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Results for “effective diffusivity”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 541 records · Page 30
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Spot Radiative Ignition and Subsequent Three Dimensional Flame Spread Over Thin Cellulose Fuels

Spontaneous radiative ignition and transition to flame spread over thin cellulose fuel samples was studied aboard the USMP-3 STS-75 Space Shuttle mission, and in three test series in the 10 second Japan Microgravity Center (JAMIC). A focused beam from a tungsten/halogen lamp was used to ignite the center of the fuel sample while an external air flow was varied from 0 to 10 cm/s. Non-piloted radiative ignition of the paper was found to occur more easily in microgravity than in normal gravity. Ignition of the sample was achieved under all conditions studied (shuttle cabin air, 21%-50% O2 in JAMIC), with transition to flame spread occurring for all but the lowest oxygen and flow conditions. While radiative ignition in a quiescent atmosphere was achieved, the flame quickly extinguished in air. The ignition delay time was proportional to the gas-phase mixing time, which is estimated using the inverse flow rate. The ignition delay was a much stronger function of flow at lower oxygen concentrations. After ignition, the flame initially spread only upstream, in a fan-shaped pattern. The fan angle increased with increasing external flow and oxygen concentration from zero angle (tunneling flame spread) at the limiting 0.5 cm/s external air flow, to 90 degrees (semicircular flame spread) for external flows at and above 5 cm/s, and higher oxygen concentrations. The fan angle was shown to be directly related to the limiting air flow velocity. Despite the convective heating from the upstream flame, the downstream flame was inhibited due to the 'oxygen shadow' of the upstream flame for the air flow conditions studied. Downstream flame spread rates in air, measured after upstream flame spread was complete and extinguished, were slower than upstream flame spread rates at the same flow. The quench regime for the transition to flame spread was skewed toward the downstream, due to the augmenting role of diffusion for opposed flow flame spread, versus the canceling effect of diffusion at very low cocurrent flows.

Olson, Sandra L.↗
DOE OSTI2018

Water-lubricated intercalation in V2O5·nH2O for high-capacity and high-rate aqueous rechargeable zinc batteries

Co-intercalation is an effective approach to tune the diffusion coefficient with which cations insert into the electrodes for energy storage devices. By applying this concept in aqueous Zn batteries, a prospective system for stationary energy storage, we demonstrate the critical role of structural H2O on Zn2+ intercalation into bilayer V2O5·nH2O. The H2O solvation of Zn2+ largely reduces its effective charge and thus electrostatic interaction with the V2O5 framework, evidently promoting the diffusion of solvated Zn2+. Benefited from the ‘lubricating’ effect, the aqueous Zn battery shows a specific energy of ~ 305 Wh kg-1 (based on cathode), comparable to those of LiCoO2//Graphite batteries. Meanwhile, it can maintain an energy density of 199 Wh kg-1 at a high power density of 24 kW kg-1 with a capacity retention of 88% after 900 cycles, making it a promising candidate for high-performance, low-cost, safe and environmentally friendly energy storage device.

Yan, Mengyu↗
DOE OSTI2021

Effective field theory of stochastic diffusion from gravity

Planar black holes in AdS have long-lived quasinormal modes which capture the physics of charge and momentum diffusion in the dual field theory. How should we characterize the effective dynamics of a probe system coupled to the conserved currents of the dual field theory? Specifically, how would such a probe record the long-lived memory of the black hole and its Hawking fluctuations? We address this question by exhibiting a universal gauge invariant framework which captures the physics of stochastic diffusion in holography: a designer scalar with a gravitational coupling governed by a single parameter, the Markovianity index. We argue that the physics of gauge and gravitational perturbations of a planar Schwarzschild-AdS black hole can be efficiently captured by such designer scalars. We demonstrate that this framework allows one to decouple, at the quadratic order, the long-lived quasinormal and Hawking modes from the short-lived ones. It furthermore provides a template for analyzing fluctuating open quantum field theories with memory. In particular, we use this set-up to analyze the diffusive Hawking photons and gravitons about a planar Schwarzschild-AdS black hole and derive the quadratic effective action that governs fluctuating hydrodynamics of the dual CFT. Along the way we also derive results relevant for probes of hyperscaling violating backgrounds at finite temperature.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1990

The effect of catastrophic collisional fragmentation and diffuse medium accretion on a computational interstellar dust system

The effects of catastrophic collisional fragmentation and diffuse medium accretion on a the interstellar dust system are computed using a Monte Carlo computer model. The Monte Carlo code has as its basis an analytic solution of the bulk chemical evolution of a two-phase interstellar medium, described by Liffman and Clayton (1989). The model is subjected to numerous different interstellar processes as it transfers from one interstellar phase to another. Collisional fragmentation was found to be the dominant physical process that shapes the size spectrum of interstellar dust. It was found that, in the diffuse cloud phase, 90 percent of the refractory material is locked up in the dust grains, primarily due to accretion in the molecular medium. This result is consistent with the observed depletions of silicon. Depletions were found to be affected only slightly by diffuse cloud accretion.

