Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Spectrum Accountability”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 541 records · Page 30
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

A cryogenic white light absorption spectroscopy setup with in situ gamma irradiation and thermo-optical annealing for optical fiber radiation-induced attenuation characterization

Silica optical fiber sensors offer a fast, distributed measurement solution in various cryogenic and radiation environments, such as magnets for fusion power. Under these conditions, light-absorbing point defects limit lifetime via radiation-induced attenuation (RIA). To support RIA kinetics prediction, we present an in situ, broadband absorption spectroscopy setup combining gamma irradiation with liquid nitrogen cooling. The apparatus enables continuous monitoring of narrowband RIA levels and the use of secondary optical annealing light sources, alongside broadband spectrum measurements to characterize RIA defects through spectrum decomposition. Initial results confirm the inevitable photobleaching effect of the probe light source, which must be accounted for. In addition, we report RIA kinetics during cycles of gamma irradiation at 77 K and isochronal thermal annealing steps from liquid nitrogen to room temperature, showcasing the setup’s ability to replicate real fiber operation scenarios. These instruments form an ideal platform to further study the kinetics of RIA coupled with thermal and optical annealing.

Absorption spectroscopy↗
DOE OSTI2015

Effect of noncircularity of experimental beam on CMB parameter estimation

Measurement of Cosmic Microwave Background (CMB) anisotropies has been playing a lead role in precision cosmology by providing some of the tightest constrains on cosmological models and parameters. However, precision can only be meaningful when all major systematic effects are taken into account. Non-circular beams in CMB experiments can cause large systematic deviation in the angular power spectrum, not only by modifying the measurement at a given multipole, but also introducing coupling between different multipoles through a deterministic bias matrix. Here we add a mechanism for emulating the effect of a full bias matrix to the PLANCK likelihood code through the parameter estimation code SCoPE. We show that if the angular power spectrum was measured with a non-circular beam, the assumption of circular Gaussian beam or considering only the diagonal part of the bias matrix can lead to huge error in parameter estimation. We demonstrate that, at least for elliptical Gaussian beams, use of scalar beam window functions obtained via Monte Carlo simulations starting from a fiducial spectrum, as implemented in PLANCK analyses for example, leads to only few percent of sigma deviation of the best-fit parameters. However, we notice more significant differences in the posterior distributions for some of the parameters, which would in turn lead to incorrect errorbars. These differences can be reduced, so that the errorbars match within few percent, by adding an iterative reanalysis step, where the beam window function would be recomputed using the best-fit spectrum estimated in the first step.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

DUST FORMATION IN MACRONOVAE

We examine dust formation in macronovae (as known as kilonovae), which are the bright ejecta of neutron star binary mergers and one of the leading sites of r-process nucleosynthesis. In light of information about the first macronova candidate associated with GRB 130603B, we find that dust grains of r-process elements have difficulty forming because of the low number density of the r-process atoms, while carbon or elements lighter than iron can condense into dust if they are abundant. Dust grains absorb emission from ejecta with an opacity even greater than that of the r-process elements, and re-emit photons at infrared wavelengths. Such dust emission can potentially account for macronovae without r-process nucleosynthesis as an alternative model. This dust scenario predicts a spectrum with fewer features than the r-process model and day-scale optical-to-ultraviolet emission.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1973

The effect of Fe I absorption on the Mg II emission at 2795 A in alpha Orionis

The Fe I absorption line at 2795.01 A is derived from the observations of Mg II resonance emission in alpha Orionis by Kondo et al (1972). A spectrum is synthesized, including Mg II emission and self-absorption and also Fe I absorption, which accounts for the observed asymmetry in the Mg II 2795.5 line and for the discrepancy between the theoretical and observed intensity ratios of the two Mg II lines. The astrophysical significance of this strong Fe I absorption is discussed.

Modisette, J. L.↗
NASA NTRS1974

Proton tissue dose for the blood forming organ in human geometry: Isotropic radiation

A computer program is described which calculates doses averaged within five major segments of the blood forming organ in the human body taking into account selfshielding of the detailed body geometry and nuclear star effects for proton radiation of arbitrary energy spectrum (energy less than 1 GeV) and isotropic angular distribution. The dose calculation includes the first term of an asymptotic series expansion of transport theory which is known to converge rapidly for most points in the human body. The result is always a conservative estimate of dose and is given as physical dose (rad) and dose equivalent (rem).

