 100 x 100 element photodiode-array camera. The velocity at each point is computed from four successive camera frames, each recorded with a different beam direction. The measured mean velocities between 5 and 50 m/sec agree well with data from the literature.

Hiller, B.↗

NASA NTRS1983

Laser-induced fluorescence spectroscopy for combustion diagnostics

The types of spectroscopic and collisional measurements that are needed to develop laser-induced fluorescence as a diagnostic technique are discussed, with emphasis placed on combustion measurements. The spectroscopic measurements under collision-free conditions include production of radicals, excitation scan studies, lifetime measurements, and fluorescence scans. The collisional studies discussed here are quenching, energy transfer, and polarization phenomena. The results of recent laboratory experiments are presented.

Crosley, D. R.↗

NASA NTRS1983

Photodiagnostics of turbulent flows using laser-induced fluorescence

An optical probe technique that will allow remote measurements of temperature (and density), along with their time dependent fluctuations, to be made in a supersonic turbulent wind tunnel flow was developed. Laser-induced fluorescence from nitric oxide which was seeded into the flowing gas medium (nitrogen) at low concentrations was used. The fluorescence emission intensity following laser excitation of the nitric oxide (NO) ground state rotational levels is then related to thermodynamic quantities of the bulk fluid.

Bershader, D.↗

NASA NTRS1984

Saturated laser fluorescence in turbulent sooting flames at high pressure

The primary objective was to develop a quantitative, single pulse, laser-saturated fluorescence (LSF) technique for measurement of radical species concentrations in practical flames. The species of immediate interest was the hydroxyl radical. Measurements were made in both turbulent premixed diffusion flames at pressures between 1 and 20 atm. Interferences from Mie scattering were assessed by doping with particles or by controlling soot loading through variation of equivalence ratio and fuel type. The efficacy of the LSF method at high pressure was addressed by comparing fluorescence and adsorption measurements in a premixed, laminar flat flame at 1-20 atm. Signal-averaging over many laser shots is sufficient to determine the local concentration of radical species in laminar flames. However, for turbulent flames, single pulse measurements are more appropriate since a statistically significant number of laser pulses is needed to determine the probability function (PDF). PDFs can be analyzed to give true average properties and true local kinetics in turbulent, chemically reactive flows.

King, G. B.↗

NASA NTRS1984

Shot noise limited detection of OH using the technique of laser induced fluorescence

Nearly shot-noise limited detection of OH using the technique of laser-induced fluorescence is reported. A LIDAR configuration is used to excite fluorescence in a large volume and a narrow-bandwidth interference filter provides spectral discrimination. This arrangement alleviates the effect of ozone interference and facilitates image processing at relatively close distances. The detection limit is determined mainly by the shot-noise of the solar background. Ground-based measurements in Dearborn indicate a detection limit of better than 1 x 10 to the 6th power OH/cubic cm over a forty-minute acquisition period. Under favorable conditions, a comparable detection limit was also observed for airborne measurements.

Bakalyar, D. M.↗

NASA NTRS1983

Oil film thickness using airborne laser-induced oil fluorescence backscatter

Remote airborne measurement of oil film thickness on ocean surface using laser-induced water Raman backscatter is discussed. It is pointed out that the theoretical model of oil fluorescence by Horvath et al. (1971) contains the necessary constituents to provide for the natural background fluorescence that is also induced by the laser during the course of an oil thickness experiment. How the various parameters of the model are obtained from typical airborne profile data is discussed, and it is shown that the water Raman backscatter may be used to assist further in the application of the data. The regions or water types over which the technique might be most useful or applicable are discussed.

Hoge, F. E.↗

NASA NTRS1985

Analysis of vibronic transitions in titanium doped sapphire using the temperature of the fluorescence spectra

An analysis of the fluorescence spectra of titanium-doped sapphire crystals for temperatures ranging from 13 to 578 K is made. Zero- and multiphoton assisted electronic transitions are observed at temperatures below 125 K. Zero-phonon transition energies agree with previously reported measured and predicted values. Photon-assisted transitions suggest that two principle modes of lattice vibrations with energies of 220 and 260/cm are coupled to the electronic 2T2g state. A single phonon energy of 173/cm is observed to couple to the 2Eg electronic state. Crossover energy is estimated to be about 11,800/cm using a simple harmonic approximation. Lineshape analysis is performed. The fluorescence lifetime as measured to be a constant 3.9 microsec below 150 k decreasing to 2.9 microsec at 300 K.

Byvik, C. E.↗

NASA NTRS1986

Fluorescence from VUV excitation of formaldehyde

The 105-180-nm photoabsorption and fluorescence cross sections of H2CO are determined experimentally using a synchrotron-radiation light source and the apparatus described by Lee (1980). The results are presented in tables and graphs and discussed. VUV emission with threshold wavelength 140.3 nm is detected and attributed to the A 1Pi - X 1Sigma(+) system of CO, and UV emission from the HCO (B-X) system is found below a 147.5-nm threshold, the H-HCO dissociation energy having an upper limit of 3.61 + or - 0.03 eV. At 116 nm, the maximum quantum yields of the VUV and UV fluorescences are about 1.6 and 0.23 percent, respectively.