Liffman, Kurt↗
NASA NTRS1949

Effect of screens in wide-angle diffusers

An experimental investigation at low airspeeds was made of the filling effect observed when a screen or similar resistance is placed across a diffuser. The filling effect is found to be real in that screens can prevent separation or restore separated flow in diffusers even of extreme divergence and to depend principally on screen location and pressure-drop coefficient of the screen. Results are given for three different diffusers of circular cross section with a variety of screen arrangements. Effects of single screens and multiple screens are shown. The mechanics of the filling effect is explained, and possible efficiencies are discussed. Results of arrangements of multiple screens in wide-angle diffusers are given to show a possible application to damping screens as used in wind tunnels to reduce turbulence. (author)

Schubauer, G B↗
DOE OSTI2017

The Role of Anisotropy on the Self-Organization of Gas Bubble Superlattice

Self-organization of nanoscale void/gas bubble superlattices has been widely observed in irradiation experiments however yet to be well understood. The recent discovery of incoherent face-centered-cubic (fcc) Xe bubble lattice in body-centered-cubic (bcc) UMo challenges the widely accepted coherency between superlattices and matrices. A complete mechanistic understanding of bubble lattice self-organization may have a large impact to materials science and nuclear energy advancement, and is the objective of this project. The knowledge obtained through a coherent integration of experimental and computational approach will advance the current understanding of self-organization mechanisms of nanostructures under irradiation. To realize this goal, two appealing self-organization mechanisms previously proposed in open literatures have been identified: anisotropic elastic interaction between voids and kinetic anisotropy such as one-dimensional (1D) self-interstitial atoms (SIA) diffusion. For the first year, the focus is on the effect 1D diffusion using bcc Mo and W, with the former being elastically anisotropic while the latter isotropic. Efforts have been made to investigate the fundamental interaction between inert gas and metal matrices, the mechanism for void/bubble superlattice formation and their stabilities under irradiation and annealing, and the experimental conditions for bubble superlattice formation and evolution, and to establish advanced characterization techniques for bubble superlattice.

36 MATERIALS SCIENCE↗
NASA NTRS2001

Get the Red Out: Removing Diffuse Sky Illumination from Mars Pathfinder Images

Radiative transfer calculations are performed to remove the effect of diffuse illumination on the color of the martian surface. We describe the methods and apply them to a radiometric calibration target, and to a superpan cube of the rock Yogi. Additional information is contained in the original extended abstract.

Stoker, Carol↗
NASA NTRS1999

Effects of Buoyancy in Hydrogen Jet Diffusion Flames

This project was carried out to understand the effects of heat release and buoyancy on the flame structure of diffusion flames. Experiments were conducted at atmospheric pressure in both normal gravity and microgravity conditions in the NASA LeRC 2.2 s drop tower. Experiments were also conducted in a variable pressure combustion facility in normal gravity to scale buoyancy and thus, to supplement the drop tower experiments. Pure H2 or H2 mixed with He was used as the jet fluid to avoid the complexities associated with soot formation. Fuel jet burning in quiescent air was visualized and quantified by the Rainbow Schlieren Deflectometry (RSD) to obtain scalar profiles (temperature, oxygen concentration) within the flame. Burner tube diameter (d) was varied from 0.3 to 1.19 mm producing jet exit Reynolds numbers ranging from 40 to 1900, and generating flames encompassing laminar and transitional (laminar to turbulent) flow structure. Some experiments were also complemented with the CFD analysis. In a previous paper, we have presented details of the RSD technique, comparison of computed and measured scalar distributions, and effects of buoyancy on laminar and transitional H2 gas-jet diffusion flames. Results obtained from the RSD technique, variable pressure combustion chamber, and theoretical models have been published. Subsequently, we have developed a new drop rig with improved optical and image acquisition. In this set up, the schlieren images are acquired in real time and stored digitally in RAM of an onboard computer. This paper deals with laminar diffusion flames of pure H2 in normal and microgravity.

