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At least 541 records · Page 30

Clearing a Path to Commercialization of Marine Renewable Energy Technologies Through Public–Private Collaboration

Governments are increasingly turning toward public–private partnerships to bring industry support to improving public assets or services. Here, we describe a unique public–private collaboration where a government entity has developed mechanisms to support public and private sector advancement and commercialization of monitoring technologies for marine renewable energy. These support mechanisms include access to a range of skilled personnel and test facilities that promote rapid innovation, prove reliability, and inspire creativity in technology development as innovations move from concept to practice. The ability to iteratively test hardware and software components, sensors, and systems can accelerate adoption of new methods and instrumentation designs. As a case study, we present the development of passive acoustic monitoring technologies customized for operation in energetic waves and currents. We discuss the value of testing different systems together, under the same conditions, as well as the progression through different test locations. The outcome is multiple, complementary monitoring technologies that are well suited to addressing an area of high environmental uncertainty and reducing barriers to responsible deployment of low-carbon energy conversion systems, creating solutions for the future.

16 TIDAL AND WAVE POWER↗

SERGHEI (SERGHEI-SWE) v1.0: a performance-portable high-performance parallel-computing shallow-water solver for hydrology and environmental hydraulics

The Simulation EnviRonment for Geomorphology, Hydrodynamics, and Ecohydrology in Integrated form (SERGHEI) is a multi-dimensional, multi-domain, and multi-physics model framework for environmental and landscape simulation, designed with an outlook towards Earth system modelling. At the core of SERGHEI's innovation is its performance-portable high-performance parallel-computing (HPC) implementation, built from scratch on the Kokkos portability layer, allowing SERGHEI to be deployed, in a performance-portable fashion, in graphics processing unit (GPU)-based heterogeneous systems. In this work, we explore combinations of MPI and Kokkos using OpenMP and CUDA backends. In this contribution, we introduce the SERGHEI model framework and present with detail its first operational module for solving shallow-water equations (SERGHEI-SWE) and its HPC implementation. This module is designed to be applicable to hydrological and environmental problems including flooding and runoff generation, with an outlook towards Earth system modelling. Its applicability is demonstrated by testing several well-known benchmarks and large-scale problems, for which SERGHEI-SWE achieves excellent results for the different types of shallow-water problems. Finally, SERGHEI-SWE scalability and performance portability is demonstrated and evaluated on several TOP500 HPC systems, with very good scaling in the range of over 20 000 CPUs and up to 256 state-of-the art GPUs.

58 GEOSCIENCES↗

Understanding the relative importance of vertical and horizontal flow in ice-wedge polygons

Abstract. Ice-wedge polygons are common Arctic landforms. The future of these landforms in a warming climate depends on the bidirectional feedback between the rate of ice-wedge degradation and changes in hydrological characteristics. This work aims to better understand the relative roles of vertical and horizontal water fluxes in the subsurface of polygonal landscapes, providing new insights and data to test and calibrate hydrological models. Field-scale investigations were conducted at an intensively instrumented location on the Barrow Environmental Observatory (BEO) near Utqiaġvik, AK, USA. Using a conservative tracer, we examined controls of microtopography and the frost table on subsurface flow and transport within a low-centered and a high-centered polygon. Bromide tracer was applied at both polygons in July 2015 and transport was monitored through two thaw seasons. Sampler arrays placed in polygon centers, rims, and troughs were used to monitor tracer concentrations. In both polygons, the tracer first infiltrated vertically until encountering the frost table and was then transported horizontally. Horizontal flow occurred in more locations and at higher velocities in the low-centered polygon than in the high-centered polygon. Preferential flow, influenced by frost table topography, was significant between polygon centers and troughs. Estimates of horizontal hydraulic conductivity were within the range of previous estimates of vertical conductivity, highlighting the importance of horizontal flow in these systems. This work forms a basis for understanding complexity of flow in polygonal landscapes.

