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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 541 records · Page 30
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Containerless synthesis of interesting glasses

One aspect of containerless glass experimentation was thoroughly examined: glass forming ability. It is argued that although containerless processing will abet glass formation, other ground-based methods can do the job better. However, these methods have limitations, such as sample dimensions and concomitant ability to make property measurements. Most importantly, perhaps, is the observation that glass properties are a function of preparation procedure. Thus, it seems as though there still is an argument for use of containerless processing for glass forming.

Weinberg, Michael C.↗
NASA NTRSDate not supplied

Dielectric Energy Storage Materials for Space Sensors: Effect of Processing on the Performance

This paper explores the development of innovative materials for the dielectric energy storage for space components. The CaCuN 3 Ti 4 O 12 or CCTO belonging to perovskite family is of interest due to its colossal dielectric constant. It was demonstrated that materials synthesized at low temperature show nonequilibrium state and exhibit differences in the dielectric and resistivity values. The goal is to obtain high dielectric constant along with high resistivity values for achieving enhanced breakdown voltage. By using other members of the perovskite structures, it was demonstrated that similar colossal dielectric constant is observed and is dependent on processing methods. We have used heterovalent and dissimilar sized atom to replace Ca +2 ion. Accordingly, we replaced Ca +2 ion with heavy Ga +3 ion and developed gallium-based material system, Ga 2/3 Cu 3 Ti 4 O 12 . Following successful synthesis, we measured its dielectric constant and resistivity and compared with CCTO material system. Results of five sets of samples showed that lower temperature processing demonstrated mechanism of grain growth, but due to copper flow in high temperature processed samples dielectric constant and resistivity values were different.

Dielectric Energy↗
NASA NTRS1978

Gamma-ray Astrophysics: a New Look at the Universe

Gamma-ray astronomy which includes the spectral region from above approximately 100 keV to greater than or equal to 1000 GeV permits investigation of the most energetic photons originating in our galaxy and beyond and provides the most direct means of studying the largest transfers of energy occurring in astrophysical processes. Of all the electromagnetic spectrum, high-energy gamma-ray astronomy measures most directly the presence and dynamic effects of the energetic charged cosmic ray particles, element synthesis, and particle acceleration. Further, gamma rays suffer negligible absorption or scatterings as they travel in straight paths; hence, they may survive billions of years and still reveal their source. The high energy processes in stellar objects (including our Sun), the dynamics of the cosmic-ray gas, the formation of clouds and nebulae, galactic evolution and even certain aspects of cosmology and the origin of the universe may be explored by gamma-ray observations.

Trombka, J. I.↗
NASA NTRS1985

Video image processing

Current technology projections indicate a lack of availability of special purpose computing for Space Station applications. Potential functions for video image special purpose processing are being investigated, such as smoothing, enhancement, restoration and filtering, data compression, feature extraction, object detection and identification, pixel interpolation/extrapolation, spectral estimation and factorization, and vision synthesis. Also, architectural approaches are being identified and a conceptual design generated. Computationally simple algorithms will be research and their image/vision effectiveness determined. Suitable algorithms will be implimented into an overall architectural approach that will provide image/vision processing at video rates that are flexible, selectable, and programmable. Information is given in the form of charts, diagrams and outlines.

Murray, N. D.↗
NASA NTRS2018

Igneous Rocks Formed by Hypervelocity Impact

Igneous rocks are the primary building blocks of planetary crusts. Most igneous rocks originate via decompression melting and/or wet melting of protolith lithologies within planetary interiors and their classification and compositional, petrographic, and textural characteristics, arewell-studied. As our exploration of the Solar System continues, so too does the inventory of intrusive and extrusive igneous rocks, settings, and processes. The results of planetary exploration have also clearly demonstrated that impact cratering is a ubiquitous geological process that has affected, andwill continue to affect, all planetary objectswith a solid surface,whether that be rock or ice. It is nowrecognized that the production of igneous rocks is a fundamental outcome of hypervelocity impact. The goal of this review is to provide an up-to-date synthesis of our knowledge and understanding of igneous rocks formed by hypervelocity impact. Following a brief overview of the basics of the impact process, we describe howand whymelts are generated during impact events and howimpactmelting differs fromendogenic igneous processes.While the processmay differ,we showthat the products of hypervelocity impact can share close similarities with volcanic and shallow intrusive igneous rocks of endogenic origin. Such impact melt rocks, as they are termed, can display lobate margins and cooling cracks, columnar joints and at the hand specimen andmicroscopic scale, such rocks can displaymineral textures that are typical of volcanic rocks, such as quench crystallites, ophitic, porphyritic, aswell as features such as vesicles, flowtextures, and so on.Historically, these similarities led to themisidentification of some igneous rocks now known to be impact melt rocks as being of endogenic origin. This raises the question as to how to distinguish between an impact versus an endogenic origin for igneous-like rocks on other planetary bodies where fieldwork and sample analysis may not be possible and all that may be available is remote sensing data.While the interpretation of some impact melt rocks may be relatively straightforward (e.g., for clast-rich varieties and those with clear projectile contamination) we conclude that distinguishing between impact and endogenic igneous rocks is a non-trivial task that ultimately may require sample investigation and analysis to be conducted. Caution is, therefore, urged in the interpretation of igneous rocks on planetary surfaces.

