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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1989

Ultraviolet spectrometer observations of Neptune and Triton

Results from the occultation of the sun by Neptune imply a temperature of 750 + or - 150 kelvins in the upper levels of the atmosphere (composed mostly of atomic and molecular hydrogen) and define the distributions of methane, acetylene, and ethane at lower levels. The ultraviolet spectrum of the sunlit atmosphere of Neptune resembles the spectra of the Jupiter, Saturn, and Uranus atmospheres in that it is dominated by the emissions of H Lyman alpha (340 + or - 20 rayleighs) and molecular hydrogen. The extreme ultraviolet emission in the range from 800 to 1100 angstroms at the four planets visited by Voyager scale approximately as the inverse square of their heliocentric distances. Weak auroral emissions have been tentatively identified on the night side of Neptune. Airglow and occultation observations of Triton's atmosphere show that it is composed mainly of molecular nitrogen, with a trace of methane near the surface. The temperature of Triton's upper atmosphere is 95 + or - 5 kelvins, and the surface pressure is roughly 14 microbars.

Broadfoot, A. L.↗

NASA NTRS1989

Land-surface temperature measurement from space - Physical principles and inverse modeling

To apply the multiple-wavelength (split-window) method used for satellite measurement of sea-surface temperature from thermal-infrared data to land-surface temperatures, the authors statistically analyze simulations using an atmospheric radiative transfer model. The range of atmospheric conditions and surface temperatures simulated is wide enough to cover variations in clear atmospheric properties and surface temperatures, both of which are larger over land than over sea. Surface elevation is also included in the simulation as the most important topographic effect. Land covers characterized by measured or modeled spectral emissivities include snow, clay, sands, and tree leaf samples. The empirical inverse model can estimate the surface temperature with a standard deviation less than 0.3 K and a maximum error less than 1 K, for viewing angles up to 40 degrees from nadir under cloud-free conditions, given satellite measurements in three infrared channels. A band in the region from 10.2 to 11.0 microns will usually give the most reliable single-band estimate of surface temperature. In addition, a band in either the 3.5-4.0-micron region or in the 11.5-12.6-micron region must be included for accurate atmospheric correction, and a band below the ozone absorption feature at 9.6 microns (e.g., 8.2-8.8 microns) will increase the accuracy of the estimate of surface temperature.

Wan, Zhengming↗

DOE OSTI2025

Targeted Chemical Looping Materials Discovery by an Inverse Design

Chemical looping with oxygen uncoupling (CLOU) materials is actively sought for combustion of carbonaceous materials to achieve complete conversion and capture of carbon dioxide. These materials may play a vital role in reducing atmospheric carbon via negative carbon output. However, there is no one‐size‐fits‐all approach as different operating conditions and feedstocks may require different CLOU materials. As a result, the exploration and discovery of high‐performance CLOU materials can be a slow process. To address this challenge, a high‐throughput inverse machine learning workflow that identifies optimum materials from perovskite oxides for a given set of targets is developed—temperature and Gibbs free energy of oxygen formation. The model is trained on high‐throughput density functional theory calculations of CLOU materials and inverts the materials design process using a genetic algorithm to produce realistic substituted SrFeO 3‐δ compositions as output. Using the inverse model, it is able to identify several interesting new families of CLOU materials: Sr 1‐ x A x Fe 1‐ y B y O 3‐δ (e.g., A = Ca or K; B = Mg, Bi, Mn, Ni, Co, Cu, or Zn). These materials have shown promising properties, and some of them even outperform the benchmark material in terms of oxygen release kinetics under relevant CLOU operating conditions.