Khandelwal, G. S.↗
NASA NTRS1987

Generation of high-frequency broadband electrostatic noise - The role of cold electrons

Broadband electrostatic noise (BEN) is commonly observed in the plasma sheet boundary layer in association with ion beams. The generation of these waves in a plasma consisting of an ion beam and a background of hot ions, hot electrons, and cold electrons is investigated. The cold electrons are of ionospheric origin. A complete, systematic study of electrostatic ion beam instabilities, including cold electrons, has been done, and it is shown that for the plasma configuration described, four instabilities can be excited: (1) ion acoustic, (2) Buneman, (3) beam resonant, and (4) electron acoustic instabilities. A low and high beam temperature division is shown to exist that separates when different instabilities can be excited. For typically observed parameters in the plasma sheet boundary layer, the ion beams lie in the high-temperature regime. In this regime, the beam resonant and electron acoustic instabilities are excited, and these instabilities can account for the high-frequency (higher than 500 Hz), low-power portion of the BEN spectrum. In the absence of cold electrons, no such wave growth occurs.

Schriver, David↗
NASA NTRS2002

Experimental Feedback Control of Flow Induced Cavity Tones

An experimental study of the application of discrete-time, linear quadratic control design methods to the cavity tone problem is described. State space models of the dynamics from a synthetic jet actuator at the leading edge of the cavity to two pressure sensors in the cavity were computed from experimental data. Variations in model order, control order, control bandwidth, and properties of a Kalman state estimator were studied. Feedback control reduced the levels of multiple cavity tones at Mach 0.275, 0.35, and 0.45. Closed loop performance was often limited by excitation of sidebands of cavity tones, and creation of new tones in the spectrum. State space models were useful for explaining some of these limitations, but were not able to account for non-linear dynamics, such as interactions between tones at different frequencies.

Cabell, Randolph H.↗
NASA NTRS2020

Chandra and XMM-Newton Observations of A2256: Cold Fronts, Merger Shocks, and Constraint on the IC Emission

We present the results of deep Chandra and XMM-Newton observations of a complex merging galaxy cluster Abell 2256 (A2256) that hosts a spectacular radio relic (RR). The temperature and metallicity maps show clear evidence of a merger between the western subcluster (SC) and the primary cluster (PC). We detect five X-ray surface brightness edges. Three of them near the cluster center are cold fronts (CFs): CF1 is associated with the infalling SC; CF2 is located in the east of the PC; and CF3 is to the west of the PC core. The other two edges at cluster outskirts are shock fronts(SFs): SF1 near the RR in the NW has Mach numbers derived from the temperature and the density jumps, respectively, of MT=1.62±0.12 and Mρ=1.23±0.06; SF2 in the SE has MT=1.54±0.05 and Mρ=1.16±0.13. In the region of the RR, there is no evidence for the correlation between X-ray and radio substructures, from which we estimate an upper limit for the inverse-Compton emission, and therefore set a lower limit on the magnetic field (∼450 kpc from PC center) of B>1.0μG for a single power-law electron spectrum or B>0.4μG for a broken power-law electron spectrum. We propose a merger scenario including a PC, an SC, and a group. Our merger scenario accounts for the X-ray edges, diffuse radio features, and galaxy kinematics, as well as projection effects.