Osinski, Gordon R.↗
NASA NTRS1984

Photochemistry of the atmosphere of Titan - Comparison between model and observations

Updated chemical schemes and estimates of key rate coefficients are used in the present investigation of the photochemistry of Titan atmosphere C- H- and O-atom containing simple molecules, according to a model incorporating exospheric boundary conditions, vertical transport, and condensation processes at the tropopause. It is suggested that the composition, climatology, and evolution of the Titan atmosphere are controlled by five major processes: CH4 photolysis and photosensitized dissociation, H-to-H2 conversion and hydrogen escape, higher hydrocarbon synthesis, nitrogen and hydrocarbon coupling, and oxygen and hydrocarbon coupling. The model accounts for the minor species concentrations observed by Voyager instruments. Implications of abiotic organic synthesis on Titan for the origin of life on earth are briefly discussed.

Yung, Y. L.↗
NASA NTRS1991

A Taguchi study of the aeroelastic tailoring design process

A Taguchi study was performed to determine the important players in the aeroelastic tailoring design process and to find the best composition of the optimization's objective function. The Wing Aeroelastic Synthesis Procedure (TSO) was used to ascertain the effects that factors such as composite laminate constraints, roll effectiveness constraints, and built-in wing twist and camber have on the optimum, aeroelastically tailored wing skin design. The results show the Taguchi method to be a viable engineering tool for computational inquiries, and provide some valuable lessons about the practice of aeroelastic tailoring.

Bohlmann, Jonathan D.↗
NASA NTRS1991

Implementation of 3-D isoparametric finite elements on supercomputer for the formulation of recursive dynamical equations of multi-body systems

A computational algorithmic procedure is developed and implemented for the dynamic analysis of a multibody system with rigid/flexible interconnected bodies. The algorithm takes into consideration the large rotation/translation and small elastic deformations associated with the rigid-body degrees of freedom and the flexibility of the bodies in the system respectively. Versatile three-dimensional isoparametric brick elements are employed for the modeling of the geometric configurations of the bodies. The formulation of the recursive dynamical equations of motion is based on the recursive Kane's equations, strain energy concepts, and the techniques of component mode synthesis. In order to minimize CPU-intensive matrix multiplication operations and speed up the execution process, the concepts of indexed arrays is utilized in the formulation of the equations of motion. A spin-up maneuver of a space robot with three flexible links carrying a solar panel is used as an illustrative example.

Shareef, N. H.↗
NASA NTRS1991

Planetary geomorphology research: FY 1990-1991

Progress in the following research areas is discussed: (1) volatile ice sublimation in a simulated Martian polar environment; (2) a global synthesis of Venusian tectonics; (3) a summary of nearly a decade of field studies of eolian processes in cold volcanic deserts; and (4) a model for interpretation of Martian sediment distribution using Viking observations. Some conclusions from the research are presented.

Malin, M. C.↗
NASA NTRS1993

Digital test signal generation: An accurate SNR calibration approach for the DSN

In support of the on-going automation of the Deep Space Network (DSN) a new method of generating analog test signals with accurate signal-to-noise ratio (SNR) is described. High accuracy is obtained by simultaneous generation of digital noise and signal spectra at the desired bandwidth (base-band or bandpass). The digital synthesis provides a test signal embedded in noise with the statistical properties of a stationary random process. Accuracy is dependent on test integration time and limited only by the system quantization noise (0.02 dB). The monitor and control as well as signal-processing programs reside in a personal computer (PC). Commands are transmitted to properly configure the specially designed high-speed digital hardware. The prototype can generate either two data channels modulated or not on a subcarrier, or one QPSK channel, or a residual carrier with one biphase data channel. The analog spectrum generated is on the DC to 10 MHz frequency range. These spectra may be up-converted to any desired frequency without loss on the characteristics of the SNR provided. Test results are presented.