36 MATERIALS SCIENCE↗

NASA NTRS2006

Atlantic to Mediterranean Sea Level Difference Driven by Winds near Gibraltar Strait

Observations and numerical simulations show that winds near Gibraltar Strait cause an Atlantic Ocean to Mediterranean Sea sea level difference of 20 cm peak to peak with a 3-cm standard deviation for periods of days to years. Theoretical arguments and numerical experiments establish that this wind-driven sea level difference is caused in part by storm surges due to alongshore winds near the North African coastline on the Atlantic side of Gibraltar. The fraction of the Moroccan coastal current offshore of the 284-m isobath is deflected across Gibraltar Strait, west of Camarinal Sill, resulting in a geostrophic surface pressure gradient that contributes to a sea level difference at the stationary limit. The sea level difference is also caused in part by the along-strait wind setup, with a contribution proportional to the along-strait wind stress and to the length of Gibraltar Strait and adjoining regions and inversely proportional to its depth.

atmospheric pressure fluctuations↗

DOE OSTI2026

Temperature Inversions below 1 km from a V-Band Scanning Radiometer at the North Slope of Alaska

A single-channel (56.7 GHz) scanning radiometer was deployed in August 2022 at the Atmospheric Radiation Measurement (ARM) North Slope of Alaska site near Utqiaġvik. The radiometer is designed to provide temperature profiles between 0 and 1 km every 5 min. Averaging kernels show that this single-channel radiometer, taking observations at 10 discrete elevation angles, yields approximately the same information as a seven-channel V-band radiometer scanning three elevation angles. The instrument is able to reproduce the occurrence of temperature inversions between the surface and 1 km and their strength showing a correlation of 0.85, bias of −0.6 K, and slope of 1.04 with respect to radiosondes. Uncertainty in the inversion base height varies from 50 m near the surface to ∼300 m above 0.4 km when compared with radiosondes. Conversely, the inversion top height is overestimated and has higher uncertainty due to the degrading effects of the averaging kernels on the vertical resolution of the retrievals. Thanks to the high temporal resolution of the retrievals, the diurnal cycle of boundary layer temperature was evaluated showing that the radiometer can capture some aspects of the boundary layer thermal structure. The present analysis provides an overview of the capabilities of this simple observing configuration for selected applications.

Atmospheric profilers↗

NASA NTRS1992

Tropospheric chemical models

The differences in atmospheric composition over the globe and the short- and long-term variations in this composition are the net effect of several atmospheric and biospheric processes: biospheric emissions, atmospheric circulation, atmospheric chemical transformations and finally deposition back to the surface. Accurate and realistic atmospheric chemistry and circulation models are essential to interpret the observed global distributions and trends of atmospheric species in terms of these underlying processes. Comparisons between model predictions and observations test current understanding of these processes and models used in conjunction with inverse methods allow deductions of the rates of these processes from the observations. With the planned inclusion of at least CO and CH4 observations on the Earth Observing System (EOS) satellites, together with the large global data set expected from in situ observations under the International Global Atmospheric Chemistry (IGAC) Project, the further development of global three-dimensional high-resolution atmospheric chemistry and circulation models in order to interpret this new data is a high-priority endeavor.

Prinn, R. G.↗

NASA NTRS2005

Should We Believe Atmospheric Temperatures Measured by Entry Accelerometers Traveling at "Slow" Near-Sonic Speeds?

Mars Pathfinder's Accelerometer instrument measured an unexpected and large temperature inversion between 10 and 20 kilometer altitude. Other instruments have failed to detect similar temperature inversions. I test whether this inversion is real or not by examining what changes have to be made to the assumptions in the accelerometer data processing to obtain a more "expected" temperature profile. Changes in derived temperature of up to 30K, or 15%, are necessary, which correspond to changes in derived density of up to 25% and changes in derived pressure of up to 10%. If the drag coefficient is changed to satisfy this, then instead of decreasing from 1.6 to 1.4 from 20 kilometers to 10 kilometers, the drag coefficient must increase from 1.6 to 1.8 instead. If winds are invoked, then speeds of 60 meters per second are necessary, four times greater than those predicted. Refinements to the equation of hydrostatic equilibrium modify the temperature profile by an order of magnitude less than the desired amount. Unrealistically large instrument drifts of 0.5-1.0 meters per square second are needed to adjust the temperature profile as desired. However, rotational contributions to the accelerations may have the necessary magnitude and direction to make this correction. Determining whether this hypothesis is true will require further study of the rigid body equations of motion, with detailed knowledge of the positions of all six accelerometers. The paradox concerning this inversion is not yet resolved. It is important to resolve it because the paradox has some startling implications. At one extreme, are temperature profiles derived from accelerometers inherently inaccurate by 20K or more? At the other extreme, are RS temperature profiles inaccurate by this same amount?

