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Limits on the density of neutral gas within 100 parsecs from observations of the soft X-ray background

Observations are presented in two soft X-ray bands, the Be band (0.077-0.111 keV) and the B-prime (0.105-0.188 keV), for nine directions in the sky. The ratio of count rates in these two bands remains constant as the rates vary by a factor of three, even though the effective interstellar absorption cross sections in the bands differ by a factor of about 3.5. For a model in which the bulk of the observed soft X-ray emission originates in a uniform low-density region surrounding the sun, the constant ratio between the band rates places an upper limit on the amount of neutral material that can be homogeneously mixed with the X-ray-emitting gas. The 2 sigma upper limit on the H I column density over an average path through the local emitting region is 6.6 x 10 to the 18th/sq cm. If the average path length is about 100 pc, then clouds similar to the one in which the sun is embedded could still have a filling factor as large as 25 percent.

Juda, M.↗

Friction Velocity Estimation Using Dual-Frequency Altimeter Data

Global estimation of wind speeds near the sea-surface can be obtained using normalized radar cross sections sigma(o) from satellite-borne single-frequency altimeters. Indeed recent validation studies of Geosat altimeter-derived wind speeds show that several often cited semiempirical algorithms yield linear trends between wind-speeds from altimeter data and wind speeds from (a) ships of opportunity (Etcheto 1992), (b) buoys (Carter 1992), and (c) atmospheric models (Guillaume 1992). Although the linear trends are striking, there is considerable scatter since the range of standard deviations is from 1.5 to 3 m/s. In fact, the scatter of some particular measurements about the regressions is striking because they depart from the 'standard' by as much as +/- 5 m/s, which is large - even for full gale winds of 20 m/s. These anomalies can cause serious problems for gas exchange, heat, and aerosol estimates. They can also induce considerable errors in wind-driven oceanic circulation models and sea-surface wave models. This paper explores the possibility of improving the accuracy of wind speed estimation using dual-frequency altimeters.

Bliven, Larry F.↗

The 2010 May Flaring Episode of Cygnus X-3 in Radio, X-Rays, and gamma-Rays

In 2009, Cygnus X-3 (Cyg X-3) became the first microquasar to be detected in the GeV gamma-ray regime, via the satellites Fermi and AGILE. The addition of this new band to the observational toolbox holds promise for building a more detailed understanding of the relativistic jets of this and other systems. We present a rich dataset of radio, hard and soft X-ray, and gamma-ray observations of Cyg X-3 made during a flaring episode in 2010 May. We detect a approx.3-d softening and recovery of the X-ray emission, followed almost immediately by a approx.1-Jy radio flare at 15 GHz, followed by a 4.3sigma gamma-ray flare (E > 100 MeV) approx.1.5 d later. The radio sampling is sparse, but we use archival data to argue that it is unlikely the gamma-ray flare was followed by any significant unobserved radio flares. In this case, the sequencing of the observed events is difficult to explain in a model in which the gamma-ray emission is due to inverse Compton scattering of the companion star's radiation field. Our observations suggest that other mechanisms may also be responsible for gamma-ray emission from Cyg X-3.

Williams, Peter K. G.↗

The Isothermal Dendritic Growth Experiment (IDGE)

