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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 541 records · Page 30

Gravity as a factor in the animal environment.

Review of current knowledge, research, and research planning on the influence of gravity upon living organisms. Discussed factors affecting the adaptability of animals to increased acceleration fields include age, sex, posture, and body size. Affected functions and aspects reviewed cover growth and mature body size, body composition, maintenance feed requirements, and feed utilization efficiency. It is expected that research involving the exposure of animals to altered gravity states will lead to new biological concepts of very broad importance.

Smith, A. H.↗

Ultrasonic techniques for repair of aircraft structures with bonded composite patches

This is a paper on a research and development project to demonstrate a novel ultrasonic process for the field application of boron/epoxy (B/Ep) patches for repair of aircraft structures. The first phase of the project was on process optimization and testing to develop the most practical ultrasonic processing techniques. Accelerated testing and aging behavior of precured B/Ep patches, which were ultrasonically bonded to simulated B-52 wing panel assemblies, were performed by conducting flight-by-flight spectrum loading fatigue tests. The spectrum represented 2340 missions/flights or 30 years of service. The effects of steady-state applied temperature and prior exposure of the B/Ep composite patches were evaluated. Representative experimental results of this phase of the project are presented.

Smith, S. H.↗

The Moon as a Science Platform

The Moon offers a valuable platform for space sciences studies: (1) No atmosphere, (2) Farside is radio quiet. There is a compelling science program: (1) Cosmic dawn and the dark ages, (2) Particle acceleration and space weather. The technology and engineering development are making good progress. A staged roadmap with science and technology development at every step is presented.

space science studies↗

Long term reliability study and life time model of quantum cascade lasers

Here, we present results of quantum cascade laser lifetime tests under various aging conditions including an accelerated life test. The total accumulated life time exceeds 1.5 × 106 device hours. The longest single device aging time was 46 500 hours without failure in the room temperature aging test. Four failures were found in a group of 19 devices subjected to the accelerated life test with a heat-sink temperature of 60 °C and a continuous-wave current of 1 A. Failure mode analyses revealed that thermally induced oxidation of InP in the semi-insulating layer is the cause of failure. An activation energy of 1.2 eV is derived from the dependence of the failure rate on laser core temperature. The mean time to failure of the quantum cascade lasers operating at a typical condition with the current density of 5 kA/cm2 and heat-sink temperature of 25 °C is expected to be 809 000 hours.

Xie, Feng↗

Review of polymer oxidation and its relationship with materials performance and lifetime prediction

All polymers are intrinsically susceptible to oxidation, which is the underlying process for thermally driven materials degradation and of concern in various applications. There are many approaches for predicting oxidative polymer degradation. Aging studies usually are meant to accelerate oxidation chemistry for predictive purposes. Kinetic models attempt to describe reaction mechanisms and derive rate constants, whereas rapid qualification tests should provide confidence for extended performance during application, and similarly TGA tests are meant to provide rapid guidance for thermal degradation features. What are the underlying commonalities or diverging trends and complications when we approach thermo-oxidative aging of polymers in such different ways? This review presents a brief status report on the important aspects of polymer oxidation and focuses on the complexity of thermally accelerated polymer aging phenomena. Thermal aging and lifetime prediction, the importance of DLO, property correlations, kinetic models, TGA approaches, and a framework for predictive aging models are briefly discussed. An overall perspective is provided showing the challenges associated with our understanding of polymer oxidation as it relates to lifetime prediction requirements.

36 MATERIALS SCIENCE↗

Evolution of the role of molybdenum in duplex stainless steels during thermal aging: From enhancing spinodal decomposition to forming heterogeneous precipitates

Thermal aging of ferrite in duplex stainless steels leads to a complex microstructural evolution that can give way to large deleterious changes in mechanical properties. The microstructural evolution mechanisms that happen concurrently are strongly linked to minor changes in composition. By characterizing duplex stainless steels with various compositions over a range of aging conditions, it was revealed that adding a modest amount of Mo to cast austenitic stainless steel (such as changing from grade CF3 to grade CF3M) not only increases the kinetics of spinodal decomposition and Ni-Si-Mn-rich G-phase precipitation, but it also forms a separate Mo-rich phase. At shorter equivalent aging times, Mo segregates from Fe and towards Cr accelerating spinodal decomposition. At longer aging times, Mo enriches in the Ni-Si-Mn clusters before phase separating into an adjoined Mo-rich cluster. We found that these phase changes and precipitation events result in a rather steep drop in fracture and impact toughness. These results will inform the design of similar alloys for use at high temperatures.