Withers, Paul↗

DOE OSTI2020

The significant impact of aerosol vertical structure on lower atmosphere stability and its critical role in aerosol–planetary boundary layer (PBL) interactions

The aerosol–planetary boundary layer (PBL) interaction was proposed as an important mechanism to stabilize the atmosphere and exacerbate surface air pollution. Despite the tremendous progress made in understanding this process, its magnitude and significance still have large uncertainties and vary largely with aerosol distribution and meteorological conditions. In this study, we focus on the role of aerosol vertical distribution in thermodynamic stability and PBL development by jointly using micropulse lidar, sun photometer, and radiosonde measurements taken in Beijing. Despite the complexity of aerosol vertical distributions, cloud-free aerosol structures can be largely classified into three types: well-mixed, decreasing with height, and inverse structures. The aerosol–PBL relationship and diurnal cycles of the PBL height and PM 2.5 associated with these different aerosol vertical structures show distinct characteristics. The vertical distribution of aerosol radiative forcing differs drastically among the three types, with strong heating in the lower, middle, and upper PBL, respectively. Such a discrepancy in the heating rate affects the atmospheric buoyancy and stability differently in the three distinct aerosol structures. Absorbing aerosols have a weaker effect of stabilizing the lower atmosphere under the decreasing structure than under the inverse structure. As a result, the aerosol–PBL interaction can be strengthened by the inverse aerosol structure and can be potentially neutralized by the decreasing structure. Moreover, aerosols can both enhance and suppress PBL stability, leading to both positive and negative feedback loops. This study attempts to improve our understanding of the aerosol–PBL interaction, showing the importance of the observational constraint of aerosol vertical distribution for simulating this interaction and consequent feedbacks.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2024

Dynamic changes in evapotranspiration, canopy photosynthesis and expansive growth in open field under rapid fluctuating radiation

Abstract In open fields, plants experience dynamic changes in environment, particularly radiation, temperature, wind, and humidity but their short-term responses have not been adequately characterized under natural conditions. In this study, we assessed causal effects of rapid radiation fluctuation on seven plant parameters in open fields of cotton and sweet corn canopies. The parameters are evapotranspiration ( ET ), canopy photosynthesis indicated by CO2 flux from air to canopy ( FCO2 ), sensible heat energy flux ( H ), canopy conductance for water vapor ( gcw ), canopy surface temperature ( Ts ), shoot and leaf elongation rate, and stem diameter change. The energy and CO2 fluxes were measured with Bowen ratio/energy balance/CO2 gradient (BREB+) technique, using averaging time of 5 min. Shoot + leaf elongation and stem diameter change were monitored with position transducers using averaging time of 1 min. All parameters were all found to respond to change in radiation and transpiration within minutes or sooner. While radiation effects on canopy gas exchanges are expected, illuminating are the indirect but immediate effects on shoot + leaf growth and stem diameter change through radiation effects on transpiration and plant water status. A novel finding is that gcw also responded within minutes or sooner to radiation fluctuations and that FCO2 was related almost linearly to gcw . Results are discussed in terms of soil-plant-atmosphere continuum, and interpreted in terms of dynamic interactions between transpiration and plant water status. The clear inverse relationship between ET and elongation rate or stem diameter changes provides additional evidence supporting the validity of 5-min averaging for the BREB + technique.