The Isothermal Dendritic Growth Experiment (IDGE) constituted a series of three NASA-supported microgravity experiments, all of which flew aboard the space shuttle, Columbia. This experimental space flight series was designed and operated to grow and record dendrite solidification in the absence of gravity-induced convective heat transfer, and thereby produce a wealth of benchmark-quality data for testing solidification scaling laws. The data and analysis performed on the dendritic growth speed and tip size in Succinontrie (SCN) demonstrates that although the theory yields predictions that are reasonably in agreement with experiment, there are significant discrepancies. However, some of these discrepancies can be explained by accurately describing the diffusion of heat. The key finding involves recognition that the actual three-dimensional shape of dendrites includes time-dependent side-branching and a tip region that is not a paraboloid of revolution. Thus, the role of heat transfer in dendritic growth is validated, with the caveat that a more realistic model of the dendrite then a paraboloid is needed to account for heat flow in an experimentally observed dendrite. We are currently conducting additional analysis to further confirm and demonstrate these conclusions. The data and analyses for the growth selection physics remain much less definitive. From the first flight, the data indicated that the selection parameter, sigma*, is not exactly a constant, but exhibits a slight dependence on the supercooling. Additional data from the second flight are being examined to investigate the selection of a unique dendrite speed, tip size and shape. The IDGE flight series is now complete. We are currently completing analyses and moving towards final data archiving. It is gratifying to see that the IDGE published results and archived data sets are being used actively by other scientists and engineers. In addition, we are also pleased to report that the techniques and IDGE hardware system that the authors developed with NASA, are being currently employed on both designated flight experiments, like EDSE, and on flight definition experiments, like TDSE.

Glicksman, Martin E.↗

Tracking Data Certification for the Lunar Reconnaissance Orbiter

This paper details the National Aeronautics and Space Administration (NASA) Goddard Space Flight Center (GSFC) Flight Dynamics Facility (FDF) tracking data certification effort of the Lunar Reconnaissance Orbiter (LRO) Space Communications Network (SCN) complement of tracking stations consisting of the NASA White Sands 1 antenna (WS1), and the commercial provider Universal Space Network (USN) antennas at South Point, Hawaii; Dongara Australia; Weilheim, Germany; and Kiruna, Sweden. Certification assessment required the cooperation and coordination of parties not under the control of either the LRO project or ground stations as uplinks on cooperating spacecraft were necessary. The LRO range-tracking requirement of 10m 1 sigma could be satisfactorily demonstrated using any typical spacecraft capable of range tracking. Though typical Low Earth Orbiting (LEO) or Geosynchronous Earth Orbiting (GEO) spacecraft may be adequate for range certification, their measurement dynamics and noise would be unacceptable for proper Doppler certification of 1-3mm/sec 1 sigma. As LRO will orbit the Moon, it was imperative that a suitable target spacecraft be utilized which can closely mimic the expected lunar orbital Doppler dynamics of +/-1.6km/sec and +/-1.5m/sq sec to +/-0.15m/sq sec, is in view of the ground stations, supports coherent S-Band Doppler tracking measurements, and can be modeled by the FDF. In order to meet the LRO metric tracking data specifications, the SCN ground stations employed previously uncertified numerically controlled tracking receivers. Initial certification testing revealed certain characteristics of the units that required resolution before being granted certification.

Morinelli, Patrick J.↗

The 2006 Cape Canaveral Air Force Station Range Reference Atmosphere Model Validation Study and Sensitivity Analysis to the National Aeronautics and Space Administration's Space Shuttle

NASA's Space Shuttle utilizes atmospheric thermodynamic properties to evaluate structural dynamics and vehicle flight performance impacts by the atmosphere during ascent. Statistical characteristics of atmospheric thermodynamic properties at Kennedy Space Center (KSC) used in Space. Shuttle Vehicle assessments are contained in the Cape Canaveral Air Force Station (CCAFS) Range Reference Atmosphere (RRA) Database. Database contains tabulations for monthly and annual means (mu), standard deviations (sigma) and skewness of wind and thermodynamic variables. Wind, Thermodynamic, Humidity and Hydrostatic parameters 1 km resolution interval from 0-30 km 2 km resolution interval 30-70 km Multiple revisions of the CCAFS RRA database have been developed since initial RRA published in 1963. 1971, 1983, 2006 Space Shuttle program utilized 1983 version for use in deriving "hot" and "cold" atmospheres, atmospheric density dispersions for use in vehicle certification analyses and selection of atmospheric thermodynamic profiles for use in vehicle ascent design and certification analyses. During STS-114 launch preparations in July 2005 atmospheric density observations between 50-80 kft exceeded density limits used for aerodynamic ascent heating constraints in vehicle certification analyses. Mission specific analyses were conducted and concluded that the density bias resulted in small changes to heating rates and integrated heat loading on the vehicle. In 2001, the Air Force Combat Climatology Center began developing an updated RRA for CCAFS.

