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At least 541 records · Page 30
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Stratospheric Aerosol and Gas Experiment II measurements of the quasi-biennial oscillations in ozone and nitrogen dioxide

The first measurements ever to show a quasi-biennial oscillation (QBO) in NO2 have been made by the Stratospheric Aerosol and Gas Experiment II) (SAGE II) and are presented in this work along with observations of the well-known QBO in stratospheric ozone. The SAGE II instrument was launched aboard the Earth Radiation Budget satellite near the end of 1984. Measurements of ozone and nitrogen dioxide through early 1990 are analyzed for the presence of a quasi-biennial oscillation. The measurements show the global extent of both the O3 and NO2 QBO in the 25- to 40-km region of the stratosphere. The SAGE II QBO results for ozone compare favorably to theory and previous measurements. The QBO in NO2 is found to be consistent with the vertical and horizontal transport of NOy. Both species exhibit a QBO at extratropical latitudes consistent with strong meridional transport into the winter hemisphere.

Zawodny, Joseph M.↗
NASA NTRS1991

The mid-Cretaceous super plume, carbon dioxide, and global warming

Carbon-dioxide releases associated with a mid-Cretaceous super plume and the emplacement of the Ontong-Java Plateau have been suggested as a principal cause of the mid-Cretaceous global warming. A carbonate-silicate cycle model is developed to quantify the possible climatic effects of these CO2 releases, utilizing four different formulations for the rate of silicate-rock weathering as a function of atmospheric CO2. CO2 emissions resulting from super-plume tectonics could have produced atmospheric CO2 levels from 3.7 to 14.7 times the modern preindustrial value of 285 ppm. Based on the temperature sensitivity to CO2 increases used in the weathering-rate formulations, this would cause a global warming of from 2.8 to 7.7 C over today's glogal mean temperature. Altered continental positions and higher sea level may have been contributed about 4.8 C to mid-Cretaceous warming. Thus, the combined effects of paleogeographic changes and super-plume related CO2 emissions could be in the range of 7.6 to 12.5 C, within the 6 to 14 C range previously estimated for mid-Cretaceous warming. CO2 releases from oceanic plateaus alone are unlikely to have been directly responsible for more than 20 percent of the mid-Cretaceous increase in atmospheric CO2.

Caldeira, Ken↗
NASA NTRS1990

Silicon dioxide space coatings studied ellipsometrically

Mechanisms of initial oxidation of silicon for the formation of silicon dioxide have been investigated. The oxidation of silicon in an atomic oxigen plasma environment is found to exhibit two distinct and linear oxide growth curves for each of the plasma powers used in ashing (25, 50, and 100 watts). Data obtained indicate that the exponent to the pressure in the oxide growth rate formula changes from 1.4 + or - 0.1 to 0.7 + or - 0.1 as one crosses the critical thickness. These data contradict the theory predicting that this exponent should be 1 for both regimes. The activation energy for oxidation in the zone reaction regime is found to be 0.17 eV, in contrast to the published value of 1-2 eV for thermally grown oxides.

De, Bhola N.↗
NASA NTRS1992

Relating SMMR 37 GHz polarization difference to precipitation and atmospheric carbon dioxide concentration - A reappraisal

The relations of Scanning Multi-channel Microwave Radiometer (SMMR) 37 GHz polarization difference to precipitation and atmospheric carbon dioxide (CO2) concentrations are reviewed. Annual precipitation data, a surrogate for green leaf vegetation density, are compared with the coincident SMMR 37 GHz polarization difference from arid and semi-arid West Africa for 1982-85. The SMMR 37 GHz polarization difference was found to be poorly correlated with precipitation in arid and semi-arid zones, contrary to previous reports. Coincident SMMR 37 GHz polarization difference and atmospheric CO2 concentration data from July 1981 to June 1983 are also reviewed. Previously suggested relations of the SMMR 37 GHz polarization difference to atmospheric CO2 concentrations were found to be heavily biased by winter conditions in the Northern Hemisphere. The use of the SMMR 37 GHz polarization difference for determining green leaf vegetation density, net primary production, atmospheric CO2 draw-down and related processes is questioned.

Tucker, C. J.↗
NASA NTRS1992

Model for oxygen recombination on silicon-dioxide surfaces. II - Implications toward reentry heating

This paper briefly reviews the model for recombination of oxygen on a silicon-dioxide surface presented in detail in a previous paper. New data supporting the model is also presented. The ramifications of the model toward the production of excited molecular oxygen is examined as it pertains to surface heating. A reentry simulation is given and compared to STS-2 reentry data, and conclusions are drawn as to the implications of the recombination model toward reentry heating. A possible buffering of the heating above a critical temperature associated with the physics of the model is also discussed.