Chong Ge↗
NASA NTRS2020

Chandra and XMM-Newton Observations of A2256: Cold Fronts, Merger Shocks, and Constraint on the IC Emission

We present the results of deep Chandra and XMM-Newton observations of a complex merging galaxy cluster Abell 2256 (A2256) that hosts a spectacular radio relic (RR).The temperature and metallicity maps show clear evidence of a merger between the western subcluster (SC) and the primary cluster (PC). We detect five X-ray surface brightness edges. Three of them near the cluster center are cold fronts (CFs): CF1is associated with the infalling SC; CF2 is located in the east of the PC; and CF3 is to the west of the PC core. The other two edges at cluster outskirts are shock fronts(SFs): SF1 near the RR in the NW has Mach numbers derived from the temperature and the density jumps, respectively, of MT=1.62±0.12andMρ=1.23±0.06; SF2 in the SE has MT=1.54±0.05andMρ=1.16±0.13. In the region of the RR, there is no evidence for the correlation between X-ray and radio substructures, from which we estimate an upper limit for the inverse-Compton emission, and therefore set a lower limit on the magnetic field (∼450 kpc from PC center) of B>1.0μG for a single power-law electron spectrum or B>0.4μG for a broken power-law electron spectrum. We propose a merger scenario including a PC, an SC, and a group. Our merger scenario accounts for the X-ray edges, diffuse radio features, and galaxy kinematics, as well as projection effects.

Chong Ge↗
DOE OSTI2016

Technical Note: SPEKTR 3.0—A computational tool for x-ray spectrum modeling and analysis

Purpose: A computational toolkit (SPEKTR 3.0) has been developed to calculate x-ray spectra based on the tungsten anode spectral model using interpolating cubic splines (TASMICS) algorithm, updating previous work based on the tungsten anode spectral model using interpolating polynomials (TASMIP) spectral model. The toolkit includes a MATLAB (The Mathworks, Natick, MA) function library and improved user interface (UI) along with an optimization algorithm to match calculated beam quality with measurements. Methods: The SPEKTR code generates x-ray spectra (photons/mm{sup 2}/mAs at 100 cm from the source) using TASMICS as default (with TASMIP as an option) in 1 keV energy bins over beam energies 20–150 kV, extensible to 640 kV using the TASMICS spectra. An optimization tool was implemented to compute the added filtration (Al and W) that provides a best match between calculated and measured x-ray tube output (mGy/mAs or mR/mAs) for individual x-ray tubes that may differ from that assumed in TASMICS or TASMIP and to account for factors such as anode angle. Results: The median percent difference in photon counts for a TASMICS and TASMIP spectrum was 4.15% for tube potentials in the range 30–140 kV with the largest percentage difference arising in the low and high energy bins due to measurement errors in the empirically based TASMIP model and inaccurate polynomial fitting. The optimization tool reported a close agreement between measured and calculated spectra with a Pearson coefficient of 0.98. Conclusions: The computational toolkit, SPEKTR, has been updated to version 3.0, validated against measurements and existing models, and made available as open source code. Video tutorials for the SPEKTR function library, UI, and optimization tool are available.

60 APPLIED LIFE SCIENCES↗
NASA NTRS1986

Investigation of seasonal variability of the wind stress curl over the North Atlantic Ocean by means of empirical orthogonal function analysis

The seasonal variability of the wind stress curl over the North Atlantic is investigated by means of empirical orthogonal function (EOF) analysis. The curl field is calculated from 1 year of First Global GARP Experiment wind data. It was found that 44 percent of the variability is contained in four significant eigenvectors. Their spatial patterns are characterized by basin-sized oscillations with larger amplitude to the north of 40 deg N. Their associated time series coefficients have the highest amplitude during the winter and show a tendency toward a white frequency spectrum which nevertheless exhibits noticeable peaks or gaps at certain frequencies. Physically, the first EOF is seen as the seasonal fluctuations of the mean wind stress curl pattern. Five other eigenvectors are also found to be above the noise level, but they account for only a smaller percentage of variability (19 percent). They are characterized by smaller spatial scales than the basin size. Their time series coefficients show a whiter frequency spectrum.

Barnier, B.↗
DOE OSTI2015

Communication: Does a single CH{sub 3}CN molecule attached to Ru(bipy){sub 3}{sup 2+} affect its absorption spectrum?