54 ENVIRONMENTAL SCIENCES↗

Vegetation Warming Experiment: Landscape-scale digital camera imagery for vegetation phenology, Utqiagvik (Barrow), Alaska, 2017

Images captured using a StarDot NetCam SC phenocamera looking east from the top of the Barrow Environmental Observatory (BEO) Sled Shed, Barrow (now Utqiagvik), Alaska. The camera was installed to remotely monitor plant phenology and operation of the BNL TEST group's ZPW (Zero Power Warming) chambers during the growing season of 2017. Images were captured from early spring (24 April) through to late fall (15 November). Snowmelt, vegetation growth and senescence, and snow accumulation were captured. Images were uploaded to the BNL FTP server every 10 minutes. jpg images have been compressed in *.tar.gz format (12.1 GB) and additional information in *.pdf and *.txt files. The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

2018 Long-Term Hydrologic Monitoring Program Report for Rio Blanco, Colorado, Site

This report presents the monitoring data collected by the U.S. Department of Energy (DOE) Office of Legacy Management (LM) at the Rio Blanco, Colorado, Site (Figure 1). The Rio Blanco site was the location of an underground nuclear test during which three nuclear devices were detonated nearly simultaneously in a single borehole in 1973. The test resulted in residual radionuclide contamination at the detonation depths of 5840, 6230, and 6690 feet (ft) (DOE 2015). Monitoring includes the collection of samples from groundwater wells and surface water locations near the site to assess for any potential impacts that may be attributed to the Rio Blanco nuclear test. This report summarizes the laboratory analytical results obtained from the sampling event conducted in 2018. This annual report and previous reports are available on the LM public website at https://www.lm.doe.gov/rio_blanco/Sites.aspx. Data collected during this and previous monitoring events are available on the Geospatial Environmental Mapping System (GEMS) website at https://gems.lm.doe.gov/#site=RBL.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

LLNL SFA OBER FY23 Program Management and Performance Report: BioGeoChemistry at Interfaces

The focus of the BioGeoChemistry at Interfaces SFA has been to identify and quantify the biogeochemical processes and the underlying mechanisms that control actinide mobility in an effort to reliably predict and control the cycling and migration of actinides in the environment. The research approach has included: (1) Field Studies that capture actinide behavior on the timescale of decades (Research Thrust 1), and (2) Fundamental Laboratory Studies that isolate specific biogeochemical processes observed in the field (Research Thrust 2). These Research Thrusts are underpinned by the unique capabilities and staff expertise at Lawrence Livermore National Laboratory, allowing the BioGeoChemistry at Interfaces SFA to advance our understanding of actinide migration behavior in the environment, and serve as a resource for environmental radiochemistry research internationally (Figure 1). In FY23, our SFA research focused on transient redox gradients across stratified waters, sediment-water interfaces, and mineral-water interfaces to address processes controlling cycling of redox-sensitive metals. Nevertheless, Research Thrusts 1 and 2 are guided by the following broad central hypotheses that were developed during our last program review held at the end of FY18: Thrust 1 Hypothesis: Biogeochemical processes occurring on the timescale of years to decades lead to greater actinide recalcitrance in sediments and limits their migration in surface and groundwater. Thrust 2 Hypothesis: Long-term biogeochemical processes include mineral and surface alteration, which leads to stabilization of actinide surface associations or incorporation into mineral precipitates. Our strategic goal is to use the knowledge gained from our Science Plan to advance our understanding of the behavior of actinides and other radionuclides (e.g. Cs) and provide DOE with the scientific basis for remediation and long-term stewardship of DOE’s legacy sites. More broadly, we are improving our understanding of transport phenomena in environmental systems sciences with a particular emphasis on environmentally relevant (long-term) timescales. While we retained some of our historical focus on actinide biogeochemistry this past fiscal year, biogeochemical processes occurring at unique Test Bed locations associated with this SFA provide fundamental information on abiotic and biotic redox processes that control the cycling of redox sensitive metals under dynamic and transient conditions. Furthermore, in collaboration with SFA teams at Argonne National Laboratory, our SFA has begun to transition away from the current research focus and develop a new research program in terrestrial wetland systems. The Terrestrial Wetland Function and Resilience SFA program plan will be delivered to the Environmental System Science (ESS) program within BER at the end of FY23.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Tropical Tree Crop Simulation with a Process-Based, Daily Timestep Simulation Model (ALMANAC): Description of Model Adaptation and Examples with Coffee and Cocoa Simulations