Jumper, E. J.↗
NASA NTRS1991

Developing real-time control software for Space Station Freedom carbon dioxide removal

This paper presents AiResearch experience to date in using the NASA/Boeing Application Generator (AG) to develop real-time control systems for the Carbon Dioxide Removal Assembly (CDRA) in Work Package 01. The AG provides an integrated design and development tool encompassing: system analysis, modeling, control law design, simulation, code generation, real-time hardware-in-the-loop simulation and operation, and documentation. This allows rapid interactive prototyping of real-time control systems in a single, integrated, environment. Advantages and disadvantages of using the AG for real-time control system development will be addressed, with the CDRA specification to delivery cycle serving as a basis for discussion. Suggestions for improving the AG are offered and observations on its potential as a top-level system specification tool are made.

Rowe, Steven A.↗
NASA NTRS1991

A sensitive method for measuring atmospheric concentrations of sulfur dioxide

A new method for measuring tropospheric sulfur dioxide concentrations is proposed which is based on the mist chamber sampling method. At the present stage of development, the detection limit of the method is approximately 20 parts per trillion for a 45-min sampling time, with lower concentrations detectable with lower precision. The overall reproducibility of the method (+/-95 percent confidence intervals) is estimated at +/-10 percent. The technique is relatively simple, inexpensive, and lightweight, making it ideally suited for numerous field applications in atmospheric chemistry and biogeochemical studies from both ground-based and airborne platforms.

Klemm, O.↗
NASA NTRS1992

Analysis of thermo-chemical nonequilibrium models for carbon dioxide flows

The aerothermodynamics of thermochemical nonequilibrium carbon dioxide flows is studied. The chemical kinetics models of McKenzie and Park are implemented in separate three-dimensional computational fluid dynamics codes. The codes incorporate a five-species gas model characterized by a translational-rotational and a vibrational temperature. Solutions are obtained for flow over finite length elliptical and circular cylinders. The computed flowfields are then employed to calculate Mach-Zehnder interferograms for comparison with experimental data. The accuracy of the chemical kinetics models is determined through this comparison. Also, the methodology of the three-dimensional thermochemical nonequilibrium code is verified by the reproduction of the experiments.

Rock, Stacey G.↗
NASA NTRS1992

Sublimation rates of carbon monoxide and carbon dioxide from comets at large heliocentric distances

Using a simple model for outgassing from a small flat surface area, the sublimation rates of carbon monoxide and carbon dioxide, two species more volatile than water ice that are known to be present in comets, are calculated for a suddenly activated discrete source on the rotating nucleus. The instantaneous sublimation rate depends upon the comet's heliocentric distance and the Sun's zenith angle at the location of the source. The values are derived for the constants of CO and CO2 in an expression that yields the local rotation-averaged sublimation rate as a function of the comet's spin parameters and the source's cometocentric latitude.

Sekanina, Zdenek↗
NASA NTRS1992

Spatial and temporal variations of the fluxes of carbon dioxide and sensible and latent heat over the FIFE site

Airborne measurements of flux densities of carbon dioxide CO2, sensible heat, and latent heat (H2O) obtained over the First ISLSCP Field Experiment (FIFE) site during three intensive field campaigns in 1987 and one in 1989 are examined to characterize the spatial and temporal variations of CO2 and energy transfer processes. These data were collected by the National Research Council Twin Otter using low-level flight patterns, all flown at constant pressure altitude during relatively clear days. The spatial variations are larger in 1989 than in 1987 and a higher correlation is observed between the fluxes and the surface features. The temporal patterns are easier to characterize with the relatively homogeneous situation of 1987. Functional relationships obtained between fluxes of CO2 and latent heat, CO2 fluxes and greenness index, latent heat fluxes and greenness index, and between sensible heat fluxes and surface air temperature differences are presented for one day in 1987 and one in 1989 as an example of the kind of information that can be obtained from grid flights at constant pressure altitude.