Gutierrez-Luaces, Benito O.↗
NASA NTRS2003

A Probabilistic Approach to Technology Identification, Evaluation, and Selection for Affordable Transport Concepts

Most grant goals were accomplished over the course of the grant, albeit only partial success was achieved in applying ASDL s existing advanced design methods to HAVOC. The limited success in applying ASDL's advanced design methods occurred due to: fundamental 20 of 197 limitations in the RSM metamodeling process used; the highly computationally intensive nature of HAVOC as compared to many other advanced system synthesis and sizing codes; and the highly curved nature of low I(sub sp) rocket system spaces. These challenges encountered during the grant led to ongoing efforts in more efficient and robust sequential metamodeling/surrogate optimization based advanced design methods which are expected to overcome all of the challenges encountered with RSM during the grant. Other achievements over the course of the grant included the documentation of the existing HAVOC cost module and formulation of new cost estimation relationships in support of APS analysis of 3rd Gen RLV. Further achievements beyond the scope of the grant as originally defined were also achieved such as HAVOC code and portability improvements, historical propulsion performance and reliability regression relationships, and new visualization routines to vacilitate visualization of HAVOC DOE case file results.

Source record↗
NASA NTRS2011

Hydrogen Isotope Measurements of Organic Acids and Alcohols by Pyrolysis-GC-MS-TC-IRMS

One possible process responsible for methane generation on Mars is abiotic formation by Fischer-Tropsch-type (FTT) synthesis during serpentinization reactions. Measurement of carbon and hydrogen isotopes of intermediary organic compounds can help constrain the origin of this methane by tracing the geochemical pathway during formation. Of particular interest within the context of this work is the isotopic composition of organic intermediaries produced on the surfaces of mineral catalysts (i.e. magnetite) during hydrothermal experiments, and the ability to make meaningful and reproducible hydrogen isotope measurements. Reported here are results of experiments to characterize the hydrogen isotope composition of low molecular weight organic acids and alcohols. The presence of these organic compounds has been suggested by others as intermeadiary products made during mineral surface catalyzed reactions. This work compliments our previous study characterizing the carbon isotope composition of similar low molecular weight intermediary organic compounds (Socki, et al, American Geophysical Union Fall meeting, Abstr. #V51B-2189, Dec., 2010). Our hydrogen isotope measurements utilize a unique analytical technique combining Pyrolysis-Gas Chromatograph-Mass Spectrometry-High Temperature Conversion-Isotope Ratio Mass Spectrometry (Py-GC-MS-TC-IRMS). Our technique is unique in that it carries a split of the pyrolyzed GC-separated product to a Thermo DSQ-II? quadrupole mass spectrometer as a means of making qualitative and semi-quantitative compositional measurements of separated organic compounds, therefore both chemical and isotopic measurements can be carried out simultaneously on the same sample.

Socki, Richard A.↗
NASA NTRS1994

Bench-scale synthesis of nanoscale materials

A novel flow-through hydrothermal method used to synthesize nanoscale powders is introduced by Pacific Northwest Laboratory. The process, Rapid Thermal Decomposition of precursors in Solution (RTDS), uniquely combines high-pressure and high-temperature conditions to rapidly form nanoscale particles. The RTDS process was initially demonstrated on a laboratory scale and was subsequently scaled up to accommodate production rates attractive to industry. The process is able to produce a wide variety of metal oxides and oxyhydroxides. The powders are characterized by scanning and transmission electron microscopic methods, surface-area measurements, and x-ray diffraction. Typical crystallite sizes are less than 20 nanometers, with BET surface areas ranging from 100 to 400 sq m/g. A description of the RTDS process is presented along with powder characterization results. In addition, data on the sintering of nanoscale ZrO2 produced by RTDS are included.