36 MATERIALS SCIENCE↗

De-pollution efficacy of photocatalytic roofing granules

Photocatalytic building surfaces can harness sunlight to reduce urban air pollution. The NO x abatement capacity of TiO 2 -coated granules used in roofing products was evaluated for commercial product development. A laboratory test chamber and ancillary setup were built following conditions prescribed by ISO Standard 22197-1. It was validated by exposing reference P25-coated aluminum plates to a 3 L min -1 air flow enriched in 1 ppm NO under UVA irradiation (360 nm, 11.5 W m -2 ). We characterized prototype granule-surfaced asphalt shingles and loose granules prepared with different TiO 2 loadings and post-treatment formulations. Tests performed at surface temperatures of 25 and 60 °C showed that NO x abatement was more effective at the higher temperature. Preliminary tests explored the use of 1 ppm NO 2 and of 1 ppm and 0.3 ppm NO/NO 2 mixtures. Specimens were aged in a laboratory accelerated weathering apparatus, and by exposure to the outdoor environment over periods that included dry and rainy seasons. Laboratory aging led to higher NO removal and NO 2 formation rates, and the same catalyst activation was observed after field exposure with frequent precipitation. However, exposure during the dry season reduced the performance. This inactivation was mitigated by cleaning the surface of field-exposed specimens. Doubling the TiO 2 loading led to a 50–150% increase in NO removal and NO x deposition rates. Finally, application of different post-treatment coatings decreased NO removal rates (21–35%) and NO x deposition rates (26–74%) with respect to untreated granules. The mass balance of nitrogenated species was assessed by extracting granules after UV exposure in a 1 ppm NO-enriched atmosphere.

54 ENVIRONMENTAL SCIENCES↗

C-14 content of ten meteorites measured by tandem accelerator mass spectrometry

Measurements of C-14 in three North American and seven Antarctic meteorites show in most cases that this cosmogenic isotope, which is tightly bound, was separated from absorbed atmospheric radiocarbon by stepwise heating extractions. The present upper limit to age determination by the accelerator method varies from 50,000 to 70,000 years, depending on the mass and carbon content of the sample. The natural limit caused by cosmic ray production of C-14 in silicate rocks at 2000 m elevation is estimated to be 55,000 + or - 5000 years. An estimation is also made of the 'weathering ages' of the Antarctic meteorites from the specific activity of loosely bound CO2 which is thought to be absorbed from the terrestrial atmosphere. Accelerator measurements are found to agree with previous low level counting measurements, but are more sensitive and precise.

Brown, R. M.↗

Understanding PV Polymer Backsheet Degradation through X-Ray Scattering

Understanding how photovoltaic (PV) module backsheet polymers age and degrade in response to environmental stresses is important for designing polymers that can maintain their structural integrity after decades of outdoor use. X-ray scattering is a powerful technique for exploring backsheet polymer structure at the angstrom- (wide-angle, WAXS) and nanometer- (small-angle, SAXS) length-scales. We present the use of SAXS and WAXS to study pristine and aged polymer backsheets. The structural insight from these techniques can be used to compare the degradation induced by accelerated testing with the degradation seen in field-aged PV materials.

14 SOLAR ENERGY↗

AC and DC Fault Management for Megawatt Electrified Aircraft Electrical Powertrains Task 3: Lifetime and Reliability of Electrical Insulators

This research project was a collaborative investigation between researchers at the RTX Technology Research Center (RTRC) and the University of Texas at Austin and made a significant contribution to enabling electric aircraft. The transport of electric power between the points of generation and use requires power cables. These cables must be smaller, lighter and provide a more predictable life than power cables used in stationary applications. Consequently, this investigation provided heretofore unavailable information supporting the safety and reliability of smaller lighter power cables for electrified aircraft. In addition, the research identified key additional engineering data needed to support quantitative reliability assessments. Important advances included: • Demonstrated that at least one manufacturer can make a novel, smaller, lighter power cable that is free from serious defects. • Developed and published an appropriate analytical construct to describe the life of this novel cable. This is a necessary step for use in aviation where the understanding of remaining life is critical. • Demonstrated thermal-mechanical aging that suggested 1000+ flights before the thermal-mechanical processes produced defects large enough that the defect growth was accelerated electrically. • Showed that electrical aging took place at two rates. The first possibly lasting weeks to months and the second possibly days to weeks. If robust, this provides a good diagnostic for cable replacement. • Demonstrated that the traditional electrical testing of cable materials using manufactured voids can be misleading due to the size of the voids. Emerging laser drilling technology permitted demonstration that the physics of failure in realistically small voids is different from that in the unrealistically large voids used in earlier research, which is very important for high-quality, high-performance, small aircraft cables. Although this project represents a significant contribution to the specifics of cable aging in the aircraft environment, important additional research remains to be completed, including: • Non-uniform thermal cycling by applying the heat from the center conductor to maximize thermal stress next to the core area where the electric gradient is the strongest. This builds on the uniform thermal cycling that has been completed. • The augmentation of the thermal-mechanical failure rate by electrical processes. Better understanding of these time constants strongly affects the ability to predict life. • Termination design: Terminations provide not only electrical reflection potential, but a location for a series arc fault and an area where ozone can diffuse into the center conductor and negatively affect cable insulation. • The abrasion and ozone resistance of the cable jacket. • Pressure cycling as an accelerant of thermal, mechanical, and/or electrical aging. • Possible methods for online PD detection and offline PD localization