Tris(bipyridine)ruthenium(II) (Ru(bipy){sub 3}{sup 2+}) is a prototypical transition metal coordination complex whose photophysical properties have attracted considerable attention. A much debated issue is whether the metal-to-ligand charge transfer (MLCT) transition that accounts for the complex’s beautiful red color is fully delocalized across all three bipyridine ligands or located on just one ligand. Here, we show based on gas-phase action spectroscopy that attachment of a single acetonitrile molecule does not change the absorption spectrum from that of the bare ions, which is indicative of a delocalized state. However, the gas-phase spectra of the bare and one solvent molecule complexes are significantly blueshifted relative to that obtained in bulk acetonitrile, which suggests that in solution the polarizability of many solvent molecules working together can localize the MLCT state. Our data clearly show that more than one solvent molecule is needed to break the symmetry of the MLCT excited state and reproduce its solution-phase characteristics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1980

The rings of Saturn - New near-infrared reflectance measurements and a 0.326-4.08 micron summary

A new high-photometric-precision reflectance spectrum of Saturn's rings covering the spectral region 0.65 to 2.5 microns is presented and three previously unreported absorption features at 1.25, 0.85, and probably 1.04 microns are identified. The 1.25- and 1.04 micron absorptions are due to water ice. The 0.85 microns feature may be due to a combination of 0.81- and 0.90 micron ice absorptions but this feature appears too strong relative to the 1.04 micron band to be completely explained by water ice. Another possibility is that the 0.85 micron band is due to Fe(3+)-bearing minerals in an ice-mineral mixture. This explanation could also account for the drop in the visible and ultraviolet reflectance and the rise in reflectance around 3.6 microns. Finally, a composite spectrum from 0.325 to 4.08 is presented which will be useful for future analysis and laboratory studies.

Clark, R. N.↗
DOE OSTI2023

Demographic Microsimulator for Integrated Urban Systems: Adapting Panel Survey of Income Dynamics to Capture the Continuum of Life

Agent-based models (ABMs) simulate activity and travel decisions at the disaggregate level of households, and individuals. To do this, ABMs require detailed information pertaining to socioeconomic and demographic characteristics of individuals. Various synthetic population generators (SPGs) have been proposed to address this need. However, most of the SPGs currently in practice are cross-sectional in nature, and do not account for the interrelationships among household's or individual's life progression. This is a major shortcoming of SPGs as literature has shown that transportation decisions are impacted by lifecycle events that unfold over a span of time. While some demographic evolution simulators have been proposed to address this shortcoming, they: i) are developed using cross-sectional data, ii) do not capture the full spectrum of lifecycle events and their interdependency. Overcoming these drawbacks, this paper proposes a Demographic Microsimulator (DEMOS) which captures the 'continuum of life' by accounting for a range of household-, and individual-level lifecycle events. DEMOS is developed using the Panel Survey of Income Dynamics, which is one of the world's longest running longitudinal surveys. DEMOS sub-models consider key lifecycle events which are influenced by a host of demographic variables. The whole framework is applied to evolve the population of San Francisco Bay Area over a 9-year horizon. Results indicate that the household and individual evolution are tightly connected, and that the structural framework (i.e., model sequencing) is a key element in capturing the population trend accurately.

ADVANCED PROPULSION SYSTEMS,ENERGY PLANNING, POLIC↗
DOE OSTI2017

Optical analysis of nanoparticle packing after drying in microdroplets

The optical spectra of nanostructured patterns with different degrees of order, obtained by dehydration self-assembly of nanoparticles in solution microdroplets placed on a planar substrate, have been analyzed. The reflectance spectrum of the best-ordered pattern contains a characteristic peak, the position of which is determined by the average lattice period in the layer. It is shown that the height of this peak depends on the degree of order of the pattern structure. Patterns with different degrees of order have been simulated using a software for modeling the self-assembly process, which takes into account the properties of particles, substrate, and solvent, as well as the contact line dynamics during solvent evaporation. A peak occurs in the reflectance spectrum due to the resonance Rayleigh scattering in the ordered layer. The described technique for optical diagnostics can be used to analyze the degree of particle order in a pattern.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