Hsiao, Theodore C.↗

NASA NTRS1973

Column densities resulting from shuttle sublimator/evaporator operation

The proposed disposal of H2O from the shuttle fuel cell operation by ejecting it in vapor form through a supersonic nozzle at the rate of 100 lb/day has been investigated from the point of view of the possible interference to astronomical experiments. If the nozzle is located at the tail and directed along the shuttle longitudinal axis, the resulting column density will be less than 10 to th 12th power molecules/sq cm at viewing angles larger than 48 deg above the longitudinal axis. The molecules in the trail will diffuse rapidly. The column density contribution from molecules expelled on the previous orbit is 1.3 x 10 to the 8th power molecules/sq cm. This contribution diminishes by the inverse square root of the number of orbits since the molecules were expelled. The molecular backscatter from atmospheric molecules is also calculated. If the plume is directed into the flight path, the column density along a perpendicular is found to be 1.5 x 10 to the 11th power molecules/sq cm. The return flux is estimated to be of the order of 10 to the 12th power molecules/sq cm/sec at the stagnation point. With reasonable care in design of experiments to protect them from the backscatter flux of water molecules, the expulsion of 100 lb/day does not appear to create an insurmountable difficulty for the shuttle experiments.

Naumann, R. J.↗

NASA NTRS1990

Gamma guidance of trajectories for coplanar, aeroassisted orbital transfer

The optimization and guidance of trajectories for coplaner, aeroassisted orbital transfer (AOT) from high Earth orbit (HEO) to low Earth orbit (LEO) are examined. In particular, HEO can be a geosynchronous Earth orbit (GEO). It is assumed that the initial and final orbits are circular, that the gravitational field is central and is governed by the inverse square law, and that at most three impulses are employed: one at HEO exit, one at atmospheric exit, and one at LEO entry. It is also assumed that, during the atmospheric pass, the trajectory is controlled via the lift coefficient. The presence of upper and lower bounds on the lift coefficient is considered. First, optimal trajectories are computed by minimizing the total velocity impulse (hence, the propellant consumption) required for AOT transfer. The sequential gradient-restoration algorithm (SGRA) is used for optimal control problems. The optimal trajectory is shown to include two branches: a relatively short descending flight branch (branch 1) and a long ascending flight branch (branch 2). Next, attention is focused on guidance trajectories capable of approximating the optimal trajectories in real time, while retaining the essential characteristics of simplicity, ease of implementation, and reliability. For the atmospheric pass, a feedback control scheme is employed and the lift coefficient is adjusted according to a two-stage gamma guidance law. Further improvements are possible via a modified gamma guidance which is more stable with respect to dispersion effects arising from navigation errors, variations of the atmospheric density, and uncertainties in the aerodynamic coefficients than gamma guidance trajectory. A byproduct of the studies on dispersion effects is the following design concept. For coplaner aeroassisted orbital transfer, the lift-range-to-weight ratio appears to play a more important role than the lift-to-drag ratio. This is because the lift-range-to-weight ratio controls mainly the minimum altitude (hence, the peak heating rate) of the guidance trajectory; on the other hand, the lift-to-drag ratio controls mainly the duration of the atmospheric pass of the guidance trajectory.

Miele, A.↗

NASA NTRS1992

Occurrence of global-scale emissions on Jupiter - Proposed identification of Jovian dimer H2 emission

Two occasions of exceptionally widespread but distinct emission activity were observed in Jupiter's near-IR K-band spectrum during September and November of 1988. Two different sets of emission features were involved on the two dates of observation. During these occasions, the normally absent emission features extended from the South polar limb to at least the equator, over a large range of longitudes. Meanwhile, Jupiter's auroral H2 and H3(+) emissions remained confined to their usual magnetic polar domains. The global-scale emission features observed during those periods appear to have originated from the H2 dimer, (H2)2, during two different excitation modes. Inverse predissociation may have driven the November event. The September event probably originated deeper within the Jovian atmosphere, where excited H2 is more likely to combine with an unexcited H2 before radiating. Unusual magnetospheric loading probably precipitated these events.