model↗

BTMS Testing Section

Cell testing is an important part of understanding the performance and life capabilities of state-of-the art energy storage technologies, particularly with respect to the distinct technical and functional requirements posed by the BTMS program. In order to test energy storage components and systems against these requirements, test procedures must be created. System usage scenarios are concurrently being developed with testing of baseline cells intended to illustrate their capabilities relative to a broad set of initial system assumptions. The results from these early performance tests and aging procedures, though only loosely framed by a baseline 1 MWh BTMS system supporting six 350kW DCFC units, will produce both slow and accelerated cycle-life aging information through a mix of empirical observations and modeling.

25 ENERGY STORAGE↗

Initial results on 5 MHz quartz oscillators equipped with BVA resonators

The techniques of fabricating BVA resonators are discussed in terms of aging, amplitude-frequency effect, and acceleration sensitivity. Results on 5 MHz resonators concerning aging versus drive level, reduced amplitude-frequency effect, frequency and phase stability performance, and frequency retrace following power interruption are presented. It is indicated that a zero aging rate is possible at a drive level which depends on the qaurtz material used. For natural AT quartz, a level of 70 to 90 micro W appears to be optimum, and for SC quartz approximately 160 micro W.

Besson, R. J.↗

2019 Nishikawa Tetsuji Prize Talk

The talk is given at the IPAC19 on the occasion of acceptance of the Nishikawa Tetsuji Prize for a recent, significant, original contribution to the accelerator field, with no age limit with citation “for original work on electron lenses in synchrotron colliders, outstanding contribution to the construction and operation of high-energy, high-luminosity hadron colliders and for tireless leadership in the accelerator community.”

43 PARTICLE ACCELERATORS↗

Lifetime Extension of the Gas Discharge Detectors with Plasma Etching of Silicon Deposits in 80%CF{sub 4} + 20%CO{sub 2}

A method of elimination of silicon compounds from the anode wire of an aged proportional counter is presented. The aging of a counter with a 70%Ar + 30%CO{sub 2} and a 60%Ar + 30%CO{sub 2} + 10%СF{sub 4} working mixture was stimulated by a {sup 90}Sr β source. To accelerate the process of aging, the gas mixture flow to the counter was supplied through a pipe with RTV coated wall. As a result, the amplitude of the signal decreased 70% already at accumulated charge of Q = 0.03 C/cm. The etching of the silicon compounds on the wire surface with an 80%CF{sub 4} + 20%CO{sub 2} gas mixture discharge led to full recovery of the operating characteristics of detector and an increase in the lifetime. A scanning electron microscopy and X-ray spectroscopy analysis of the recovered wire surface were performed. In accordance with the results, a good quality of wire cleaning from SiO{sub 2} compounds was obtained.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Understanding the trilemma of fast charging, energy density and cycle life of lithium-ion batteries

Increasing energy density of Li-ion batteries (LiBs) along with fast charging capability are two key approaches to eliminate range anxiety and boost mainstream adoption of electric vehicles (EVs). Either the increase of energy density or of charge rate, however, heightens the risk of lithium plating and thus deteriorates cell life. The trilemma of fast charging, energy density and cycle life are studied systematically in this work utilizing a physics-based aging model with incorporation of both lithium plating and solid-electrolyte-interphase (SEI) growth. The model is able to capture the key feature of temperature-dependent aging behavior of LiBs, or more specifically, the existence of an optimal temperature with the longest cycle life. We demonstrate that this optimal temperature is a result of competition between SEI growth and lithium plating. Further, it is revealed that either the increase of charge rate or of energy density accelerates lithium plating induced aging. As such, the optimal temperature for cell life increases from ~20 °C for a high-power cell at 1C charge to ~35–45 °C with the increase of charge rate and/or energy density. In conclusion, it would be beneficial to further increase the charge temperature in order to enable robust fast charging of high energy EV cells.