Desjardins, R. L.↗
NASA NTRS1992

Aircraft- and tower-based fluxes of carbon dioxide, latent, and sensible heat

Fluxes of carbon dioxide, water vapor, and sensible heat obtained over a grassland ecosystem, during the First International Satellite Land Surface Climatology Project (ISLSCP) Field Experiment (FIFE), using an aircraft- and two tower-based systems are compared for several days in 1987 and in 1989. The tower-based cospectral estimates of CO2, sensible heat, water vapor, and momentum, expressed as a function of wavenumber K times sampling height z, are relatively similar to the aircraft-based estimates for K x z greater than 0.1. A measurable contribution to the fluxes is observed by tower-based systems at K x z less than 0.01 but not by the aircraft-based system operating at an altitude of approximately 100 m over a 15 x 15 km area. Using all available simultaneous aircraft and tower data, flux estimates by both systems were shown to be highly correlated. As expected from the spatial variations of the greenness index, surface extrapolation of airborne flux estimates tended to lie between those of the two tower sites. The average fluxes obtained, on July 11, 1987, and August 4, 1989, by flying a grid pattern over the FIFE site agreed with the two tower data sets for CO2, but sensible and latent heat were smaller than those obtained by the tower-based systems. However, in general, except for a small underestimation due to the long wavelength contributions and due to flux divergence with height, the differences between the aircraft- and tower-based surface estimates of fluxes appear to be mainly attributable to differences in footprint, that is, differences in the area contributing to the surface flux estimates.

Desjardins, R. L.↗
NASA NTRS1992

Intercomparison of eddy correlation carbon dioxide sensors during FIFE 1989

An intercomparison was made of the infrared gas analyzers used in the First ISLSCP Field Experiment (FIFE) 1989 to measure surface fluxes of carbon dioxide immediately following intensive field campaign 5. Fluxes of CO2 agreed to within 15 percent when all instruments are compared; when models of the same type of analyzer were compared, the agreement was within 5 percent. The stability of the calibration coefficients is examined, and it is shown that frequent calibration of the gas analyzers is required. Differences in the physical design of the analyzer models discussed here, such as sampling volume and sensitivity of the electronics to thermal drift, influence the precision of the flux estimates. Spectra and cospectra reveal the degree to which instrumental noise limits the complete sampling of all frequencies of eddies contributing to flux transport.

Moncrieff, J. B.↗
NASA NTRS1992

Temperature dependence and mechanism of the reaction between O(3P) and chlorine dioxide

Second-order rate constants for the decay of O(3P) in excess chlorine dioxide, k(II), were measured as a function of total pressure (20-600 Torr argon) and temperature (248-312 K), using flash photolysis-atomic resonance fluorescence. Results indicate that k(II) is pressure dependent with a value, K(b), that is nonzero at zero pressure, and both the third-order rate constant and k(b) have negative temperature dependences.

Colussi, A. J.↗
NASA NTRS1992

Evaluation of the carbon dioxide removal assembly requirements for the Space Station Freedom in the Manned Tended Capability through Permanently Manned Capability configurations

Analyses have been conducted to assess the capability of the Atmosphere Revitalization Subsystem to control ambient CO2 levels of the Space Station Freedom (SSF). The adequacy of the Carbon Dioxide Removal Assembly (CDRA) performance to meet design requirements has been evaluated. Analyses considered transient effects of crew location and metabolic loading on SSF Restructure configurations. The analyses consisted of computer simulations of on-orbit conditions using both supplier-provided and adjusted CO2 removal performance approximations along with derived crew metabolic activities and locations. Results show that while the current performance of the CDRA will maintain CO2 levels within specifications for Man-Tended Operations, it cannot maintain the SSF atmosphere below specifications during Permanently Manned Operations. Potential design options are discussed and other relevant analyses are summarized.

Knox, J. C.↗
NASA NTRS1992

Operation of a breadboard liquid-sorbent/membrane-contactor system for removing carbon dioxide and water vapor from air

Processes to remove and recover carbon dioxide (CO2) and water vapor from air are essential for successful long-duration space missions. This paper presents results of a developmental program focused on the use of a liquid-sorbent/membrane-contactor (LSMC) system for removal of CO2 and water vapor from air. In this system, air from the spacecraft cabin atmosphere is circulated through one side of a hollow-fiber membrane contactor. On the other side of the membrane contactor is flowed a liquid sorbent, which absorbs the CO2 and water vapor from the feed air. The liquid sorbent is then heated to desorb the CO2 and water vapor. The CO2 is subsequently removed from the system as a concentrated gas stream, whereas the water vapor is condensed, producing a water stream. A breadboard system based on this technology was designed and constructed. Tests showed that the LSMC breadboard system can produce a CO2 stream and a liquid-water stream. Details are presented on the operation of the system, as well as the effects on performance of variations in feed conditions.