Decker, Ryan↗

Theoretical study of the dissociation energy and the red and violet band systems of CN

The dissociation energy (D sub O) of CN is determined to be 7.65 + or - 0.06 eV. This corresponds to delta H sub f (CN) = 105.3 + or - 1.5 kcal/mole, in excellent agreement with Engleman and Rouse (1975), but considerably larger than the recent value deduced from shock-tube studies by Colket (1984). The result is obtained not only from extensive ab initio MRCI calculations using a very large Gaussian basis set, but also from extrapolation of the directly computed value by comparison of computed and experimental results fo NO, C2, and N2. As an additional calibration of the methods, the D sub O value for CN was computed from the corresponding value for CN(-) using the experimental electron affinity data. The lifetime of the nu prime = 0 level of the violet (B 2 sigma + yields X 2 sigma +) system was computed to be 62.4 ns, in good agreement with both experiment and previous calculations. Lifetimes for the red (A 2 pi yields X 2 sigma +) system decrease with increasing nu prime, which is consistent both with the recent experiment and calculations. While the computed lifetimes are significantly longer that those obtained from the experiment, they are shorter than those deduced from an analysis of the solar spectrum. However the D sub O and f (sub OO) are consistent with Lambert's model for the solar spectrum.

Bauschlicher, Charles W., Jr.↗

Comparing Consider-Covariance Analysis with Sigma-Point Consider Filter and Linear-Theory Consider Filter Formulations

Recent literature in applied estimation theory reflects growing interest in the sigma-point (also called unscented ) formulation for optimal sequential state estimation, often describing performance comparisons with extended Kalman filters as applied to specific dynamical problems [c.f. 1, 2, 3]. Favorable attributes of sigma-point filters are described as including a lower expected error for nonlinear even non-differentiable dynamical systems, and a straightforward formulation not requiring derivation or implementation of any partial derivative Jacobian matrices. These attributes are particularly attractive, e.g. in terms of enabling simplified code architecture and streamlined testing, in the formulation of estimators for nonlinear spaceflight mechanics systems, such as filter software onboard deep-space robotic spacecraft. As presented in [4], the Sigma-Point Consider Filter (SPCF) algorithm extends the sigma-point filter algorithm to the problem of consider covariance analysis. Considering parameters in a dynamical system, while estimating its state, provides an upper bound on the estimated state covariance, which is viewed as a conservative approach to designing estimators for problems of general guidance, navigation and control. This is because, whether a parameter in the system model is observable or not, error in the knowledge of the value of a non-estimated parameter will increase the actual uncertainty of the estimated state of the system beyond the level formally indicated by the covariance of an estimator that neglects errors or uncertainty in that parameter. The equations for SPCF covariance evolution are obtained in a fashion similar to the derivation approach taken with standard (i.e. linearized or extended) consider parameterized Kalman filters (c.f. [5]). While in [4] the SPCF and linear-theory consider filter (LTCF) were applied to an illustrative linear dynamics/linear measurement problem, in the present work examines the SPCF as applied to nonlinear sequential consider covariance analysis, i.e. in the presence of nonlinear dynamics and nonlinear measurements. A simple SPCF for orbit determination, exemplifying an algorithm hosted in the guidance, navigation and control (GN&C) computer processor of a hypothetical robotic spacecraft, was implemented, and compared with an identically-parameterized (standard) extended, consider-parameterized Kalman filter. The onboard filtering scenario examined is a hypothetical spacecraft orbit about a small natural body with imperfectly-known mass. The formulations, relative complexities, and performances of the filters are compared and discussed.