25 ENERGY STORAGE↗

CALPHAD-based ICME design of single-step aging to enhance mechanical strength of WAAM Haynes 282

To match the strength of wire-arc additive manufactured Haynes 282 to its wrought counterpart via a single-step aging heat treatment, the CALPHAD (Calculation of Phase Diagrams) method is integrated with physics-based process-structure-property models and experimental validation. The integrated computational materials engineering (ICME) framework simulates the effects of aging on γ′ and M 23 C 6 precipitation and the resulting yield strength. To improve simulation reliability, the interfacial energies between γ/γ′ and γ/M 23 C 6 carbides were estimated by comparison with precipitation kinetic modeling and measured precipitate sizes. γ′ and M23C6 were found to precipitate simultaneously between 640 and 860 °C, producing microstructures similar to those produced by two-step aging. The optimal γ′ size for peak yield stress was calculated to be 20–23 nm. WAAM Haynes 282 aged at 780 °C for 50 h exceeded the mechanical performance of its wrought counterpart subjected to two-step aging, though desired properties can also be achieved at 800 °C for 16 h or less. The error in yield strength is less than 20 MPa, demonstrating good agreement between the modeling framework and experiments. Creep studies showed that WAAM Haynes 282 exceeded the calculated rupture time, reaching 481 h. This proposed methodology can accelerate the design of aging heat treatments for any γ′-strengthened nickel-base alloy, minimizing the resources required for trial-and-error experiments.

CALPHAD↗

Effects of Aging and Different Mechanical Recycling Processes on the Structure and Properties of Poly(lactic acid)-clay Nanocomposites

The growing use of poly(lactic acid) (PLA) and PLA-based nanocomposites in packaging has raised the interest of studying the mechanical recycling of the wastes and the properties of the recycled materials. The main objective of this work was to study the effect of two different mechanical recycling processes on the structure and properties of a PLA-montmorillonite nanocomposite. The two recycling processes included accelerated thermal and photochemical aging steps to simulate the degradation experienced by post-consumer plastics during their service life. One of them also included a demanding washing process prior to the reprocessing. A decrease in the molecular weight of PLA was observed in the recycled materials, especially in those subjected to the washing step, which explained the small decrease in microhardness and the increased water uptake at long immersion times. Water absorption at short immersion times was similar in virgin and recycled materials and was accurately described using a Fickian model. The recycled materials showed increased thermal, optical and gas barrier properties due to the improved clay dispersion that was observed by XRD and TEM analysis. The results suggest that recycled PLA-clay nanocomposites can be used in demanding applications.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Evidence for Cosmic Acceleration Is Robust to Observed Correlations between Type Ia Supernova Luminosity and Stellar Age

Type Ia supernovae (SNe Ia) are powerful standardizable candles for constraining cosmological models and provided the first evidence of the accelerated expansion of the universe. Their precision derives from empirical correlations, now measured from >1000 SNe Ia, between their luminosities, light-curve shapes, colors, and most recently with the stellar mass of their host galaxy. As mass correlates with other galaxy properties, alternative parameters have been investigated to improve SN Ia standardization though none have been shown to significantly alter the determination of cosmological parameters. We re-examine a recent claim, based on 34 SN Ia in nearby passive host galaxies, of a 0.05 mag Gyr -1 dependence of standardized SN Ia luminosity on host age, which, if extrapolated to higher redshifts, would be a bias up to 0.25 mag, challenging the inference of dark energy. We reanalyze this sample of hosts using both the original method and a Bayesian hierarchical model and find after a fuller accounting of the uncertainties the significance of a dependence on age to be ≤2σ and ~1σ after the removal of a single poorly sampled SN Ia. Here, to test the claim that a trend seen in old stellar populations can be applied to younger ages, we extend our analysis to a larger sample that includes young hosts. We find the residual dependence of host age (after all standardization typically employed for cosmological measurements) to be consistent with zero for 254 SNe Ia from the Pantheon sample, ruling out the large but low significance trend seen in passive hosts.

79 ASTRONOMY AND ASTROPHYSICS↗