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Sulfonated aromatic polymer as a future proton exchange membrane: A review of sulfonation and crosslinking methods
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Distribution and source identification of polycyclic aromatic hydrocarbons (PAHs) with PCA-MLR and PMF methods in the topsoil of Chengdu at SW, China
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DNAJB8 oligomerization is mediated by an aromatic-rich motif that is dispensable for substrate activity
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VAS1-mediated nitrogen reshuffling in aromatic amino acid homeostasis
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Closed-loop recycling of semi-aromatic polyesters upcycled from poly(ethylene terephthalate)
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Engineering Pseudomonas putida for efficient aromatic conversion to bioproduct using high throughput screening in a bioreactor
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Fast Kinetics Reveals Rate-Limiting Oxidation and the Role of the Aromatic Cage in the Mechanism of
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Aromatic Ring Fluorination Patterns Modulate Inhibitory Potency of Fluorophenylhydroxamates Complexe
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Contrasting Mechanisms of Aromatic and Aryl-Methyl Substituent Hydroxylation by the Rieske Monooxygenase Salicylate 5-Hydroxylase
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Novel 3D Cubic Topology in Hybrid Lead Halides with a Symmetric Aromatic Triammonium Exhibiting Water Stability
The limitations of three-dimensional (3D) perovskites are related to their narrow structural tunability of the organic cations and their moisture sensitivity. Herein, we report a new family of 3D cubic hybrid metal halides (T-Et 6 ) 3 Pb 11 X 31 (X = I, Br), where T is 1,3,5-tris-(4-aminophenyl)benzene. The materials are synthesized through an in situ N-alkylation of T and an efficient one-step solvothermal reaction containing ethanol, initiating a tunable synthetic avenue for the acquisition of structurally complex hybrid halides with luminophores. (T-Et 6 ) 3 Pb 11 X 31 consist of an unprecedented Ia3̅ framework of [Pb 11 X 31 ] 9– one-dimensional (1D) chains embedded with (T-Et 6 ) 3+ cations, affording an overall 3D topology. Here, the constituent [Pb 11 X 31 ] 9– chains include exclusively octahedral lead halide units with clusters of face- and edge-sharing connectivity, giving rise to weak broad emission centered at ~660 nm observed at 78 K. (T-Et 6 ) 3 Pb 11 I 31 demonstrates water stability for at least 7 days. Synthesis through ambient pressure results in tunable structural variations of zero-dimensional (0D) structures rendering T 7 Pb 3 Br 27 ·DMF and T 2 Sn 3 Br 18 ·4H 2 O·0.5Br 2 , both of which feature blue PL emission at room temperature.
The Impact of Second Coordination Sphere Methionine-Aromatic Interactions in Copper Proteins
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