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At least 541 records · Page 30

Ineffectiveness of ultrasound at low frequency for treating per- and polyfluoroalkyl substances in sewage sludge

Concerns have been raised about per- and polyfluoroalkyl substances (PFAS) in sewage sludge given the urgent need of finding suitable disposal methods for sludge. Here in this study, we evaluated the effect of ultrasonication on PFAS changes in sewage sludge. It was revealed that although ultrasonication at 20 kHz increased the soluble chemical oxygen demand (SCOD) of treated sewage sludge, this technique was ineffective for degrading perfluoroalkyl acids (PFAAs) and their precursors. Ultrasonic treatment for longer time (>15 min) led to concentration increase of perfluorooctanoic acid (PFOA), perfluoroheptanoic acid (PFHpA), and perfluorohexanoic acid (PFHxA) in the liquid phase, possibly due to their release from disrupted sludge flocs during cavitation. Adding permanganate (10 mM) to the ultrasonic system could also enhance the disruption of sludge particles, resulting in higher concentrations of PFOA and PFHxA in the solid phase and PFOA, PFHpA, PFHxA, and perfluorobutanesulfonic acid (PFBS) in the liquid phase. Overall, ultrasonic pretreatment at 20 kHz and 0.7 W/mL is unlikely to remove PFAS from sewage sludge. Instead, it could increase the risk of PFAS pollution upon final sludge disposal. Effective treatment technologies are thus demanded if PFAS in sludge are regulated.

54 ENVIRONMENTAL SCIENCES↗

Ultrasound Evaluation of Thyroid Gland Pathologies After Radiation Therapy and Chemotherapy to Treat Malignancy During Childhood

Purpose: The purpose of this study was to evaluate correlations between treatment of malignancy by radiation therapy during childhood and the occurrence of thyroid gland pathologies detected by ultrasonography in follow-up examinations. Methods and Materials: Reductions of thyroid gland volume below 2 standard deviations of the weight-specific mean value, occurrence of ultrasonographically detectable thyroid gland pathologies, and hypothyroidism were retrospectively assessed in 103 children and adolescents 7 months to 20 years of age (median: 7 years of age) at baseline (1997-2013) treated with chemoradiation therapy (with the thyroid gland dose assessable) or with chemotherapy alone and followed by ultrasonography and laboratory examinations through 2014 (median follow-up time: 48 months). Results: A relevant reduction of thyroid gland volume was significantly correlated with thyroid gland dose in univariate (P<.001) and multivariate analyses for doses above 2 Gy. Odds ratios were 3.1 (95% confidence interval: 1.02-9.2; P=.046) for medium doses (2-25 Gy) and 14.8 (95% confidence interval: 1.4-160; P=.027) for high doses (>25 Gy). Thyroid gland dose was significantly higher in patients with thyroid gland pathologies during follow-up (P=.03). Univariate analysis revealed significant correlations between hypothyroidism and thyroid gland dose (P<.001). Conclusions: Ultrasonographically detectable changes, that is, volume reductions, pathologies, and hypothyroidism, after malignancy treatment during childhood are associated with thyroid gland dose. Both ultrasonography and laboratory follow-up examinations should be performed regularly after tumor therapy during childhood, especially if the treatment included radiation therapy.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Ultrasound-assisted facile synthesis of a new tantalum(V) metal-organic framework nanostructure: Design, characterization, systematic study, and CO{sub 2} adsorption performance

This work presents a fast route for the preparation of a new Ta(V) metal-organic framework nanostructure with high surface area, significant porosity, and small size distribution. X-ray diffraction (XRD), scanning electron microscopy (SEM), Transition electron microscopy (TEM), energy dispersive spectrometer (EDS), thermo-gravimetric analysis (TGA), differential scanning calorimetry (DSC), fourier transform infrared spectroscopy (FTIR), CHNS/O elemental analyser, and Brunauer-Emmett-Teller (BET) surface area analysis were applied to characterize the synthesized product. Moreover, the influences of ultrasonic irradiation including temperature, time, and power on different features of the final products were systematically studied using 2{sup k-1} factorial design experiments, and the response surface optimization was used for determining the best welding parameter combination. The results obtained from analyses of variances showed that ultrasonic parameters affected the size distribution, thermal behaviour, and surface area of Ta-MOF samples. Based on response surface methodology, Ta-MOF could be obtained with mean diameter of 55 nm, thermal stability of 228 °C, and high surface area of 2100 m{sup 2}/g. The results revealed that the synthesized products could be utilized in various applications such as a novel candidate for CO{sub 2} adsorption. - Graphical abstract: A facile route was used for fabrication of a new metal -organic framework based on tantalum nanostructures that have high surface area, considerable porosity, homogenous morphology, and small size distribution.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Evaluation of macrozone dimensions by ultrasound and EBSD techniques

Titanium alloys are known to have texture heterogeneities, i.e. regions much larger than the grain dimensions, where the local orientation distribution of the grains differs from one region to the next. The electron backscattering diffraction (EBSD) technique is the method of choice to characterize these macro regions, which are called macrozones. Qualitatively, the images obtained by EBSD show that these macrozones may be larger or smaller, elongated or equiaxed. However, often no well-defined boundaries are observed between the macrozones and it is very hard to obtain objective and quantitative estimates of the macrozone dimensions from these data. In the present work, we present a novel, non-destructive ultrasonic technique that provides objective and quantitative characteristic dimensions of the macrozones. The obtained dimensions are based on the spatial autocorrelation function of fluctuations in the sound velocity. Thus, a pragmatic definition of macrozone dimensions naturally arises from the ultrasonic measurement. This paper has three objectives: 1) to disclose the novel, non-destructive ultrasonic technique to measure macrozone dimensions, 2) to propose a quantitative and objective definition of macrozone dimensions adapted to and arising from the ultrasonic measurement, and which is also applicable to the orientation data obtained by EBSD, and 3) to compare the macrozone dimensions obtained using the two techniques on two samples of the near-alpha titanium alloy IMI834. In addition, it was observed that macrozones may present a semi-periodical arrangement. - Highlights: Black-Right-Pointing-Pointer Discloses a novel, ultrasonic NDT technique to measure macrozone dimensions Black-Right-Pointing-Pointer Proposes a quantitative and objective definition of macrozone dimensions Black-Right-Pointing-Pointer Compares macrozone dimensions obtained using EBSD and ultrasonics on 2 Ti samples Black-Right-Pointing-Pointer Observes that macrozones may have a semi-periodical arrangement.

36 MATERIALS SCIENCE↗