Suto, Masako↗

NASA NTRS1987

Ocean color spectral variability studies using solar-induced chlorophyll fluorescence

It is suggested that chlorophyll-induced ocean color spectral variability can be studied using only a passive airborne spectroradiometer instrument, with solar-induced chlorophyll fluorescence used as the standard against which all correlations are performed. The intraspectral correlation (ISC) method is demonstrated with results obtained during an airborne mapping mission in the New York Bight. The curvature algorithm is applied to the solar-induced chlorophyll fluorescence at about 690 nm, and good agreement is found with results obtained using active-passive correlation spectroscopy. The ISC method has application to spectral variability and resulting chlorophyll concentration measurement in different environmental conditions and in different water types.

Hoge, Frank E.↗

NASA NTRS1987

Environmental effects on laser-induced fluorescence spectra of natural waters

Laser fluorosensing can be used to monitor dissolved organic carbon (DOC), but analysis of the data can be hindered by several environmental phenomena. These phenomena include attenuation of the laser beam and differential attenuation of the fluorescence by the water column, variability in the molecular weight composition of the DOC, and temperature, pH, and metal ion effects on DOC fluorescence. These factors are discussed in terms of their effect on laboratory and remote field data analysis. Experimental results are provided. Analysis of fluorosensor data of DOC may be improved by compensating for the environmental factors. An improved methodology is discussed, and a suggestion is made for indirect monitoring of pH and metal ion concentration.

Vodacek, Anthony↗

NASA NTRS1987

Measurements of temperature, density, pressure, and their fluctuations in supersonic turbulence using laser-induced fluorescence

A laser-induced fluorescence method has been developed that provides simultaneous measurements of temperature, density, and their fluctuations owing to turbulence in unheated compressible flows. Pressure and its fluctuations are also deduced using the equation of state. Fluorescence is induced in nitric oxide that has been seeded into a nitrogen flow in concentrations of 100 ppm. Measurements are obtained from each laser pulse, with a spatial resolution of 1 mm and a temporal resolution of 125 ns. The method was applied to a supersonic, turbulent, boundary-layer flow with a free-stream Mach number of 2. For stream conditions in the range from 150-300 K and 0.3-1 atm, temperature is measured with an uncertainty of approximately 1 percent rms, while density and pressure uncertainties are approximately 2 percent rms.

Gross, K. P.↗

NASA NTRS1988

Two-photon-excited fluorescence spectroscopy of atomic fluorine at 170 nm

Two-photon-excited fluorescence spectroscopy of atomic fluorine is reported. A doubled dye laser at 286-nm is Raman shifted in H2 to 170 nm (sixth anti-Stokes order) to excite ground-state 2P(0)J fluorine atoms to the 2D(0)J level. The fluorine atoms are detected by one of two methods: observing the fluorescence decay to the 2PJ level or observing F(+) production through the absorption of an additional photon by the excited atoms. Relative two-photon absorption cross sections to and the radiative lifetimes of the 2D(0)J states are measured.

Herring, G. C.↗

NASA NTRS1988

The fluorescence of cometary OH

A new solar spectral atlas, improved oscillator strengths, and additional transitions have been incorporated in calculations of the fluorescent equilibrium of the OH molecule in comets as a function of heliocentric distance and radial velocity. Comparisons of detailed, ultraviolet band profiles have been made with the observed, high-resolution spectra of eight comets. While a purely fluorescent equilibrium calculation is sufficient to reproduce the major variations seen in the band structure from one comet to another, some collisional quenching of the inversion of the X2II3/2 Lambda-doublet ground state is required to match the detailed features. The relative population inversion of the upper and lower levels of the ground state is also calculated as a function of both distance and velocity, with the results being consistent with 18 cm radio observations. Predictions of the infrared OH vibrational bands are made; the 1-0 band should be observable if a sufficiently high spectral resolution is employed.

Schleicher, David G.↗

NASA NTRS1988

CH(A, B-X) fluorescence from vacuum ultraviolet excitation of CH3

The fluorescence due to single-photon and two-photon excitation of CH3 produced by the reaction of CH4 with F or Cl in a flow tube is investigated experimentally. The excitation source is an excimer laser operating with pulse duration 6 nsec and repetition rate 20 Hz, and the fluorescence is observed using a 0.25-m spectrometer and a 1024-channel diode array; the results are presented graphically. Emission is detected at 157 nm (with approximate cross section 8 x 10 to the -19th sq cm) and 193 nm, but not at 248 nm. The applicability of these data to studies of hydrocarbon combustion, the methane oxidation cycle in the atmosphere, interstellar molecule formation, and diamond film fabrication is indicated.

Ye, Chao↗

NASA NTRS1988

Identification of new fluorescence processes in the UV spectra of cool stars from new energy levels of Fe II and Cr II

Two fluorescence processes operating in atmospheres of cool stars, symbiotic stars, and the Sun are presented. Two emission lines, at 1347.03 and 1360.17 A, are identified as fluorescence lines of Cr II and Fe II. The lines are due to transitions from highly excited levels, which are populated radiatively by the hydrogen Lyman alpha line due to accidental wavelength coincidences. Three energy levels, one in Cr II and two in Fe II, are reported.

Johansson, Sveneric↗