A flavor of SO(10) unification with a spinor Higgs

We investigate Higgs Parity unification — a realization of SO(10) grand unification based on the Higgs Parity mechanism in which the Standard Model (SM) Higgs resides in a spinor representation. The theory has an intermediate left-right symmetric stage where the SU(2)R symmetry breaking scale is fixed by the vanishing of the SM Higgs quartic coupling. The strong CP problem is solved by parity. Gauge coupling unification successfully predicts αs(MZ) to within 1%. The spinor Higgs naturally leads to a seesaw origin for SM flavor observables. We identify a novel mechanism where large mixing of third generation fermions with additional heavy vector-like fermions accounts for the anarchical nature of the PMNS matrix and the lack of hierarchy in the neutrino mass spectrum, relative to the up-quarks. A fit to quark and lepton masses and mixings, with a minimal parameter set, predicts 1) A testable relation between the top quark mass and αs(MZ) which is about (1 – 2)σ from current best fit values, 2) The order of magnitude of the baryon asymmetry of the universe, via leptogenesis from second-generation right-handed neutrino decays. 3) The proton decay and the neutron EDM are likely observable in next generation experiments, and 4) A normal ordered neutrino mass spectrum where 0νββ decay and the mass of the lightest neutrino are out of reach of next generation experiments.

Baryo-and Leptogenesis↗
DOE OSTI2023

MnEdgeNet for accurate decomposition of mixed oxidation states for Mn XAS and EELS L2,3 edges without reference and calibration

Accurate decomposition of the mixed Mn oxidation states is highly important for characterizing the electronic structures, charge transfer and redox centers for electronic, and electrocatalytic and energy storage materials that contain Mn. Electron energy loss spectroscopy (EELS) and soft X-ray absorption spectroscopy (XAS) measurements of the Mn L2,3 edges are widely used for this purpose. To date, although the measurements of the Mn L2,3 edges are straightforward given the sample is prepared properly, an accurate decomposition of the mix valence states of Mn remains non-trivial. For both EELS and XAS, 2+, 3+, and 4+ reference spectra need to be taken on the same instrument/beamline and preferably in the same experimental session because the instrumental resolution and the energy axis offset could vary from one session to another. To circumvent this hurdle, in this study, we adopted a deep learning approach and developed a calibration-free and reference-free method to decompose the oxidation state of Mn L2,3 edges for both EELS and XAS. A deep learning regression model is trained to accurately predict the composition of the mix valence state of Mn. To synthesize physics-informed and ground-truth labeled training datasets, we created a forward model that takes into account plural scattering, instrumentation broadening, noise, and energy axis offset. With that, we created a 1.2 million-spectrum database with 1-by-3 oxidation state composition ground truth vectors. The library includes a sufficient variety of data including both EELS and XAS spectra. By training on this large database, our convolutional neural network achieves 85% accuracy on the validation dataset. We tested the model and found it is robust against noise (down to PSNR of 10) and plural scattering (up to t/λ = 1). We further validated the model against spectral data that were not used in training. In particular, the model shows high accuracy and high sensitivity for the decomposition of Mn 3 O 4 , MnO, Mn 2 O 3 , and MnO 2 . The accurate decomposition of Mn 3 O 4 experimental data shows the model is quantitatively correct and can be deployed for real experimental data. Our model will not only be a valuable tool to researchers and material scientists but also can assist experienced electron microscopists and synchrotron scientists in the automated analysis of Mn L edge data.

25 ENERGY STORAGE↗
DOE OSTI2019

Fermi bubbles from stochastic acceleration of electrons in a Galactic outflow

The discovery of the Fermi bubbles – a huge bilobular structure seen in GeV gamma-rays above and below the Galactic centre – implies the presence of a large reservoir of high energy particles at ~10 kpc from the disk. The absence of evidence for a strong shock coinciding with the edge of the bubbles, and constraints from multi-wavelength observations point towards stochastic acceleration by turbulence as a likely mechanism of acceleration. We have studied the time-dependent acceleration of electrons in a large-scale outflow from the Galactic centre. For the first time, we propose a detailed numerical solution of the particle kinetic equation that includes the acceleration, transport and relevant energy loss processes. We also take into account the addition of shock acceleration of electrons at the bubble’s blast wave. Fitting to the observed spectrum and surface brightness distribution of the bubbles allows determining the transport coefficients, thereby shedding light on the origin of the Fermi bubbles.

43 PARTICLE ACCELERATORS↗