Coffee (Coffea species) and Cocoa (Theobroma cacao) are important cash crops grown in the tropics but traded globally. This study was conducted to apply the ALMANAC model to these crops for the first time, and to test its ability to simulate them under agroforestry management schemes and varying precipitation amounts. To create this simulation, coffee was grown on a site in Kaua’i, Hawai’i, USA, and cocoa was grown on a site in Sefwi Bekwai, Ghana. A stand-in for a tropical overstory tree was created for agroforestry simulations using altered parameters for carob, a common taller tropical tree for these regions. For both crops, ALMANAC was able to realistically simulate yields when compared to the collected total yield data. On Kaua’i, the mean simulated yield was 2% different from the mean measured yield, and in all three years, the simulated values were within 10% of the measured values. For cocoa, the mean simulated yield was 3% different from the mean measured yield and the simulated yield was within 10% of measured yields for all four available years. When precipitation patterns were altered, in Ghana, the wetter site showed lower percent changes in yield than the drier site in Hawai’i. When agroforestry-style management was simulated, a low Leaf Area Index (LAI) of the overstory showed positive or no effect on yields, but when LAI climbed too high, the simulation was able to show the detrimental effect this competition had on crop yields. These simulation results are supported by other literature documenting the effects of agroforestry on tropical crops. This research has applied ALMANAC to new crops and demonstrated its simulation of different management and environmental conditions. The results show promise for ALMANAC’s applicability to these scenarios as well as its potential to be further tested and utilized in new circumstances.

60 APPLIED LIFE SCIENCES↗

Erosion resistance test of SiC mirror sample for ITER divertor VUV spectrometer

A series of tests have been performed to validate the resistance of the Silicon Carbide (SiC) mirror as the first mirror material of ITER VUV spectrometers to all ITER environmental conditions. Here we focused on the erosion (and deposition) of the SiC mirror sample caused by high-energy neutral particles. The flux of neutral particles reaching the first mirror was calculated using the ZEMAX software with a simplified entrance duct model. In the calculation, the particle flux reaching the first wall is necessary and the previously reported values derived from the SOLPS calculations were used. Based on this estimated particle flux, the erosion resistance tests were performed to check the erosion effect due to the high-energy neutral particles on the first mirror of ITER divertor VUV spectrometer. In the experiment, erosion was induced by exposing the SiC mirror sample to hydrogen and deuterium plasmas (and ions). The target fluence of incident ions in experiment is based on the estimation of the flux of neutral particles in ITER. The surface shape, composition, erosion depth, and surface roughness were measured to check the damage of the mirror surface after erosion test. Based on simulations and erosion resistance tests, it was concluded that the SiC mirror can be used as the first mirror of ITER divertor VUV spectrometer.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The complex circuitry of interactions determining coexistence among plants and mycorrhizal fungi

We present a mechanistic model of coexistence among a mycorrhizal fungus and one or two plant species that compete for a single nutrient. Plant–fungal coexistence is more likely if the fungus is better at extracting the environmental nutrient than the plant and the fungus acquires carbon from the plant above a minimum rate. When they coexist, their interaction can shift from mutualistic to parasitic at high nutrient availability. The fungus is a second nutrient source for plants and can promote the coexistence of two plant competitors if one is better at environmental nutrient extraction and the other is better at acquiring the nutrient from the fungus. Because it extracts carbon from both plants, the fungus also serves as a conduit of apparent competition between the plants. Consequently, the plant with the lower environmental nutrient extraction rate can drive the plant with the higher environmental nutrient extraction rate extinct at high carbon supply rates. Furthermore, this model illustrates mechanisms to explain several observed patterns, including shifts in plant–mycorrhizal growth responses and coexistence along nutrient gradients, equivocal results among experiments testing the effect of mycorrhizal fungi on plant diversity, and differences in plant diversity among ecosystems dominated by different mycorrhizal groups.

54 ENVIRONMENTAL SCIENCES↗

Dissecting Anvil Cloud Response to Sea Surface Warming

Abstract We derive an anvil cloud diagnostic from the continuity equation of cloud ice and apply it to the output of convection‐permitting Energy Exascale Earth System Model (E3SM) simulations run in radiative‐convective equilibrium mode. This diagnostic shows that anvil cloud fraction can be reliably diagnosed as a product of cloud detrainment and lifetime. Detrainment is found to be approximated well by a product of clear sky convergence and cloud ice mixing ratio, while cloud lifetime is dominated by sedimentation. Taken together, this diagnostic expresses anvil cloud fraction as a function of five physically measurable quantities. Of these, clear‐sky convergence changes drive the anvil cloud reduction with warming while an increase in cloud ice mixing ratio buffers the decrease. Accordingly, this study provides a theoretical foundation upon which the Stability‐Iris hypothesis can be tested.