Agrawal, A. K.↗
DOE OSTI2021

Bulk and surface diffusion of neodymium in alpha-uranium: Ab initio calculations and kinetic Monte Carlo simulations

A fundamental understanding of lanthanide transport in metallic fuels is critical for high fidelity modeling of the fuel-cladding chemical interaction (FCCI) phenomenon, which can lead to the formation of brittle intermetallic compounds and premature failure of the cladding. Here we report a combined ab initio density functional theory (DFT) and kinetic Monte Carlo (KMC) study of the bulk diffusivity of Nd in α-U, fully taking into account the effect of radiation enhanced diffusion. In this work, the vacancy mechanism is considered to be the dominant mechanism for the bulk diffusion of Nd since a Nd interstitial is found to be intrinsically unstable in α-U. The surface diffusivity of a Nd adatom on α-U (001) surface has been further predicted using KMC simulations parameterized by DFT calculations. The present study suggests that Nd transport via the surface diffusion mechanism can be many orders of magnitude faster than bulk diffusion. Furthermore, the results from the present lower length scale study can be used to inform mesoscale phase-field simulations to determine the effective diffusion coefficient of Nd through α-U with a porous microstructure.

36 MATERIALS SCIENCE↗
NASA NTRS1981

Effects of free-stream turbulence on diffuser performance

An experimental evaluation of the effects of free-stream turbulence on the performance of a subsonic two-dimensional diffuser has been made. Increases of the diffuser's static pressure recovery coefficient of 11.3 and 23.9 percent at total included divergence angles of 12 and 20 degrees respectively were obtained when the value of the inlet integral free-stream scale of turbulence in the flow direction was at least 7.2 times larger than the inlet boundary layer displacement thickness, when the inlet total free-stream turbulence intensity was at least 3.5 percent, and when the axes of upstream rods used to generate turbulence were perpendicular to the flow and parallel to the diverging walls of the diffuser. It is hypothesized that a larger scale of turbulence with the specified eddy axis orientation transmits the free-stream energy to the walls more effectively and, when coupled with large turbulence intensities, are mechanisms which act to decrease the distortion and delay separation within the diffuser.

Hoffmann, J. A.↗
NASA NTRS1973

Effect of bottom topography, eddy diffusivity, and wind variation on circulation in a two-layer stratified lake

The steady-state, wind-driven circulation is calculated in a stratified lake composed of two layers having uniform but unequal densities and eddy diffusivities. The position of the thermocline and the velocities in both layers are calculated from an asymptotic solution of the shallow lake equations when the Ekman number in the epilimnion (upper layer) is of order one but the ratio of hypolimnion (lower layer) to epilimnion eddy diffusivities is much less than one. Large differences in the thermocline shape and the velocities occur between the solution for uniform wind stress and the one for unit order wind stress gradients. For the latter solution the hypolimnion eddy diffusivity magnitude and the bottom topography have a large and important effect.

Gedney, R. T.↗
NASA NTRS1980

Effects of free-stream turbulence on diffuser performance

An experimental evaluation of the effects of free stream turbulence on the performance of a subsonic two dimensional diffuser was made. The diffuser's static pressure recovery coefficient was increased 11.4 and 21.1 percent at total. Divergence angles of 12 and 20 degrees respectively were obtained when the value of the inlet integral free stream scale of turbulence in the flow direction was at least 7.5 times larger than the inlet boundary layer displacement thickness, and when the inlet total free stream turbulence intensity was at least 3.5 percent. It is hypothesized that a larger scale of turbulence transmits the free stream energy to the wall more effectively and when coupled with large turbulence intensities, acts to decrease the distortion and delay separation within the diffuser.

Hoffmann, J. A.↗
DOE OSTI2019

Diffuse ionized gas and its effects on nebular metallicity estimates of star-forming galaxies

ABSTRACT We investigate the impact of the diffuse ionized gas (DIG) on abundance determinations in star-forming (SF) galaxies. The DIG is characterized using the H α equivalent width (WH α). From a set of 1 409 SF galaxies from the Mapping Nearby Galaxies at APO (MaNGA) survey, we calculate the fractional contribution of the DIG to several emission lines using high-S/N data from SF spaxels (instead of using noisy emission-lines in DIG-dominated spaxels). Our method is applicable to spectra with observed WH α ≳ 10 Å (which are not dominated by DIG emission). Since the DIG contribution depends on galactocentric distance, we provide DIG-correction formulae for both entire galaxies and single aperture spectra. Applying those to a sample of $\, \gt 90\, 000$ SF galaxies from the Sloan Digital Sky Survey, we find the following. (1) The effect of the DIG on strong-line abundances depends on the index used. It is negligible for the ([O iii]/H β)/([N ii]/H α) index, but reaches ∼0.1 dex at the high-metallicity end for [N ii]/H α. (2) This result is based on the ∼kpc MaNGA resolution, so the real effect of the DIG is likely greater. (3) We revisit the mass–metallicity–star formation rate (SFR) relation by correcting for the DIG contribution in both abundances and SFR. The effect of DIG removal is more prominent at higher stellar masses. Using the [N ii]/Hα index, O/H increases with SFR at high stellar mass, contrary to previous claims.