Mccray, Scott B.↗
NASA NTRS1993

The abundance of sulfur dioxide below the clouds of Venus

We present a new method for determining the abundance of sulfur dioxide below the clouds of Venus. Absorption by the 3nu3 band of SO2 near 2.45 microns has been detected in high-resolution spectra of the night side of Venus recorded at the Canada-France Hawaii telescope in 1989 and 1991. The inferred SO2 abundance is 130 +/- 40 ppm at all observed locations and pertains to the 35-45 km region. These values are comparable to those measured by the Pioneer Venus and Venera 11/12 entry probes in 1978. This stability stands in contrast to the apparent massive decrease in SO2 observed at the cloud tops since these space missions. These results are consistent with laboratory and modeling studies of the SO2 destruction rates in the lower atmosphere of Venus. The new spectroscopic technique presented here allows a remote monitoring of the SO2 abundance below the clouds, a likely tracer of Venusian volcanism.

Bezard, Bruno↗
NASA NTRS1993

Allowable exposure limits for carbon dioxide during extravehicular activity

The intent was to review the research pertaining to human exposure to carbon dioxide (CO2) and to recommend allowable exposure limits for extravehicular activity (EVA). Respiratory, renal, and gastrointestinal systems may be adversely affected by chronic low dose CO2 exposure. Ventilation was increased 15 percent with 1 percent CO2 and 50 percent with 2 percent CO2. Chronic exposure to less than 2 percent CO2 led to 20 day cycles of uncompensated and compensated respiratory acidosis. Acid-base changes were small. Histopathologic changes in guinea pig lungs have been noted with long term exposure to 1 percent CO2. No changes were seen with exposure to 0.5 percent CO2. Cycling of bone calcium stores with associated changes in blood and urinary calcium levels occurs with long term CO2 exposure. Histologic changes in bone have been noted in guinea pigs exposed to 1 percent CO2. Renal calcification has been noted in guinea pigs with exposure to as low as 0.5 percent CO2. An increase in gastric acidity was noted in subjects with long term exposure to 1 percent CO2. Cardiovascular and neurologic function were largely unaffected. A decrease in the incidence of respiratory, renal, and gastrointestinal disease was noted in submariners coincident with a decrease in ambient CO2 from 1.2 percent to 0.8-0.9 percent. Oxygen (O2) and CO2 stimulate respiration independently and cumulatively. The addition of CO2 to high dose O2 led to the faster onset of seizure activity in mice. Experiments evaluating the physiologic responses to intermittent, repetitive exposures to low dose CO2 and 100 percent O2 mixtures should be performed. A reduction in the current NASA standard for CO2 exposure during EVA of 1 percent (7.6 mmHg) for nominal and 2 percent (15.2 mmHg) for heavy exertion to 0.5 percent (3.8 mmHg) for nominal and 1 percent (7.6 mmHg) for heavy exertion may be prudent. At a minimum, the current NASA standard should not be liberalized.

Seter, Andrew J.↗
NASA NTRS1993

Extraction and isotopic analysis of medium molecular weight hydrocarbons from Murchison using supercritical carbon dioxide

The large variety of organic compounds present in carbonaceous chondrites poses particular problems in their analysis not the least of which is terrestrial contamination. Conventional analytical approaches employ simple chromatographic techniques to fractionate the extractable compounds into broad classes of similar chemical structure. However, the use of organic solvents and their subsequent removal by evaporation results in the depletion or loss of semi-volatile compounds as well as requiring considerable preparative work to assure solvent purity. Supercritical fluids have been shown to provide a powerful alternative to conventional liquid organic solvents used for analytical extractions. A sample of Murchison from the Field Museum was analyzed. Two interior fragments were used; the first (2.85 g) was crushed in an agate pestel and mortar to a grain size of ca. 50-100 micron, the second (1.80 g) was broken into chips 3-8 mm in size. Each sample was loaded into a stainless steel bomb and placed in the extraction chamber of an Isco supercritical fluid extractor maintained at 35 C. High purity (99.9995 percent) carbon dioxide was used and was pressurized using an Isco syringe pump. The samples were extracted dynamically by flowing CO2 under pressure through the bomb and venting via a 50 micron fused filica capillary into 5 mls of hexane used as a collection solvent. The hexane was maintained at a temperature of 0.5 C. A series of extractions were done on each sample using CO2 of increasing density. The principal components extracted in each fraction are summarized.

Gilmour, Iain↗