54 ENVIRONMENTAL SCIENCES↗

Impact Noise Monitoring for Gelled Water Mitigation Test Series - North Pad

This report represents the 1st shot (in a series of 8) conducted on September 15, 2022. One 10 lb C4 charge (along with ~200g of Potassium Bromide (KBr)) was detonated inside 9920 North Pad Boom Box. Noise sampling was performed at several points on Site 9920 to characterize the noise mitigation provided by the block structure. This data will help inform safe locations for Members of the Workforce (MOWs) to be located during future testing with similar net explosive weights. During the test, all MOW/site visitors were bunkered inside Building 9926/Mobile Firing Control Point (MFCP) to prevent personnel exposure to any hazards associated with the testing

42 ENGINEERING↗

Reviews and syntheses: Ironing out wrinkles in the soil phosphorus cycling paradigm

Soil phosphorus (P) management remains a critical challenge for agriculture worldwide, and yet we are still unable to predict soil P dynamics as confidently as that of carbon (C) or nitrogen (N). This is due to both the complexity of inorganic P (P i ) and organic P (P o ) cycling and the methodological constraints that have limited our ability to trace P dynamics in the soil–plant system. In this review, we describe the challenges for building parsimonious, accurate, and useful biogeochemical models that represent P dynamics and explore the potential of new techniques to usher P biogeochemistry research and modeling forward. We conclude that research efforts should focus on the following: (1) updating the McGill and Cole (1981) model of P o mineralization by clarifying the role and prevalence of biochemical and biological P o mineralization, which we suggest are not mutually exclusive and may co-occur along a continuum of P o substrate stoichiometry; (2) further understanding the dynamics of phytate, a six C compound that can regulate the poorly understood stoichiometry of soil P; (3) exploring the effects of C and P o saturation on P sorption and P o mineralization; and (4) resolving discrepancies between hypotheses about P cycling and the methods used to test these hypotheses.

54 ENVIRONMENTAL SCIENCES↗

A compact dication source for Ba 2+ tagging and heavy metal ion sensor development

Here, we present a tunable metal ion beam that delivers controllable ion currents in the picoamp range for testing of dry-phase ion sensors. Ion beams are formed by sequential atomic evaporation and single or multiple electron impact ionization, followed by acceleration into a sensing region. Controllability of the ionic charge state is achieved through tuning of electrode potentials that influence the retention time in the ionization region. Barium, lead, and cadmium samples have been used to test the system, with ion currents identified and quantified using a quadrupole mass analyzer. Realization of a clean Ba 2+ ion beam within a bench-top system represents an important technical advance toward the development and characterization of barium tagging systems for neutrinoless double beta decay searches in xenon gas. This system also provides a testbed for investigation of novel ion sensing methodologies for environmental assay applications, with dication beams of Pb 2+ and Cd 2+ also demonstrated for this purpose.

47 OTHER INSTRUMENTATION↗

Vegetation Warming Experiment: Landscape-scale digital camera imagery for vegetation phenology, Utqiagvik (Barrow), Alaska, 2020

Images captured using a StarDot NetCam SC phenocamera looking east from the top of the Barrow Environmental Observatory (BEO) Sled Shed, Utqiagvik, Alaska. The camera was installed to remotely monitor plant phenology and operation of the Brookhaven National Laboratory (BNL) TEST group's ZPW (Zero Power Warming) chambers during the growing season of 2020. Images were captured from early spring (14 April) through to late fall (10 November). Snowmelt, vegetation growth and senescence, and snow accumulation were captured. Images (*.jpg) have been combined into *.zip format (1.9 GB) and the data package includes a metadata document with example fields of view from the camera (*.pdf).The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

The effect of copper additives on hybrid Zr-based chemical conversion coating morphology and chemical compositions

In the realm of corrosion protection, Zr-based conversion coatings offer an environmentally friendly, chromate-free alternative to conventional coating. This study uses advanced X-ray, electron microscopy and electrochemical testing techniques to better understand the impact of varying Cu²⁺ ion concentrations on the characteristics of Zr-based coatings on Fe substrates. Our findings demonstrate that within the tested conditions, higher Cu²⁺ additive concentrations at 40 ppm enhance surface characteristics, increasing stability towards anti-corrosion capability, particularly under NaCl treatment. Conversely, at a lower Cu²⁺ concentration of 20 ppm, coatings exhibited more significant dissolution of Cu clusters and increased vulnerability to chloride-induced degradation. X-ray photoelectron spectroscopy and synchrotron X-ray fluorescence (XRF) and X-ray absorption near edge structure (XANES) spectroscopy analyses revealed Cu²⁺ formation in Cu20, while Cu40 retained its metallic state (Cu⁰) with a slower reaction rate. Cu20 offers some protection but lacks durability, whereas in Cu40, lower I corr , and enhance corrosion resistance, making it ideal for protective coatings in salt-water environments. This study underscores the importance of balancing Cu²⁺ ions concentration in the coating solution to optimize performance, highlighting the role of Cu in enhancing both surface properties and long-term stability.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