Buehler, M. F.↗
NASA NTRS1999

Formation of Amino Acid Thioesters for Prebiotic Peptide Synthesis: Catalysis By Amino Acid Products

The origin of life can be described as a series of events in which a prebiotic chemical process came increasingly under the control of its catalytic products. In our search for this prebiotic process that yielded catalytic takeover products (such as polypeptides), we have been investigating a reaction system that generates peptide-forming amino acid thioesters from formaldehyde, glycolaldehyde, and ammonia in the presence of thiols. As shown below, this model process begins by aldol condensation of formaldehyde and glycolaldehyde to give trioses and releases. These sugars then undergo beta-dehydration yielding their respective alpha-ketoaldehydes. Addition of ammonia to the alpha-ketoaldehydes yields imines which can either: (a) rearrange in the presence of thesis to give amino acid thioesters or (be react with another molecule of aldehyde to give imidazoles. This 'one-pot' reaction system operates under mild aqueous conditions, and like modem amino acid biosynthesis, uses sugar intermediates which are converted to products by energy-yielding redox reactions. Recently, we discovered that amino acids, such as the alanine reaction product, catalyze the first and second steps of the process. In the presence of ammonia the process also generates other synthetically useful products, like the important biochemical -- pyruvic acid.

Weber, Arthur L.↗
NASA NTRS2006

Miniature Arcs for Synthesis of Carbon Nanotubes in Microgravity

Although many methods are available for producing single-walled carbon nanotubes (SWNTs), the conventional carbon arc process remains the most popular due to its simplicity and large production rate. In the carbon arc, SWNTs are catalytically synthesized by rapidly evaporating a graphite anode impregnated with NiN metal catalyst from which the nanotubes grow in an inert atmosphere. However, high temperatures inside the carbon arc generate strong buoyancy driven convection, and it is hypothesized that the non-uniform environment created by this flow has a large effect on the growth and morphology of the SWNTs. To study the effect of buoyancy on the arc process, a miniature carbon arc apparatus was developed to synthesize SWNTs in a microgravity environment substantially free from these strong convective flows. The reactor was operated for either 2.2 or 5 seconds during free-fall in the drop towers at the NASA Glenn Research Center. Two apparatus designs differing mainly in their production rate and power capacity were investigated. The first consisted of a miniaturized carbon arc employing a 1 mm diameter graphite anode and powered by a 0.54 F capacitor bank charged to 65 V. The second, larger apparatus employed a 4 mm diameter anode and was powered by a portable battery pack capable of providing in excess of 300 amps at 30 volts to the arc for the duration of a 5 second drop. Initial results indicated that transient heating is a very large effect in the short-duration drop tower carbon arcs, and thermal equilibrium of the arc plasma, buffer gas, and apparatus was not attained during the short microgravity periods. In addition, removal of the buoyant convection by the microgravity now allowed clear observation of large jets of evaporated carbon vapor streaming from the anode and mixing with the inert buffer gas. The initial mixing of these jets with the cold buffer gas combined with the thermal transient made it difficult to establish a uniform high temperature environment around the arc in the 2.1 to 5 second microgravity time interval, and even with a very high-powered arc, the arc region was cooler than in continuously operated arcs. Despite these difficulties, the miniature arc produced SWNTs in microgravity. However, given the large thermal transient to overcome, no dramatic difference in sample yield or composition was noted between normal gravity and q2-,andL%econd long microgravity runs.

Alford, J. M.↗
NASA NTRS1986

Feedback maximization

Consideration is given to synthesis methods for feedback systems with nonlinear dynamic compensation, which permits increased feedback while preserving robustness, global stability, good transient responses, and stability of the output processes. Material needed for the realization of design goals from the areas of linear systems, nonlinear oscillation, and stability of nonlinear systems is covered. The three main parts of the book are: (1) linear feedback systems, (2) nonlinear feedback system analysis, and (3) synthesis methods for globally stable Nyquist-stable feedback systems with increased feedback.

Lurie, B. J.↗
NASA NTRS1982

Prebiotic organic matter - Possible pathways for synthesis in a geological context

Models for the accretion of the earth, core formation, differentiation of the planet into core, mantle, crust, and atmosphere, and prebiotic synthesis of organic materials are reviewed. The development of the Haldane-Oparin and Urey models is traced, and the effect of accretion time on the outgassing process and the composition of the consequent atmosphere is examined. Model prebiotic atmospheres are calculated, the extent of equilibration of the primitive atmosphere is studied and the evolution of the atmosphere prior to organic chemical evolution is reviewed. Finally, experimental progress in synthesis of biological monomers and polymers under presumed early earth conditions is covered.

Chang, S.↗