Trafton, L. M.↗

NASA NTRS1993

The North Atlantic circulation in the early 1980s - An estimate from inversion of a finite-difference model

A finite-difference model of the North Atlantic is constructed for the purpose of making an estimate of the circulation through an inverse calculation. The data base is eclectic, and includes hydrography, oxygen, nutrients, current meter and float records, atmospheric momentum, heat and water vapor transfers, as well as estimates of certain integral fluxes. Owing to the available hydrographic database, the model resolution is restricted to 1 deg at best, and is much coarser in many aspects. This limited resolution is a major obstacle to accurate estimates of climatological fluxes. In its final form, there are about 9000 constraints in 29,000 formal unknowns plus 9000 noise unknowns. The system is solved as a tapered least-squares system by a sparse conjugate gradient algorithm. With the exception of a few float velocities, all constraints are found to be consistent within error estimates. The model produces estimates of large-scale fluxes and flux divergences for all conventional properties including heat and nutrients as well as carbon dioxide and alkalinity. Meridional fluxes of carbon are found to be indistinguishable from zero, whereas the North Atlantic tends to export nutrients to the south, but carry heat to the north. Traditional oceanographic depictions of the circulation through combination of nonsynoptic data into steady models may have reached their useful limit in the present calculation, as the conflicts between the data and physical requirements become quantitatively apparent.

Martel, Francoise↗

NASA NTRS2007

A Slow Retrieval Algorithm for Satellite and Surface Based Instruments

We present results of a retrieval algorithm for satellite and ground based instruments using the Arizona radiative transfer code. A state vector describing the atmospheric and surface condition is iteratively modified until the calculated radiances match the observed values. Elements of the state vector include: aerosol concentrations, radius, optical properties, mass-weighted altitudes, chlorophyll concentration and wind speed. While computationally expensive, many assumptions used in other retrieval algorithms are not invoked. We present co-located retrievals for MODIS, SEAWIFS and nearby AERONET sites. MODIS AQUA and SEA WIFS: Ten MODIS (.412 - 2.110 microns) and eight SEA WIFS (.412-.865 microns) radiances (.412-.865 microns) include channels where aerosols absorb and reflect radiation. We focus on retrieving bio-mass burning aerosols that are advected over open ocean. Since chlorophyll absorbs at frequencies where black carbon absorbs, our retrieval algorithm accounts for chlorophyll absorption by simultaneously retrieving both aerosol and chlorophyll amount. Our retrieved chlorophyll concentrations are similar to those from the Ocean Color Group. AERONET: Both Almucantar and Principle plane radiances are used to retrieve the state of the atmosphere and ocean conditions. Our retrieved aerosol size distributions and optical properties are consistent with the aerosol inversions from the AERONET group.

Weaver, C.↗

NASA NTRS2014

Detecting Trend and Seasonal Changes in Bathymetry Derived from HICO Imagery: A Case Study of Shark Bay, Western Australia

The Hyperspectral Imager for the Coastal Ocean (HICO) aboard the International Space Station has offered for the first time a dedicated space-borne hyperspectral sensor specifically designed for remote sensing of the coastal environment. However, several processing steps are required to convert calibrated top-of-atmosphere radiances to the desired geophysical parameter(s). These steps add various amounts of uncertainty that can cumulatively render the geophysical parameter imprecise and potentially unusable if the objective is to analyze trends and/or seasonal variability. This research presented here has focused on: (1) atmospheric correction of HICO imagery; (2) retrieval of bathymetry using an improved implementation of a shallow water inversion algorithm; (3) propagation of uncertainty due to environmental noise through the bathymetry retrieval process; (4) issues relating to consistent geo-location of HICO imagery necessary for time series analysis, and; (5) tide height corrections of the retrieved bathymetric dataset. The underlying question of whether a temporal change in depth is detectable above uncertainty is also addressed. To this end, nine HICO images spanning November 2011 to August 2012, over the Shark Bay World Heritage Area, Western Australia, were examined. The results presented indicate that precision of the bathymetric retrievals is dependent on the shallow water inversion algorithm used. Within this study, an average of 70% of pixels for the entire HICO-derived bathymetry dataset achieved a relative uncertainty of less than +/-20%. A per-pixel t-test analysis between derived bathymetry images at successive timestamps revealed observable changes in depth to as low as 0.4 m. However, the present geolocation accuracy of HICO is relatively poor and needs further improvements before extensive time series analysis can be performed.