Lisano, Michael E.↗

Decreasing Proton Single Event Effects in CubeSats with Shielding

Shields-1, NORAD ID 43850,has been operating in polar low earth orbit since December 2018. The shielding has resulted in a lower total ionizing dose over time than typical aluminum thin-walled CubeSat structures. The reduced ionizing dosage caused by Shields-1 increases the reliability of commercial parts and reduces internal charging. Furthermore, the Shields-1 shielding reduces the ionizing particle fluence inside the spacecraft that contributes to the ionizing dose. NOVICE Sigma shielding software, using the (Aerospace Proton) AP8 –(Aerospace Electron) AE8 solar minimum trapped belt environment for a 1-year mission, estimates a 21.3 g/cm2 aluminum effective shielding for the Shields-1 electronics enclosure. This high areal density reduces not only the total number of energetic protons, but also reduces the number of ionizing particles over all modeled energies from the estimated shielded fluence for a 1-year mission. NOVICE Adjoint CAD modeling of the Shields-1 structure, with the detector located within the electronics enclosure, estimates that the total number of particles is reduced from 2.20x 10exp9 protons/cm2 to 1.52x 10exp8 protons/cm2, which represents 6.90% of the remaining particles(figure 1). By slowing down approximations of the integral proton fluence, a minimum proton threshold is estimated at 151 MeV. In comparison, a 0.204-cm aluminum thin-walled 3-unit (U) structure, with a 0.907 g/cm2 effective shielding, has 25.0% remaining particles and a minimum proton threshold of 36.2 MeV(figure 1). Proton energies that contribute to single event effects in radiation tolerant or higher semiconductor hardness are typically 100 MeV and higher. The Shields-1 electronics enclosure is estimated to attenuate energies: 100 MeV by 76.5%, 200 MeV by 61.7%, and 500 MeV by 63.0%(figure 2), when comparing the space environment proton differential fluence with the shielded differential fluence. The aluminum thin-walled structure is estimated to attenuate proton energies: 100 MeV by 13.7%, 200 MeV by 12.4%, and 500 MeV by 12.6%(figure 2), which are lower than for the Shields-1 electronics enclosure. The significant differences in attenuation between the Shields-1 electronics enclosure and aluminum thin-walled 3U structure show the additional utility of increasing shielding effectiveness for reducing the numbers of energetic protons that contribute to single event effects.

Larry Thomsen↗

X-ray emission associated with radio galaxies in the Perseus cluster

In this paper, we report on new x-ray observations of the Perseus cluster made using four separate pointings of the Roentgen Satellite (ROSAT) Positron Sensitive Proportional Counter (PSPC). We searched for x-ray emission associated with 16 radio galaxies and detected six above 3 sigma. We made use of the PSPC spectra to determine if the x-ray emission associated with radio galaxies in Perseus is thermal or nonthermal in origin (i.e., hot gas or an active galactic nuclei (AGN)). For the head-tail radio galaxy IC 310, we find that the data are best fit by a power law model with an unusually large spectral index alpha = 2.7. This is consistent with its unresolved spatial structure. On the other hand, a second resolved x-ray source associated with another radio galaxy 2.3 Mpc from the Perseus center (V Zw 331) is best fit by a thermal model. For three sources with insufficient flux for a full spectral analysis, we calculated hardness ratios. On this basis, the x-ray emission associated with the well known head-tail source NGC 1265 is consistent with thermal radiation. The x-ray spectra of UGC 2608 and UGC 2654 probably arise from hot gas, although very steep power-law spectra (alpha greater than 3.2) are also possible. The spectrum of NGC 1275 is quite complex due to the presence of an AGN and the galaxy's location at the center of a cluster cooling flow.