Vale Asari, N.↗
NASA NTRS1950

Effect of Ram-jet Pressure Pulsations on Supersonic-diffuser Performance

Experimental study of effects of combustion roughness and controlled mechanical oscillations on diffuser operation was conducted on an 8-inch ram jet at Mach number 1.87. Within experimental accuracy, the optimum mean combustion-chamber static pressure occurred when the maximum instantaneous static pressure equalled the optimum steady-flow value and the corresponding decrement in optimum mean static pressure was equal to one-half the total amplitude of the pressure pulsations. A marked attenuation of amplitude of cold-buzz pressure fluctuations was effected over limited range of subcritical diffuser operation by means of properly tuned rotating disk located in combustion chamber.

Connors, James F↗
DOE OSTI2025

Remarks on the thesis of Aitor Bengoechea Fernández: Generalization of Doppler effect processing using S(α,β) thermal diffusion laws

The thesis titled “Generalization of Doppler effect processing using S(α,β) thermal diffusion laws” addresses a critical gap in the modeling of neutron scattering phenomena in nuclear materials, particularly where crystal lattice effects intersect with low-energy resonances. Conducted within the Doctoral School ED 352 at Aix-Marseille Université and hosted at CEA Cadarache, the research presents a theoretical and numerical framework for extending the applicability of Thermal Scattering Laws (TSLs) using higher-order correlation functions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2026

Development of physics-consistent conditional diffusion model to overcome data scarcity in critical heat flux

Deep generative modeling provides a powerful pathway to overcome data scarcity in energy-related applications where experimental data are often limited. By learning the underlying probability distribution of the training dataset, deep generative models, such as the diffusion model, can generate high-fidelity synthetic samples that statistically resemble the training data. Such synthetic data generation can significantly enrich the size and diversity of the available training data, and more importantly, improve the robustness of downstream machine learning models in predictive tasks. The objective of this paper is to investigate the effectiveness of diffusion models for overcoming data scarcity in nuclear energy applications. By leveraging a public dataset on critical heat flux which covers a wide range of commercial nuclear reactor operational conditions, we developed a diffusion model that can generate an arbitrary amount of synthetic samples. Since a vanilla diffusion model can only generate samples randomly, we also developed a conditional diffusion model capable of generating targeted critical heat flux data under user-specified thermal-hydraulic conditions. The performance of the diffusion model was evaluated based on its ability to capture empirical feature distributions and pair-wise correlations, as well as to maintain physical consistency. The results showed that both the diffusion model and conditional diffusion model can successfully generate realistic and physics-consistent critical heat flux data. Furthermore, uncertainty quantification results demonstrate that the conditional diffusion model is highly effective in augmenting critical heat flux data while maintaining acceptable levels of uncertainty.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2021

Improving Gas Selectivity in Membranes Using Polymer-Grafted Silica Nanoparticles

Herein, we demonstrate that tuning of structural parameters and material chemistry enables control of the permeability and selectivity of gases (CO 2 , He, and CH 4 ) in membranes based on poly(butyl methacrylate)-grafted nanoparticles (PGNs). Our data show that the presence of nanoparticles and the overall dense packing of grafted chains noticeable in PGNs with low grafting density have an adverse effect on the diffusivity of gases. This effect is compensated by an improvement in the solubility of CO 2 gas promoted by the silica nanoparticle surface, yielding a substantial improvement in the permeability of CO 2 versus CH 4 . Furthermore, in membranes with high grafting density, changes in the structural arrangements and alterations in the membrane porosity, evident from small-angle X-ray scattering and positron annihilation lifetime spectroscopy, positively influence the permeability of He and CO 2 gases. In contrast, CH 4 permeability in the same membranes is significantly suppressed, suggesting the formation of a unique, highly selective environment for gas separation. As a result, an improvement of up to 50% in selectivity for gas pairs containing large CH 4 molecules is observed. Our studies provide fundamental insights into the role that structural parameters play in gas transport through polymer membranes, laying a foundation for the rational design of membranes with improved permeability and selectivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