coastal marine↗

NASA NTRS1978

Temperature structure and emergent flux of the Jovian planets

Long path, low temperature, moderate resolution spectra of methane and ammonia, broadened by hydrogen and helium, are used to calculate non-gray model atmospheres for the four Jovian planets. The fundamental and first overtone of hydrogen contributes enough absorption to create a thermal inversion for each of the planets. The suite of emergent spectral fluxes and representative limb darkenings and brightenings are calculated for comparison with the Voyager infrared spectra. The temperature differences between Jovian belts and zones corresponds to a difference in the ammonia cirrus particle radii (1 to 3 micron in zones; 10 micron in belts). The Jovian tropopause is approximately at the 0.1 bar level. A thin ammonia cirrus haze should be distributed throughout the Saturnian troposphere; and NH3 gas must be slightly supersaturated or ammonia ice particles are carried upwards convectively in the upper troposphere of Saturn. Substantial methane clouds exist on both Uranus and Neptune. There is some evidence for almost isothermal structures in the deep atmospheres of these two planets.

Silvaggio, P.↗

NASA NTRS2015

Estimation of Surface Temperature and Heat Flux by Inverse Heat Transfer Methods Using Internal Temperatures Measured While Radiantly Heating a Carbon/Carbon Specimen up to 1920 F

The ability to solve the heat conduction equation is needed when designing materials to be used on vehicles exposed to extremely high temperatures; e.g. vehicles used for atmospheric entry or hypersonic flight. When using test and flight data, computational methods such as finite difference schemes may be used to solve for both the direct heat conduction problem, i.e., solving between internal temperature measurements, and the inverse heat conduction problem, i.e., using the direct solution to march forward in space to the surface of the material to estimate both surface temperature and heat flux. The completed research first discusses the methods used in developing a computational code to solve both the direct and inverse heat transfer problems using one dimensional, centered, implicit finite volume schemes and one dimensional, centered, explicit space marching techniques. The developed code assumed the boundary conditions to be specified time varying temperatures and also considered temperature dependent thermal properties. The completed research then discusses the results of analyzing temperature data measured while radiantly heating a carbon/carbon specimen up to 1920 F. The temperature was measured using thermocouple (TC) plugs (small carbon/carbon material specimens) with four embedded TC plugs inserted into the larger carbon/carbon specimen. The purpose of analyzing the test data was to estimate the surface heat flux and temperature values from the internal temperature measurements using direct and inverse heat transfer methods, thus aiding in the thermal and structural design and analysis of high temperature vehicles.

Pizzo, Michelle↗

NASA NTRS1972

Radio occultation measurements of the Mars atmosphere with Mariners 6 and 7.

An analysis of the Mariner 6 and 7 occultation data has been completed. Final profiles of temperature, pressure, and electron density have been obtained for the Mariner 6 and 7 entry and exit cases, and results are presented for both the lower atmosphere and the ionosphere. At all four occultation points, the lapse rate of temperature was subadiabatic up to altitudes in excess of 20 km. A pronounced temperature inversion was present above the surface at the Mariner 6 exit point. All four profiles exhibit a sharp, superadiabatic drop in temperature at high altitudes, with temperatures falling below the frost point of carbon dioxide. These results give a strong indication of frozen carbon dioxide in the middle atmosphere of Mars.

Hogan, J. S.↗