Rhee, George↗

UV Spectral Variability and the Lyman-Alpha Forest in the Lensed Quasar Q0957+561

Far-ultraviolet spectra of the gravitational lens components Q0957+561 A and B were obtained with the Hubble Space Telescope Faint Object Spectrograph (FOS) at five equally spaced epochs, one every two weeks. We confirm the flux variability of the quasar's Lyman-alpha and O VI lambda 1037 emission lines reported in IUE (International Ultraviolet Explorer) spectra. The fluxes in these lines vary on a time scale of weeks in the local rest frame (LRF), independently of each other and of the surrounding continuum. The individual spectra of each image were co-added to investigate the properties of the Lyman-alpha forest along the two lines of sight to the quasar. Absorption lines having equivalent width W (sub lambda) greater than or equal to 0.3 Angstroms in the LRF not previously identified as interstellar lines, metal lines, or higher order Lyman lines were taken to be LY-alpha forest lines. The existence of each line in this consistently selected set was then verified by its presence in two archival FOS spectra with approx. 1.5 times higher signal to noise than our co-added spectra. Ly-alpha forest lines with W (sub lambda) greater than or equal to 0.3 Angstroms appear at 42 distinct wavelengths in the spectra of the two images. Two absorption lines in the spectrum of image A have no counterpart at that wavelength in the spectrum of image B, and two lines in image B have no counterpart in image A. Based on the separation of the lines of sight at the redshift of the absorption lines appearing in only one spectrum, the density of the absorbing clouds in the direction of Q0957+561 must change significantly over a distance of 79 (+34, -26) h (sub 50) (sup -1) kpc in the simplified model where the absorbers are treated as spherical clouds and the characteristic dimension is the radius. (We adopt H (sub 0)= 50 h (sub 50) km s (sup -1) kpc (sup -1), q (sub 0) = 1/2, and LAMBDA = 0 throughout the paper.) The two limits define the 68% confidence interval on the characteristic dimension, equivalent to the 1 sigma confidence interval for a Gaussian distribution. The 95% confidence interval extends from (32 - 250) h (sub 50) (sup -1) kpc. We show in the Appendix that the fraction of Ly-alpha forest lines that appear in only one spectrum can be expressed as a rapidly converging power series in 1/r, where r the ratio of the radius of the cloud to the separation of the two LOS at the redshift of the cloud. This power series can be rewritten to give r in terms of the fraction of Ly-alpha forest wavelengths that appear in the spectrum of only one image. A simple linear approximation to the solution which everywhere agrees with the power series solution to better than 0.8% for r greater than or equal to 2 is derived in the Appendix.

Dolan, J. F.↗

Creep response of the lunar crust in mare regions from an analysis of crater deformation

The settling trends of 318 lunar mare craters are compared with predictions of numerical finite-element models in order to determine the creep response of the upper lunar mare crust. No settling is evident in craters smaller than 5 km in diameter. Settling rates of larger craters increase as function of crater size in a manner suggesting a nonlinear lunar creep response corresponding to the power law epsilon = 8.3 x 10 to the minus 34th sigma squared where epsilon is the strain rate and sigma is the differential stress. However, the observed nonlinearity is probably an apparent nonlinearity resulting from the temperature-induced viscosity decrease with depth due to a lunar crustal temperature gradient of 3 C/km and a creep activation energy of 20 kcal/mole. It is concluded that creep in the lunar medium is essentially Newtonian, and that the effective viscosity of the upper lunar mare is (1.6 plus or minus 0.3) x 10 to the 25th poise.

Kunze, A. W. G.↗

Partitioning of excess energy in the photolysis of cyanogen chloride and cyanogen bromide at 193 nm

The nascent quantum state distributions of CN(X2 Sigma +) fragments produced in the dissociation of ClCN and BrCN by photolysis at 193 nm, in an effusive beam, have been measured. The rotational distribution of the fragments is highly excited. The results show that the excited electronic state which dissociates is bent. A simple parameterization is shown to fit the results. This parameterization is based on a semiclassical model which has dynamical implications.

Halpern, J. B.↗

Influence of Humidity On the Aerosol Scattering Coefficient and Its Effect on the Upwelling Radiance During ACE-2

Aerosol scattering coefficients (sigma(sub sp)) have been measured over the ocean at different relative humidities (RH) as a function of altitude in the region surrounding the Canary Islands during the Second Aerosol Characterization Experiment (ACE-2) in June and July 1997. The data were collected by the University of Washington passive humidigraph (UWPH) mounted on the Pelican research aircraft. Concurrently, particle size distributions, absorption coefficients and aerosol optical depth were measured throughout 17 flights. A parameterization of sigma(sub sp) as a function of RH was utilized to assess the impact of aerosol hydration on the upwelling radiance (normalized to the solar constant and cosine of zenith angle). The top of the atmosphere radiance signal was simulated at wavelengths corresponding to visible and near-infrared bands of the EOS (Earth Observing System) AM-1 (Terra) detectors, MODIS (Moderate Resolution Imaging Spectroradiometer) and MISR (Multi-angle Imaging Spectroradiometer). The UWPH measured sigma(sub sp) at two RHs, one below and the other above ambient conditions. Ambient sigma(sub sp) was obtained by interpolation of these two measurements. The data were stratified in terms of three types of aerosols: Saharan dust, clean marine (marine boundary layer background) and polluted marine aerosols (i.e., two- or one-day old polluted aerosols advected from Europe). An empirical relation for the dependence of sigma(sub sp) on RH, defined by sigma(sub sp)(RH) = k.(1 - RH/100)(sup gamma), was used with the hygroscopic exponent gamma derived from the data. The following gamma values were obtained for the 3 aerosol types: gamma(dust) = 0.23 +/- 0.05, gamma(clean marine) = 0.69 +/- 0.06 and gamma(polluted marine) = 0.57 +/- 0.06. Based on the measured gammas, the above equation was utilized to derive aerosol models with different hygroscopicities. The satellite simulation signal code 6S was used to compute the upwelling radiance corresponding to each of those aerosol models at several ambient humidities. For the prelaunch estimated precision of the sensors and the assumed viewing geometry of the instrument, the simulations suggest that the spectral and angular dependence of the reflectance measured by MISR is not sufficient to distinguish aerosol models with various different combinations of values for dry composition, gamma and ambient RH. A similar behavior is observed for MODIS at visible wavelengths. However, the 2100 nm band of MODIS appears to be able to differentiate between at least same aerosol models with different aerosol hygroscopicity given the MODIS calibration error requirements. This result suggests the possibility of retrieval of aerosol hygroscopicity by MODIS.

Gasso, S.↗

Tuning and Robustness Analysis for the Orion Absolute Navigation System

The Orion Multi-Purpose Crew Vehicle (MPCV) is currently under development as NASA's next-generation spacecraft for exploration missions beyond Low Earth Orbit. The MPCV is set to perform an orbital test flight, termed Exploration Flight Test 1 (EFT-1), some time in late 2014. The navigation system for the Orion spacecraft is being designed in a Multi-Organizational Design Environment (MODE) team including contractor and NASA personnel. The system uses an Extended Kalman Filter to process measurements and determine the state. The design of the navigation system has undergone several iterations and modifications since its inception, and continues as a work-in-progress. This paper seeks to show the efforts made to-date in tuning the filter for the EFT-1 mission and instilling appropriate robustness into the system to meet the requirements of manned space ight. Filter performance is affected by many factors: data rates, sensor measurement errors, tuning, and others. This paper focuses mainly on the error characterization and tuning portion. Traditional efforts at tuning a navigation filter have centered around the observation/measurement noise and Gaussian process noise of the Extended Kalman Filter. While the Orion MODE team must certainly address those factors, the team is also looking at residual edit thresholds and measurement underweighting as tuning tools. Tuning analysis is presented with open loop Monte-Carlo simulation results showing statistical errors bounded by the 3-sigma filter uncertainty covariance. The Orion filter design uses 24 Exponentially Correlated Random Variable (ECRV) parameters to estimate the accel/gyro misalignment and nonorthogonality. By design, the time constant and noise terms of these ECRV parameters were set to manufacturer specifications and not used as tuning parameters. They are included in the filter as a more analytically correct method of modeling uncertainties than ad-hoc tuning of the process noise. Tuning is explored for the powered-flight ascent phase, where measurements are scarce and unmodelled vehicle accelerations dominate. On orbit, there are important trade-off cases between process and measurement noise. On entry, there are considerations about trading performance accuracy for robustness. Process Noise is divided into powered flight and coasting ight and can be adjusted for each phase and mode of the Orion EFT-1 mission. Measurement noise is used for the integrated velocity measurements during pad alignment. It is also used for Global Positioning System (GPS) pseudorange and delta- range measurements during the rest of the flight. The robustness effort has been focused on maintaining filter convergence and performance in the presence of unmodeled error sources. These include unmodeled forces on the vehicle and uncorrected errors on the sensor measurements. Orion uses a single-frequency, non-keyed GPS receiver, so the effects due to signal distortion in Earth's ionosphere and troposphere are present in the raw measurements. Results are presented showing the efforts to compensate for these errors as well as characterize the residual effect for measurement noise tuning. Another robustness tool in use is tuning the residual edit thresholds. The trade-off between noise tuning and edit thresholds is explored in the context of robustness to errors in dynamics models and sensor measurements. Measurement underweighting is also presented as a method of additional robustness when processing highly accurate measurements in the presence of large filter uncertainties.

Holt, Greg N.↗

Constraining the Climate and Ocean PH of the Early Earth with a Geological Carbon Cycle Model

The early Earth's environment is controversial. Climatic estimates range from hot to glacial, and inferred marine pH spans strongly alkaline to acidic. Better understanding of early climate and ocean chemistry would improve our knowledge of the origin of life and its coevolution with the environment. Here, we use a geological carbon cycle model with ocean chemistry to calculate self-consistent histories of climate and ocean pH. Our carbon cycle model includes an empirically justified temperature and pH dependence of seafloor weathering, allowing the relative importance of continental and seafloor weathering to be evaluated. We find that the Archean climate was likely temperate (0-50deg C) due to the combined negative feedbacks of continental and seafloor weathering. Ocean pH evolves monotonically from 6.6(sup + 0.6) (sub -0.4) (2 sigma) at 4.0 Ga to 7.0(sup +0.7) (sub-0.5) (2 sigma) at the Archean-Proterozoic boundary, and to 7.9(sup +0.1) (sub -0.2) (2 sigma) at the Proterozoic-Phanerozoic boundary. This evolution is driven by the secular decline of pCO2, which in turn is a consequence of increasing solar luminosity, but is moderated by carbonate alkalinity delivered from continental and seafloor weathering. Archean seafloor weathering may have been a comparable carbon sink to continental weathering, but is less dominant than previously assumed, and would not have induced global glaciation. We show how these conclusions are robust to a wide range of scenarios for continental growth, internal heat flow evolution and outgassing history, greenhouse gas abundances, and changes in the biotic enhancement of weathering.

Krissansen-Totton, Joshua↗

Lunar-surface UV Photometric Investigation of Exospheres (LUPINE): Thermal Modeling of Payload in a Relevant Daylit Environment

Direct upward remote sensing of the moon’s exosphere from a surface vantage can address production of water-related lunar volatiles as well as their exospheric loss, ballistic transport, and ultimate adsorption in permanently shadowed regions (PSRs). Far UV (FUV) dayside measurements of atomic oxygen, liberated from regolith by energetic solar protons and micrometeorite impact, can provide critical insight into the endogenic lunar water cycle by constraining total column density [O] at site of production. A notional Lunar-surface UV Photometric Investigation of Exospheres (LUPINE) instrument is designed to exploit solar-pumped atomic oxygen fluorescence at 130.4-nm, in a manner similar to the Apollo 17 UV Spectrometer (UVS) experiment [Fastie 1973; Feldman and Morrison, 1991] and the LRO Lyman-alpha Mapping Project (LAMP) spectrograph [Cook et al., 2013], by implementing a zenith-directed FUV photometer from the lunar surface at low (± 10°) selenographic latitude during the lunar day. Atomic oxygen production from solar energetic particle impact sources is thought to maximize in near solar noon [Sarantos et al., 2012], and the lander-embedded zenith-directed LUPINE photometer, in contrast to UVS and LAMP twilight measurements from orbit, can potentially capture the full column abundance of lunar regolith liberated oxygen. Herein we describe adaptation of FUV reflective optics, pulse-counting electronics, and scattered-light-suppression technologies developed for LEO FUV photometry for the challenging thermal environment of the daylit lunar surface. Preliminary thermal modeling and TVAC measurements of heritage FUV photometer components suggests that, if allowed to shed ~8W of waste heat into the bus of a reference Commercial Lunar Payload Services (CLPS) lander, the LUPINE photometer will be kept sufficiently cool to limit dark current to less than 20 counts/s. This level of dark signal enables an OI 130.4-nm 3-sigma detection threshold of ~1 mR for assumed 2-hour integrations.

Lunar UV Photometer↗

Influence of Humidity on the Aerosol Scattering Coefficient and Its Effect on the Upwelling Radiance During ACE-2

Aerosol scattering coefficients (sigma(sub sp)) have been measured over the ocean at different relative humidities (RH) as a function of attitude in the region surrounding the Canary Islands during the Second Aerosol Characterization Experiment (ACE-2) in June and July 1997. The data were collected by the University of Washington passive humidigraph (UWPH) mounted on the Pelican research aircraft. Concurrently, particle size distributions absorption coefficients and aerosol optical depth were measured throughout 17 flights. A parameterization of sigma(sub sp) as a function of RH was utilized to assess the impact of aerosol hydration on the upwelling radiance (normalized to the solar constant and cosine of zenith angle). The top of the atmosphere radiance signal was simulated at wavelengths corresponding to visible and near-infrared bands or the EOS-AM ("Terra") detectors, MODIS and MISR. The UWPH measured (sigma(sub sp)) at 2 RHs, one below and the other above ambient conditions. Ambient (sigma(sub sp)) was obtained by interpolation of these 2 measurements. The data were stratified in terms of 3 types of aerosols: Saharan dust, clean marine (marine boundary layer background) and polluted marine aerosols (i.e., 2- or 1-day old polluted aerosols advected from Europe). An empirical relation for the dependence of (sigma(sub sp)) on RH, defined by (sigma(sub sp))(RH) = k. ((1 - RH/100)(exp -gamma), was used with the hygroscopic exponent gamma derived from the data. The following gamma values were obtained for the 3 aerosol types: gamma(dust) = 0.23 +/- 0.05, gamma(clean marine) = 0.69 +/- 0.06 and gamma(polluted marine) = 0.57 + 0.06. Based on the measured (gamma)(s), the above equation was utilized to derive aerosol models with different hygroscopicities. The satellite simulation signal code 6S was used to compute the upwelling radiance corresponding to each of those aerosol models at several ambient humidities. For the pre-launch estimated precision of the sensors and the assumed viewing geometry of the instrument, the simulations suggest that the spectral and angular dependence of the reflectance measured by MISR is not sufficient to distinguish aerosol models with various different combinations of values ror dry composition. y and ambient RH. A similar behavior is observed for MODIS at visible wavelengths. However, the 2100 nm band of MODIS appears to be able to differentiate between at least some aerosol models with different aerosol hygroscopicity given the MODIS calibration error requirements. This result suggests the possibility of retrieval of aerosol hygroscopicity by MODIS.

Gasso, B. S.↗